CN1007991B - 用含铝硅磷酸盐分子筛催化剂的加氢裂化法 - Google Patents
用含铝硅磷酸盐分子筛催化剂的加氢裂化法Info
- Publication number
- CN1007991B CN1007991B CN 85109634 CN85109634A CN1007991B CN 1007991 B CN1007991 B CN 1007991B CN 85109634 CN85109634 CN 85109634 CN 85109634 A CN85109634 A CN 85109634A CN 1007991 B CN1007991 B CN 1007991B
- Authority
- CN
- China
- Prior art keywords
- sapo
- catalyst
- weight
- zeolite
- hydrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002808 molecular sieve Substances 0.000 title claims description 22
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 title claims description 22
- 238000007327 hydrogenolysis reaction Methods 0.000 title abstract description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 8
- 239000001301 oxygen Substances 0.000 claims abstract description 8
- 238000010521 absorption reaction Methods 0.000 claims abstract description 6
- 239000003054 catalyst Substances 0.000 claims description 153
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical group O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 78
- 238000004517 catalytic hydrocracking Methods 0.000 claims description 75
- 238000000034 method Methods 0.000 claims description 73
- 239000010457 zeolite Substances 0.000 claims description 67
- 229910021536 Zeolite Inorganic materials 0.000 claims description 64
- 241000269350 Anura Species 0.000 claims description 59
- 239000000203 mixture Substances 0.000 claims description 44
- 238000009835 boiling Methods 0.000 claims description 28
- 229930195733 hydrocarbon Natural products 0.000 claims description 27
- 150000002430 hydrocarbons Chemical class 0.000 claims description 27
- 239000001257 hydrogen Substances 0.000 claims description 26
- 229910052739 hydrogen Inorganic materials 0.000 claims description 26
- 238000006243 chemical reaction Methods 0.000 claims description 25
- 239000004215 Carbon black (E152) Substances 0.000 claims description 24
- 238000005984 hydrogenation reaction Methods 0.000 claims description 24
- 239000000463 material Substances 0.000 claims description 24
- 239000010779 crude oil Substances 0.000 claims description 23
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 21
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- 239000003208 petroleum Substances 0.000 claims description 19
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 18
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims description 18
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 14
- 239000007789 gas Substances 0.000 claims description 12
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- 239000011159 matrix material Substances 0.000 claims description 10
- 230000008569 process Effects 0.000 claims description 10
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 9
- 229910052809 inorganic oxide Inorganic materials 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 9
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
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- 238000012545 processing Methods 0.000 claims description 5
- 229910052703 rhodium Inorganic materials 0.000 claims description 5
- 229910052719 titanium Inorganic materials 0.000 claims description 5
- 239000010936 titanium Substances 0.000 claims description 5
- 229910052721 tungsten Inorganic materials 0.000 claims description 5
- 229910052750 molybdenum Inorganic materials 0.000 claims description 4
- 102000040350 B family Human genes 0.000 claims description 3
- 108091072128 B family Proteins 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000003245 coal Substances 0.000 claims description 3
- 238000006477 desulfuration reaction Methods 0.000 claims description 3
- 230000023556 desulfurization Effects 0.000 claims description 3
