CN100486705C - 用于生产轻烯烃的固体酸催化剂及其使用方法 - Google Patents

用于生产轻烯烃的固体酸催化剂及其使用方法 Download PDF

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CN100486705C
CN100486705C CNB2005800341217A CN200580034121A CN100486705C CN 100486705 C CN100486705 C CN 100486705C CN B2005800341217 A CNB2005800341217 A CN B2005800341217A CN 200580034121 A CN200580034121 A CN 200580034121A CN 100486705 C CN100486705 C CN 100486705C
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reaction
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CN101035619A (zh
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崔烍
朴德守
金奭俊
崔安燮
金希永
朴容起
李哲伟
崔源春
韩尚润
金廷悧
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Korea Research Institute of Chemical Technology KRICT
SK Innovation Co Ltd
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SK CORP
Korea Research Institute of Chemical Technology KRICT
SK Energy Co Ltd
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
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    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
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    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
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    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
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    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
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    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
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    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
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    • B01J29/00—Catalysts comprising molecular sieves
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    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
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    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
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    • C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
    • C07C4/06—Catalytic processes
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    • B01J2235/15—X-ray diffraction
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10G2300/1044—Heavy gasoline or naphtha having a boiling range of about 100 - 180 °C
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    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
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    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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  • Chemical & Material Sciences (AREA)
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  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Physics & Mathematics (AREA)
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  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
CNB2005800341217A 2004-09-10 2005-08-30 用于生产轻烯烃的固体酸催化剂及其使用方法 Expired - Lifetime CN100486705C (zh)

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KR1020040072644A KR100632563B1 (ko) 2004-09-10 2004-09-10 접촉 분해용 고체산 촉매 및 이를 이용하여 전범위납사로부터 경질 올레핀을 선택적으로 제조하는 공정
KR1020040072644 2004-09-10

