AU2004316446B2 - Chemical method for recycling polyethylene terephtalate (PET) wastes - Google Patents
Chemical method for recycling polyethylene terephtalate (PET) wastes Download PDFInfo
- Publication number
- AU2004316446B2 AU2004316446B2 AU2004316446A AU2004316446A AU2004316446B2 AU 2004316446 B2 AU2004316446 B2 AU 2004316446B2 AU 2004316446 A AU2004316446 A AU 2004316446A AU 2004316446 A AU2004316446 A AU 2004316446A AU 2004316446 B2 AU2004316446 B2 AU 2004316446B2
- Authority
- AU
- Australia
- Prior art keywords
- terephthalic acid
- stage
- ethylene glycol
- reaction
- media
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/02—Preparation of carboxylic acids or their salts, halides or anhydrides from salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C63/00—Compounds having carboxyl groups bound to a carbon atoms of six-membered aromatic rings
- C07C63/14—Monocyclic dicarboxylic acids
- C07C63/15—Monocyclic dicarboxylic acids all carboxyl groups bound to carbon atoms of the six-membered aromatic ring
- C07C63/26—1,4 - Benzenedicarboxylic acid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J11/00—Recovery or working-up of waste materials
- C08J11/04—Recovery or working-up of waste materials of polymers
- C08J11/10—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
- C08J11/16—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with inorganic material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J11/00—Recovery or working-up of waste materials
- C08J11/04—Recovery or working-up of waste materials of polymers
- C08J11/10—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
- C08J11/18—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material
- C08J11/22—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic oxygen-containing compounds
- C08J11/24—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic oxygen-containing compounds containing hydroxyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Sustainable Development (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polyesters Or Polycarbonates (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/IB2004/000257 WO2005082826A1 (es) | 2004-01-27 | 2004-01-27 | Procedimiento quimico de reciclado de polietilentereftalato (pet) de desecho |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| AU2004316446A2 AU2004316446A2 (en) | 2005-09-09 |
| AU2004316446A1 AU2004316446A1 (en) | 2005-09-09 |
| AU2004316446B2 true AU2004316446B2 (en) | 2010-12-23 |
Family
ID=34897651
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2004316446A Ceased AU2004316446B2 (en) | 2004-01-27 | 2004-01-27 | Chemical method for recycling polyethylene terephtalate (PET) wastes |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US7893122B2 (cg-RX-API-DMAC10.html) |
| EP (1) | EP1710226B1 (cg-RX-API-DMAC10.html) |
| JP (1) | JP4647625B2 (cg-RX-API-DMAC10.html) |
| KR (1) | KR100983349B1 (cg-RX-API-DMAC10.html) |
| AU (1) | AU2004316446B2 (cg-RX-API-DMAC10.html) |
| CA (1) | CA2595393C (cg-RX-API-DMAC10.html) |
| DE (1) | DE602004022199D1 (cg-RX-API-DMAC10.html) |
| DK (1) | DK1710226T3 (cg-RX-API-DMAC10.html) |
| ES (1) | ES2328139T3 (cg-RX-API-DMAC10.html) |
| IL (1) | IL176986A (cg-RX-API-DMAC10.html) |
| PT (1) | PT1710226E (cg-RX-API-DMAC10.html) |
| WO (1) | WO2005082826A1 (cg-RX-API-DMAC10.html) |
