CN100457267C - 用于从烯烃制备不饱和醛的混合金属氧化物催化剂的制法 - Google Patents

用于从烯烃制备不饱和醛的混合金属氧化物催化剂的制法 Download PDF

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CN100457267C
CN100457267C CNB2004800418977A CN200480041897A CN100457267C CN 100457267 C CN100457267 C CN 100457267C CN B2004800418977 A CNB2004800418977 A CN B2004800418977A CN 200480041897 A CN200480041897 A CN 200480041897A CN 100457267 C CN100457267 C CN 100457267C
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compound
nitrate
solution
catalyst
temperature
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CN1929918A (zh
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J·W·考夫曼
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Saudi Basic Industries Corp
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Saudi Basic Industries Corp
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0236Drying, e.g. preparing a suspension, adding a soluble salt and drying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08Silica
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002Mixed oxides other than spinels, e.g. perovskite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/888Tungsten
    • B01J23/8885Tungsten containing also molybdenum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/03Precipitation; Co-precipitation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CNB2004800418977A 2003-12-19 2004-12-19 用于从烯烃制备不饱和醛的混合金属氧化物催化剂的制法 Expired - Fee Related CN100457267C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/741,383 2003-12-19
US10/741,383 US7229945B2 (en) 2003-12-19 2003-12-19 Process of making mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins

Publications (2)

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CN1929918A CN1929918A (zh) 2007-03-14
CN100457267C true CN100457267C (zh) 2009-02-04

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US (1) US7229945B2 (enExample)
EP (1) EP1694440A4 (enExample)
JP (1) JP5103019B2 (enExample)
KR (1) KR101122346B1 (enExample)
CN (1) CN100457267C (enExample)
WO (1) WO2005062806A2 (enExample)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004004900A1 (ja) * 2002-07-05 2004-01-15 Mitsubishi Rayon Co., Ltd. メタクリル酸製造用触媒の製造方法
US7452843B2 (en) * 2003-12-29 2008-11-18 Umicore Ag & Co. Kg Exhaust treatment devices, catalyst, and methods of making and using the same
US7494952B2 (en) * 2006-01-17 2009-02-24 Saudi Basic Industries Corporation Process of making mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
EP2121185A4 (en) * 2007-01-19 2014-04-16 Evernu Technology Llc SELECTIVE OXIDATION OF ALKANES AND / OR ALKENES TO PRECIOUS OXYGENATES
JP4639247B2 (ja) * 2008-07-23 2011-02-23 石油資源開発株式会社 炭化水素リフォーミング用触媒およびその製造方法ならびにこれを用いた合成ガスの製法
CN101746733B (zh) 2008-12-11 2012-10-03 中科合成油技术有限公司 一种连续化制备金属氧化物材料和催化剂的方法及设备
CN102247862B (zh) * 2010-05-18 2013-12-04 中国石油天然气股份有限公司 一种多层复合金属氧化物催化剂及其制备方法
US8722940B2 (en) 2012-03-01 2014-05-13 Saudi Basic Industries Corporation High molybdenum mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
JP6238354B2 (ja) * 2014-02-07 2017-11-29 日本化薬株式会社 不飽和アルデヒドおよび/または不飽和カルボン酸製造用触媒およびその製造方法ならびに不飽和アルデヒドおよび/または不飽和カルボン酸の製造方法
CN107684927B (zh) * 2016-08-03 2020-07-28 万华化学集团股份有限公司 一种用于氯化氢氧化制备氯气的催化剂及其制备方法和用途
JP6205044B2 (ja) * 2016-10-24 2017-09-27 旭化成株式会社 酸化物触媒の製造方法
EA202191429A1 (ru) * 2018-12-04 2021-09-01 Сабик Глобал Текнолоджис Б.В. Каталитическая композиция для получения углеводородов с2 из метана
US11478784B2 (en) 2020-02-04 2022-10-25 Saudi Arabian Oil Company Catalyst compositions for ammonia decomposition
CN113522301A (zh) * 2021-06-28 2021-10-22 谷育英 烯烃氧化制不饱和醛催化剂及其制备方法和应用