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US (2) US7601663B2 (enExample)
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Families Citing this family (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100651329B1 (ko) * 2005-10-07 2006-11-30 에스케이 주식회사 탄화수소 원료로부터 경질 올레핀을 제조하는 공정
FR2905122B1 (fr) * 2006-08-24 2009-07-24 Inst Francais Du Petrole Procede de production de propylene en presence d'un catalyseur macroporeux se presentant sous forme de billes spheriques
JP4689576B2 (ja) * 2006-10-24 2011-05-25 財団法人石油産業活性化センター 炭化水素油の接触分解触媒及び該触媒を用いる炭化水素油の接触分解方法
JP4689577B2 (ja) * 2006-10-24 2011-05-25 財団法人石油産業活性化センター 炭化水素油の接触分解触媒及び該触媒を用いる炭化水素油の接触分解方法
CN101172238B (zh) * 2006-11-01 2010-04-14 中国石油化工股份有限公司 一种纳米固体超强酸及其制备方法
US20110098519A1 (en) * 2007-08-13 2011-04-28 Kanaparthi Ramesh Modified catalyst composition for conversion of alcohol to alkene
KR100904297B1 (ko) * 2007-10-26 2009-06-25 한국화학연구원 연속적인 2단계 촉매 반응을 이용한 합성가스로부터 경질올레핀의 제조방법
EP2082801A1 (en) 2008-01-25 2009-07-29 Total Petrochemicals Research Feluy Process for obtaining modified molecular sieves
KR100979580B1 (ko) * 2008-02-05 2010-09-01 에스케이에너지 주식회사 경질올레핀 생산용 탄화수소 접촉 분해 촉매 및 그제조방법
WO2010016338A1 (ja) * 2008-08-06 2010-02-11 旭化成ケミカルズ株式会社 ゼオライト含有触媒及びその製造方法並びにプロピレンの製造方法
CN101683621B (zh) * 2008-09-28 2012-01-25 中国石油化工股份有限公司 用于固定床催化裂解制低碳烯烃的催化剂
BRPI0805207B1 (pt) * 2008-11-25 2019-11-12 Petroleo Brasileiro Sa Petrobras processo de craqueamento catalítico de uma corrente de hidrocarbonetos para maximização de olefinas leves
CN103813856B (zh) 2011-07-21 2016-08-10 瑞来斯实业有限公司 流化床催化裂化（fcc）催化剂添加剂及其制备方法
CN103987457A (zh) 2011-10-17 2014-08-13 埃克森美孚研究工程公司 制备磷改性的沸石催化剂的方法
AU2012369895B2 (en) 2012-02-14 2015-11-12 Reliance Industries Ltd. A process for catalytic conversion of low value hydrocarbon streams to light olefins
JP6053366B2 (ja) 2012-07-26 2016-12-27 千代田化工建設株式会社 ゼオライト触媒、ゼオライト触媒の製造方法および低級オレフィンの製造方法
US10099210B2 (en) 2013-04-29 2018-10-16 Saudi Basic Industries Corporation Catalytic methods for converting naphtha into olefins
US9441167B2 (en) * 2013-12-19 2016-09-13 Basf Corporation Boron oxide in FCC processes
US9895680B2 (en) * 2013-12-19 2018-02-20 Basf Corporation FCC catalyst compositions containing boron oxide
KR101803406B1 (ko) 2014-08-01 2017-12-01 한국화학연구원 나프타와 메탄올 혼합 접촉분해 반응공정
JP6428423B2 (ja) * 2015-03-20 2018-11-28 三菱ケミカル株式会社 ゼオライト成形体
EP3095839A1 (en) * 2015-05-20 2016-11-23 Total Marketing Services Biodegradable hydrocarbon fluids by hydrogenation
US9981888B2 (en) 2016-06-23 2018-05-29 Saudi Arabian Oil Company Processes for high severity fluid catalytic cracking systems
ES2802257T3 (es) * 2016-12-13 2021-01-18 Smh Co Ltd Sistema catalítico y procedimiento para la conversión de una alimentación de hidrocarburos que comprende un compuesto de hidrocarburo saturado en productos olefínicos
US20180161743A1 (en) * 2016-12-14 2018-06-14 Exxonmobil Research And Engineering Company Method for oxygenate conversion in a fluid catalytic cracker
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JP7348716B2 (ja) * 2017-05-31 2023-09-21 古河電気工業株式会社 ナフサから生成されるオレフィン製造用触媒構造体、該触媒構造体を備えるオレフィン製造装置及びオレフィン製造用触媒構造体の製造方法
US10870802B2 (en) 2017-05-31 2020-12-22 Saudi Arabian Oil Company High-severity fluidized catalytic cracking systems and processes having partial catalyst recycle
US10889768B2 (en) 2018-01-25 2021-01-12 Saudi Arabian Oil Company High severity fluidized catalytic cracking systems and processes for producing olefins from petroleum feeds
WO2019226854A1 (en) * 2018-05-23 2019-11-28 Kellogg Brown & Root Llc Regulatory controller for usage in a catalytic olefins unit
KR102079063B1 (ko) 2018-06-20 2020-04-13 한국화학연구원 경질올레핀 제조용 촉매, 이의 제조방법, 및 이를 이용하여 경질올레핀을 제조하는 방법
JP7239100B2 (ja) * 2018-09-03 2023-03-14 Ｅｎｅｏｓ株式会社 炭素数６～８の単環芳香族炭化水素の製造方法
CN111822043B (zh) * 2019-04-23 2023-06-09 中国石油化工股份有限公司 多产乙烯的含硼催化裂解催化剂、其制备方法和应用方法
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US11332680B2 (en) 2020-09-01 2022-05-17 Saudi Arabian Oil Company Processes for producing petrochemical products that utilize fluid catalytic cracking of lesser and greater boiling point fractions with steam
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US11352575B2 (en) 2020-09-01 2022-06-07 Saudi Arabian Oil Company Processes for producing petrochemical products that utilize hydrotreating of cycle oil
US11242493B1 (en) 2020-09-01 2022-02-08 Saudi Arabian Oil Company Methods for processing crude oils to form light olefins
KR102602154B1 (ko) * 2021-08-03 2023-11-15 포항공과대학교 산학협력단 Pst-32 및 pst-2 제올라이트 촉매를 이용한 탄화수소 전환방법
KR102573887B1 (ko) 2021-09-10 2023-09-04 한국화학연구원 전기 가열로를 활용한 순환 유동층 반응기

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1031834A (zh) * 1987-08-08 1989-03-22 中国石油化工总公司石油化工科学研究院 制取低碳烯烃的烃类催化转化方法
CN1040609A (zh) * 1988-08-26 1990-03-21 国际壳牌研究有限公司 烃类进料的催化裂化方法
US5171921A (en) * 1991-04-26 1992-12-15 Arco Chemical Technology, L.P. Production of olefins
US6211104B1 (en) * 1997-10-15 2001-04-03 China Petrochemical Corporation Catalyst for catalytic pyrolysis process for the production of light olefins and the preparation thereof
US6342153B1 (en) * 1997-12-23 2002-01-29 China Petrochemical Corporation Pillared clay catalysts for heavy oil catalytic pyrolisis process and the preparation method thereof
WO2004072002A1 (ja) * 2003-02-14 2004-08-26 Mitsui Chemicals, Inc. 低級オレフィンの製造方法

