CA2798296C - Flexible pvc compositions made with plasticizers derived from renewable sources - Google Patents

Flexible pvc compositions made with plasticizers derived from renewable sources Download PDF

Info

Publication number
CA2798296C
CA2798296C CA2798296A CA2798296A CA2798296C CA 2798296 C CA2798296 C CA 2798296C CA 2798296 A CA2798296 A CA 2798296A CA 2798296 A CA2798296 A CA 2798296A CA 2798296 C CA2798296 C CA 2798296C
Authority
CA
Canada
Prior art keywords
composition
acetylated
weight percent
epoxidized
biochemical
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CA2798296A
Other languages
English (en)
French (fr)
Other versions
CA2798296A1 (en
Inventor
Bharat I. Chaudhary
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Global Technologies LLC
Original Assignee
Dow Global Technologies LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies LLC filed Critical Dow Global Technologies LLC
Publication of CA2798296A1 publication Critical patent/CA2798296A1/en
Application granted granted Critical
Publication of CA2798296C publication Critical patent/CA2798296C/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0016—Plasticisers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/101—Esters; Ether-esters of monocarboxylic acids
    • C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/15—Heterocyclic compounds having oxygen in the ring
    • C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
    • C08K5/1515—Three-membered rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or halogen-containing compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/443—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or halogen-containing compounds
    • C08L23/286—Chlorinated polyethene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)
CA2798296A 2010-05-10 2011-05-04 Flexible pvc compositions made with plasticizers derived from renewable sources Active CA2798296C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US33284810P 2010-05-10 2010-05-10
US61/332,848 2010-05-10
PCT/US2011/035143 WO2011143028A1 (en) 2010-05-10 2011-05-04 Flexible pvc compositions made with plasticizers derived from renewable sources

Publications (2)

Publication Number Publication Date
CA2798296A1 CA2798296A1 (en) 2011-11-17
CA2798296C true CA2798296C (en) 2016-12-13

Family

ID=44359741

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2798296A Active CA2798296C (en) 2010-05-10 2011-05-04 Flexible pvc compositions made with plasticizers derived from renewable sources

Country Status (10)

Country Link
US (1) US8697787B2 (enExample)
EP (1) EP2569371B1 (enExample)
JP (1) JP5797260B2 (enExample)
KR (1) KR101825239B1 (enExample)
CN (1) CN102985481A (enExample)
BR (1) BR112012028732B1 (enExample)
CA (1) CA2798296C (enExample)
MX (1) MX2012013102A (enExample)
TW (1) TW201204780A (enExample)
WO (1) WO2011143028A1 (enExample)

