CN100371358C - 含全氟(乙基乙烯基醚)的无定形含氟聚合物 - Google Patents
含全氟(乙基乙烯基醚)的无定形含氟聚合物 Download PDFInfo
- Publication number
- CN100371358C CN100371358C CNB971978700A CN97197870A CN100371358C CN 100371358 C CN100371358 C CN 100371358C CN B971978700 A CNB971978700 A CN B971978700A CN 97197870 A CN97197870 A CN 97197870A CN 100371358 C CN100371358 C CN 100371358C
- Authority
- CN
- China
- Prior art keywords
- perfluor
- vinyl ether
- ethyl vinyl
- peve
- tfe
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D129/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Coating compositions based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Coating compositions based on derivatives of such polymers
- C09D129/10—Homopolymers or copolymers of unsaturated ethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/26—Tetrafluoroethene
- C08F214/262—Tetrafluoroethene with fluorinated vinyl ethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
- C08F216/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
- C08F216/14—Monomers containing only one unsaturated aliphatic radical
- C08F216/1408—Monomers containing halogen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C09D127/18—Homopolymers or copolymers of tetrafluoroethene
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
- Y10T428/31544—Addition polymer is perhalogenated
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US2639796P | 1996-09-13 | 1996-09-13 | |
| US60/026,397 | 1996-09-13 | ||
| US08/929,213 US5919878A (en) | 1996-09-13 | 1997-09-09 | Amorphous fluoropolymer containing perfluoro(ethyl vinyl ether) |
| US08/929,213 | 1997-09-09 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1230201A CN1230201A (zh) | 1999-09-29 |
| CN100371358C true CN100371358C (zh) | 2008-02-27 |
Family
ID=26701190
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB971978700A Expired - Fee Related CN100371358C (zh) | 1996-09-13 | 1997-09-11 | 含全氟(乙基乙烯基醚)的无定形含氟聚合物 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US5919878A (enExample) |
| EP (1) | EP0925314B1 (enExample) |
| JP (1) | JP3980649B2 (enExample) |
| CN (1) | CN100371358C (enExample) |
| DE (1) | DE69708659T2 (enExample) |
| WO (1) | WO1998011146A1 (enExample) |
Families Citing this family (60)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5866711A (en) * | 1996-09-13 | 1999-02-02 | E. I. Du Pont De Nemours And Company | Fluorocyanate and fluorocarbamate monomers and polymers thereof |
| US6036945A (en) | 1997-04-11 | 2000-03-14 | Shamrock Technologies, Inc. | Delivery systems for active ingredients including sunscreen actives and methods of making same |
| US6242547B1 (en) * | 1997-04-15 | 2001-06-05 | E. I. Du Pont De Nemours And Company | Vinyl fluoride interpolymers of low crystallinity |
| WO1999062999A1 (en) * | 1998-05-29 | 1999-12-09 | Daikin Industries, Ltd. | Spherulite-micronizing agent for crystalline fluororesin and crystalline fluororesin composition containing the micronizing agent |
| US6248823B1 (en) * | 1998-07-02 | 2001-06-19 | E. I. Du Pont De Nemours And Company | Solvents for amorphous fluoropolymers |
| US7049380B1 (en) * | 1999-01-19 | 2006-05-23 | Gore Enterprise Holdings, Inc. | Thermoplastic copolymer of tetrafluoroethylene and perfluoromethyl vinyl ether and medical devices employing the copolymer |
| US6365276B1 (en) * | 1999-11-12 | 2002-04-02 | Mitsushita Chemical America, Inc. | Coated metal articles methods for preparing the same laminated composites containing the same, and methods for preparing such laminated composites |
