CN100422221C - 用于烯烃聚合反应的方法 - Google Patents

用于烯烃聚合反应的方法 Download PDF

Info

Publication number
CN100422221C
CN100422221C CNB028123816A CN02812381A CN100422221C CN 100422221 C CN100422221 C CN 100422221C CN B028123816 A CNB028123816 A CN B028123816A CN 02812381 A CN02812381 A CN 02812381A CN 100422221 C CN100422221 C CN 100422221C
Authority
CN
China
Prior art keywords
catalyst component
diameter
diameter value
formula
polymkeric substance
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CNB028123816A
Other languages
English (en)
Chinese (zh)
Other versions
CN1518562A (zh
Inventor
G·科利纳
O·福斯科
E·基科特卡里安
A·吉尔
V·多勒
H·克拉森
K·H·卡格尔鲍尔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Technology Co BV
Original Assignee
Basell Technology Co BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Technology Co BV filed Critical Basell Technology Co BV
Publication of CN1518562A publication Critical patent/CN1518562A/zh
Application granted granted Critical
Publication of CN100422221C publication Critical patent/CN100422221C/zh
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CNB028123816A 2001-12-12 2002-12-10 用于烯烃聚合反应的方法 Expired - Lifetime CN100422221C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP01204842 2001-12-12
EP01204842.7 2001-12-12

Publications (2)

Publication Number Publication Date
CN1518562A CN1518562A (zh) 2004-08-04
CN100422221C true CN100422221C (zh) 2008-10-01

Family

ID=8181409

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB028123816A Expired - Lifetime CN100422221C (zh) 2001-12-12 2002-12-10 用于烯烃聚合反应的方法

Country Status (19)

Country Link
US (1) US7138469B2 (enExample)
EP (1) EP1453867B1 (enExample)
JP (1) JP4511185B2 (enExample)
KR (1) KR101080666B1 (enExample)
CN (1) CN100422221C (enExample)
AR (1) AR037790A1 (enExample)
AU (1) AU2002366733B9 (enExample)
BR (1) BR0207072B1 (enExample)
CA (1) CA2452573C (enExample)
ES (1) ES2527049T3 (enExample)
HU (1) HUP0303960A3 (enExample)
MX (1) MXPA03008573A (enExample)
MY (1) MY136330A (enExample)
PL (1) PL204746B1 (enExample)
RU (1) RU2308461C2 (enExample)
SA (1) SA03230560B1 (enExample)
TW (1) TWI268939B (enExample)
WO (1) WO2003054035A1 (enExample)
ZA (1) ZA200305940B (enExample)