Families Citing this family (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX2010008963A (es) 2008-02-15 2011-02-24 Union Carbide Chem Plastic Sistema plastificante de reemplazo para formulaciones plastificadas con ftalato.
US8802988B2 (en) 2009-09-30 2014-08-12 Dow Global Technologies Llc Acetylated derivatives of castor oil and their blends with epoxidized fatty acid esters
JP5693589B2 (ja) 2009-09-30 2015-04-01 ダウ グローバル テクノロジーズ エルエルシー １２−ヒドロキシステアリン酸のアセチル化グリセリドおよびエポキシ化脂肪酸エステルとのブレンド
CA2775975C (en) 2009-09-30 2016-11-08 Dow Global Technologies Llc Heat stabilized polymeric composition with epoxidized fatty acid ester plasticizer
US8552098B2 (en) 2009-09-30 2013-10-08 Dow Global Technologies Llc Purified acetylated derivatives of castor oil and compositions including same
CN102985481A (zh) 2010-05-10 2013-03-20 陶氏环球技术有限责任公司 由源自可再生资源的增塑剂制备的挠性pvc组合物
EP2571935B1 (en) * 2010-05-21 2014-12-17 Dow Global Technologies LLC Thermoplastic compositions and formed articles thereof
TW201209168A (en) 2010-07-28 2012-03-01 Dow Global Technologies Llc Plasticizers made from oil extracted from microorganisms and polar polymeric compositions comprising the same
US9034965B2 (en) * 2010-08-06 2015-05-19 Arkema Inc. Epoxidized composition and methods for making the same
US9056965B2 (en) * 2011-09-30 2015-06-16 Dow Global Technologies Llc Process for mixing polyvinyl chloride with a bio-based plasticizer
JP2014534985A (ja) * 2011-09-30 2014-12-25 ダウ グローバル テクノロジーズ エルエルシー 熱老化中の色保持を目的とした可塑剤
JP6151260B2 (ja) * 2011-10-14 2017-06-21 ガラタ ケミカルズ，エルエルシー 再生可能原料から誘導される可塑剤
MX357165B (es) * 2012-02-08 2018-06-28 Dow Global Technologies Llc Composiciones de plastificante y metodos para fabricar composiciones de plastificante.
WO2013148255A1 (en) 2012-03-30 2013-10-03 3M Innovative Properties Company Compositions containing tetrahydrofurfuryl and/or alkyl-substituted tetrahydrofurfuryl esters of citric acid
CN104379653B (zh) 2012-06-22 2017-07-18 陶氏环球技术有限责任公司 乙酰化多元醇羟基硬脂酸酯增塑剂和经增塑的聚合物组合物
EP2864406B1 (en) * 2012-06-26 2017-03-08 Dow Global Technologies LLC Plasticizers and plasticized polymeric compositions
MX370205B (es) 2012-10-18 2019-12-05 Dow Global Technologies Llc Plastificantes de alquil esteres de acidos grasos epoxidados y metodos para hacer plastificantes de alquil esteres de acidos grasos epoxidados.
JP6189967B2 (ja) 2012-11-12 2017-08-30 ダウ グローバル テクノロジーズ エルエルシー エポキシ化脂肪酸アルキルエステルを作製するための方法
KR102017370B1 (ko) 2012-11-12 2019-09-02 다우 글로벌 테크놀로지스 엘엘씨 에폭시화 지방산 알킬 에스테르 가소제 및 에폭시화 지방산 알킬 에스테르 가소제의 제조 방법
EP2738774A1 (en) * 2012-11-30 2014-06-04 Borealis AG A cable construction
CN110256857B (zh) * 2012-12-29 2022-01-04 美国圣戈班性能塑料公司 柔性管
WO2014163871A1 (en) * 2013-03-11 2014-10-09 Dow Global Technologies Llc Synergistic blends of calcium carbonate and calcined clay
CA2904869C (en) * 2013-03-15 2021-02-16 Dow Global Technologies Llc Epoxidized-fatty-acid-alkyl-ester plasticizers from natural-oil soap stock and methods for making such epoxidized-fatty-acid-alkyl-ester plasticizers
CN103214766B (zh) * 2013-04-26 2015-06-17 开平市宝来塑胶制品有限公司 一种耐磨耐老化pvc增强软管及其制备方法
JP6524105B2 (ja) * 2013-10-02 2019-06-05 ダウ グローバル テクノロジーズ エルエルシー 生物可塑剤及び可塑化ポリマー組成物
US9346939B2 (en) * 2013-11-01 2016-05-24 Galata Chemicals Llc Flexible PVC compounds having a low metals content
US10087346B2 (en) 2014-05-13 2018-10-02 Magink Comérico Imagem Gráfica Ltda.—Me Dispersion of homopolymer of vinyl chloride
CN104140617A (zh) * 2014-08-07 2014-11-12 安徽玉发塑业有限公司 一种耐老化pvc管材及其制备方法
CN104292686A (zh) * 2014-09-04 2015-01-21 六安市顺达塑业有限公司 一种耐磨损pvc管材及其制备方法
SE539458C2 (en) * 2014-09-15 2017-09-26 Perstorp Ab A highly stable plasticized polyvinyl halide composition comprising pentaerythritoltetravalerate and an epoxidized unsaturated fatty acid ester.
DK3006491T3 (en) 2014-10-08 2017-02-27 Armacell Entpr Gmbh & Co Kg Flexible insulation foam with low smoke generation
EP3279283A4 (en) * 2015-04-01 2018-12-26 Nitto Denko Corporation Adhesive tape
ES2987487T3 (es) 2015-10-13 2024-11-15 Bmi Group Danmark Aps Elemento de sellado
JP2017078100A (ja) * 2015-10-19 2017-04-27 三井化学株式会社 樹脂組成物、該組成物からなる成形体およびパイプ
DK3665010T3 (da) 2017-08-07 2024-09-30 Transcendia Inc Flerlagsfilm til stomiposer
AU2018369626C1 (en) 2017-11-14 2024-08-08 Avery Dennison Corporation PVC compositions, films, laminates and related methods
JP7650862B2 (ja) 2019-08-29 2025-03-25 ダウ グローバル テクノロジーズ エルエルシー ポリ塩化ビニル固体と添加剤との均一混合物を作製する方法
WO2021041497A1 (en) 2019-08-29 2021-03-04 Dow Global Technologies Llc Method of making a homogeneous mixture of polyolefin solids and liquid additive
KR102506279B1 (ko) * 2020-07-01 2023-03-03 한화솔루션 주식회사 가소제 조성물, 및 이를 포함하는 염화비닐 수지 조성물
CN113648451A (zh) * 2021-08-19 2021-11-16 青岛大学 一种新型α-氰基丙烯酸酯类医用粘合剂及其制备方法
KR102615316B1 (ko) * 2023-01-12 2023-12-19 유상근 재생 원료를 활용한 pvc 시트 및 이의 제조 방법
WO2025128797A1 (en) 2023-12-13 2025-06-19 Blue Evolution, Inc Ecofriendly, biodegradable biological polysaccharide composition for packaging materials