- 229910052763 palladium Inorganic materials 0.000 claims description 3
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 3
- 229910052684 Cerium Inorganic materials 0.000 claims description 2
- 229910052692 Dysprosium Inorganic materials 0.000 claims description 2
- 229910052691 Erbium Inorganic materials 0.000 claims description 2
- 229910052693 Europium Inorganic materials 0.000 claims description 2
- 229910052688 Gadolinium Inorganic materials 0.000 claims description 2
- 229910052689 Holmium Inorganic materials 0.000 claims description 2
- 229910052765 Lutetium Inorganic materials 0.000 claims description 2
- 229910052779 Neodymium Inorganic materials 0.000 claims description 2
- 229910052777 Praseodymium Inorganic materials 0.000 claims description 2
- 229910052772 Samarium Inorganic materials 0.000 claims description 2
- 229910052771 Terbium Inorganic materials 0.000 claims description 2
- 229910052775 Thulium Inorganic materials 0.000 claims description 2
- 229910052769 Ytterbium Inorganic materials 0.000 claims description 2
- YIFVJYNWLCNYGB-UHFFFAOYSA-N [Si]=O.[Zr] Chemical compound [Si]=O.[Zr] YIFVJYNWLCNYGB-UHFFFAOYSA-N 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- DCRIQAAPAFMPKP-UHFFFAOYSA-N aluminum oxygen(2-) titanium(4+) Chemical compound [O-2].[O-2].[Al+3].[Ti+4] DCRIQAAPAFMPKP-UHFFFAOYSA-N 0.000 claims description 2
- 125000002091 cationic group Chemical group 0.000 claims description 2
- 150000001768 cations Chemical class 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- 230000006837 decompression Effects 0.000 claims description 2
- 229910052746 lanthanum Inorganic materials 0.000 claims description 2
- OTUXRAAQAFDEQT-UHFFFAOYSA-N magnesium oxosilicon(2+) oxygen(2-) Chemical compound [O-2].[Mg+2].[Si+2]=O.[O-2] OTUXRAAQAFDEQT-UHFFFAOYSA-N 0.000 claims description 2
- 229910052697 platinum Inorganic materials 0.000 claims description 2
- 150000002431 hydrogen Chemical class 0.000 claims 5
- 229910052707 ruthenium Inorganic materials 0.000 claims 4
- FDTUSPNGYPXVIO-UHFFFAOYSA-N [B+]=O.[O-2].[Al+3].[O-2] Chemical compound [B+]=O.[O-2].[Al+3].[O-2] FDTUSPNGYPXVIO-UHFFFAOYSA-N 0.000 claims 1
- 230000000274 adsorptive effect Effects 0.000 claims 1
- 239000004927 clay Substances 0.000 claims 1
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- 230000009466 transformation Effects 0.000 description 23
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 22
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 14
- 238000002360 preparation method Methods 0.000 description 13
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 9
- -1 offretite Inorganic materials 0.000 description 9
- 125000004432 carbon atom Chemical group C* 0.000 description 8
- 238000005342 ion exchange Methods 0.000 description 8
- 239000005864 Sulphur Substances 0.000 description 7
- 229910052782 aluminium Inorganic materials 0.000 description 7
- 239000010953 base metal Substances 0.000 description 7
- 238000001354 calcination Methods 0.000 description 7
- 238000009826 distribution Methods 0.000 description 7
- 229910052757 nitrogen Inorganic materials 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- AFABGHUZZDYHJO-UHFFFAOYSA-N 2-Methylpentane Chemical compound CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 238000010586 diagram Methods 0.000 description 6
- 238000007598 dipping method Methods 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 5
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 5
- 239000004411 aluminium Substances 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 5
- 125000003118 aryl group Chemical group 0.000 description 5
- 230000003197 catalytic effect Effects 0.000 description 5
- 238000012512 characterization method Methods 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
