CA2620152A1 - Hydrolysis resistant polyamide compositions, and articles formed therefrom - Google Patents
Hydrolysis resistant polyamide compositions, and articles formed therefrom Download PDFInfo
- Publication number
- CA2620152A1 CA2620152A1 CA002620152A CA2620152A CA2620152A1 CA 2620152 A1 CA2620152 A1 CA 2620152A1 CA 002620152 A CA002620152 A CA 002620152A CA 2620152 A CA2620152 A CA 2620152A CA 2620152 A1 CA2620152 A1 CA 2620152A1
- Authority
- CA
- Canada
- Prior art keywords
- acid
- polyamide composition
- carbon atoms
- copolyamide
- plasticizer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 49
- 239000004952 Polyamide Substances 0.000 title claims abstract description 40
- 229920002647 polyamide Polymers 0.000 title claims abstract description 40
- 230000007062 hydrolysis Effects 0.000 title abstract description 19
- 238000006460 hydrolysis reaction Methods 0.000 title abstract description 19
- 150000001412 amines Chemical class 0.000 claims abstract description 16
- 238000002844 melting Methods 0.000 claims abstract description 11
- 230000008018 melting Effects 0.000 claims abstract description 11
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 4
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims description 32
- 239000004014 plasticizer Substances 0.000 claims description 31
- 125000004432 carbon atom Chemical group C* 0.000 claims description 29
- -1 aliphatic diamine Chemical class 0.000 claims description 18
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 16
- IPRJXAGUEGOFGG-UHFFFAOYSA-N N-butylbenzenesulfonamide Chemical compound CCCCNS(=O)(=O)C1=CC=CC=C1 IPRJXAGUEGOFGG-UHFFFAOYSA-N 0.000 claims description 14
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 12
- HQHCYKULIHKCEB-UHFFFAOYSA-N tetradecanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCC(O)=O HQHCYKULIHKCEB-UHFFFAOYSA-N 0.000 claims description 9
- RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 claims description 8
- 239000000178 monomer Substances 0.000 claims description 8
- 125000002723 alicyclic group Chemical group 0.000 claims description 6
- 125000003118 aryl group Chemical group 0.000 claims description 6
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 claims description 6
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 claims description 6
- LWBHHRRTOZQPDM-UHFFFAOYSA-N undecanedioic acid Chemical compound OC(=O)CCCCCCCCCC(O)=O LWBHHRRTOZQPDM-UHFFFAOYSA-N 0.000 claims description 6
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims description 5
- 229920000305 Nylon 6,10 Polymers 0.000 claims description 5
- 125000001931 aliphatic group Chemical group 0.000 claims description 5
- 150000004984 aromatic diamines Chemical class 0.000 claims description 5
- 150000003951 lactams Chemical class 0.000 claims description 5
- 229940124530 sulfonamide Drugs 0.000 claims description 4
- QFGCFKJIPBRJGM-UHFFFAOYSA-N 12-[(2-methylpropan-2-yl)oxy]-12-oxododecanoic acid Chemical compound CC(C)(C)OC(=O)CCCCCCCCCCC(O)=O QFGCFKJIPBRJGM-UHFFFAOYSA-N 0.000 claims description 3
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 claims description 3
- 229960002255 azelaic acid Drugs 0.000 claims description 3
