CA2837834C - Scandium extraction method - Google Patents
Scandium extraction method Download PDFInfo
- Publication number
- CA2837834C CA2837834C CA2837834A CA2837834A CA2837834C CA 2837834 C CA2837834 C CA 2837834C CA 2837834 A CA2837834 A CA 2837834A CA 2837834 A CA2837834 A CA 2837834A CA 2837834 C CA2837834 C CA 2837834C
- Authority
- CA
- Canada
- Prior art keywords
- scandium
- extraction
- amide derivative
- acidic solution
- magnesium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229910052706 scandium Inorganic materials 0.000 title claims abstract description 89
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 title claims abstract description 81
- 238000000605 extraction Methods 0.000 title claims abstract description 67
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 36
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 26
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 26
- 239000011575 calcium Substances 0.000 claims abstract description 26
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 26
- 239000011777 magnesium Substances 0.000 claims abstract description 26
- 239000003929 acidic solution Substances 0.000 claims abstract description 21
- 150000001408 amides Chemical class 0.000 claims abstract description 17
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 15
- BEBCJVAWIBVWNZ-UHFFFAOYSA-N glycinamide Chemical class NCC(N)=O BEBCJVAWIBVWNZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 7
- 238000000638 solvent extraction Methods 0.000 claims abstract description 7
- UMMQVDUMUMBTAV-YFKPBYRVSA-N (2s)-2-amino-3-(1h-imidazol-5-yl)propanamide Chemical class NC(=O)[C@@H](N)CC1=CN=CN1 UMMQVDUMUMBTAV-YFKPBYRVSA-N 0.000 claims abstract description 5
- PMLJIHNCYNOQEQ-REOHCLBHSA-N L-aspartic 1-amide Chemical class NC(=O)[C@@H](N)CC(O)=O PMLJIHNCYNOQEQ-REOHCLBHSA-N 0.000 claims abstract description 5
- HKXLAGBDJVHRQG-YFKPBYRVSA-N L-lysinamide Chemical class NCCCC[C@H](N)C(N)=O HKXLAGBDJVHRQG-YFKPBYRVSA-N 0.000 claims abstract description 5
- 239000000243 solution Substances 0.000 claims description 19
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 18
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 10
- 229910000480 nickel oxide Inorganic materials 0.000 claims description 6
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 9
- -1 2-halogenated acetyl halide Chemical class 0.000 description 14
- 230000003472 neutralizing effect Effects 0.000 description 14
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 12
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 12
- 239000003960 organic solvent Substances 0.000 description 12
- 239000007864 aqueous solution Substances 0.000 description 11
- VJLDTOPHCSPHKF-UHFFFAOYSA-N 2-(2-amino-2-oxoethoxy)-2-octyldecanoic acid Chemical compound CCCCCCCCC(C(O)=O)(OCC(N)=O)CCCCCCCC VJLDTOPHCSPHKF-UHFFFAOYSA-N 0.000 description 9
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 239000002253 acid Substances 0.000 description 8
- 239000002244 precipitate Substances 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- 239000004471 Glycine Substances 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 7
- 230000002378 acidificating effect Effects 0.000 description 7
- 239000007788 liquid Substances 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000012074 organic phase Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 238000003786 synthesis reaction Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000005481 NMR spectroscopy Methods 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 239000008346 aqueous phase Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 4
- 239000000284 extract Substances 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical class OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000002386 leaching Methods 0.000 description 3
