GB890437A - Polycarbonamides - Google Patents
PolycarbonamidesInfo
- Publication number
- GB890437A GB890437A GB4124058A GB4124058A GB890437A GB 890437 A GB890437 A GB 890437A GB 4124058 A GB4124058 A GB 4124058A GB 4124058 A GB4124058 A GB 4124058A GB 890437 A GB890437 A GB 890437A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polycarbonamide
- diamine
- polymerized
- hydroxy
- hexamethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyamides (AREA)
Abstract
A polycarbonamide possessing improved hydrolytic stability is made by polymerizing linear polycarbonamide-forming reactants in the presence of diamine sufficient to provide from 40 to 140 gram equivalents of amine end groups in excess of the number of carboxyl end groups per 106 grams of polycarbonamide. The polymerization is preferably effected in the presence of sodium hypophosphite monohydrate. The polycarbonamides preferably contain antioxidants, e.g. dibutyl cresol, dilauryl thiodipropionate, propyl gallate, hydroxy- and methoxy-benzophenones, cupric stearate, aldehyde-alkyl phenol condensates, ascorbyl palmitate, sodium phenyl phosphinate, butylated hydroxyanisole, gum guaiac, nordihydroguianetic acid, lecithin, oat gum, tocophenol, diphenylol propane, phenyl-b -naphthylamine, sym-phenyl-naphthyl ethylene diamine, sym-dinaphthyl ethylene diamine and certain polymeric amino compounds. In the Examples:- (1) hexamethylene diammonium adipate is polymerized in the presence of hexamethylene diamine, the resultant polycarbonamide being extruded into a ribbon, cut into pieces and coated with p 1,1-bis-(2-methyl-4-hydroxy-5-tertiary-butylphenyl) butane; (2) a polycarbonamide is made as in (1) with the addition of sodium hypophosphite monhydrate to the reaction mixture; (3) a polycarbonamide is made as in (1) with the addition of sodium hypophosphite monohydrate and a mixture of 2-mercaptobenzimidazole and cupric stearate; (4) a polycarbonamide made as in (1) is blended with N,N-di-b -naphthyl-4,41-diaminodiphenyl; (5) a polycarbonamide is made as in (1) with the addition of bis(2-methyl-4-hydroxy-5-tertiary-butylphenyl) sulphide to the reaction mixture; (6) S -caprolactam is polymerized in the presence of hexamethylene diamine and (7) hexamethylene diammonium sebacate is polymerized in the presence of hexamethylene diamine and sodium hypophosphate monohydrate. The products of the examples being exposed to water under high temperatures and pressures to test their resistance. Specifications 461,236, 506,125 and U.S.A. Specifications 2,071,250, 2,241,322 and 2,434,662 are referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US71647258A | 1958-02-20 | 1958-02-20 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB890437A true GB890437A (en) | 1962-02-28 |
Family
ID=24878115
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4124058A Expired GB890437A (en) | 1958-02-20 | 1958-12-22 | Polycarbonamides |
Country Status (3)
Country | Link |
---|---|
DE (1) | DE1420696A1 (en) |
FR (1) | FR1220968A (en) |
GB (1) | GB890437A (en) |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3280052A (en) * | 1961-10-19 | 1966-10-18 | Jun Watanabe | Polyamides stabilized against discoloration from carbon disulfide by the addition of copper stearate and thioacetoamides |
US3296217A (en) * | 1964-06-01 | 1967-01-03 | Monsanto Co | Continuous polymerization process for polyamide preparation |
US3308091A (en) * | 1963-06-24 | 1967-03-07 | Du Pont | Stabilized polyamides containing cupric acetate, cupric chloride and 2-mercaptobenzothiazole |
US3386967A (en) * | 1965-01-19 | 1968-06-04 | Allied Chem | Polycaproamide having excess number of carboxyl end groups over amino end groups |
US3402152A (en) * | 1964-05-15 | 1968-09-17 | Monsanto Co | Process for preparing a polyamide |
US3511815A (en) * | 1968-05-08 | 1970-05-12 | Ahmet Nuri Sayin | Deep dyeing polycarbonamide filament |
US3533986A (en) * | 1966-03-07 | 1970-10-13 | Ici Ltd | Polyamides |
DE2802989A1 (en) * | 1977-01-24 | 1978-07-27 | Ato Chimie | HYDROLYSIS-RESISTANT COPOLYAETHERESTERAMIDE |
US5458782A (en) * | 1994-01-07 | 1995-10-17 | Cuno Incorporated | Hydrolytically stable nylon membrane |
CN102471530A (en) * | 2009-07-30 | 2012-05-23 | 纳幕尔杜邦公司 | Heat resistant polyamide compositions having high amine ends |
US9505912B2 (en) | 2006-08-23 | 2016-11-29 | Basf Se | Polyamide molding materials with improved thermal aging and hydrolysis stability |