- 239000000314 lubricant Substances 0.000 claims description 3
- NATWUQFQFMZVMT-UHFFFAOYSA-N n-ethyl-2-methylbenzenesulfonamide Chemical compound CCNS(=O)(=O)C1=CC=CC=C1C NATWUQFQFMZVMT-UHFFFAOYSA-N 0.000 claims description 3
- OHPZPBNDOVQJMH-UHFFFAOYSA-N n-ethyl-4-methylbenzenesulfonamide Chemical compound CCNS(=O)(=O)C1=CC=C(C)C=C1 OHPZPBNDOVQJMH-UHFFFAOYSA-N 0.000 claims description 3
- 150000003456 sulfonamides Chemical group 0.000 claims description 3
- DXNCZXXFRKPEPY-UHFFFAOYSA-N tridecanedioic acid Chemical compound OC(=O)CCCCCCCCCCCC(O)=O DXNCZXXFRKPEPY-UHFFFAOYSA-N 0.000 claims description 3
- GUOSQNAUYHMCRU-UHFFFAOYSA-N 11-Aminoundecanoic acid Chemical compound NCCCCCCCCCCC(O)=O GUOSQNAUYHMCRU-UHFFFAOYSA-N 0.000 claims description 2
- YCMLQMDWSXFTIF-UHFFFAOYSA-N 2-methylbenzenesulfonimidic acid Chemical compound CC1=CC=CC=C1S(N)(=O)=O YCMLQMDWSXFTIF-UHFFFAOYSA-N 0.000 claims description 2
- 239000003086 colorant Substances 0.000 claims description 2
- 239000004611 light stabiliser Substances 0.000 claims description 2
- 239000006082 mold release agent Substances 0.000 claims description 2
- DHRXPBUFQGUINE-UHFFFAOYSA-N n-(2-hydroxypropyl)benzenesulfonamide Chemical compound CC(O)CNS(=O)(=O)C1=CC=CC=C1 DHRXPBUFQGUINE-UHFFFAOYSA-N 0.000 claims description 2
- 230000001590 oxidative effect Effects 0.000 claims description 2
- LMYRWZFENFIFIT-UHFFFAOYSA-N toluene-4-sulfonamide Chemical compound CC1=CC=C(S(N)(=O)=O)C=C1 LMYRWZFENFIFIT-UHFFFAOYSA-N 0.000 claims description 2
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 21
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 20
- 239000000243 solution Substances 0.000 description 14
- 229920000642 polymer Polymers 0.000 description 12
- 239000008188 pellet Substances 0.000 description 11
- 239000002253 acid Substances 0.000 description 10
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 229920000572 Nylon 6/12 Polymers 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 8
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 8
- 239000012266 salt solution Substances 0.000 description 8
- 239000000654 additive Substances 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 239000003381 stabilizer Substances 0.000 description 6
- 239000002518 antifoaming agent Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000004448 titration Methods 0.000 description 4
- OLFNXLXEGXRUOI-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-bis(2-phenylpropan-2-yl)phenol Chemical compound C=1C(N2N=C3C=CC=CC3=N2)=C(O)C(C(C)(C)C=2C=CC=CC=2)=CC=1C(C)(C)C1=CC=CC=C1 OLFNXLXEGXRUOI-UHFFFAOYSA-N 0.000 description 3
- WTKWFNIIIXNTDO-UHFFFAOYSA-N 3-isocyanato-5-methyl-2-(trifluoromethyl)furan Chemical compound CC1=CC(N=C=O)=C(C(F)(F)F)O1 WTKWFNIIIXNTDO-UHFFFAOYSA-N 0.000 description 3
- OKOBUGCCXMIKDM-UHFFFAOYSA-N Irganox 1098 Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)NCCCCCCNC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 OKOBUGCCXMIKDM-UHFFFAOYSA-N 0.000 description 3
- 239000004959 Rilsan Substances 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 235000019445 benzyl alcohol Nutrition 0.000 description 3
- 150000004985 diamines Chemical class 0.000 description 3