Families Citing this family (50)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7972692B2 (en) | 2005-12-15 | 2011-07-05 | Kimberly-Clark Worldwide, Inc. | Biodegradable multicomponent fibers |
| KR101283172B1 (ko) | 2006-04-07 | 2013-07-08 | 킴벌리-클라크 월드와이드, 인크. | 생분해성 부직 라미네이트 |
| US8710172B2 (en) | 2006-07-14 | 2014-04-29 | Kimberly-Clark Worldwide, Inc. | Biodegradable aliphatic-aromatic copolyester for use in nonwoven webs |
| KR101297937B1 (ko) | 2006-07-14 | 2013-08-19 | 킴벌리-클라크 월드와이드, 인크. | 부직 웹에 사용하기 위한 생분해성 지방족 폴리에스테르 |
| WO2008008074A1 (en) | 2006-07-14 | 2008-01-17 | Kimberly-Clark Worldwide, Inc. | Biodegradable polyactic acid for use in nonwoven webs |
| US8470222B2 (en) | 2008-06-06 | 2013-06-25 | Kimberly-Clark Worldwide, Inc. | Fibers formed from a blend of a modified aliphatic-aromatic copolyester and thermoplastic starch |
| US8841386B2 (en) * | 2008-06-10 | 2014-09-23 | Kimberly-Clark Worldwide, Inc. | Fibers formed from aromatic polyester and polyether copolymer |
| CN105254858A (zh) * | 2009-03-03 | 2016-01-20 | 可口可乐公司 | 生物基聚对苯二甲酸乙二酯包装及制备其的方法 |
| US20130199692A1 (en) * | 2010-07-30 | 2013-08-08 | North Carolina State University | Surface Functionalization of Polyester |
| US9458354B2 (en) | 2010-10-06 | 2016-10-04 | Resinate Technologies, Inc. | Polyurethane dispersions and methods of making and using same |
| CA2838825A1 (en) | 2011-06-10 | 2012-12-13 | Kristopher M. Felice | Clear coatings acrylic coatings |
| CN103703137B (zh) | 2012-01-27 | 2016-11-23 | 株式会社吉那里斯 | 由对苯二甲酸钾盐制造有用化学品的方法 |
| US10196496B2 (en) | 2013-03-31 | 2019-02-05 | Pranay Jain | Process for recycling a metalized polyester film |
| BR102014029870B1 (pt) * | 2014-11-28 | 2018-05-08 | Univ Federal Do Espirito Santo Ufes | resina supressora de pó de minérios e uso da resina |
| JP2018510225A (ja) | 2015-01-30 | 2018-04-12 | レジネート マテリアルズ グループ、インコーポレイテッド | Pet及びpttのリサイクル流の統合処理方法 |
| JP6671067B2 (ja) * | 2015-04-10 | 2020-03-25 | 国立研究開発法人産業技術総合研究所 | 架橋化evaの可溶化方法、可溶化方法を用いた使用済み太陽電池からの資源回収法 |
| US9550713B1 (en) | 2015-07-09 | 2017-01-24 | Loop Industries, Inc. | Polyethylene terephthalate depolymerization |
| US9981902B2 (en) | 2015-10-23 | 2018-05-29 | Columbia Insurance Company | Process for production of an ester and diol from reclaimed carpet material |
| ITUB20160843A1 (it) * | 2016-02-18 | 2017-08-18 | Recyclinnova S R L S | Processo di conversione di rifiuti in Polietilene Tereftalato (PET) in prodotti chimici di valore |
| RU2616299C1 (ru) * | 2016-05-19 | 2017-04-14 | Общество с ограниченной ответственностью "ХИМТЕХ-ИНЖИНИРИНГ" | Способ щелочного гидролиза отходов ПЭТФ с получением терефталевой кислоты |
| US10252976B1 (en) | 2017-09-15 | 2019-04-09 | 9449710 Canada Inc. | Terephthalic acid esters formation |
| US12071519B2 (en) | 2017-09-15 | 2024-08-27 | 9449710 Canada Inc. | Terephthalic acid esters formation |
| MY205894A (en) | 2018-06-25 | 2024-11-19 | 9449710 Canada Inc | Terephthalic acid esters formation |
| SE542172C2 (en) * | 2018-07-13 | 2020-03-10 | Soedra Skogsaegarna Ekonomisk Foerening | Process for separation |
| DE102018122210B4 (de) * | 2018-09-12 | 2023-06-29 | Rittec Umwelttechnik Gmbh | Verfahren und Verwendung einer Vorrichtung zur Wiederaufarbeitung von Polyalkylenterephthalat enthaltenden Abfällen |
| TWI694064B (zh) * | 2018-09-26 | 2020-05-21 | 遠東新世紀股份有限公司 | 對苯二甲酸的製造方法及其系統 |
| JP7461062B2 (ja) * | 2019-02-27 | 2024-04-03 | エコール ポリテクニーク フェデラル デ ローザンヌ (イーピーエフエル) | プラスチック材料の、テレフタル酸(tpa)、エチレングリコール、及び/又はそのプラスチック材料を形成する他のモノマーへの分解 |
