CA2595393C - Chemical process for recycling polyethylene terephthalate (pet) wastes - Google Patents

Chemical process for recycling polyethylene terephthalate (pet) wastes Download PDF

Info

Publication number
CA2595393C
CA2595393C CA2595393A CA2595393A CA2595393C CA 2595393 C CA2595393 C CA 2595393C CA 2595393 A CA2595393 A CA 2595393A CA 2595393 A CA2595393 A CA 2595393A CA 2595393 C CA2595393 C CA 2595393C
Authority
CA
Canada
Prior art keywords
terephthalic acid
stage
reaction
ethylene glycol
media
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA2595393A
Other languages
English (en)
French (fr)
Other versions
CA2595393A1 (en
Inventor
Arturo Guadalupe Fregoso-Infante
Roxanna Vega-Rangel
Maricruz Figueroa-Gomez-Crespo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
UNIVERSIDAD IBEROAMERICANA AC
Original Assignee
UNIVERSIDAD IBEROAMERICANA AC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by UNIVERSIDAD IBEROAMERICANA AC filed Critical UNIVERSIDAD IBEROAMERICANA AC
Publication of CA2595393A1 publication Critical patent/CA2595393A1/en
Application granted granted Critical
Publication of CA2595393C publication Critical patent/CA2595393C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/02—Preparation of carboxylic acids or their salts, halides or anhydrides from salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C63/00—Compounds having carboxyl groups bound to a carbon atoms of six-membered aromatic rings
    • C07C63/14—Monocyclic dicarboxylic acids
    • C07C63/15—Monocyclic dicarboxylic acids all carboxyl groups bound to carbon atoms of the six-membered aromatic ring
    • C07C63/26—1,4 - Benzenedicarboxylic acid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00—Recovery or working-up of waste materials
    • C08J11/04—Recovery or working-up of waste materials of polymers
    • C08J11/10—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
    • C08J11/16—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with inorganic material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00—Recovery or working-up of waste materials
    • C08J11/04—Recovery or working-up of waste materials of polymers
    • C08J11/10—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
    • C08J11/18—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material
    • C08J11/22—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic oxygen-containing compounds
    • C08J11/24—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic oxygen-containing compounds containing hydroxyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/62—Plastics recycling; Rubber recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Sustainable Development (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyesters Or Polycarbonates (AREA)
CA2595393A 2004-01-27 2004-01-27 Chemical process for recycling polyethylene terephthalate (pet) wastes Expired - Fee Related CA2595393C (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/IB2004/000257 WO2005082826A1 (es) 2004-01-27 2004-01-27 Procedimiento quimico de reciclado de polietilentereftalato (pet) de desecho

Publications (2)

Publication Number Publication Date
CA2595393A1 CA2595393A1 (en) 2005-09-09
CA2595393C true CA2595393C (en) 2012-04-17

Family

ID=34897651

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2595393A Expired - Fee Related CA2595393C (en) 2004-01-27 2004-01-27 Chemical process for recycling polyethylene terephthalate (pet) wastes

Country Status (12)

Country Link
US (1) US7893122B2 (cg-RX-API-DMAC10.html)
EP (1) EP1710226B1 (cg-RX-API-DMAC10.html)
JP (1) JP4647625B2 (cg-RX-API-DMAC10.html)
KR (1) KR100983349B1 (cg-RX-API-DMAC10.html)
AU (1) AU2004316446B2 (cg-RX-API-DMAC10.html)
CA (1) CA2595393C (cg-RX-API-DMAC10.html)
DE (1) DE602004022199D1 (cg-RX-API-DMAC10.html)
DK (1) DK1710226T3 (cg-RX-API-DMAC10.html)
ES (1) ES2328139T3 (cg-RX-API-DMAC10.html)
IL (1) IL176986A (cg-RX-API-DMAC10.html)
PT (1) PT1710226E (cg-RX-API-DMAC10.html)
WO (1) WO2005082826A1 (cg-RX-API-DMAC10.html)