- 125000001183 hydrocarbyl group Chemical group 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- ORECYURYFJYPKY-UHFFFAOYSA-N n,n'-bis(2,2,6,6-tetramethylpiperidin-4-yl)hexane-1,6-diamine;2,4,6-trichloro-1,3,5-triazine;2,4,4-trimethylpentan-2-amine Chemical compound CC(C)(C)CC(C)(C)N.ClC1=NC(Cl)=NC(Cl)=N1.C1C(C)(C)NC(C)(C)CC1NCCCCCCNC1CC(C)(C)NC(C)(C)C1 ORECYURYFJYPKY-UHFFFAOYSA-N 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 229930195734 saturated hydrocarbon Natural products 0.000 description 3
- SDVHRXOTTYYKRY-UHFFFAOYSA-J tetrasodium;dioxido-oxo-phosphonato-$l^{5}-phosphane Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)P([O-])([O-])=O SDVHRXOTTYYKRY-UHFFFAOYSA-J 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- 229920000571 Nylon 11 Polymers 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 150000001991 dicarboxylic acids Chemical class 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 2
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- PWGJDPKCLMLPJW-UHFFFAOYSA-N 1,8-diaminooctane Chemical compound NCCCCCCCCN PWGJDPKCLMLPJW-UHFFFAOYSA-N 0.000 description 1
- JINGUCXQUOKWKH-UHFFFAOYSA-N 2-aminodecanoic acid Chemical compound CCCCCCCCC(N)C(O)=O JINGUCXQUOKWKH-UHFFFAOYSA-N 0.000 description 1
- JZUHIOJYCPIVLQ-UHFFFAOYSA-N 2-methylpentane-1,5-diamine Chemical compound NCC(C)CCCN JZUHIOJYCPIVLQ-UHFFFAOYSA-N 0.000 description 1
- DZIHTWJGPDVSGE-UHFFFAOYSA-N 4-[(4-aminocyclohexyl)methyl]cyclohexan-1-amine Chemical compound C1CC(N)CCC1CC1CCC(N)CC1 DZIHTWJGPDVSGE-UHFFFAOYSA-N 0.000 description 1
- 239000004953 Aliphatic polyamide Substances 0.000 description 1
- 229920003317 Fusabond® Polymers 0.000 description 1
- 239000004609 Impact Modifier Substances 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 1
- 206010042618 Surgical procedure repeated Diseases 0.000 description 1
- OXIKYYJDTWKERT-UHFFFAOYSA-N [4-(aminomethyl)cyclohexyl]methanamine Chemical compound NCC1CCC(CN)CC1 OXIKYYJDTWKERT-UHFFFAOYSA-N 0.000 description 1
- 229960000583 acetic acid Drugs 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 229920003231 aliphatic polyamide Polymers 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 150000008331 benzenesulfonamides Chemical class 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 230000000875 corresponding effect Effects 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- YQLZOAVZWJBZSY-UHFFFAOYSA-N decane-1,10-diamine Chemical compound NCCCCCCCCCCN YQLZOAVZWJBZSY-UHFFFAOYSA-N 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- 238000010102 injection blow moulding Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000010128 melt processing Methods 0.000 description 1
- OFVXDJYBTSEQDW-UHFFFAOYSA-N nonane-1,8-diamine Chemical compound CC(N)CCCCCCCN OFVXDJYBTSEQDW-UHFFFAOYSA-N 0.000 description 1
- SXJVFQLYZSNZBT-UHFFFAOYSA-N nonane-1,9-diamine Chemical compound NCCCCCCCCCN SXJVFQLYZSNZBT-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229920006024 semi-aromatic copolyamide Polymers 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