| IT1318596B1 (it) * | 2000-06-23 | 2003-08-27 | Ausimont Spa | Copolimeri termoprocessbili del tfe. |
| GB2368810A (en) * | 2000-11-09 | 2002-05-15 | Toppan Printing Co Ltd | Treatment of a surface of a polymer |
| US6649720B2 (en) * | 2001-02-14 | 2003-11-18 | Atofina Chemicals, Inc. | Ethane as a chain transfer agent for vinylidene fluoride polymerization |
| US6734227B2 (en) * | 2001-09-24 | 2004-05-11 | 3M Innovative Properties Company | Optical elements comprising a fluoropolymer surface treatment |
| US20030118836A1 (en) * | 2001-10-24 | 2003-06-26 | Lee Jeong Chang | Fluoropolymer laminates and a process for manufacture thereof |
| JP3888232B2 (ja) * | 2001-12-18 | 2007-02-28 | ユニマテック株式会社 | 含フッ素三元共重合体 |
| US20030211264A1 (en) * | 2002-05-09 | 2003-11-13 | Farnsworth Ted Ray | Expanded polytetrafluoroethylene (ePTFE)-reinforced perfluoroelastomers (FFKM) |
| US20040024448A1 (en) | 2002-08-05 | 2004-02-05 | Chang James W. | Thermoplastic fluoropolymer-coated medical devices |
| US20040026245A1 (en) * | 2002-08-09 | 2004-02-12 | Vivek Agarwal | High temperature oleophobic materials |
| US6969166B2 (en) | 2003-05-29 | 2005-11-29 | 3M Innovative Properties Company | Method for modifying the surface of a substrate |
| US20040241395A1 (en) * | 2003-05-29 | 2004-12-02 | 3M Innovative Properties Company | Method of modifying a surface of a substrate and articles therefrom |
| US20040241396A1 (en) * | 2003-05-29 | 2004-12-02 | 3M Innovative Properties Company | Method of modifying a surface of a substrate and articles therefrom |
| US20040241323A1 (en) * | 2003-05-29 | 2004-12-02 | 3M Innovative Properties Company | Method for applying adhesive to a substrate |
| WO2005105401A1 (en) * | 2004-05-04 | 2005-11-10 | Minuta Technology Co. Ltd. | Mold made of amorphous fluorine resin and fabrication method thereof |
| US7147912B2 (en) * | 2004-08-18 | 2006-12-12 | E. I. Du Pont De Nemours And Company | Amphipathic proteinaceous coating on nanoporous polymer |
| US20080149472A1 (en) * | 2004-12-22 | 2008-06-26 | Velliyur Nott Mallikarjuna Rao | Photochlorination and Fluorination Process for Preparation of Fluorine-Containing Hydrocarbons |
| EP2377610A3 (en) * | 2004-12-22 | 2012-02-08 | E. I. Du Pont De Nemours And Company | Process for increasing the fluorine content by photochemical reactions |
| JP5027670B2 (ja) * | 2004-12-22 | 2012-09-19 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 光化学反応用の末端官能化パーフルオロ(アルキルビニルエーテル)反応器壁の官能化共重合体、炭化水素およびハロ炭化水素中のフッ素含有率の増加方法およびオレフィン製造方法 |
| JP2006316174A (ja) * | 2005-05-13 | 2006-11-24 | Yunimatekku Kk | フッ素化処理含フッ素共重合体の製造法 |
| US7683130B2 (en) * | 2005-07-18 | 2010-03-23 | E.I. Du Pont De Nemours And Company | Filled perfluoropolymer composition comprising a low melting fluoropolymer additive |
| US20070015875A1 (en) * | 2005-07-18 | 2007-01-18 | Globus Yevgeniy I | Foamed article comprising filled perfluoropolymer composition |
| KR20130118995A (ko) * | 2005-09-30 | 2013-10-30 | 듀폰-미쯔이 플루오로케미칼 가부시끼가이샤 | 균일하게 분포된 나노-크기의 무기 입자를 갖는 중합체 조성물 |
| JP2007112916A (ja) * | 2005-10-21 | 2007-05-10 | Yunimatekku Kk | 非晶質含フッ素共重合体 |
| EP2527397A1 (en) * | 2005-10-31 | 2012-11-28 | Daikin Industries, Ltd. | Method for molding polytetrafluoroethylene, polytetrafluoroethylene molded body, crosslinkable polytetrafluoroethylene, powdered polytetrafluoroethylene crosslinked body, resin blend composition of matter and resin blend molded body |