- 229910017604 nitric acid Inorganic materials 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 229910052761 rare earth metal Inorganic materials 0.000 description 3
- 238000005201 scrubbing Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- DLFVBJFMPXGRIB-UHFFFAOYSA-N thioacetamide Natural products CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 3
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 150000001412 amines Chemical group 0.000 description 2
- 239000010432 diamond Substances 0.000 description 2
- LAWOZCWGWDVVSG-UHFFFAOYSA-N dioctylamine Chemical compound CCCCCCCCNCCCCCCCC LAWOZCWGWDVVSG-UHFFFAOYSA-N 0.000 description 2
- 238000000921 elemental analysis Methods 0.000 description 2
- 238000002354 inductively-coupled plasma atomic emission spectroscopy Methods 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- KDXKERNSBIXSRK-UHFFFAOYSA-N lysine Chemical group NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 2
- 238000010534 nucleophilic substitution reaction Methods 0.000 description 2
- 238000010979 pH adjustment Methods 0.000 description 2
- 230000001376 precipitating effect Effects 0.000 description 2
- 150000002910 rare earth metals Chemical class 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- WBZVQGYKIVWFGQ-UHFFFAOYSA-N 2-(2-amino-2-oxoethoxy)acetic acid Chemical group NC(=O)COCC(O)=O WBZVQGYKIVWFGQ-UHFFFAOYSA-N 0.000 description 1
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- GTLDINRZFOGPQE-UHFFFAOYSA-N 2-chloro-n,n-bis(2-ethylhexyl)acetamide Chemical compound CCCCC(CC)CN(C(=O)CCl)CC(CC)CCCC GTLDINRZFOGPQE-UHFFFAOYSA-N 0.000 description 1
- SAIKULLUBZKPDA-UHFFFAOYSA-N Bis(2-ethylhexyl) amine Chemical compound CCCCC(CC)CNCC(CC)CCCC SAIKULLUBZKPDA-UHFFFAOYSA-N 0.000 description 1
- VGCXGMAHQTYDJK-UHFFFAOYSA-N Chloroacetyl chloride Chemical compound ClCC(Cl)=O VGCXGMAHQTYDJK-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical group OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 1
- 239000004472 Lysine Chemical group 0.000 description 1
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 235000003704 aspartic acid Nutrition 0.000 description 1
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Chemical group OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000012295 chemical reaction liquid Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012024 dehydrating agents Substances 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- HNDVDQJCIGZPNO-UHFFFAOYSA-N histidine Natural products OC(=O)C(N)CC1=CN=CN1 HNDVDQJCIGZPNO-UHFFFAOYSA-N 0.000 description 1
- 125000000487 histidyl group Chemical group [H]N([H])C(C(=O)O*)C([H])([H])C1=C([H])N([H])C([H])=N1 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910001710 laterite Inorganic materials 0.000 description 1
- 239000011504 laterite Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229940094933 n-dodecane Drugs 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- JKMQHCSHMVCWED-UHFFFAOYSA-N oxalic acid;scandium Chemical compound [Sc].OC(=O)C(O)=O JKMQHCSHMVCWED-UHFFFAOYSA-N 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- DVMZCYSFPFUKKE-UHFFFAOYSA-K scandium chloride Chemical compound Cl[Sc](Cl)Cl DVMZCYSFPFUKKE-UHFFFAOYSA-K 0.000 description 1
- HYXGAEYDKFCVMU-UHFFFAOYSA-N scandium oxide Chemical compound O=[Sc]O[Sc]=O HYXGAEYDKFCVMU-UHFFFAOYSA-N 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229940086542 triethylamine Drugs 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C237/00—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups
- C07C237/02—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atoms of the carboxamide groups bound to acyclic carbon atoms of the carbon skeleton
- C07C237/04—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atoms of the carboxamide groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated
- C07C237/06—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atoms of the carboxamide groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated having the nitrogen atoms of the carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/28—Amines
