CA2531230C - Procede de preparation de dispersions de polycarbodiimide stables dans l'eau, depourvues de solvants organiques et pouvant etre utilisees en tant qu'agent de reticulation - Google Patents
Procede de preparation de dispersions de polycarbodiimide stables dans l'eau, depourvues de solvants organiques et pouvant etre utilisees en tant qu'agent de reticulation Download PDFInfo
- Publication number
- CA2531230C CA2531230C CA2531230A CA2531230A CA2531230C CA 2531230 C CA2531230 C CA 2531230C CA 2531230 A CA2531230 A CA 2531230A CA 2531230 A CA2531230 A CA 2531230A CA 2531230 C CA2531230 C CA 2531230C
- Authority
- CA
- Canada
- Prior art keywords
- polycarbodiimide
- mono
- water
- process according
- amine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000006185 dispersion Substances 0.000 title claims abstract description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 24
- 238000000034 method Methods 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000003431 cross linking reagent Substances 0.000 title claims abstract description 8
- 239000003960 organic solvent Substances 0.000 title claims abstract description 6
- 239000000203 mixture Substances 0.000 claims abstract description 20
- 150000001718 carbodiimides Chemical class 0.000 claims abstract description 18
- 150000001875 compounds Chemical class 0.000 claims abstract description 14
- 150000001412 amines Chemical group 0.000 claims abstract description 12
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 11
- 239000003054 catalyst Substances 0.000 claims abstract description 11
- 239000005056 polyisocyanate Substances 0.000 claims abstract description 10
- 229920001228 polyisocyanate Polymers 0.000 claims abstract description 10
- 238000000576 coating method Methods 0.000 claims abstract description 9
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 9
- 239000011248 coating agent Substances 0.000 claims abstract description 7
- 239000011347 resin Substances 0.000 claims abstract description 7
- 229920005989 resin Polymers 0.000 claims abstract description 7
- 239000000872 buffer Substances 0.000 claims abstract description 6
- 230000006870 function Effects 0.000 claims abstract description 6
- 238000001704 evaporation Methods 0.000 claims abstract description 3
- 239000000463 material Substances 0.000 claims abstract description 3
- 239000000758 substrate Substances 0.000 claims abstract description 3
- 229920005862 polyol Polymers 0.000 claims description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 14
- 150000003077 polyols Chemical class 0.000 claims description 14
- KORSJDCBLAPZEQ-UHFFFAOYSA-N dicyclohexylmethane-4,4'-diisocyanate Chemical compound C1CC(N=C=O)CCC1CC1CCC(N=C=O)CC1 KORSJDCBLAPZEQ-UHFFFAOYSA-N 0.000 claims description 11
- 239000002585 base Substances 0.000 claims description 10
- 229920000768 polyamine Polymers 0.000 claims description 8
- IUUONVQOMMQAEH-UHFFFAOYSA-N 1-methyl-2,3-dihydro-1$l^{5}-phosphole 1-oxide Chemical group CP1(=O)CCC=C1 IUUONVQOMMQAEH-UHFFFAOYSA-N 0.000 claims description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
- 150000004985 diamines Chemical class 0.000 claims description 6
- 125000005442 diisocyanate group Chemical group 0.000 claims description 6
- 150000002009 diols Chemical class 0.000 claims description 6
- -1 norbonyldiisocyanate Substances 0.000 claims description 6
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 5
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 4
- 229920000570 polyether Polymers 0.000 claims description 4
- 125000005270 trialkylamine group Chemical group 0.000 claims description 4
- 239000005059 1,4-Cyclohexyldiisocyanate Substances 0.000 claims description 2
- ALQLPWJFHRMHIU-UHFFFAOYSA-N 1,4-diisocyanatobenzene Chemical compound O=C=NC1=CC=C(N=C=O)C=C1 ALQLPWJFHRMHIU-UHFFFAOYSA-N 0.000 claims description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 2