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- 239000012188 paraffin wax Substances 0.000 description 5
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- PFEOZHBOMNWTJB-UHFFFAOYSA-N 3-methylpentane Chemical compound CCC(C)CC PFEOZHBOMNWTJB-UHFFFAOYSA-N 0.000 description 4
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- 238000002474 experimental method Methods 0.000 description 4
- 239000001282 iso-butane Substances 0.000 description 4
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 4
- 150000004706 metal oxides Chemical class 0.000 description 4
- 239000010970 precious metal Substances 0.000 description 4
- 229910052761 rare earth metal Inorganic materials 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
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- 238000011160 research Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical compound CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 description 2
- HDGQICNBXPAKLR-UHFFFAOYSA-N 2,4-dimethylhexane Chemical compound CCC(C)CC(C)C HDGQICNBXPAKLR-UHFFFAOYSA-N 0.000 description 2
- KBPCCVWUMVGXGF-UHFFFAOYSA-N 2,6-dimethylheptane Chemical compound CC(C)CCCC(C)C KBPCCVWUMVGXGF-UHFFFAOYSA-N 0.000 description 2
- JVSWJIKNEAIKJW-UHFFFAOYSA-N 2-Methylheptane Chemical compound CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 2
- GXDHCNNESPLIKD-UHFFFAOYSA-N 2-methylhexane Chemical compound CCCCC(C)C GXDHCNNESPLIKD-UHFFFAOYSA-N 0.000 description 2
- RNTWWGNZUXGTAX-UHFFFAOYSA-N 3,4-dimethylhexane Chemical compound CCC(C)C(C)CC RNTWWGNZUXGTAX-UHFFFAOYSA-N 0.000 description 2
- LAIUFBWHERIJIH-UHFFFAOYSA-N 3-Methylheptane Chemical compound CCCCC(C)CC LAIUFBWHERIJIH-UHFFFAOYSA-N 0.000 description 2
- VLJXXKKOSFGPHI-UHFFFAOYSA-N 3-methylhexane Chemical compound CCCC(C)CC VLJXXKKOSFGPHI-UHFFFAOYSA-N 0.000 description 2
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- DOGIHOCMZJUJNR-UHFFFAOYSA-N 4-methyloctane Chemical compound CCCCC(C)CCC DOGIHOCMZJUJNR-UHFFFAOYSA-N 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical group C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 description 2
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- WGECXQBGLLYSFP-UHFFFAOYSA-N (+-)-2,3-dimethyl-pentane Natural products CCC(C)C(C)C WGECXQBGLLYSFP-UHFFFAOYSA-N 0.000 description 1
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Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/76—Iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/82—Phosphates
- B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
- B01J29/85—Silicoaluminophosphates [SAPO compounds]
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
- C10G47/12—Inorganic carriers
- C10G47/16—Crystalline alumino-silicate carriers
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US68294684A | 1984-12-18 | 1984-12-18 | |
US682,946 | 1984-12-18 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN85109634A CN85109634A (zh) | 1986-06-10 |
CN1007991B true CN1007991B (zh) | 1990-05-16 |
Family
ID=24741900
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN 85109634 Expired CN1007991B (zh) | 1984-12-18 | 1985-12-17 | 用含铝硅磷酸盐分子筛催化剂的加氢裂化法 |
CN 89100867 Pending CN1034679A (zh) | 1984-12-18 | 1989-02-16 | 含铝硅磷酸盐分子筛的催化剂 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN 89100867 Pending CN1034679A (zh) | 1984-12-18 | 1989-02-16 | 含铝硅磷酸盐分子筛的催化剂 |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0207133A1 (fr) |
JP (1) | JPS62501426A (fr) |
CN (2) | CN1007991B (fr) |
AU (1) | AU5307686A (fr) |
FI (1) | FI863335A0 (fr) |
WO (1) | WO1986003694A1 (fr) |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4724066A (en) * | 1985-01-22 | 1988-02-09 | Mobil Oil Corporation | Composites of microporous aluminum phosphates and zeolites and conversions over these catalysts |