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5856259A (en) * 1994-12-21 1999-01-05 Mitsubishi Rayon Co., Ltd. Preparation process of supported catalyst for the synthesis of methacrolein and methacrylic acid
CN1379757A (zh) * 1999-10-18 2002-11-13 三菱丽阳株式会社 生产丙烯腈的方法、用于其中的催化剂及其制备方法
US6632772B2 (en) * 1998-09-23 2003-10-14 Lg Chemical, Ltd. Method of coating a catalyst to a support for use in acrolein oxidation

Family Cites Families (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2458429C3 (de) * 1973-12-11 1978-05-03 Daicel Ltd., Osaka (Japan) Katalysator, Verfahren zu seiner Herstellung und seine Verwendung zur Herstellung von a, ßungesättigten Aldehyden
DE2431511C3 (de) * 1974-07-01 1980-10-02 Institut Chimitscheskoj Fisiki Akademii Nauk Ssr, Moskau Verfahren zur Herstellung von a , ß -ungesättigten Säuren und Aldehyden
US4049577A (en) * 1975-12-15 1977-09-20 The Dow Chemical Company Catalyst for making acrolein
DE2626887B2 (de) * 1976-06-16 1978-06-29 Basf Ag, 6700 Ludwigshafen Katalysator für die Oxadation von (Methacrolein zu (Meth)Acrylsäure
US4556731A (en) 1977-07-28 1985-12-03 The Standard Oil Company Process for the oxidation of olefins using catalysts containing various promoter elements
JPS58119346A (ja) * 1982-01-06 1983-07-15 Nippon Shokubai Kagaku Kogyo Co Ltd プロピレン酸化用触媒
JPS5946132A (ja) 1982-09-06 1984-03-15 Nippon Shokubai Kagaku Kogyo Co Ltd メタクロレイン合成用触媒
US4537874A (en) * 1982-10-22 1985-08-27 Nippon Shokubai Kagaku Kogyo Co Ltd Catalyst for production of unsaturated aldehydes
JPS6122040A (ja) 1984-07-10 1986-01-30 Mitsubishi Rayon Co Ltd メタクロレイン及びメタクリル酸の製造法
DE3740271A1 (de) 1987-11-27 1989-06-01 Basf Ag Verfahren zur herstellung einer fuer die gasphasenoxidation von propylen zu acrolein und acrylsaeure katalytisch aktiven masse
US4837191A (en) * 1988-05-16 1989-06-06 The Standard Oil Company Catalytic mixture for the ammoxidation of paraffins
JPH0813332B2 (ja) 1989-09-25 1996-02-14 三菱レイヨン株式会社 メタクロレイン及びメタクリル酸の製造用触媒の調製法
US5276178A (en) 1989-12-06 1994-01-04 Nippon Shokubai Co., Ltd. Process for producing methacrolein and methacrylic acid
JPH0784400B2 (ja) * 1990-04-03 1995-09-13 株式会社日本触媒 不飽和アルデヒドおよび不飽和酸の製造方法
KR950004031B1 (ko) 1991-02-27 1995-04-22 미쓰이도오아쓰가가꾸 가부시끼가이샤 메타크롤레인의 제조방법 및 메타크롤레인의 제조에 사용하는 촉매의 제조방법
US5532199A (en) 1992-06-19 1996-07-02 Mitsubishi Rayon Co., Ltd. Carrier-supported catalyst for the synthesis of unsaturated aldehydes and unsaturated carboxylic acids and process for preparing the same
KR100277241B1 (ko) 1993-06-25 2001-02-01 고오사이 아끼오 불포화 알데하이드 및 불포화 카복실산의 제조방법
KR100247524B1 (ko) * 1994-05-31 2000-03-15 겐지 아이다 아크릴산 제조용 촉매 및 이 촉매를 이용한 아크릴산의 제조방법
ES2140684T3 (es) 1994-06-22 2000-03-01 Asahi Chemical Ind Metodo para la fabricacion de metacroleina.