Families Citing this family (50)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7972692B2 (en) 2005-12-15 2011-07-05 Kimberly-Clark Worldwide, Inc. Biodegradable multicomponent fibers
KR101283172B1 (ko) 2006-04-07 2013-07-08 킴벌리-클라크 월드와이드, 인크. 생분해성 부직 라미네이트
US8710172B2 (en) 2006-07-14 2014-04-29 Kimberly-Clark Worldwide, Inc. Biodegradable aliphatic-aromatic copolyester for use in nonwoven webs
KR101297937B1 (ko) 2006-07-14 2013-08-19 킴벌리-클라크 월드와이드, 인크. 부직 웹에 사용하기 위한 생분해성 지방족 폴리에스테르
WO2008008074A1 (en) 2006-07-14 2008-01-17 Kimberly-Clark Worldwide, Inc. Biodegradable polyactic acid for use in nonwoven webs
US8470222B2 (en) 2008-06-06 2013-06-25 Kimberly-Clark Worldwide, Inc. Fibers formed from a blend of a modified aliphatic-aromatic copolyester and thermoplastic starch
US8841386B2 (en) * 2008-06-10 2014-09-23 Kimberly-Clark Worldwide, Inc. Fibers formed from aromatic polyester and polyether copolymer
CN105254858A (zh) * 2009-03-03 2016-01-20 可口可乐公司 生物基聚对苯二甲酸乙二酯包装及制备其的方法
US20130199692A1 (en) * 2010-07-30 2013-08-08 North Carolina State University Surface Functionalization of Polyester
US9458354B2 (en) 2010-10-06 2016-10-04 Resinate Technologies, Inc. Polyurethane dispersions and methods of making and using same
CA2838825A1 (en) 2011-06-10 2012-12-13 Kristopher M. Felice Clear coatings acrylic coatings
CN103703137B (zh) 2012-01-27 2016-11-23 株式会社吉那里斯 由对苯二甲酸钾盐制造有用化学品的方法
US10196496B2 (en) 2013-03-31 2019-02-05 Pranay Jain Process for recycling a metalized polyester film
BR102014029870B1 (pt) * 2014-11-28 2018-05-08 Univ Federal Do Espirito Santo Ufes resina supressora de pó de minérios e uso da resina
JP2018510225A (ja) 2015-01-30 2018-04-12 レジネート マテリアルズ グループ、インコーポレイテッド Pet及びpttのリサイクル流の統合処理方法
JP6671067B2 (ja) * 2015-04-10 2020-03-25 国立研究開発法人産業技術総合研究所 架橋化evaの可溶化方法、可溶化方法を用いた使用済み太陽電池からの資源回収法
US9550713B1 (en) 2015-07-09 2017-01-24 Loop Industries, Inc. Polyethylene terephthalate depolymerization
US9981902B2 (en) 2015-10-23 2018-05-29 Columbia Insurance Company Process for production of an ester and diol from reclaimed carpet material
ITUB20160843A1 (it) * 2016-02-18 2017-08-18 Recyclinnova S R L S Processo di conversione di rifiuti in Polietilene Tereftalato (PET) in prodotti chimici di valore
RU2616299C1 (ru) * 2016-05-19 2017-04-14 Общество с ограниченной ответственностью "ХИМТЕХ-ИНЖИНИРИНГ" Способ щелочного гидролиза отходов ПЭТФ с получением терефталевой кислоты
US10252976B1 (en) 2017-09-15 2019-04-09 9449710 Canada Inc. Terephthalic acid esters formation
US12071519B2 (en) 2017-09-15 2024-08-27 9449710 Canada Inc. Terephthalic acid esters formation
MY205894A (en) 2018-06-25 2024-11-19 9449710 Canada Inc Terephthalic acid esters formation
SE542172C2 (en) * 2018-07-13 2020-03-10 Soedra Skogsaegarna Ekonomisk Foerening Process for separation
DE102018122210B4 (de) * 2018-09-12 2023-06-29 Rittec Umwelttechnik Gmbh Verfahren und Verwendung einer Vorrichtung zur Wiederaufarbeitung von Polyalkylenterephthalat enthaltenden Abfällen
TWI694064B (zh) * 2018-09-26 2020-05-21 遠東新世紀股份有限公司 對苯二甲酸的製造方法及其系統
JP7461062B2 (ja) * 2019-02-27 2024-04-03 エコール ポリテクニーク フェデラル デ ローザンヌ (イーピーエフエル) プラスチック材料の、テレフタル酸(tpa)、エチレングリコール、及び/又はそのプラスチック材料を形成する他のモノマーへの分解
US11248103B2 (en) 2019-03-20 2022-02-15 9449710 Canada Inc. Process for the depolymerization of polyethylene terephthalate (PET)
KR102223614B1 (ko) * 2019-06-12 2021-03-05 한국화학연구원 극성용매 혼합물을 사용한 에스테르 작용기를 포함하는 고분자의 해중합
US12528927B2 (en) * 2020-02-20 2026-01-20 Georgia Tech Research Corporation Mechanocatalytic depolymerization of plastics
WO2021211423A1 (en) 2020-04-13 2021-10-21 Northwestern University Methods for depolymerizing polyesters
KR102425247B1 (ko) * 2020-06-26 2022-07-27 한국화학연구원 에스테르 작용기를 포함하는 고분자의 친환경적인 해중합 방법
KR102462599B1 (ko) * 2020-09-18 2022-11-03 한국화학연구원 에스테르 작용기를 포함하는 고분자의 해중합 촉매 및 이를 이용한 해중합 방법
RU2754972C1 (ru) * 2020-09-24 2021-09-08 Федеральное государственное бюджетное образовательное учреждение высшего образования "Российский химико-технологический университет имени Д.И. Менделеева" (РХТУ им. Д.И. Менделеева) Способ переработки отходов полиэтилентерефталата
US20240228736A1 (en) * 2021-01-07 2024-07-11 Agency For Science, Technology And Research A Process for Preparing a Monoester of Terephthalic Acid and Its Derivatives
CN116981725A (zh) * 2021-02-26 2023-10-31 高丽大学校产学协力团 用于回收聚对苯二甲酸乙二醇酯(pet)的pet化学和生物集成降解方法
IT202100006077A1 (it) * 2021-03-15 2022-09-15 gr3n SA Metodo per il riciclaggio di uno scarto tessile comprendente una componente cellulosica ed una componente in poliestere
JP7531056B2 (ja) * 2021-07-19 2024-08-08 エルジー・ケム・リミテッド リサイクルプラスチック合成用単量体組成物、その製造方法、およびそれを用いたリサイクルプラスチック、成形品および可塑剤組成物
AU2022335930A1 (en) * 2021-09-06 2024-03-07 Samsara Eco Pty Limited Recycling of polyester
TW202330758A (zh) 2021-09-16 2023-08-01 美商賽克股份有限公司 從由廢棄材料解聚合所形成再生二酸形成聚酯之方法
KR102381508B1 (ko) * 2021-09-28 2022-04-01 김 영 범 고유점도가 0.75㎗/g 이상인 고중합도의 폴리에틸렌테레프탈레이트를 이용한 테레프탈산의 제조방법
US12577365B2 (en) 2021-10-25 2026-03-17 Northwestern University Polyester hydrogenolytic deconstruction via tandem catalysis
KR102766336B1 (ko) * 2021-11-25 2025-02-12 롯데케미칼 주식회사 화학적 재활용 pet의 제조 방법
JP7849216B2 (ja) * 2022-04-28 2026-04-21 キリンホールディングス株式会社 テレフタル酸の回収方法
GB202207361D0 (en) * 2022-05-19 2022-07-06 Stuff4Life Ltd Chemical process
CN116875326B (zh) * 2023-04-27 2026-02-06 湖北民族大学 一种以废弃塑料瓶为原料的破乳剂及其制备方法与应用
JPWO2024225470A1 (cg-RX-API-DMAC10.html) * 2023-04-28 2024-10-31
KR102826861B1 (ko) 2023-06-26 2025-07-01 테라클 주식회사 Pet 해중합 생성물의 정제방법
KR102833682B1 (ko) 2023-09-12 2025-07-18 테라클 주식회사 제지슬러지 소각재를 이용한 pet 해중합으로부터 테레프탈산을 제조하는 방법
KR102774288B1 (ko) * 2024-04-30 2025-02-27 테라클 주식회사 폴리에스테르 해중합을 이용한 고순도 테레프탈산 제조방법 및 이로부터 얻어진 고순도의 테레프탈산