EP2749603B1 (en) | 2012-12-28 | 2017-06-07 | Lotte Advanced Materials Co., Ltd. | Polyamide resin compositions and articles including the same |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL285687A (en) * | 1961-11-24 | |||
US3274150A (en) * | 1962-10-24 | 1966-09-20 | Du Pont | Polyamides stabilized with alkali metal iodides in combination with phenylene diamines or a bis phenol |
DE19537003A1 (en) * | 1995-10-04 | 1997-04-10 | Inventa Ag | Adhesion promoter based on polyamide |
US20070083033A1 (en) | 2005-10-06 | 2007-04-12 | Fish Robert B Jr | Hydrolysis resistant polyamide compositions, and articles formed therefrom |
FR3113058B1 (en) | 2020-07-29 | 2023-05-12 | Arkema France | POLYAMIDE FOR TEXTILE APPLICATION |
-
1958
- 1958-12-22 GB GB4124058A patent/GB890437A/en not_active Expired
-
1959
- 1959-01-13 FR FR783841A patent/FR1220968A/en not_active Expired
- 1959-02-20 DE DE19591420696 patent/DE1420696A1/en active Pending
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3280052A (en) * | 1961-10-19 | 1966-10-18 | Jun Watanabe | Polyamides stabilized against discoloration from carbon disulfide by the addition of copper stearate and thioacetoamides |
US3308091A (en) * | 1963-06-24 | 1967-03-07 | Du Pont | Stabilized polyamides containing cupric acetate, cupric chloride and 2-mercaptobenzothiazole |
US3402152A (en) * | 1964-05-15 | 1968-09-17 | Monsanto Co | Process for preparing a polyamide |
US3296217A (en) * | 1964-06-01 | 1967-01-03 | Monsanto Co | Continuous polymerization process for polyamide preparation |
US3386967A (en) * | 1965-01-19 | 1968-06-04 | Allied Chem | Polycaproamide having excess number of carboxyl end groups over amino end groups |
US3533986A (en) * | 1966-03-07 | 1970-10-13 | Ici Ltd | Polyamides |
US3511815A (en) * | 1968-05-08 | 1970-05-12 | Ahmet Nuri Sayin | Deep dyeing polycarbonamide filament |
DE2802989A1 (en) * | 1977-01-24 | 1978-07-27 | Ato Chimie | HYDROLYSIS-RESISTANT COPOLYAETHERESTERAMIDE |
US5458782A (en) * | 1994-01-07 | 1995-10-17 | Cuno Incorporated | Hydrolytically stable nylon membrane |
EP0738181A1 (en) * | 1994-01-07 | 1996-10-23 | Cuno Incorporated | Hydrolytically stable nylon membrane |
EP0738181A4 (en) * | 1994-01-07 | 1998-10-21 | Cuno Inc | Hydrolytically stable nylon membrane |
US9505912B2 (en) | 2006-08-23 | 2016-11-29 | Basf Se | Polyamide molding materials with improved thermal aging and hydrolysis stability |
CN102471530A (en) * | 2009-07-30 | 2012-05-23 | 纳幕尔杜邦公司 | Heat resistant polyamide compositions having high amine ends |
EP2749603B1 (en) | 2012-12-28 | 2017-06-07 | Lotte Advanced Materials Co., Ltd. | Polyamide resin compositions and articles including the same |
Also Published As
Publication number | Publication date |
---|---|
FR1220968A (en) | 1960-05-30 |
DE1420696A1 (en) | 1968-10-10 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
GB890437A (en) | Polycarbonamides | |
US3686143A (en) | Guanidine and amidine accelerators for vulcanization of fluoroelastomers | |
AU2010259649B2 (en) | Polyamide resin composition and molded article | |
AU1875883A (en) | Polyurea dispersion | |
US3388092A (en) | Resins and elastomers from siloxy carboranyl polymers | |
US3098841A (en) | Polynuclear polyamines | |
CN107652665A (en) | Composite flame-retardant environment-friendly polyurethane method for producing elastomers | |
GB1403916A (en) | Transparent thermoplastically formable copolyamides | |
US2936298A (en) | Stabilized polymers | |
GB1203737A (en) | Novel catalysts and their use in cationic polymerisations | |
GB1164750A (en) | Polycarbonamides having an improved Antistatic Property | |
US3454412A (en) | Stabilized synthetic polyamides | |
US3531423A (en) | Thermal and oxidative stabilized polyamides | |
US3384615A (en) | Stabilization of polyamides | |
GB1251520A (en) | ||
US3026294A (en) | Process for curing chlorosulfonated polyethylene elastomers | |
US3133899A (en) | Preparation of polyarylethers | |
ES429057A1 (en) | Polyamide concentrates containing sulphonate groups | |
GB1334409A (en) | Polyurethane-amides | |
US3839392A (en) | Polyamides | |
US2888503A (en) | 2, 6 dialkoxy, 4 alkyl phenol antiozidants | |
GB1438122A (en) | Metal-rubber adhesion system | |
GB1346798A (en) | Process for the preparation of polyamides | |
GB1342565A (en) | Mouldable compositions for articles which are resistant to shock and to wear at high termperature | |
KR890003838A (en) | Polyamide resin |