- 229920002292 Nylon 6 Polymers 0.000 claims description 2
- 229910052744 lithium Inorganic materials 0.000 claims description 2
- 229920000515 polycarbonate Polymers 0.000 claims description 2
- 239000004417 polycarbonate Substances 0.000 claims description 2
- 150000003512 tertiary amines Chemical class 0.000 claims description 2
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical group CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims description 2
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 claims description 2
- 235000019441 ethanol Nutrition 0.000 claims 2
- CDMDQYCEEKCBGR-UHFFFAOYSA-N 1,4-diisocyanatocyclohexane Chemical compound O=C=NC1CCC(N=C=O)CC1 CDMDQYCEEKCBGR-UHFFFAOYSA-N 0.000 claims 1
- 239000003513 alkali Substances 0.000 claims 1
- 125000002843 carboxylic acid group Chemical group 0.000 claims 1
- 229960004756 ethanol Drugs 0.000 claims 1
- 229920005906 polyester polyol Polymers 0.000 claims 1
- 229920000136 polysorbate Polymers 0.000 claims 1
- 150000001732 carboxylic acid derivatives Chemical group 0.000 abstract description 4
- 238000005755 formation reaction Methods 0.000 description 7
- 239000000243 solution Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 239000004971 Cross linker Substances 0.000 description 4
- 230000035484 reaction time Effects 0.000 description 4
- 238000013112 stability test Methods 0.000 description 4
- 239000005058 Isophorone diisocyanate Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 238000007792 addition Methods 0.000 description 3
- 238000002329 infrared spectrum Methods 0.000 description 3
- 239000012948 isocyanate Substances 0.000 description 3
- 150000002513 isocyanates Chemical class 0.000 description 3
- 239000012299 nitrogen atmosphere Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 2
- IIGAAOXXRKTFAM-UHFFFAOYSA-N N=C=O.N=C=O.CC1=C(C)C(C)=C(C)C(C)=C1C Chemical compound N=C=O.N=C=O.CC1=C(C)C(C)=C(C)C(C)=C1C IIGAAOXXRKTFAM-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 2
- 239000012972 dimethylethanolamine Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000002433 hydrophilic molecules Chemical class 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 125000006850 spacer group Chemical group 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 229960003080 taurine Drugs 0.000 description 2
- UEEJHVSXFDXPFK-UHFFFAOYSA-O N-dimethylethanolamine Chemical compound C[NH+](C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-O 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000332 continued effect Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000002649 leather substitute Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229960004063 propylene glycol Drugs 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000012064 sodium phosphate buffer Substances 0.000 description 1
- GWLWWNLFFNJPDP-UHFFFAOYSA-M sodium;2-aminoethanesulfonate Chemical group [Na+].NCCS([O-])(=O)=O GWLWWNLFFNJPDP-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/02—Polymeric products of isocyanates or isothiocyanates of isocyanates or isothiocyanates only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/02—Polymeric products of isocyanates or isothiocyanates of isocyanates or isothiocyanates only
- C08G18/025—Polymeric products of isocyanates or isothiocyanates of isocyanates or isothiocyanates only the polymeric products containing carbodiimide groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/2815—Monohydroxy compounds
- C08G18/283—Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Paints Or Removers (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL1023817 | 2003-07-03 | ||