Family Cites Families (112)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR499931A (fr) 1917-12-08 1920-02-26 Twitchell Process C Sulfonate de métaux alcalins et son procédé de fabrication
US2397592A (en) 1940-08-02 1946-04-02 Gen Cable Corp Resinous compositions for wire coatings and the like
US2403215A (en) 1943-10-14 1946-07-02 Du Pont Resinous compositions and electrical conductors insulated therewith
US2500918A (en) 1945-08-10 1950-03-14 Goodrich Co B F Acylation of hydroxylated esters
US2458484A (en) 1946-06-17 1949-01-04 Gen Mills Inc Process of preparing epoxy derivatives from unsaturated aliphatic compounds
US2666752A (en) 1950-01-17 1954-01-19 Sherwin Williams Co Stabilizer for halogen-containing polymers
US2618622A (en) 1950-01-17 1952-11-18 Sherwin Williams Co Plasticizer for vinyl halides
GB790314A (en) 1955-02-23 1958-02-05 Lankro Chem Ltd New derivatives or acetylated castor oil and esters of acetylated ricinoleic acid, and polymers plasticised therewith
GB934689A (en) 1959-04-22 1963-08-21 Swift & Co Epoxy fatty acid esters and polyvinyl resin compositions containing them
NL131832C (enExample) 1959-11-12
US3138566A (en) 1960-01-08 1964-06-23 Gen Mills Inc Fluid resins prepared from epoxidized unsaturated fatty acids or esters
BE647338A (enExample) 1963-05-01 1964-10-30
FR1437722A (fr) * 1964-04-03 1966-05-06 Allied Chem Compositions à base de polymères vinyliques servant de revêtement du sol
US3409580A (en) 1964-05-01 1968-11-05 Ethyl Corp Polyvinyl halide plastisols containing cyclohexyl amines and cellular products therefrom
NL127901C (enExample) 1966-02-10
US3639318A (en) 1968-05-29 1972-02-01 Union Carbide Corp Plasticized polyvinyl chloride film
DE2009047C2 (de) 1970-02-26 1982-04-08 Degussa Ag, 6000 Frankfurt Verfahren zur Herstellung von Epoxystearinsäureestern
DE2021530A1 (de) 1970-05-02 1971-11-25 Henkel & Cie Gmbh Verfahren zur Herstellung von Oxyfettsaeureestern
US3891694A (en) 1970-05-18 1975-06-24 Monsanto Co Plasticizer purification
US3668091A (en) 1971-02-02 1972-06-06 Ashland Oil Inc Ultraviolet light bleaching of carboxylic acid esters and epoxy compounds
US3712875A (en) 1971-02-22 1973-01-23 Union Carbide Corp Synergistic additive system for anti-fog vinyl film
US3780140A (en) 1971-08-06 1973-12-18 Du Pont Ethylene/carbon monoxide polymer compositions
US3868341A (en) 1972-06-02 1975-02-25 Western Electric Co Clear flame retardant composition
GB1415770A (en) 1972-09-18 1975-11-26 Tenneco Chem Falme-retardant phosphate esters and flame retardant resinous compositions
US3872187A (en) 1972-09-18 1975-03-18 Tenneco Chem Aryloxyalkyl haloalkyl phosphates
US4083816A (en) * 1976-06-25 1978-04-11 The United States Of America As Represented By The Secretary Of Agriculture Acetoxymethyl derivatives of polyunsaturated fatty triglycerides as primary plasticizers for polyvinylchloride
DE2652328A1 (de) 1976-11-17 1978-05-18 Neynaber Chemie Gmbh Bleiverbindungen enthaltende stabilisator-gleitmittel-kombination fuer formmassen auf basis von polyvinylchlorid
US4346145A (en) 1981-01-05 1982-08-24 Western Electric Co., Inc. Coating composition and coated articles