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2471811C2 (ru) * 2007-10-15 2013-01-10 Базелль Полиолефин Италия С.Р.Л. Способ получения полимеров пропилена с высокой текучестью
US9611338B2 (en) 2007-12-18 2017-04-04 Basell Poliolefine Italia S.R.L. Copolymers of propylene with hexene-1 and blown films obtained from them
JP5400794B2 (ja) * 2007-12-19 2014-01-29 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ 軟質で可撓性のポリオレフィン組成物
JP5676586B2 (ja) 2009-06-19 2015-02-25 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ 耐衝撃性プロピレンポリマー組成物の製造方法
WO2011061067A1 (en) 2009-11-17 2011-05-26 Basell Poliolefine Italia S.R.L. Thermoshrinkable films
RU2425059C1 (ru) * 2010-01-28 2011-07-27 Учреждение Российской Академии Наук Ордена Трудового Красного Знамени Институт Нефтехимического Синтеза Им. А.В. Топчиева Ран (Инхс Ран) Способ получения титан-магниевого нанокатализатора (со)полимеризации альфа-олефинов и сопряженных диенов
EP2614115B1 (en) 2010-09-06 2016-04-27 Basell Poliolefine Italia S.r.l. Polyolefin compositions having improved sealability
BR112013014016B1 (pt) 2010-12-09 2020-09-15 Basell Poliolefine Italia S.R.L. Película de polímero permeável e itens de embalagem de alimentos
EP2594593A1 (en) 2011-11-17 2013-05-22 Basell Poliolefine Italia S.r.l. Process for the preparation of heterophasic propylene polymer compositions
EP2607389A1 (en) 2011-12-20 2013-06-26 Basell Polyolefine GmbH Process for preparing olefin polymer by slurry loop polymerization having high powder density
EP2743278A1 (en) 2012-12-11 2014-06-18 Basell Polyolefine GmbH Process for degassing and buffering polyolefin particles obtained by olefin polymerization
EP2743073A1 (en) * 2012-12-12 2014-06-18 Basell Poliolefine Italia S.r.l. Propylene-based terpolymers
EP2757114A1 (en) * 2013-01-18 2014-07-23 Basell Poliolefine Italia S.r.l. Catalyst components for the polymerization of olefins
BR112015030327B1 (pt) * 2013-06-03 2020-12-01 Lummus Novolen Technology Gmbh sistema de catalisador útil para a polimerização de propileno ou copolímeros de propileno, processos para a produção de tais sistemas catalisadores, e polímero obtido
ES2651456T3 (es) 2013-08-14 2018-01-26 Borealis Ag Composición de propileno con mejor resistencia al impacto a baja temperatura
BR112016003128B1 (pt) 2013-08-21 2021-08-24 Borealis Ag Composição de poliolefina de alto fluxo com alta rigidez e resistência e artigos automotivos
MX2016001705A (es) 2013-08-21 2016-05-18 Borealis Ag Composicion de poliolefina de alto flujo con alta rigidez y tenacidad.
EP2853563B1 (en) 2013-09-27 2016-06-15 Borealis AG Films suitable for BOPP processing from polymers with high XS and high Tm
ES2568615T3 (es) 2013-10-11 2016-05-03 Borealis Ag Película para etiquetas orientada en la dirección de la máquina
WO2015059229A1 (en) 2013-10-24 2015-04-30 Borealis Ag Low melting pp homopolymer with high content of regioerrors and high molecular weight
WO2015059117A1 (en) * 2013-10-24 2015-04-30 Basell Poliolefine Italia S.R.L. Process for the preparation of porous propylene polymers
EA031527B1 (ru) 2013-11-22 2019-01-31 Бореалис Аг Гомополимер пропилена с низкой эмиссией и с высокой скоростью течения расплава
WO2015082379A1 (en) 2013-12-04 2015-06-11 Borealis Ag Phthalate-free pp homopolymers for meltblown fibers
JP6203405B2 (ja) 2013-12-18 2017-09-27 ボレアリス エージー 剛性／靭性バランスが改良されたｂｏｐｐフィルム
CN105829364B (zh) 2014-01-17 2017-11-10 博里利斯股份公司 用于制备丙烯/1‑丁烯共聚物的方法
ES2767498T3 (es) 2014-02-06 2020-06-17 Borealis Ag Copolímeros de impacto transparentes y suaves
CN112225997B (zh) 2014-02-06 2023-09-22 北欧化工公司 高冲击强度的柔性共聚物
EP2907841A1 (en) 2014-02-14 2015-08-19 Borealis AG Polypropylene composite
ES2659731T3 (es) 2014-05-20 2018-03-19 Borealis Ag Composición de polipropileno para aplicaciones en interiores de automóviles
RU2723242C2 (ru) 2015-12-11 2020-06-09 Базелл Полиолефин Италия С.Р.Л. Сополимеры пропиленовые
BR112018010717B1 (pt) 2015-12-11 2022-01-25 Basell Poliolefine Italia S.R.L. Composição de polímero à base de propileno
CN113179643B (zh) * 2019-01-09 2024-07-05 巴塞尔聚烯烃意大利有限公司 用于烯烃聚合的催化剂组分
JPWO2023171433A1 (enExample) * 2022-03-11 2023-09-14

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1125951A (zh) * 1993-06-24 1996-07-03 陶氏化学公司 钛(i)或锆(i)络合物和由它们制得的加成聚合催化剂
US5648428A (en) * 1993-04-28 1997-07-15 Fina Technology, Inc. Process for preparing an isotactic/syndiotactic polymer blend in a single reactor
WO2001032307A1 (en) * 1999-11-05 2001-05-10 Phillips Petroleum Company Polymerization catalyst systems and processes using alkly lithium compounds as a cocatalyst

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL162661B (nl) * 1968-11-21 1980-01-15 Montedison Spa Werkwijze om een katalysator te bereiden voor de poly- merisatie van alkenen-1.
YU35844B (en) * 1968-11-25 1981-08-31 Montedison Spa Process for obtaining catalysts for the polymerization of olefines
US4192774A (en) * 1978-01-27 1980-03-11 Shell Oil Company Preparation of an active TiCl3 catalyst
IT1096661B (it) * 1978-06-13 1985-08-26 Montedison Spa Procedimento per la preparazione di prodotti in forma sferoidale solidi a temperatura ambiente
IT1098272B (it) * 1978-08-22 1985-09-07 Montedison Spa Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine
US4657883A (en) * 1985-10-07 1987-04-14 Amoco Corporation Ester-modified olefin polymerization catalyst
JP2523109B2 (ja) * 1986-05-02 1996-08-07 三菱化学株式会社 オレフイン重合用触媒成分
IT1227258B (it) 1988-09-30 1991-03-28 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine
IT1230134B (it) * 1989-04-28 1991-10-14 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine.
JP2940684B2 (ja) * 1989-12-29 1999-08-25 三井化学株式会社 オレフィン重合用固体状触媒成分およびこの触媒成分を用いたオレフィンの重合方法
TW198726B (enExample) * 1989-12-29 1993-01-21 Mitsui Petroleum Chemicals Ind
IT1246614B (it) 1991-06-03 1994-11-24 Himont Inc Procedimento per la polimerizzazione in fase gas delle olefine
IT1250731B (it) 1991-07-31 1995-04-21 Himont Inc Procedimento per la preparazione di polietilene lineare a bassa densita'
CA2077744C (en) * 1991-09-30 2003-04-15 Edwar Shoukri Shamshoum Homogeneous-heterogeneous catalyst system for polyolefins
IT1262934B (it) * 1992-01-31 1996-07-22 Montecatini Tecnologie Srl Componenti e catalizzatori per la polimerizzazione di olefine
IT1262935B (it) * 1992-01-31 1996-07-22 Montecatini Tecnologie Srl Componenti e catalizzatori per la polimerizzazione di olefine
IT1254279B (it) * 1992-03-13 1995-09-14 Montecatini Tecnologie Srl Procedimento per la polimerizzazione in fase gas delle olefine
IT1256648B (it) 1992-12-11 1995-12-12 Montecatini Tecnologie Srl Componenti e catalizzatori per la polimerizzazione delle olefine
BE1006438A3 (fr) * 1992-12-17 1994-08-30 Solvay Systeme catalytique, utilisation de ce systeme catalytique pour la (co)polymerisation d'olefines, procede de preparation de ce systeme catalytique et procede de (co)polymerisation d'olefines.
US5643846A (en) * 1993-04-28 1997-07-01 Fina Technology, Inc. Process for a isotactic/syndiotactic polymer blend in a single reactor
US5589539A (en) * 1994-11-23 1996-12-31 Union Carbide Chemicals & Plastics Technology Corporation Process for preparing an in situ polyethylene blend
IL117114A (en) 1995-02-21 2000-02-17 Montell North America Inc Components and catalysts for the polymerization ofolefins
AU736901B2 (en) 1997-03-29 2001-08-02 Montell Technology Company B.V. "Magnesium dichloride-alcohol adducts, process for their preparation and catalyst components obtained therefrom"
US6051525A (en) * 1997-07-14 2000-04-18 Mobil Corporation Catalyst for the manufacture of polyethylene with a broad or bimodal molecular weight distribution