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/32—Carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/40—Mixtures
- C22B3/402—Mixtures of acyclic or carbocyclic compounds of different types
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B59/00—Obtaining rare earth metals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Geology (AREA)
- Manufacturing & Machinery (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Metallurgy (AREA)
- Environmental & Geological Engineering (AREA)
- Geochemistry & Mineralogy (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Extraction Or Liquid Replacement (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2012056134A JP5367862B2 (ja) | 2012-03-13 | 2012-03-13 | スカンジウム抽出剤およびこの抽出剤を用いたスカンジウム抽出方法 |
| JP2012-056134 | 2012-03-13 | ||
| PCT/JP2013/054419 WO2013136941A1 (ja) | 2012-03-13 | 2013-02-21 | スカンジウム抽出方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2837834A1 CA2837834A1 (en) | 2013-09-19 |
| CA2837834C true CA2837834C (en) | 2015-02-17 |
Family
ID=49160859
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2837834A Expired - Fee Related CA2837834C (en) | 2012-03-13 | 2013-02-21 | Scandium extraction method |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US9481638B2 (enExample) |
| EP (1) | EP2712940B1 (enExample) |
| JP (1) | JP5367862B2 (enExample) |
| CN (1) | CN103764857B (enExample) |
| AU (1) | AU2013233618B2 (enExample) |
| CA (1) | CA2837834C (enExample) |
| PH (1) | PH12013502500A1 (enExample) |
| WO (1) | WO2013136941A1 (enExample) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5367862B2 (ja) | 2012-03-13 | 2013-12-11 | 国立大学法人九州大学 | スカンジウム抽出剤およびこの抽出剤を用いたスカンジウム抽出方法 |
| JP5398885B1 (ja) | 2012-08-20 | 2014-01-29 | 国立大学法人九州大学 | ガリウム抽出方法 |
| JP5734268B2 (ja) | 2012-12-12 | 2015-06-17 | 国立大学法人九州大学 | ニッケル抽出方法 |
| JP5595554B1 (ja) * | 2013-03-18 | 2014-09-24 | 国立大学法人九州大学 | ニッケル、コバルト及び／又はスカンジウムを含有する酸性溶液から不純物を分離する方法 |
| US10030286B1 (en) * | 2013-11-13 | 2018-07-24 | Ii-Vi Incorporated | Method of direct solvent extraction of rare earth metals from an aqueous acid-leached ore slurry |
| JP2015166303A (ja) * | 2014-02-17 | 2015-09-24 | 学校法人 関西大学 | スカンジウムの分離方法 |
| JP6053724B2 (ja) | 2014-06-26 | 2016-12-27 | 国立大学法人九州大学 | イオン交換樹脂及び金属の吸着分離方法 |
| AU2015310078A1 (en) * | 2014-08-26 | 2017-02-02 | Ishihara Sangyo Kaisha, Ltd. | Method for separating scandium |
| JP6194867B2 (ja) * | 2014-09-10 | 2017-09-13 | 信越化学工業株式会社 | 抽出分離方法 |
| JP5940688B1 (ja) | 2015-01-20 | 2016-06-29 | 国立大学法人九州大学 | ジルコニウム抽出剤及びジルコニウム抽出方法 |
| EP4104923A1 (en) | 2015-10-30 | 2022-12-21 | II-VI Incorporated | Composite extractant for extracting rare earth metals from an acid-leaching slurry or an acid-leaching solution |
| US10808296B2 (en) | 2015-10-30 | 2020-10-20 | Ii-Vi Delaware, Inc. | Selective recovery of rare earth metals from an acidic slurry or acidic solution |
| JP6693647B2 (ja) * | 2015-11-25 | 2020-05-13 | 国立研究開発法人日本原子力研究開発機構 | 金属元素の分離方法 |
| JP6406234B2 (ja) * | 2015-12-16 | 2018-10-17 | 住友金属鉱山株式会社 | スカンジウムの回収方法 |
| JP6409791B2 (ja) * | 2016-02-05 | 2018-10-24 | 住友金属鉱山株式会社 | スカンジウム回収方法 |
| JP6528707B2 (ja) * | 2016-03-14 | 2019-06-12 | 住友金属鉱山株式会社 | スカンジウム精製方法 |
| AU2018370142A1 (en) * | 2017-11-17 | 2020-05-14 | Ii-Vi Delaware, Inc. | Selective recovery of rare earth metals from an acidic slurry or acidic solution |
| CN114957029B (zh) * | 2022-04-11 | 2024-08-09 | 厦门稀土材料研究所 | 一种萃取剂的制备方法及应用 |
| CN115677528B (zh) * | 2022-11-03 | 2025-02-25 | 厦门稀土材料研究所 | 一种分离铼和锝的方法 |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2876152B2 (ja) * | 1990-06-19 | 1999-03-31 | 三井サイテック株式会社 | 希土類金属の分離精製法 |
| JP2514588B2 (ja) | 1992-10-05 | 1996-07-10 | 日本ポットクリーナー販売株式会社 | 換気用フィルタ |
| JP3307204B2 (ja) | 1995-11-22 | 2002-07-24 | 大平洋金属株式会社 | レアーアースメタルの濃縮分離回収方法 |