DE3125376A1 (de) * 1981-06-27 1983-01-13 Hoechst Ag, 6000 Frankfurt Thermoplastische formmassen auf der basis von vinylchloridpolymerisaten und schlagzaehmodifizierungspolymeren
JPS5832647A (ja) * 1981-08-21 1983-02-25 Riken Vitamin Co Ltd 熱可塑性樹脂組成物
US4613533A (en) 1982-07-01 1986-09-23 E. I. Du Pont De Nemours And Company Thermoplastic elastomeric compositions based on compatible blends of an ethylene copolymer and vinyl or vinylidene halide polymer
US4627993A (en) 1982-07-01 1986-12-09 E. I. Du Pont De Nemours And Company Thermoplastic elastomeric compositions based on compatible blends of an ethylene copolymer and vinyl or vinylidene halide polymer
DE3326455A1 (de) 1983-07-22 1985-01-31 Henkel Kgaa Kosmetisch-pharmazeutische oelkomponenten
JPS6133661A (ja) 1984-02-02 1986-02-17 テルモ株式会社 医療用器具
US4556694A (en) 1984-07-26 1985-12-03 E. I. Du Pont De Nemours And Company Low temperature flexible PVC blends
DE3503383A1 (de) 1985-02-01 1986-08-07 Hoechst Ag, 6230 Frankfurt Folie auf basis von vinylchloridpolymerisat und ihre verwendung zur herstellung steifer rohrfoermiger koerper
US4670494A (en) * 1985-07-30 1987-06-02 Gary Chemical Corp. Flame retardant low smoke poly(vinyl chloride) thermoplastic composition
US4605694A (en) 1985-10-31 1986-08-12 Hercules Incorporated Plasticizing compositions for polyvinylchloride
US4857600A (en) 1988-05-23 1989-08-15 Union Carbide Corporation Process for grafting diacid anhydrides
US5036121A (en) * 1988-09-06 1991-07-30 The B. F. Goodrich Company Flame and smoke retardant cable insulation and jacketing compositions
AU610013B2 (en) 1988-09-09 1991-05-09 B.F. Goodrich Company, The Flexible blend compositions based on overpolymers of vinyl chloride polymers on ethylene copolymers
JPH0354233A (ja) 1989-04-19 1991-03-08 Furukawa Electric Co Ltd:The 複合難燃剤およびそれを含有する難燃性樹脂組成物
HU209937B (en) 1989-05-04 1994-12-28 Du Pont Polyvinyl chloride composition and calendered sheet prepared from it
US5225108A (en) 1990-05-18 1993-07-06 Witco Corporation Polymer stabilizer and polymer composition stabililzed therewith
AU8025991A (en) 1990-07-20 1992-01-23 B.F. Goodrich Company, The Improved barrier pvc resins, compounds and articles derived therefrom
JPH04261452A (ja) 1991-02-15 1992-09-17 Asahi Denka Kogyo Kk 農業用塩化ビニル系樹脂組成物
US5246783A (en) 1991-08-15 1993-09-21 Exxon Chemical Patents Inc. Electrical devices comprising polymeric insulating or semiconducting members
US5227417A (en) 1992-01-24 1993-07-13 Cooper Industries, Inc. Polyvinyl chloride based plenum cable
US5484844A (en) * 1992-04-14 1996-01-16 Mitsubishi Chemical Mkv Company Vinyl chloride resin elastomer composition
JPH07508066A (ja) 1992-05-19 1995-09-07 クロンプトン・コーポレーション 鉛ではない安定剤を用いて安定化した電気絶縁用の塩化ビニル樹脂組成物
US5466267A (en) 1992-09-17 1995-11-14 Mobil Oil Corporation Oligomeric/polymeric multifunctional additives to improve the low-temperature properties of distillate fuels
US5454806A (en) 1992-11-06 1995-10-03 Terumo Kabushiki Kaisha Medical device
JPH06168629A (ja) * 1992-11-27 1994-06-14 Hitachi Cable Ltd 電線・ケーブル
US5270366A (en) 1992-12-16 1993-12-14 Vista Chemical Company Lead stabilized, flexible polymeric blends containing polyvinylchloride
US5886072A (en) 1993-05-24 1999-03-23 Teknor Apex Company Flame retardant composition