- C08G69/265—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids from at least two different diamines or at least two different dicarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/36—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino acids, polyamines and polycarboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Proteomics, Peptides & Aminoacids (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyamides (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US72401405P | 2005-10-06 | 2005-10-06 | |
| US60/724,014 | 2005-10-06 | ||
| PCT/US2006/039238 WO2007044573A1 (en) | 2005-10-06 | 2006-10-06 | Hydrolysis resistant polyamide compositions, and articles formed therefrom |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2620152A1 true CA2620152A1 (en) | 2007-04-19 |
Family
ID=37685622
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002620152A Abandoned CA2620152A1 (en) | 2005-10-06 | 2006-10-06 | Hydrolysis resistant polyamide compositions, and articles formed therefrom |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20070083033A1 (enExample) |
| EP (1) | EP1943291B1 (enExample) |
| JP (1) | JP5199874B2 (enExample) |
| CA (1) | CA2620152A1 (enExample) |
| WO (1) | WO2007044573A1 (enExample) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070083033A1 (en) | 2005-10-06 | 2007-04-12 | Fish Robert B Jr | Hydrolysis resistant polyamide compositions, and articles formed therefrom |
| US20080011380A1 (en) * | 2005-10-06 | 2008-01-17 | Fish Robert B Jr | Pipes comprising hydrolysis resistant polyamides |
| DE102008001125A1 (de) * | 2008-04-11 | 2009-10-15 | Evonik Degussa Gmbh | Copolyamidpulver als Porenbildner in regenerierbaren keramischen Partikelfiltern |
| KR20110133041A (ko) * | 2009-03-11 | 2011-12-09 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 내염성 폴리아미드 조성물 |
| US20110020573A1 (en) * | 2009-07-22 | 2011-01-27 | E.I. Du Pont De Nemours And Company | Polyamide composition containing ionomer |
| US8530571B2 (en) * | 2009-12-21 | 2013-09-10 | E I Du Pont De Nemours And Company | Polyamide compositions having high acid ends |
| PL221727B1 (pl) * | 2012-07-23 | 2016-05-31 | Splast Spółka Z Ograniczoną Odpowiedzialnością Spółka Komandytowa | Kompozycja zawierająca poliamid |
| CN107189060B (zh) * | 2016-03-14 | 2019-09-20 | 浙江新和成特种材料有限公司 | 一种半芳香族聚酰胺及其制备方法 |
| EP3222649B1 (de) * | 2016-03-23 | 2018-04-18 | Ems-Patent Ag | Hochtemperaturbeständige polyamidformmassen und deren verwendungen insbesondere im automobilbereich |
| FR3049952B1 (fr) | 2016-04-08 | 2018-03-30 | Arkema France | Composition a base de polyamide pour des tuyaux contenant du petrole ou du gaz |
| CN107418197B (zh) * | 2017-04-18 | 2020-09-01 | 惠州市华聚塑化科技有限公司 | 一种导热尼龙工程塑料及其制备方法 |
| CN106905517A (zh) * | 2017-04-20 | 2017-06-30 | 福建中锦新材料有限公司 | 一种用于纺丝的聚酰胺6及其制造方法 |
| FR3067033B1 (fr) | 2017-06-02 | 2021-01-01 | Arkema France | Composition a base de polyamide pour des tuyaux de liquide de refroidissement |
| CN110922749A (zh) * | 2019-10-26 | 2020-03-27 | 张家港大塚化学有限公司 | Led用高耐候性、高反射率聚酰胺复合材料的制备方法 |
| EP3842496A1 (de) * | 2019-12-23 | 2021-06-30 | Ems-Chemie Ag | Polyamid-formmassen für hypochlorit-beständige anwendungen |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1558800A (en) * | 1925-10-27 | Labeling machine | ||
| GB890437A (en) | 1958-02-20 | 1962-02-28 | Du Pont | Polycarbonamides |
