CN100554287C - 烯烃聚合用催化剂组分 - Google Patents

烯烃聚合用催化剂组分 Download PDF

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Publication number
CN100554287C
CN100554287C CNB2003801061943A CN200380106194A CN100554287C CN 100554287 C CN100554287 C CN 100554287C CN B2003801061943 A CNB2003801061943 A CN B2003801061943A CN 200380106194 A CN200380106194 A CN 200380106194A CN 100554287 C CN100554287 C CN 100554287C
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China
Prior art keywords
catalyst component
solid catalyst
compound
electron donor
catalyst
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Expired - Lifetime
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CNB2003801061943A
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English (en)
Chinese (zh)
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CN1726230A (zh
Inventor
D·布里塔
G·科利纳
G·莫里尼
G·瓦伊塔尔
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Basell Poliolefine Italia SRL
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Basell Poliolefine Italia SRL
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CNB2003801061943A 2002-12-18 2003-11-25 烯烃聚合用催化剂组分 Expired - Lifetime CN100554287C (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP02080616 2002-12-18
EP02080616.2 2002-12-18
US60/435,195 2002-12-20

Publications (2)

Publication Number Publication Date
CN1726230A CN1726230A (zh) 2006-01-25
CN100554287C true CN100554287C (zh) 2009-10-28

Family

ID=35925132

Family Applications (2)

Application Number Title Priority Date Filing Date
CNB2003801061943A Expired - Lifetime CN100554287C (zh) 2002-12-18 2003-11-25 烯烃聚合用催化剂组分
CNA200380106191XA Pending CN1726080A (zh) 2002-12-18 2003-11-25 氯化镁基加合物及由其制备的催化剂组分

Family Applications After (1)

Application Number Title Priority Date Filing Date
CNA200380106191XA Pending CN1726080A (zh) 2002-12-18 2003-11-25 氯化镁基加合物及由其制备的催化剂组分

Country Status (16)

Country Link
US (1) US7427653B2 (enExample)
EP (1) EP1572756B1 (enExample)
JP (2) JP2006510751A (enExample)
KR (1) KR101102793B1 (enExample)
CN (2) CN100554287C (enExample)
AR (1) AR042496A1 (enExample)
AU (1) AU2003292199A1 (enExample)
BR (1) BR0316913B1 (enExample)
CA (1) CA2510679C (enExample)
ES (2) ES2420879T3 (enExample)
MX (1) MXPA05006584A (enExample)
RU (1) RU2322457C2 (enExample)
SA (1) SA03240450B1 (enExample)
TW (1) TW200417554A (enExample)
WO (1) WO2004055065A1 (enExample)
ZA (2) ZA200504127B (enExample)