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB822834A (en) * 1957-01-11 1959-11-04 Jaroslav Pitat A method of processing waste of polyethylene terephthalate by hydrolysis
US3801273A (en) * 1972-08-30 1974-04-02 Johnson & Johnson Methods of recovering waste cellulosic fibers
US4929749A (en) * 1989-03-15 1990-05-29 Synergistics Industries, Limited Production of terephthalate esters by degradative transesterification of scrap or virgin terephthalate polyesters
US5580905A (en) * 1994-04-28 1996-12-03 United Resource Recovery Corporation Process for recycling polyesters
JPH08253619A (ja) * 1995-03-17 1996-10-01 Matsushita Electric Ind Co Ltd プラスチック成形体の処理方法
US6031128A (en) * 1995-12-30 2000-02-29 Sunkyong Industries Co., Ltd. Process for manufacturing terephthalic acid
JP2001131269A (ja) * 1999-10-29 2001-05-15 Hitachi Chem Co Ltd 不飽和ポリエステル樹脂の製造方法及び不飽和ポリエステル樹脂組成物、並びにこれを用いた熱硬化性成形材料及びプラスチック成形品
JP3808672B2 (ja) 1999-11-26 2006-08-16 東洋製罐株式会社 回収ポリエチレンテレフタレート粉砕品からのテレフタル酸の工業的回収方法
JP3917811B2 (ja) * 2000-11-15 2007-05-23 東洋製罐株式会社 回収ポリエチレンテレフタレート粉砕品からのテレフタル酸の工業的回収方法
JP2002327088A (ja) * 2001-05-07 2002-11-15 Akio Kobayashi 精製熱可塑性ポリエステル樹脂の製造法