| CN101730578B (zh) | 2007-04-23 | 2013-06-05 | W.L.戈尔有限公司 | 复合材料 |
| US8858681B2 (en) * | 2007-04-23 | 2014-10-14 | W. L. Gore & Associates, Inc. | Patterned porous venting materials |
| US7927405B2 (en) * | 2007-04-23 | 2011-04-19 | Gore Enterprise Holdings, Inc | Porous composite article |
| US7936358B2 (en) * | 2007-04-27 | 2011-05-03 | Hewlett-Packard Development Company, L.P. | Integrated color management |
| WO2009034952A1 (ja) * | 2007-09-10 | 2009-03-19 | Inter-University Research Institute Corporation High Energy Accelerator Research Organization | 非晶質パーフルオロ樹脂の成形方法及び光学素子 |
| US8288492B2 (en) | 2007-10-23 | 2012-10-16 | E I Du Pont De Nemours And Company | Difunctional oligomers of perfluoro(methyl vinyl ether) |
| JP2009215296A (ja) * | 2008-03-07 | 2009-09-24 | Daikin Ind Ltd | フルオロエーテルアルコール、フルオロエーテルカルボン酸エステル、及び、フルオロエーテルカルボン酸 |
| US20100004583A1 (en) * | 2008-07-01 | 2010-01-07 | Alza Corporation | Hydrophobic Circuit Board Coating of Electrotransport Drug Delivery Devices |
| TWI496796B (zh) * | 2009-02-13 | 2015-08-21 | Solvay Solexis Spa | 全氟彈性體 |
| TWI482784B (zh) | 2009-02-13 | 2015-05-01 | Solvay Solexis Spa | 全氟彈性體 |
| US8138274B2 (en) | 2009-12-08 | 2012-03-20 | Le Centre National De La Recherche Scien | Process for preparation of fluorosilicon polymer |
| US8808848B2 (en) | 2010-09-10 | 2014-08-19 | W. L. Gore & Associates, Inc. | Porous article |
| JP6017550B2 (ja) * | 2011-06-09 | 2016-11-02 | ソルベイ スペシャルティ ポリマーズ イタリー エス.ピー.エー. | 超分岐フルオロエラストマー添加剤 |
| JP6150483B2 (ja) * | 2012-09-27 | 2017-06-21 | 三井・デュポンフロロケミカル株式会社 | パーフルオロ(エチルビニルエーテル)を含有する非晶質フッ素重合体溶剤組成物 |
| JP5995630B2 (ja) * | 2012-09-27 | 2016-09-21 | 三井・デュポンフロロケミカル株式会社 | 非晶質含フッ素樹脂組成物および薄膜製造方法 |
| JP6250356B2 (ja) * | 2013-10-10 | 2017-12-20 | グンゼ株式会社 | フッ素系繊維不織布の製造方法 |
| JP6395411B2 (ja) * | 2014-03-25 | 2018-09-26 | 三井・ケマーズ フロロプロダクツ株式会社 | テトラフルオロエチレンとパーフルオロ(エチルビニルエーテル)との共重合体を含む複合成形体 |
| CN104059188A (zh) * | 2014-06-18 | 2014-09-24 | 浙江巨圣氟化学有限公司 | 一种四氟乙烯与全氟代烷基乙烯基醚共聚组合物及其制备方法 |
| JP6465653B2 (ja) | 2014-12-26 | 2019-02-06 | 三井・ケマーズ フロロプロダクツ株式会社 | 耐ブリスター性に優れたpfa成形体およびpfa成形体のブリスター発生を抑制する方法 |
| JP6826834B2 (ja) | 2016-07-27 | 2021-02-10 | 三井・ケマーズ フロロプロダクツ株式会社 | トップコート用フッ素樹脂塗料及びその塗膜 |
| EP3647344A4 (en) | 2017-06-26 | 2021-02-17 | Chemours-Mitsui Fluoroproducts Co., Ltd. | FLUORINE RESIN MOLDED BODY |
| JP2019094459A (ja) * | 2017-11-27 | 2019-06-20 | 三井・ケマーズ フロロプロダクツ株式会社 | 形状記憶成形品用材料および形状記憶成形品 |
| WO2019239322A1 (en) * | 2018-06-12 | 2019-12-19 | 3M Innovative Properties Company | Fluoropolymer nanoparticle coating composition |
| US11866602B2 (en) | 2018-06-12 | 2024-01-09 | 3M Innovative Properties Company | Fluoropolymer compositions comprising fluorinated additives, coated substrates and methods |
| EP3807344B1 (en) | 2018-06-12 | 2023-12-27 | 3M Innovative Properties Company | Fluoropolymer coating compositions comprising aminosilane curing agents, coated substrates and related methods |
| JP2018184618A (ja) * | 2018-08-03 | 2018-11-22 | 三井・ケマーズ フロロプロダクツ株式会社 | テトラフルオロエチレンとパーフルオロ(エチルビニルエーテル)との共重合体の水性分散体または溶液 |
| CN114630874B (zh) | 2019-11-04 | 2023-12-05 | 3M创新有限公司 | 包含具有烯键式不饱和基团和电子供体基团的固化剂的含氟聚合物组合物及用其涂覆的基底 |
| WO2021088198A1 (en) | 2019-11-04 | 2021-05-14 | 3M Innovative Properties Company | Electronic telecommunications articles comprising crosslinked fluoropolymers and methods |