| US3647761A (en) | 1970-06-19 | 1972-03-07 | Monsanto Co | Polyamides of a c7-12 aliphatic dicarboxylic acid terephthalic acid and an aliphatic diamine |
| US4076664A (en) * | 1975-11-13 | 1978-02-28 | E. I. Du Pont De Nemours And Company | 612 OR 610/6I or 6T/636 Polyamide terpolymer |
| FR2331583A1 (fr) * | 1975-11-13 | 1977-06-10 | Du Pont | Terpolymere polyamide et sa preparation |
| JPS52135353A (en) * | 1976-05-08 | 1977-11-12 | Toyobo Co Ltd | Stretched nylon films and their manufacture |
| JPS5852821B2 (ja) * | 1976-04-19 | 1983-11-25 | 東洋紡績株式会社 | ナイロン系延伸フイルム及びその製造法 |
| US4603166A (en) * | 1983-02-16 | 1986-07-29 | Amoco Corporation | Crystalline polyamide composition from dicarboxylic acid mixture and diamine |
| JPS62252424A (ja) * | 1986-04-24 | 1987-11-04 | Ube Ind Ltd | 末端変性ポリアミドおよびその製法 |
| JPH02189338A (ja) * | 1989-01-19 | 1990-07-25 | Mitsubishi Kasei Corp | ナイロン６６延伸フイルム及びその製造方法 |
| DE3912767A1 (de) * | 1989-04-19 | 1990-10-25 | Basf Ag | Verfahren zur kontinuierlichen herstellung von copolyamiden |
| DE3922546A1 (de) * | 1989-07-08 | 1991-01-17 | Hoechst Ag | Verfahren zur herstellung von cycloolefinpolymeren |
| US5850855A (en) | 1990-01-09 | 1998-12-22 | Ems-Inventa Ag | Flexible coolant conduit and method of making same |
| JPH04170430A (ja) * | 1990-11-02 | 1992-06-18 | Mitsui Petrochem Ind Ltd | ポリアミド樹脂の製造方法 |
| JPH0781016B2 (ja) * | 1991-03-18 | 1995-08-30 | 東レ株式会社 | ポリアミド吹込成形品 |
| GB9114767D0 (en) * | 1991-07-09 | 1991-08-28 | Du Pont Canada | Food containers of nylon 6,6/6t |
| JPH07165911A (ja) * | 1993-12-16 | 1995-06-27 | Mitsui Petrochem Ind Ltd | 芳香族ポリアミド樹脂の製造方法 |
| US5763561A (en) * | 1996-09-06 | 1998-06-09 | Amoco Corporation | Polyamide compositions having improved thermal stability |
| FR2758564B1 (fr) * | 1997-01-20 | 1999-03-26 | Atochem Elf Sa | Materiau barriere resistant a l'humidite et a la transformation par etirage et/ou thermoformage a base de copolyamide pa-6,1/6,t/6,6 |
| US6191207B1 (en) * | 1997-06-19 | 2001-02-20 | Asahi Kasei Kogyo Kabushiki Kaisha | Polyamide resin composition and molded articles |
| DE10030716A1 (de) | 2000-06-23 | 2002-01-03 | Degussa | Tieftemperaturschlagzähe Polymerlegierung |
| JP4329292B2 (ja) * | 2000-12-20 | 2009-09-09 | 東レ株式会社 | ポリアミドプレポリマーの製造方法およびポリアミドの製造方法 |
| US20080011380A1 (en) * | 2005-10-06 | 2008-01-17 | Fish Robert B Jr | Pipes comprising hydrolysis resistant polyamides |
| US20070083033A1 (en) | 2005-10-06 | 2007-04-12 | Fish Robert B Jr | Hydrolysis resistant polyamide compositions, and articles formed therefrom |
-
2006
- 2006-10-05 US US11/543,749 patent/US20070083033A1/en not_active Abandoned
- 2006-10-06 EP EP06816456.5A patent/EP1943291B1/en not_active Revoked
- 2006-10-06 CA CA002620152A patent/CA2620152A1/en not_active Abandoned
- 2006-10-06 WO PCT/US2006/039238 patent/WO2007044573A1/en not_active Ceased
- 2006-10-06 JP JP2008534737A patent/JP5199874B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| WO2007044573A1 (en) | 2007-04-19 |
| JP2009511674A (ja) | 2009-03-19 |
| EP1943291B1 (en) | 2013-12-11 |
| JP5199874B2 (ja) | 2013-05-15 |
| EP1943291A1 (en) | 2008-07-16 |
| US20070083033A1 (en) | 2007-04-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Discontinued |
Effective date: 20131009 |