JP3342794B2 (ja) * 1994-12-21 2002-11-11 三菱レイヨン株式会社 メタクロレイン及びメタクリル酸合成用担持触媒の製造法
JP3786297B2 (ja) * 1995-03-03 2006-06-14 日本化薬株式会社 触媒の製造方法
JP3793317B2 (ja) * 1996-05-14 2006-07-05 日本化薬株式会社 触媒及び不飽和アルデヒドおよび不飽和酸の製造方法
JP3775872B2 (ja) 1996-12-03 2006-05-17 日本化薬株式会社 アクロレイン及びアクリル酸の製造方法
CN1108865C (zh) * 1997-09-03 2003-05-21 中国石油化工集团公司 生产丙烯腈的催化剂
US6924387B1 (en) * 1998-02-13 2005-08-02 Korea Research Institute Of Chemical Technology Solid catalyst with core-shell catalytic phase and a method of preparation thereof
DE19815278A1 (de) * 1998-04-06 1999-10-07 Basf Ag Multimetalloxidmassen
DE19855913A1 (de) * 1998-12-03 2000-06-08 Basf Ag Multimetalloxidmasse zur gasphasenkatalytischen Oxidation organischer Verbindungen
JP4185217B2 (ja) * 1999-05-25 2008-11-26 株式会社日本触媒 複合酸化物触媒、並びに(メタ)アクロレインおよび(メタ)アクリル酸の製造方法
US6693059B2 (en) * 2000-02-09 2004-02-17 Rohm And Haas Company Process for preparing a catalyst and catalytic oxidation therewith
DE10046928A1 (de) * 2000-09-21 2002-04-11 Basf Ag Verfahren zur Herstellung von Multimetalloxidmassen
DE10046957A1 (de) * 2000-09-21 2002-04-11 Basf Ag Verfahren zur Herstellung eines Multimetalloxid-Katalysators, Verfahren zur Herstellung ungesättigter Aldehyde und/oder Carbonsäuren und Bandcalziniervorrichtung
JP3892244B2 (ja) * 2001-03-21 2007-03-14 株式会社日本触媒 不飽和アルデヒドおよび不飽和カルボン酸製造用触媒の製造方法
CN100354042C (zh) * 2001-11-08 2007-12-12 三菱化学株式会社 复合氧化物催化剂及其制备方法
US6946422B2 (en) * 2002-12-12 2005-09-20 Saudi Basic Industries Corporation Preparation of mixed metal oxide catalysts for catalytic oxidation of olefins to unsaturated aldehydes
US20040192973A1 (en) * 2003-03-31 2004-09-30 Saudi Basic Industries Corporation Mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
KR101014356B1 (ko) * 2003-05-30 2011-02-15 니폰 가야꾸 가부시끼가이샤 메타크릴산 제조용 촉매의 제조방법

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5856259A (en) * 1994-12-21 1999-01-05 Mitsubishi Rayon Co., Ltd. Preparation process of supported catalyst for the synthesis of methacrolein and methacrylic acid
US6632772B2 (en) * 1998-09-23 2003-10-14 Lg Chemical, Ltd. Method of coating a catalyst to a support for use in acrolein oxidation
CN1379757A (zh) * 1999-10-18 2002-11-13 三菱丽阳株式会社 生产丙烯腈的方法、用于其中的催化剂及其制备方法

Also Published As

Publication number Publication date
EP1694440A2 (en) 2006-08-30
KR20070014115A (ko) 2007-01-31
KR101122346B1 (ko) 2012-03-26
WO2005062806A3 (en) 2006-06-22
CN1929918A (zh) 2007-03-14
US7229945B2 (en) 2007-06-12
US20050137081A1 (en) 2005-06-23
WO2005062806A2 (en) 2005-07-14
JP2007514538A (ja) 2007-06-07
EP1694440A4 (en) 2011-05-11
JP5103019B2 (ja) 2012-12-19

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