US5430108A (en) 1994-01-14 1995-07-04 Exxon Chemical Patents Inc. Polyol ester PVC plasticizers
US5495033A (en) 1994-08-29 1996-02-27 Cenex/Land O'lakes Agronomy Company Methylated herbicidal adjuvant
US5464903A (en) 1994-10-31 1995-11-07 E. I. Du Pont De Nemours And Company Process for preparing ethylene copolymer plasticized PVC
US5575965A (en) 1995-05-19 1996-11-19 Union Carbide Chemicals & Plastics Technology Corporation Process for extrusion
JP3036405B2 (ja) * 1995-06-14 2000-04-24 三菱化学エムケーブイ株式会社 塩化ビニル系樹脂組成物
US6063846A (en) 1997-05-30 2000-05-16 Teknor Apex Company Polyvinyl chloride compositions
US6114425A (en) 1997-07-17 2000-09-05 Unitex Chemical Corporation Plasticized polyvinyl chloride compound
US6274750B1 (en) 1998-07-21 2001-08-14 Cognis Corporation Dimer and trimer acid esters from epoxidized compounds and methods for their preparation
BR9917230A (pt) 1999-04-21 2002-01-08 Basf Ag Mistura de diésteres de nonanol isomérico de um ácido dicarboxìlico, e, uso da mesma
JP2000319468A (ja) 1999-05-07 2000-11-21 Asahi Denka Kogyo Kk 塩化ビニル系樹脂用安定剤組成物
US6496629B2 (en) 1999-05-28 2002-12-17 Tycom (Us) Inc. Undersea telecommunications cable
GB9919683D0 (en) * 1999-08-19 1999-10-20 Danisco Composition
DK1624014T3 (da) 1999-08-19 2010-01-11 Danisco Specifikke acylerede glycerolforbindelser som blödgöringsmidler i polymerer og fremgangsmåde til deres fremstilling
US6949597B2 (en) 1999-08-19 2005-09-27 Danisco A/S Composition
US6608142B1 (en) 2000-05-08 2003-08-19 Teknor Apex Company Polyvinyl chloride compositions
US6797753B2 (en) * 2000-06-20 2004-09-28 Battelle Memorial Institute Plasticizers derived from vegetable oils
CN1341681A (zh) 2000-09-07 2002-03-27 苏州德威实业有限公司 用于电线电缆的软聚氯乙烯塑料
US6451958B1 (en) 2001-04-06 2002-09-17 Sartomer Technology Company Inc. Radiation curable acrylate-terminated polymers having polycarbonate repeating units
JP2003064233A (ja) 2001-08-27 2003-03-05 C I Kasei Co Ltd 農業用塩化ビニル系樹脂フィルム及び塩化ビニル系樹脂組成物
US6706815B2 (en) 2001-09-06 2004-03-16 Dupont Dow Elastomers L.L.C. Impact resistant rigid PVC compositions using hydrocarbon rubbers and chlorinated polyethylene as impact modifiers
US6849694B2 (en) 2002-01-17 2005-02-01 Dupont Dow Elastomers, Llc Impact modifier compositions for rigid PVC compositions of hydrocarbon rubbers and chlorinated polyethylene
US6714707B2 (en) 2002-01-24 2004-03-30 Alcatel Optical cable housing an optical unit surrounded by a plurality of gel layers
JP2003297149A (ja) 2002-04-04 2003-10-17 Fujikura Ltd 電気絶縁性ポリ塩化ビニル樹脂組成物
US6869985B2 (en) 2002-05-10 2005-03-22 Awi Licensing Company Environmentally friendly polylactide-based composite formulations
JP4204305B2 (ja) 2002-11-08 2009-01-07 株式会社Ａｄｅｋａ ポリエステル系可塑剤及び塩素含有樹脂組成物
WO2004052977A1 (en) 2002-12-06 2004-06-24 Cognis Brasil Ltda. Plasticized poly vinyl chloride compositions
US7015285B2 (en) 2002-12-18 2006-03-21 General Electric Composition and method for improving the adhesion of polyphenylene ether moldings to polyurethane foam
US20040122149A1 (en) 2002-12-19 2004-06-24 Kadakia Vishal S. Flame-retardant polyvinyl chloride compositions
JP2004311064A (ja) 2003-04-02 2004-11-04 Fujikura Ltd 直流電力ケーブル