| JP3428292B2 (ja) * | 1996-04-26 | 2003-07-22 | 大平洋金属株式会社 | Ｓｃ金属の回収方法 |
| EP0834581A1 (en) | 1996-09-30 | 1998-04-08 | Basf Aktiengesellschaft | Use of hydrocarbon-soluble aminomethylenephosphonic acid derivatives for the solvent extraction of metal ions from aqueous solutions |
| JP3806258B2 (ja) | 1999-01-21 | 2006-08-09 | 同和鉱業株式会社 | Ｇａ，Ｉｎの溶媒抽出方法 |
| JP3385997B2 (ja) | 1999-02-12 | 2003-03-10 | 大平洋金属株式会社 | 酸化鉱石から有価金属を回収する方法 |
| JP3430973B2 (ja) | 1999-04-26 | 2003-07-28 | 大平洋金属株式会社 | 酸化鉱石からニッケルとスカンジウムを回収する方法 |
| US20050124765A1 (en) | 2003-11-25 | 2005-06-09 | Japan Atomic Energy Research Institute | Adsorbent for recovering useful rare metals by adsorption |
| JP5035788B2 (ja) * | 2006-06-06 | 2012-09-26 | 独立行政法人日本原子力研究開発機構 | 希土類金属の抽出剤と抽出方法 |
| CN101519427B (zh) | 2008-02-29 | 2015-02-25 | 中国人民解放军军事医学科学院毒物药物研究所 | 具有内皮素受体拮抗活性的肽类衍生物及其药物组合物和用途 |
| JP5504575B2 (ja) | 2008-04-21 | 2014-05-28 | 国立大学法人 宮崎大学 | ホスフィン酸を配位子とするキレート抽出剤 |
| JP5326610B2 (ja) | 2009-02-02 | 2013-10-30 | 住友金属鉱山株式会社 | 使用済みニッケル水素電池からの金属の回収方法 |
| AU2010202408B2 (en) * | 2009-06-17 | 2014-12-18 | Shin-Etsu Chemical Co., Ltd. | Method for extracting and separating rare earth elements |
| JP5679159B2 (ja) | 2010-07-05 | 2015-03-04 | 信越化学工業株式会社 | 希土類金属抽出剤の合成方法、及び希土類金属の溶媒抽出用有機相 |
| JP5487506B2 (ja) * | 2010-07-05 | 2014-05-07 | 信越化学工業株式会社 | 希土類金属抽出剤の合成方法 |
| JP5761663B2 (ja) | 2010-11-12 | 2015-08-12 | 国立大学法人 宮崎大学 | アルキルアミノリン化合物及び金属抽出剤 |
| PH12013501714A1 (en) | 2011-11-09 | 2015-10-16 | Univ Kyushu Nat Univ Corp | Cobalt extraction method |
| JP5279942B1 (ja) | 2011-11-09 | 2013-09-04 | 国立大学法人九州大学 | コバルト抽出方法 |
| JP5279938B1 (ja) * | 2011-11-09 | 2013-09-04 | 国立大学法人九州大学 | 有価金属抽出剤及びこの抽出剤を用いた有価金属抽出方法 |
| JP5367862B2 (ja) | 2012-03-13 | 2013-12-11 | 国立大学法人九州大学 | スカンジウム抽出剤およびこの抽出剤を用いたスカンジウム抽出方法 |
| JP5734268B2 (ja) | 2012-12-12 | 2015-06-17 | 国立大学法人九州大学 | ニッケル抽出方法 |
| JP5595554B1 (ja) | 2013-03-18 | 2014-09-24 | 国立大学法人九州大学 | ニッケル、コバルト及び／又はスカンジウムを含有する酸性溶液から不純物を分離する方法 |
-
2012
- 2012-03-13 JP JP2012056134A patent/JP5367862B2/ja active Active
-
2013
- 2013-02-21 WO PCT/JP2013/054419 patent/WO2013136941A1/ja not_active Ceased
- 2013-02-21 CN CN201380002904.1A patent/CN103764857B/zh not_active Expired - Fee Related
- 2013-02-21 AU AU2013233618A patent/AU2013233618B2/en not_active Ceased
- 2013-02-21 CA CA2837834A patent/CA2837834C/en not_active Expired - Fee Related
- 2013-02-21 PH PH1/2013/502500A patent/PH12013502500A1/en unknown
- 2013-02-21 US US14/130,283 patent/US9481638B2/en not_active Expired - Fee Related
- 2013-02-21 EP EP13761717.1A patent/EP2712940B1/en not_active Not-in-force
Also Published As
| Publication number | Publication date |
|---|---|
| AU2013233618A1 (en) | 2014-01-30 |
| CA2837834A1 (en) | 2013-09-19 |
| PH12013502500A1 (en) | 2014-01-20 |
| US9481638B2 (en) | 2016-11-01 |
| EP2712940A4 (en) | 2014-11-12 |
| EP2712940B1 (en) | 2016-02-17 |
| WO2013136941A1 (ja) | 2013-09-19 |
| EP2712940A1 (en) | 2014-04-02 |
| AU2013233618B2 (en) | 2016-03-03 |
| CN103764857B (zh) | 2016-05-18 |
| JP5367862B2 (ja) | 2013-12-11 |
| CN103764857A (zh) | 2014-04-30 |
| JP2013189675A (ja) | 2013-09-26 |
| US20140377150A1 (en) | 2014-12-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2837834C (en) | Scandium extraction method | |
| EP2592068B1 (en) | Method for synthesizing rare earth metal extractant | |
| CA2745229C (en) | Synthesis of rare earth metal extractant | |
| AU2017213939B2 (en) | Method for recovering scandium | |
| US9404169B2 (en) | Method for recovering scandium | |
| CA2745228C (en) | Synthesis of rare earth metal extractant | |
| CA3017299C (en) | Scandium purification method | |
| WO2014030395A1 (ja) | ガリウム抽出剤及びガリウム抽出方法 | |
| JP5420033B1 (ja) | インジウム抽出剤およびこの抽出剤を用いたインジウム抽出方法 | |
| JP5442080B2 (ja) | 有価金属分離方法 | |
| WO2016117175A1 (ja) | ジルコニウム抽出剤及びジルコニウム抽出方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request |
Effective date: 20131129 |
|
| MKLA | Lapsed |
Effective date: 20220221 |