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AU2004242899A1 (en) * 2003-05-29 2004-12-09 Basell Poliolefine Italia S.R.L Process for the preparation of a catalyst component and components therefrom obtained
EP1780225A1 (en) 2005-11-01 2007-05-02 Borealis Technology Oy Ziegler-Natta catalyst and its use to prepare multimodal polyolefin
SG189559A1 (en) * 2006-04-06 2013-05-31 China Petroleum & Chemical Magnesium halide complexes, catalyst components and catalysts for olefin polymerization prepared therefrom
CN101165074B (zh) * 2006-10-20 2010-12-22 中国石油化工股份有限公司 用于烯烃聚合的催化剂组分及其催化剂
CN101486776B (zh) * 2008-01-17 2010-12-22 中国石油化工股份有限公司 用于烯烃聚合的催化剂组分及其催化剂
JP5140764B2 (ja) 2008-09-26 2013-02-13 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ オレフィン重合用の触媒成分
RU2567391C2 (ru) 2009-08-21 2015-11-10 Чайна Петролеум Энд Кемикал Корпорейшн Компонент катализатора для полимеризации этилена, приготовление такового и катализатор, включающий компонент катализатора
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CA2805769C (en) 2010-08-24 2017-11-21 Basell Poliolefine Italia S.R.L. Catalyst components for the polymerization of olefins
US10138310B2 (en) * 2010-08-24 2018-11-27 Equistar Chemicals, Lp Preparation of LLDPE resins and films having low gels
US20120053305A1 (en) * 2010-08-24 2012-03-01 Equistar Chemicals, Lp Preparation of LLDPE having controlled xylene solubles or hexane extractables
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US8940653B2 (en) * 2010-09-30 2015-01-27 Basell Poliolefine Italia S.R.L. Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom
CN102585056A (zh) * 2011-01-05 2012-07-18 中国石油化工股份有限公司 一种用于乙烯聚合或共聚合反应的催化剂
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EP2712875A1 (en) * 2012-09-28 2014-04-02 Basell Poliolefine Italia S.r.l. Catalyst components for the polymerization of olefins
CN103788246B (zh) * 2012-10-29 2015-10-21 中国石油化工股份有限公司 一种烯烃聚合催化剂载体及其制备方法和应用
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CN104231140B (zh) * 2013-06-21 2016-12-07 中国石油天然气集团公司 一种乙烯-α-烯烃共聚催化剂及其制备和应用
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FR3023183A1 (fr) * 2014-07-04 2016-01-08 IFP Energies Nouvelles Composition catalytique et procede de dimerisation selective de l'ethylene en butene-1
KR102542653B1 (ko) * 2014-12-18 2023-06-09 보레알리스 아게 지글러-나타 촉매 및 이의 제조
CN112979842B (zh) 2015-02-05 2022-11-11 博里利斯股份公司 用于生产聚乙烯的方法
EP3347385B1 (en) * 2015-09-11 2020-02-19 Basell Poliolefine Italia S.r.l. Process for the preparation of catalyst components for the polymerization of olefins
WO2018011086A1 (en) * 2016-07-15 2018-01-18 Basell Poliolefine Italia S.R.L. Catalyst for the polymerization of olefins
WO2018114453A1 (en) * 2016-12-19 2018-06-28 Basell Poliolefine Italia S.R.L. Catalyst components for the polymerization of olefins and catalysts therefrom obtained
EP3339333B1 (en) 2016-12-22 2020-10-07 Borealis AG Ziegler-natta catalyst and preparation thereof
WO2019015638A1 (zh) 2017-07-19 2019-01-24 中国石油化工股份有限公司 包含环三藜芦烃及其衍生物的烯烃聚合催化剂
JP7304348B2 (ja) * 2017-12-05 2023-07-06 ユニベーション・テクノロジーズ・エルエルシー 活性化噴霧乾燥チーグラー・ナッタ触媒系
SG11202004922SA (en) 2017-12-05 2020-06-29 Univation Tech Llc Modified spray-dried ziegler-natta (pro)catalyst systems
US11447580B2 (en) 2017-12-27 2022-09-20 Borealis Ag Ziegler-Natta catalyst and preparation thereof
KR20200095577A (ko) 2017-12-28 2020-08-10 보레알리스 아게 촉매 및 이의 제조
SG11202011226XA (en) * 2018-06-01 2020-12-30 Dow Global Technologies Llc Ziegler-natta catalyst system having a thermally treated magnesium chloride component
US12398225B2 (en) 2019-10-04 2025-08-26 Borealis Ag Ziegler-Natta catalysts for olefin polymerization
CN114585654B (zh) 2019-10-04 2023-11-07 北欧化工公司 用于烯烃聚合的齐格勒-纳塔催化剂
US12338311B2 (en) 2019-10-04 2025-06-24 Borealis Ag Ziegler-Natta catalysts for olefin polymerization
WO2021064080A1 (en) 2019-10-04 2021-04-08 Borealis Ag Ziegler-natta catalysts for olefin polymerization
CN112812205B (zh) * 2019-11-18 2023-05-09 中国石油化工股份有限公司 一种用于烯烃聚合反应的催化剂组分及其催化剂和其制法及应用
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EP4234590A4 (en) * 2020-10-26 2024-10-09 China Petroleum & Chemical Corporation SOLID COMPONENT FOR PRODUCING AN OLEFIN POLYMERIZATION CATALYST AND PRODUCTION METHOD THEREFOR AND APPLICATION THEREOF

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US4829034A (en) * 1986-06-09 1989-05-09 Neste Oy Procedure for manufacturing catalyst components for polymerizing olefines
CN1034371A (zh) * 1986-07-21 1989-08-02 三井石油化学工株式会社 丙烯共聚物的制备方法
US5324698A (en) * 1989-09-06 1994-06-28 Neste Oy New carrier catalyst for the polymerization of ethylene
EP0661301A1 (en) * 1993-12-17 1995-07-05 Union Carbide Chemicals & Plastics Technology Corporation Process for producing ethylene polymers having reduced hexane extractable content

Also Published As

Publication number Publication date
EP1572756B1 (en) 2013-04-10
RU2322457C2 (ru) 2008-04-20
KR101102793B1 (ko) 2012-01-05
AR042496A1 (es) 2005-06-22
WO2004055065A1 (en) 2004-07-01
ZA200504131B (en) 2006-02-22
CA2510679A1 (en) 2004-07-01
MXPA05006584A (es) 2005-08-16
JP2006510751A (ja) 2006-03-30
CA2510679C (en) 2013-04-23
BR0316913A (pt) 2005-10-18
ES2368425T3 (es) 2011-11-17
CN1726080A (zh) 2006-01-25
KR20050084415A (ko) 2005-08-26
SA03240450B1 (ar) 2009-01-19
CN1726230A (zh) 2006-01-25
JP5366898B2 (ja) 2013-12-11
RU2005122489A (ru) 2006-01-20
EP1572756A1 (en) 2005-09-14
AU2003292199A1 (en) 2004-07-09
JP2010280894A (ja) 2010-12-16
US20060089251A1 (en) 2006-04-27
ZA200504127B (en) 2006-02-22
ES2420879T3 (es) 2013-08-27
BR0316913B1 (pt) 2014-09-09
US7427653B2 (en) 2008-09-23
TW200417554A (en) 2004-09-16

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Granted publication date: 20091028