JP4640753B2 (ja) 2003-12-08 2011-03-02 株式会社Adeka 塩化ビニル系樹脂組成物
FR2880892B1 (fr) 2005-01-17 2008-03-21 Gerflor Sa Utilisation d'acides gras esterifies comme plastifiants du pvc
DE102005031945A1 (de) 2005-07-08 2007-01-11 Construction Research & Technology Gmbh Verwendung von entfärbtem Biodiesel als Weichmacher
DE102005059143A1 (de) 2005-12-08 2007-06-14 J. S. Staedtler Gmbh & Co. Kg Modelliermasse sowie deren Verwendung
CN101108982A (zh) 2006-07-21 2008-01-23 时代环保能源集团（香港）投资有限公司 一种用生物柴油制取的塑料环保增塑剂
US20080086678A1 (en) 2006-08-11 2008-04-10 Business Helpers Incorporated System and method for preparing distributable multimedia presentations over the internet
JP5094109B2 (ja) 2006-12-22 2012-12-12 株式会社Ａｄｅｋａ 塩化ビニル系樹脂組成物
GB0700074D0 (en) 2007-01-03 2007-02-07 Danisco process
US20080227993A1 (en) 2007-03-17 2008-09-18 Matthew Mark Zuckerman Synthesizing and compounding molecules from and with plant oils to improve low temperature behavior of plant oils as fuels, oils and lubricants
CN100590188C (zh) 2007-05-22 2010-02-17 江阴市向阳科技有限公司 利用废弃油脂生产环氧增塑剂的方法
EP2223970B1 (en) 2007-11-28 2014-03-26 Adeka Corporation Stabilizer for chlorine-containing resins and chlorine -containing resin compositions
BRPI0705621B1 (pt) 2007-12-10 2019-04-09 Nexoleum Bioderivados Ltda. Composição plastificte de pvc
BRPI0705276A2 (pt) 2007-12-10 2009-08-11 Nexoleum Bioderivados Ltda plastificantes primários de pvc derivados de óleos vegetais, processo de obtenção de plastificantes primários de pvc derivados de oléos vegetais e composição de pvc plastificado
MX2010008963A (es) 2008-02-15 2011-02-24 Union Carbide Chem Plastic Sistema plastificante de reemplazo para formulaciones plastificadas con ftalato.
CN101544800A (zh) * 2008-05-23 2009-09-30 东莞市华立实业股份有限公司 一种环保封边条的配方
MX341364B (es) 2008-06-17 2016-08-18 Resinas Y Mat S A De C V Bioplastificantes o plastificantes oleoquimicos primarios, que a su vez actuan como estabilizadores termicos y de radiacion ultravioleta en resinas moldeables de pvc y proceso para obtencion de los mismos.
JP2010042669A (ja) 2008-07-16 2010-02-25 Daikin Ind Ltd フッ素ゴム積層体およびその製造方法
CN101367958B (zh) * 2008-09-28 2011-06-08 华南理工大学 环保型聚氯乙烯增塑剂及其制备方法
CN101591588A (zh) 2009-06-24 2009-12-02 江南大学 有机铼氧化物-过氧化脲催化制备环氧大豆油或环氧脂肪酸甲(乙)酯的方法
FR2950051B1 (fr) 2009-09-11 2012-08-03 Centre Nat Rech Scient Nouveau procede de preparation de polyols et produits tels qu'obtenus
US8802988B2 (en) 2009-09-30 2014-08-12 Dow Global Technologies Llc Acetylated derivatives of castor oil and their blends with epoxidized fatty acid esters
CN102666697B (zh) 2009-09-30 2015-01-07 陶氏环球技术有限责任公司 乙酰基化的聚甘油脂肪酸酯以及用其增塑的聚氯乙烯绝缘材料
US8552098B2 (en) * 2009-09-30 2013-10-08 Dow Global Technologies Llc Purified acetylated derivatives of castor oil and compositions including same
JP5693589B2 (ja) 2009-09-30 2015-04-01 ダウ グローバル テクノロジーズ エルエルシー １２−ヒドロキシステアリン酸のアセチル化グリセリドおよびエポキシ化脂肪酸エステルとのブレンド
CN101824193B (zh) 2010-02-24 2013-01-30 杭州高新橡塑材料股份有限公司 一种耐寒pvc电缆料及制备方法
CN102985481A (zh) 2010-05-10 2013-03-20 陶氏环球技术有限责任公司 由源自可再生资源的增塑剂制备的挠性pvc组合物
CN101914219B (zh) 2010-07-26 2012-09-05 江阴市向阳科技有限公司 一种复合环氧增塑剂的制备方法
WO2013003225A2 (en) 2011-06-29 2013-01-03 Dow Global Technologies Llc Vegetable-oil derived plasticizer