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4176090A (en) 1975-11-18 1979-11-27 W. R. Grace & Co. Pillared interlayered clay materials useful as catalysts and sorbents
US4176096A (en) * 1976-07-22 1979-11-27 Pfd/Penn Color, Inc. Predispersed composition for use in thermosetting acrylic automotive finishes
US4248739A (en) 1979-09-04 1981-02-03 W. R. Grace & Co. Stabilized pillared interlayered clays
US4935573A (en) * 1987-09-02 1990-06-19 Mobil Oil Corporation Aromatization process and catalyst utilizing a mixture of shape-selective porous crystalline silicate zeolite and pillared layered metal oxide
DE68914552T2 (de) * 1988-09-06 1994-11-03 Petroleo Brasileiro Sa Kaolin enthaltender, fluidisierter Krackkatalysator.
US4977122A (en) * 1989-06-05 1990-12-11 Exxon Research And Engineering Company Cracking catalyst
US5110685A (en) * 1990-05-18 1992-05-05 Exxon Chemical Patents, Inc. Low friction, abrasion resistant polymer coating
CN1026225C (zh) 1991-02-28 1994-10-19 中国石油化工总公司石油化工科学研究院 一种稀土y分子筛的制备方法
CA2066501C (en) * 1991-04-22 1998-12-01 Kazuhiko Murata Thermoplastic elastomer laminates and glass run channels molded therefrom
US5374349A (en) 1991-09-11 1994-12-20 Union Oil Company Of California Hydrocracking process employing catalyst containing zeolite beta and a pillared clay
US5343655A (en) 1992-10-27 1994-09-06 Tokiwa Chemical Industries Co., Ltd. Weather strip for the window glass of an automobile
JPH06192135A (ja) 1992-12-25 1994-07-12 Asahi Chem Ind Co Ltd 軽質炭化水素の変換方法
JPH06199707A (ja) 1992-12-28 1994-07-19 Asahi Chem Ind Co Ltd 軽質炭化水素の接触分解方法
JPH0773893B2 (ja) * 1993-06-07 1995-08-09 トキワケミカル工業株式会社 自動車用ウエザストリツプの成形方法
CA2230332C (en) * 1997-02-21 2001-01-23 Mitsui Chemicals, Incorporated Glass run channel
JPH11561A (ja) * 1997-06-13 1999-01-06 Tonen Corp 重質油の接触分解用添加触媒
EP0920911A1 (en) * 1997-12-05 1999-06-09 Fina Research S.A. Production of catalysts for olefin conversion
EP1078025B1 (en) 1998-05-05 2003-03-26 ExxonMobil Chemical Patents Inc. Hydrocarbon conversion to propylene with high silica medium pore zeolite catalysts
US6294081B1 (en) 1998-05-26 2001-09-25 Exxonmobil Chemical Patents, Inc. Hydroprocessing with catalytic silicoaluminophosphates having an AEL structure
FR2794116B1 (fr) * 1999-05-11 2001-07-20 Inst Francais Du Petrole Zeolithe im-5 au phosphore, composition catalytique, sa preparation et son utilisation en craquage catalytique
US6835863B2 (en) 1999-07-12 2004-12-28 Exxonmobil Oil Corporation Catalytic production of light olefins from naphtha feed
US6222087B1 (en) 1999-07-12 2001-04-24 Mobil Oil Corporation Catalytic production of light olefins rich in propylene
EP1116775A1 (en) * 2000-01-12 2001-07-18 Akzo Nobel N.V. Catalyst composition with high efficiency for the production of light olefins
WO2001081280A1 (en) 2000-04-26 2001-11-01 Equistar Chemicals, L.P. Catalytic process for making propylene and ethylene
US7098162B2 (en) 2000-07-31 2006-08-29 Valorbec Societe En Commandite Catalysts for deep catalytic cracking of petroleum naphthas and other hydrocarbon feedstocks for the selective production of light olefins and method of making thereof
CA2369318A1 (en) 2002-01-28 2003-07-28 Universite Concordia Hybrid catalysts for the deep catalytic cracking of petroleum naphthas and other hydrocarbon feedstocks for the selective production of light olefins
JP4112943B2 (ja) 2002-10-28 2008-07-02 出光興産株式会社 炭化水素の接触分解によるオレフィンの製造方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1031834A (zh) * 1987-08-08 1989-03-22 中国石油化工总公司石油化工科学研究院 制取低碳烯烃的烃类催化转化方法
CN1040609A (zh) * 1988-08-26 1990-03-21 国际壳牌研究有限公司 烃类进料的催化裂化方法
US5171921A (en) * 1991-04-26 1992-12-15 Arco Chemical Technology, L.P. Production of olefins
US6211104B1 (en) * 1997-10-15 2001-04-03 China Petrochemical Corporation Catalyst for catalytic pyrolysis process for the production of light olefins and the preparation thereof
US6342153B1 (en) * 1997-12-23 2002-01-29 China Petrochemical Corporation Pillared clay catalysts for heavy oil catalytic pyrolisis process and the preparation method thereof
WO2004072002A1 (ja) * 2003-02-14 2004-08-26 Mitsui Chemicals, Inc. 低級オレフィンの製造方法

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