US4741820A (en) * | 1986-03-27 | 1988-05-03 | Union Carbide Corporation | Reforming/dehydrocyclization catalysts and processes |
US4695368A (en) * | 1986-07-31 | 1987-09-22 | Union Oil Company Of California | Process for producing high octane gasoline |
US4859312A (en) * | 1987-01-12 | 1989-08-22 | Chevron Research Company | Process for making middle distillates using a silicoaluminophosphate molecular sieve |
US5139647A (en) * | 1989-08-14 | 1992-08-18 | Chevron Research And Technology Company | Process for preparing low pour middle distillates and lube oil using a catalyst containing a silicoaluminophosphate molecular sieve |
RU2082748C1 (ru) * | 1993-09-29 | 1997-06-27 | Институт катализа им.Г.К.Борескова СО РАН | Способ получения жидких моторных топлив |
CN1048429C (zh) * | 1994-02-05 | 2000-01-19 | 中国科学院大连化学物理研究所 | 以双模板剂合成磷酸硅铝分子筛的方法 |
RO114524B1 (ro) | 1997-10-02 | 1999-05-28 | Sc Zecasin Sa | Procedeu de fabricare a oleofinelor cu greutate moleculara mica prin conversia catalitica in strat fluidizat a metanolului |
CN1122637C (zh) * | 2001-08-29 | 2003-10-01 | 复旦大学 | 一种浓胺体系合成新型磷酸铍分子筛的方法 |
CN100448536C (zh) * | 2005-06-27 | 2009-01-07 | 中国科学院大连化学物理研究所 | 一种临氢异构化催化剂及其制备方法 |
CN101757929B (zh) * | 2008-12-24 | 2012-01-25 | 中国石油化工股份有限公司 | 一种加氢裂化催化剂及其制备方法 |
EP2526169A2 (fr) | 2010-01-21 | 2012-11-28 | Shell Oil Company | Procédé de craquage d'une charge contenant des hydrocarbures |
WO2011091206A2 (fr) * | 2010-01-21 | 2011-07-28 | Shell Oil Company | Composition d'hydrocarbures |
SG181824A1 (en) | 2010-01-21 | 2012-07-30 | Shell Int Research | Process for treating a hydrocarbon-containing feed |
SG182264A1 (en) * | 2010-01-21 | 2012-08-30 | Shell Int Research | Hydrocarbon composition |
SG181794A1 (en) * | 2010-01-21 | 2012-07-30 | Shell Int Research | Hydrocarbon composition |
CN109806907A (zh) * | 2017-11-20 | 2019-05-28 | 中国石油天然气股份有限公司 | 负载型Pt/TiO2/ZSM-5分子筛催化剂及其制备方法与应用 |
CN108851966A (zh) * | 2018-04-24 | 2018-11-23 | 浙江绍兴苏泊尔生活电器有限公司 | 一种电压力锅及烹饪方法 |
JP7182004B2 (ja) * | 2018-12-13 | 2022-12-01 | 中国石油化工股▲ふん▼有限公司 | 水素化分解触媒、その製造方法及び使用 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1506429A (en) * | 1975-05-13 | 1978-04-05 | Union Carbide Corp | Catalyst for hydrocarbon processes and process for preparing same |
US4440871A (en) * | 1982-07-26 | 1984-04-03 | Union Carbide Corporation | Crystalline silicoaluminophosphates |
IT1157983B (it) * | 1982-12-23 | 1987-02-18 | Fiat Auto Spa | Dispositivo cinematico per il comando di una valvola di un motore endotermico |
US4512875A (en) * | 1983-05-02 | 1985-04-23 | Union Carbide Corporation | Cracking of crude oils with carbon-hydrogen fragmentation compounds over non-zeolitic catalysts |
EP0124120B1 (fr) * | 1983-05-02 | 1987-06-16 | Union Carbide Corporation | Catalyseur d'hydrocraquage et procédé d'hydrocraquage |
-
1985
- 1985-12-17 AU AU53076/86A patent/AU5307686A/en not_active Abandoned
- 1985-12-17 CN CN 85109634 patent/CN1007991B/zh not_active Expired
- 1985-12-17 WO PCT/US1985/002476 patent/WO1986003694A1/fr not_active Application Discontinuation
- 1985-12-17 JP JP50030185A patent/JPS62501426A/ja active Pending
- 1985-12-17 EP EP19860900501 patent/EP0207133A1/fr not_active Withdrawn
-
1986
- 1986-08-18 FI FI863335A patent/FI863335A0/fi not_active Application Discontinuation
-
1989
- 1989-02-16 CN CN 89100867 patent/CN1034679A/zh active Pending
Also Published As
Publication number | Publication date |
---|---|
JPS62501426A (ja) | 1987-06-11 |
EP0207133A1 (fr) | 1987-01-07 |
FI863335A (fi) | 1986-08-18 |
AU5307686A (en) | 1986-07-22 |
CN1034679A (zh) | 1989-08-16 |
FI863335A0 (fi) | 1986-08-18 |
CN85109634A (zh) | 1986-06-10 |
WO1986003694A1 (fr) | 1986-07-03 |
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