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5648428A (en) * 1993-04-28 1997-07-15 Fina Technology, Inc. Process for preparing an isotactic/syndiotactic polymer blend in a single reactor
CN1125951A (zh) * 1993-06-24 1996-07-03 陶氏化学公司 钛(i)或锆(i)络合物和由它们制得的加成聚合催化剂
WO2001032307A1 (en) * 1999-11-05 2001-05-10 Phillips Petroleum Company Polymerization catalyst systems and processes using alkly lithium compounds as a cocatalyst

Also Published As

Publication number Publication date
AU2002366733B2 (en) 2008-10-16
US7138469B2 (en) 2006-11-21
CA2452573C (en) 2011-03-22
SA03230560B1 (ar) 2008-07-19
PL204746B1 (pl) 2010-02-26
ES2527049T3 (es) 2015-01-20
TWI268939B (en) 2006-12-21
EP1453867B1 (en) 2014-11-12
RU2308461C2 (ru) 2007-10-20
HUP0303960A3 (en) 2007-11-28
RU2003128027A (ru) 2005-02-27
AU2002366733A1 (en) 2003-07-09
EP1453867A1 (en) 2004-09-08
CA2452573A1 (en) 2003-07-03
TW200409780A (en) 2004-06-16
AU2002366733B9 (en) 2009-03-19
MXPA03008573A (es) 2003-12-08
ZA200305940B (en) 2005-01-26
BR0207072A (pt) 2004-01-27
KR20040064613A (ko) 2004-07-19
HUP0303960A2 (hu) 2004-03-01
MY136330A (en) 2008-09-30
KR101080666B1 (ko) 2011-11-08
JP2005513213A (ja) 2005-05-12
AR037790A1 (es) 2004-12-01
WO2003054035A1 (en) 2003-07-03
US20040077490A1 (en) 2004-04-22
CN1518562A (zh) 2004-08-04
BR0207072B1 (pt) 2012-08-21
PL374056A1 (en) 2005-09-19
JP4511185B2 (ja) 2010-07-28

Similar Documents

Publication Publication Date Title
CN100422221C (zh) 用于烯烃聚合反应的方法
RU2234516C2 (ru) Компонент форполимерного катализатора, способ его получения, катализатор полимеризации олефинов и способ полимеризации олефинов с его использованием
EP0133383B1 (en) Supported polyolefin catalyst for the polymerization of ethylene under high temperatures
JP5102419B2 (ja) オレフィン重合用触媒成分およびそこから得られた触媒
KR20010083089A (ko) 촉매 조성물, 그의 제조 방법 및 중합 반응 공정에서의 용도
US6214949B1 (en) Polymerization of polyolefins having low melt flow and high molecular weight
KR20050084415A (ko) 올레핀 중합용 촉매 성분
JP5122054B2 (ja) オレフィン重合用の予備重合触媒成分
US7019097B2 (en) Process for the (co)polymerization of ethylene
WO2005003184A1 (en) Polymerization processes using antistatic agents
EP1232193B1 (en) Catalyst for the polymerization of olefins
EP0604846B1 (en) Components and catalysts for the polymerization of olefins
CN102264771A (zh) 用于聚合烯烃的催化剂组分和由其获得的催化剂
RU2444532C2 (ru) Компоненты катализатора для полимеризации олефинов и катализаторы, полученные из них
JP2002519447A (ja) オレフィン重合用触媒成分およびそれから得られる触媒

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CX01 Expiry of patent term

Granted publication date: 20081001

CX01 Expiry of patent term