| US11248103B2 (en) | 2019-03-20 | 2022-02-15 | 9449710 Canada Inc. | Process for the depolymerization of polyethylene terephthalate (PET) |
| KR102223614B1 (ko) * | 2019-06-12 | 2021-03-05 | 한국화학연구원 | 극성용매 혼합물을 사용한 에스테르 작용기를 포함하는 고분자의 해중합 |
| US12528927B2 (en) * | 2020-02-20 | 2026-01-20 | Georgia Tech Research Corporation | Mechanocatalytic depolymerization of plastics |
| WO2021211423A1 (en) | 2020-04-13 | 2021-10-21 | Northwestern University | Methods for depolymerizing polyesters |
| KR102425247B1 (ko) * | 2020-06-26 | 2022-07-27 | 한국화학연구원 | 에스테르 작용기를 포함하는 고분자의 친환경적인 해중합 방법 |
| KR102462599B1 (ko) * | 2020-09-18 | 2022-11-03 | 한국화학연구원 | 에스테르 작용기를 포함하는 고분자의 해중합 촉매 및 이를 이용한 해중합 방법 |
| RU2754972C1 (ru) * | 2020-09-24 | 2021-09-08 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Российский химико-технологический университет имени Д.И. Менделеева" (РХТУ им. Д.И. Менделеева) | Способ переработки отходов полиэтилентерефталата |
| US20240228736A1 (en) * | 2021-01-07 | 2024-07-11 | Agency For Science, Technology And Research | A Process for Preparing a Monoester of Terephthalic Acid and Its Derivatives |
| CN116981725A (zh) * | 2021-02-26 | 2023-10-31 | 高丽大学校产学协力团 | 用于回收聚对苯二甲酸乙二醇酯(pet)的pet化学和生物集成降解方法 |
| IT202100006077A1 (it) * | 2021-03-15 | 2022-09-15 | gr3n SA | Metodo per il riciclaggio di uno scarto tessile comprendente una componente cellulosica ed una componente in poliestere |
| JP7531056B2 (ja) * | 2021-07-19 | 2024-08-08 | エルジー・ケム・リミテッド | リサイクルプラスチック合成用単量体組成物、その製造方法、およびそれを用いたリサイクルプラスチック、成形品および可塑剤組成物 |
| AU2022335930A1 (en) * | 2021-09-06 | 2024-03-07 | Samsara Eco Pty Limited | Recycling of polyester |
| TW202330758A (zh) | 2021-09-16 | 2023-08-01 | 美商賽克股份有限公司 | 從由廢棄材料解聚合所形成再生二酸形成聚酯之方法 |
| KR102381508B1 (ko) * | 2021-09-28 | 2022-04-01 | 김 영 범 | 고유점도가 0.75㎗/g 이상인 고중합도의 폴리에틸렌테레프탈레이트를 이용한 테레프탈산의 제조방법 |
| US12577365B2 (en) | 2021-10-25 | 2026-03-17 | Northwestern University | Polyester hydrogenolytic deconstruction via tandem catalysis |
| KR102766336B1 (ko) * | 2021-11-25 | 2025-02-12 | 롯데케미칼 주식회사 | 화학적 재활용 pet의 제조 방법 |
| JP7849216B2 (ja) * | 2022-04-28 | 2026-04-21 | キリンホールディングス株式会社 | テレフタル酸の回収方法 |
| GB202207361D0 (en) * | 2022-05-19 | 2022-07-06 | Stuff4Life Ltd | Chemical process |
| CN116875326B (zh) * | 2023-04-27 | 2026-02-06 | 湖北民族大学 | 一种以废弃塑料瓶为原料的破乳剂及其制备方法与应用 |
| JPWO2024225470A1 (cg-RX-API-DMAC10.html) * | 2023-04-28 | 2024-10-31 | ||
| KR102826861B1 (ko) | 2023-06-26 | 2025-07-01 | 테라클 주식회사 | Pet 해중합 생성물의 정제방법 |
| KR102833682B1 (ko) | 2023-09-12 | 2025-07-18 | 테라클 주식회사 | 제지슬러지 소각재를 이용한 pet 해중합으로부터 테레프탈산을 제조하는 방법 |
| KR102774288B1 (ko) * | 2024-04-30 | 2025-02-27 | 테라클 주식회사 | 폴리에스테르 해중합을 이용한 고순도 테레프탈산 제조방법 및 이로부터 얻어진 고순도의 테레프탈산 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB822834A (en) * | 1957-01-11 | 1959-11-04 | Jaroslav Pitat | A method of processing waste of polyethylene terephthalate by hydrolysis |
| US6580005B1 (en) * | 1999-11-26 | 2003-06-17 | Tsukishima Kikai Co., Ltd. | Process for recovering terephthalic acid from pulverized product of spent polyethylene terephthalate and system for use in such process |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3801273A (en) * | 1972-08-30 | 1974-04-02 | Johnson & Johnson | Methods of recovering waste cellulosic fibers |