NL1023817A NL1023817C2 (nl) | 2003-07-03 | 2003-07-03 | Werkwijze voor de bereiding van stabiele polycarbodiimide dispersies in water, welke geen organische oplosmiddelen bevatten en als vernettingsmiddel kunnen worden gebruikt. |
PCT/NL2004/000470 WO2005003204A2 (fr) | 2003-07-03 | 2004-07-02 | Procede de preparation de dispersions de polycarbodiimide stables dans l'eau, depourvues de solvants organiques et pouvant etre utilisees en tant qu'agent de reticulation |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2531230A1 CA2531230A1 (fr) | 2005-01-13 |
CA2531230C true CA2531230C (fr) | 2011-01-18 |
Family
ID=33563077
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2531230A Expired - Fee Related CA2531230C (fr) | 2003-07-03 | 2004-07-02 | Procede de preparation de dispersions de polycarbodiimide stables dans l'eau, depourvues de solvants organiques et pouvant etre utilisees en tant qu'agent de reticulation |
Country Status (18)
Country | Link |
---|---|
US (1) | US7439316B2 (fr) |
EP (1) | EP1644428B2 (fr) |
JP (1) | JP5035792B2 (fr) |
KR (1) | KR101132250B1 (fr) |
CN (1) | CN100543056C (fr) |
AU (1) | AU2004253814B2 (fr) |
BR (1) | BRPI0411732B1 (fr) |
CA (1) | CA2531230C (fr) |
DK (1) | DK1644428T4 (fr) |
ES (1) | ES2466382T3 (fr) |
HK (1) | HK1094215A1 (fr) |
MX (1) | MXPA05013947A (fr) |
NL (1) | NL1023817C2 (fr) |
PL (1) | PL1644428T5 (fr) |
PT (1) | PT1644428E (fr) |
RU (1) | RU2313541C2 (fr) |
WO (1) | WO2005003204A2 (fr) |
ZA (1) | ZA200509360B (fr) |
Families Citing this family (44)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8389113B2 (en) * | 2002-09-17 | 2013-03-05 | Ppg Industries Ohio, Inc. | Substrates and articles of manufacture coated with a waterborne 2K coating composition |
JP2006035190A (ja) * | 2004-07-30 | 2006-02-09 | Nisshinbo Ind Inc | 硬化塗膜の製造方法 |
NL1031053C2 (nl) * | 2006-02-02 | 2007-08-03 | Stahl Int Bv | Werkwijze voor de bereiding van dispersies van vernettingsmiddelen in water. |
JP2010530445A (ja) * | 2007-06-08 | 2010-09-09 | スリーエム イノベイティブ プロパティズ カンパニー | フルオロアルキル含有エステルオリゴマーとポリジカルボジイミド(類)とのブレンド |
US20090246393A1 (en) * | 2008-03-27 | 2009-10-01 | Ppg Industries Ohio, Inc. | Polycarbodiimides |
WO2010028217A1 (fr) * | 2008-09-05 | 2010-03-11 | The Board Of Trustees Of The University Of Illinois | Réactifs de couplage de méthyléther-carbodiimide de poly(éthylèneglycol) pour la fonctionnalisation biologique et chimique de nanoparticules solubles dans l'eau |
US8900667B2 (en) * | 2009-12-18 | 2014-12-02 | Ppg Industries Ohio, Inc. | One-component, ambient curable waterborne coating compositions, related methods and coated substrates |
EP2542601A1 (fr) * | 2010-03-02 | 2013-01-09 | PPG Industries Ohio, Inc. | Compositions de revêtement aqueuses monocomposants durcissables à l'ambiante, procédés associés et substrats revêtus |
EP2371873A1 (fr) * | 2010-04-01 | 2011-10-05 | Bayer MaterialScience AG | Procédé de carbodiimidation |
NL2005163C2 (nl) | 2010-07-28 | 2012-01-31 | Stahl Int Bv | Werkwijze voor de bereiding van multifunctionele polycarbodiimides, welke gebruikt worden als vernettingsmiddel. |
EP2423186B1 (fr) * | 2010-08-30 | 2017-05-31 | LANXESS Deutschland GmbH | Nouveau agent adhésif basé sur des carbodiimides, dispersions aqueouses et adhésives resorcinol-formaldéhyde-latex, fibres avec adhérence améliorée, leur procédé de préparation et leur application. |
JP5945172B2 (ja) * | 2011-06-29 | 2016-07-05 | 三洋化成工業株式会社 | 樹脂改質剤 |
EP2660258A1 (fr) * | 2012-05-03 | 2013-11-06 | Rhein Chemie Rheinau GmbH | Nouvelles compositions contenant des carbodiimides, un de leurs procédés de fabrication et d'utilisation |
WO2013174894A1 (fr) | 2012-05-24 | 2013-11-28 | Basf Se | Compositions aqueuses de liants |
JP5922499B2 (ja) * | 2012-05-31 | 2016-05-24 | 三洋化成工業株式会社 | 樹脂改質剤 |
WO2014044742A1 (fr) * | 2012-09-19 | 2014-03-27 | Basf Se | Procédé de purification d'un polycarbodiimide |