Also Published As

Publication number Publication date
CA2595393A1 (en) 2005-09-09
PT1710226E (pt) 2009-09-03
JP2007519798A (ja) 2007-07-19
ES2328139T3 (es) 2009-11-10
WO2005082826A1 (es) 2005-09-09
JP4647625B2 (ja) 2011-03-09
KR20060127925A (ko) 2006-12-13
US7893122B2 (en) 2011-02-22
AU2004316446B2 (en) 2010-12-23
DE602004022199D1 (de) 2009-09-03
KR100983349B1 (ko) 2010-09-20
IL176986A0 (en) 2006-12-10
EP1710226A1 (en) 2006-10-11
US20070219339A1 (en) 2007-09-20
IL176986A (en) 2010-12-30
EP1710226B1 (en) 2009-07-22
AU2004316446A2 (en) 2005-09-09
DK1710226T3 (da) 2009-10-05
AU2004316446A1 (en) 2005-09-09

Similar Documents

Publication Publication Date Title
US7893122B2 (en) Chemical process for recycling polyethylene terephthalate (PET) waste
JP3983977B2 (ja) 汚染されたポリエチレンテレフタレートを汚染除去されたポリブチレンテレフタレートに転化するための改良された方法
JP3715812B2 (ja) ポリエチレンテレフタレート廃棄物のケミカルリサイクル方法
JP4908415B2 (ja) 染着ポリエステル繊維からの有用成分製造方法
KR100271405B1 (ko) 개량된 폴리 에틸렌 테레프탈레이트 오염물질 제거방법
JP7644824B2 (ja) ポリエステルの解重合方法
AU683896B2 (en) Production of dicarboxylic acids and diols from polyester materials
JP2012523442A (ja) 加水分解によるplaのケミカルリサイクル
JP7832202B2 (ja) リサイクルプロセスのためのポリエステル廃棄物の原料精製
JP7709532B2 (ja) ポリエステルの脱色方法を含むポリエステルの解重合方法
KR100224466B1 (ko) 테레프탈산의 제조방법 (1)
JP2009173554A (ja) ペットボトル廃棄物より色相を改善したテレフタル酸ジメチルを回収する方法
JPH11302208A (ja) ポリエチレンテレフタレートからテレフタル酸およびエチレングリコールを回収する方法
KR20250066156A (ko) 버진 테레프탈산 및 재생 테레프탈산의 식별 방법
MXPA06008376A (en) Chemical method for recycling polyethylene terephtalate (pet) wastes
JPH08302061A (ja) 芳香族ポリエステル廃棄物から芳香族ジカルボン酸の回収方法
WO2005003217A1 (en) Method and plant for the recovery of terephthalic acid and ethylene glycol from polyethylene terephthalate wastes
JPH08259728A (ja) 芳香族ジカルボン酸およびアルキレングリコールの製造方法
ES2916712T3 (es) Método de obtención de ácido tereftálico a partir de residuos de tereftalato de polietileno
US20060069170A1 (en) Decomposition of Polyester
WO2025221525A1 (en) Chemical recycling of waste plastic with enhanced solid-liquid separation
JP2007169524A (ja) プラスチックの亜臨界水分解物の分離方法
JP2009006517A (ja) プラスチックからの無機物の回収方法
JP2001261598A (ja) アルキレングリコールの精製方法
JP2012116912A (ja) ポリエステルからポリエステルモノマーを製造する方法

Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed

Effective date: 20210831

MKLA Lapsed

Effective date: 20200127