| US4929749A (en) * | 1989-03-15 | 1990-05-29 | Synergistics Industries, Limited | Production of terephthalate esters by degradative transesterification of scrap or virgin terephthalate polyesters |
| US5580905A (en) * | 1994-04-28 | 1996-12-03 | United Resource Recovery Corporation | Process for recycling polyesters |
| JPH08253619A (ja) * | 1995-03-17 | 1996-10-01 | Matsushita Electric Ind Co Ltd | プラスチック成形体の処理方法 |
| US6031128A (en) * | 1995-12-30 | 2000-02-29 | Sunkyong Industries Co., Ltd. | Process for manufacturing terephthalic acid |
| JP2001131269A (ja) * | 1999-10-29 | 2001-05-15 | Hitachi Chem Co Ltd | 不飽和ポリエステル樹脂の製造方法及び不飽和ポリエステル樹脂組成物、並びにこれを用いた熱硬化性成形材料及びプラスチック成形品 |
| JP3917811B2 (ja) * | 2000-11-15 | 2007-05-23 | 東洋製罐株式会社 | 回収ポリエチレンテレフタレート粉砕品からのテレフタル酸の工業的回収方法 |
| JP2002327088A (ja) * | 2001-05-07 | 2002-11-15 | Akio Kobayashi | 精製熱可塑性ポリエステル樹脂の製造法 |
-
2004
- 2004-01-27 DK DK04705473T patent/DK1710226T3/da active
- 2004-01-27 JP JP2006550315A patent/JP4647625B2/ja not_active Expired - Fee Related
- 2004-01-27 DE DE602004022199T patent/DE602004022199D1/de not_active Expired - Lifetime
- 2004-01-27 WO PCT/IB2004/000257 patent/WO2005082826A1/es not_active Ceased
- 2004-01-27 ES ES04705473T patent/ES2328139T3/es not_active Expired - Lifetime
- 2004-01-27 CA CA2595393A patent/CA2595393C/en not_active Expired - Fee Related
- 2004-01-27 US US10/587,518 patent/US7893122B2/en not_active Expired - Fee Related
- 2004-01-27 EP EP04705473A patent/EP1710226B1/en not_active Expired - Lifetime
- 2004-01-27 PT PT04705473T patent/PT1710226E/pt unknown
- 2004-01-27 KR KR1020067015142A patent/KR100983349B1/ko not_active Expired - Fee Related
- 2004-01-27 AU AU2004316446A patent/AU2004316446B2/en not_active Ceased
-
2006
- 2006-07-20 IL IL176986A patent/IL176986A/en active IP Right Grant
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB822834A (en) * | 1957-01-11 | 1959-11-04 | Jaroslav Pitat | A method of processing waste of polyethylene terephthalate by hydrolysis |
| US6580005B1 (en) * | 1999-11-26 | 2003-06-17 | Tsukishima Kikai Co., Ltd. | Process for recovering terephthalic acid from pulverized product of spent polyethylene terephthalate and system for use in such process |
Non-Patent Citations (2)
| Title |
|---|
| HU, LIAN-CHUM et al. 'Alkali-Decomposition of Poly(ethylene terephthalate) in Mixed Media of Nonaqueous Alcohol and Ether. Study on Recycling of Poly(ethylene terephthalate.' Polymer Journal. 1997, Vol. 29, No. 9, pages 708-712 * |
| KARAYANNIDIA, G.P. et al. 'Poly(ethylene terephthalate) Recycling and Recovery of Pure Terephthalic Acid by Alkaline Hydrolysis.' Advances in Polymer Technology. 2002, Vol. 21, No. 4, pages 250-259 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2595393A1 (en) | 2005-09-09 |
| PT1710226E (pt) | 2009-09-03 |
| JP2007519798A (ja) | 2007-07-19 |
| CA2595393C (en) | 2012-04-17 |
| ES2328139T3 (es) | 2009-11-10 |
| WO2005082826A1 (es) | 2005-09-09 |
| JP4647625B2 (ja) | 2011-03-09 |
| KR20060127925A (ko) | 2006-12-13 |
| US7893122B2 (en) | 2011-02-22 |
| DE602004022199D1 (de) | 2009-09-03 |
| KR100983349B1 (ko) | 2010-09-20 |
| IL176986A0 (en) | 2006-12-10 |
| EP1710226A1 (en) | 2006-10-11 |
| US20070219339A1 (en) | 2007-09-20 |
| IL176986A (en) | 2010-12-30 |
| EP1710226B1 (en) | 2009-07-22 |
| AU2004316446A2 (en) | 2005-09-09 |
| DK1710226T3 (da) | 2009-10-05 |
| AU2004316446A1 (en) | 2005-09-09 |
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