Also Published As

Publication number Publication date
EP2569371B1 (en) 2016-09-07
CA2798296A1 (en) 2011-11-17
US8697787B2 (en) 2014-04-15
EP2569371A1 (en) 2013-03-20
MX2012013102A (es) 2012-12-17
US20110272174A1 (en) 2011-11-10
JP2013526635A (ja) 2013-06-24
BR112012028732B1 (pt) 2020-04-07
WO2011143028A1 (en) 2011-11-17
TW201204780A (en) 2012-02-01
KR20130072217A (ko) 2013-07-01
KR101825239B1 (ko) 2018-02-02
BR112012028732A2 (pt) 2016-07-19
JP5797260B2 (ja) 2015-10-21
CN102985481A (zh) 2013-03-20

Similar Documents

Publication Publication Date Title
CA2798296C (en) Flexible pvc compositions made with plasticizers derived from renewable sources
US9181415B2 (en) Acetylated derivatives of castor oil and their blends with epoxidized fatty acid esters
US9481633B2 (en) Acetylated polyglycerine fatty acid ester and a PVC insulator plasticised therewith
KR101904554B1 (ko) 아세틸화 글리세린 에스테르 및 그의 에폭시드화 지방산 에스테르와의 블렌드
CA2775975A1 (en) Heat stabilized polymeric composition with epoxidized fatty acid ester plasticizer
CA2903335C (en) Synergistic blends of calcium carbonate and calcined clay
KR102094560B1 (ko) 가소제 및 가소화된 중합체 조성물
KR102254422B1 (ko) 바이오 가소제 및 가소된 폴리머 조성물
KR100742867B1 (ko) 에폭시계 도료에 대한 내성을 갖는 고분자수지 조성물 및이를 이용하여 제조된 고분자수지재
KR101843876B1 (ko) 케이블 구조물
KR20220113098A (ko) 가소제 조성물, 및 이를 포함하는 염화비닐계 수지 조성물

Legal Events

Date Code Title Description
EEER Examination request

Effective date: 20160504