| CN116078187A (zh) * | 2022-09-09 | 2023-05-09 | 山东东岳高分子材料有限公司 | 一种拨水拨油组合物及制备和应用 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3635926A (en) * | 1969-10-27 | 1972-01-18 | Du Pont | Aqueous process for making improved tetrafluoroethylene / fluoroalkyl perfluorovinyl ether copolymers |
| JPH0488304A (ja) * | 1990-08-01 | 1992-03-23 | Mitsubishi Rayon Co Ltd | プラスチック光ファイバ |
| CN1103870A (zh) * | 1993-10-20 | 1995-06-21 | 赫彻斯特股份公司 | 改性的聚四氟乙烯的制备及其使用 |
| US5461129A (en) * | 1993-10-29 | 1995-10-24 | Nippon Mektron, Limited | Tetrafluoroethylene-perfluorovinylether copolymer |
| WO1996024625A2 (en) * | 1995-02-06 | 1996-08-15 | E.I. Du Pont De Nemours And Company | Amorphous copolymers of tetrafluoroethylene and hexafluoropropylene |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4131740A (en) * | 1977-04-20 | 1978-12-26 | E. I. Du Pont De Nemours And Company | Alkyl perfluoro-ω-fluoroformyl esters and their preparation |
| US4982009A (en) * | 1990-01-31 | 1991-01-01 | E. I. Du Pont De Nemours And Company | Hydroxy containing fluorovinyl compounds and polymers thereof |
| US5059720A (en) * | 1990-01-31 | 1991-10-22 | E. I. Du Pont De Nemours And Company | Hydroxy containing fluorovinyl compounds and polymers thereof |
| US5328946A (en) * | 1991-08-29 | 1994-07-12 | E. I. Du Pont De Nemours And Company | Solvents for tetrafluoroethylene polymers |
| JP3109523B2 (ja) * | 1992-08-28 | 2000-11-20 | イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー | テトラフルオロエチレンのコポリマーを含むゲル |
| US5266639A (en) * | 1992-08-28 | 1993-11-30 | E. I. Du Pont De Nemours And Company | Low-melting tetrafluorethylene copolymer and its uses |
| US5310838A (en) * | 1993-09-07 | 1994-05-10 | E. I. Du Pont De Nemours And Company | Functional fluoropolymers |
| US5543217A (en) * | 1995-02-06 | 1996-08-06 | E. I. Du Pont De Nemours And Company | Amorphous copolymers of tetrafluoroethylene and hexafluoropropylene |
-
1997
- 1997-09-09 US US08/929,213 patent/US5919878A/en not_active Expired - Lifetime
- 1997-09-11 DE DE69708659T patent/DE69708659T2/de not_active Expired - Lifetime
- 1997-09-11 JP JP51384798A patent/JP3980649B2/ja not_active Expired - Fee Related
- 1997-09-11 EP EP97943297A patent/EP0925314B1/en not_active Expired - Lifetime
- 1997-09-11 WO PCT/US1997/016066 patent/WO1998011146A1/en not_active Ceased
- 1997-09-11 CN CNB971978700A patent/CN100371358C/zh not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3635926A (en) * | 1969-10-27 | 1972-01-18 | Du Pont | Aqueous process for making improved tetrafluoroethylene / fluoroalkyl perfluorovinyl ether copolymers |
| JPH0488304A (ja) * | 1990-08-01 | 1992-03-23 | Mitsubishi Rayon Co Ltd | プラスチック光ファイバ |
| CN1103870A (zh) * | 1993-10-20 | 1995-06-21 | 赫彻斯特股份公司 | 改性的聚四氟乙烯的制备及其使用 |
| US5461129A (en) * | 1993-10-29 | 1995-10-24 | Nippon Mektron, Limited | Tetrafluoroethylene-perfluorovinylether copolymer |
| WO1996024625A2 (en) * | 1995-02-06 | 1996-08-15 | E.I. Du Pont De Nemours And Company | Amorphous copolymers of tetrafluoroethylene and hexafluoropropylene |
Also Published As
| Publication number | Publication date |
|---|---|
| DE69708659D1 (de) | 2002-01-10 |
| JP3980649B2 (ja) | 2007-09-26 |
| WO1998011146A1 (en) | 1998-03-19 |
| EP0925314B1 (en) | 2001-11-28 |
| DE69708659T2 (de) | 2002-08-01 |
| EP0925314A1 (en) | 1999-06-30 |
| JP2001500906A (ja) | 2001-01-23 |
| US5919878A (en) | 1999-07-06 |
| CN1230201A (zh) | 1999-09-29 |
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