US20140242281A1 (en) | 2013-02-28 | 2014-08-28 | Ppg Industries Ohio, Inc. | Methods and compositions for coating substrates |
US11008471B2 (en) | 2015-03-03 | 2021-05-18 | Solaris Technology Ltd | Waterborne light radiation absorbing polyurethane mixed polyester polymer coating system |
WO2016191868A1 (fr) | 2015-05-30 | 2016-12-08 | Dpoint Technologies Inc. | Membrane de transport de vapeur d'eau soutenue comprenant un copolymère d'oxyde de polyéthylène |
WO2017006950A1 (fr) * | 2015-07-08 | 2017-01-12 | 日清紡ケミカル株式会社 | Agent de réticulation pour résine aqueuse à base de carbodiimide |
KR102056551B1 (ko) * | 2016-01-05 | 2019-12-16 | 미쓰이 가가쿠 가부시키가이샤 | 폴리카보다이이미드 조성물, 폴리카보다이이미드 조성물의 제조 방법, 수분산 조성물, 용액 조성물, 수지 조성물 및 수지 경화물 |
CA3011278A1 (fr) * | 2016-01-15 | 2017-07-20 | Ppg Industries Ohio, Inc. | Tube ou recipient a aerosol monobloc presentant une composition de revetement |
US9957394B2 (en) | 2016-09-07 | 2018-05-01 | Ppg Industries Ohio, Inc. | Methods for preparing powder coating compositions |
JP6984838B2 (ja) | 2016-12-27 | 2021-12-22 | 日清紡ケミカル株式会社 | カルボキシル基含有水性樹脂組成物、成形体、及びポリカルボジイミド化合物の製造方法 |
US11629273B2 (en) | 2017-02-28 | 2023-04-18 | 3M Innovative Properties Company | Polyurethane adhesive with chemical resistant |
KR102428612B1 (ko) * | 2017-09-25 | 2022-08-04 | 디아이씨 가부시끼가이샤 | 합성 피혁의 제조 방법 |
EP3502157A1 (fr) | 2017-12-21 | 2019-06-26 | Covestro Deutschland AG | Dispersion aqueuse de polycarbodiimide à stabilité au stockage accrue et son procédé de production |
CN108003313B (zh) * | 2017-12-21 | 2020-08-04 | 上海朗亿功能材料有限公司 | 一种嵌段型聚碳化二亚胺水性交联剂及其制备方法 |
JP7028401B2 (ja) | 2018-02-23 | 2022-03-02 | 日清紡ケミカル株式会社 | 水性カルボジイミド含有液の製造方法 |
CN108715628B (zh) * | 2018-06-22 | 2022-04-01 | 上海朗亿功能材料有限公司 | 一种脂环族聚碳化二亚胺抗水解剂及其制备方法 |
CN108863851A (zh) * | 2018-07-13 | 2018-11-23 | 成都创世芯研科技有限公司 | 一种支化型水性碳化二亚胺型交联剂及其制备方法 |
JP2020026607A (ja) * | 2018-08-10 | 2020-02-20 | 三井化学株式会社 | 繊維処理用カルボジイミド架橋剤 |
EP3835333B1 (fr) * | 2018-08-10 | 2024-06-26 | Mitsui Chemicals, Inc. | Composition de polycarbodiimide, méthode de production de composition de polycarbodiimide, composition dispersée dans l'eau, composition de solution, composition de résine, produit durci en résine, et agent de réticulation carbodiimide pour le traitement des fibres |
JP7433311B2 (ja) | 2018-11-23 | 2024-02-19 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツング | コーティング部品の射出成型のための自動化された方法 |
BR112021008422A2 (pt) | 2018-11-23 | 2021-09-14 | Basf Coatings Gmbh | Composição, processo para a produção de uma moldagem revestida, e, uso de uma composição |
JP7462629B2 (ja) | 2018-11-23 | 2024-04-05 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツング | 基材をコーティングするための自己離型性顔料着色インモールドコーティング(imc) |
US11926076B2 (en) | 2018-11-23 | 2024-03-12 | Basf Coatings Gmbh | Manual method for injection molding coated components |
US20220153912A1 (en) * | 2019-03-22 | 2022-05-19 | Nisshinbo Chemical Inc. | Powdered polycarbodiimide compound and ester resin composition |
EP4053233A4 (fr) * | 2019-10-31 | 2023-11-08 | Nisshinbo Chemical Inc. | Composé de polycarbodiimide, composition de résine aqueuse et récipient d'emballage alimentaire |
CN111171702B (zh) * | 2020-01-17 | 2021-09-21 | 浙江佑谦特种材料有限公司 | 双重固化的聚氨酯水分散体及水性uv涂料 |
FR3120633B1 (fr) | 2021-03-15 | 2024-04-26 | Saint Gobain Weber France | Composition de revêtement contenant un polyuréthane anionique et un réticulant polycarbodiimide en dispersion aqueuse |
NL2028984B1 (en) | 2021-08-18 | 2023-02-24 | Stahl Int B V | Process for the preparation of polycarbodiimides with aziridine functions, which may be used as crosslinking agent. |
WO2023052213A1 (fr) | 2021-09-28 | 2023-04-06 | Basf Coatings Gmbh | Procédé de revêtement d'un substrat à l'aide d'une composition de revêtement comprenant un pigment naturel |
CN118103189A (zh) | 2021-10-11 | 2024-05-28 | 巴斯夫涂料有限公司 | 用于生产涂覆的非交联聚合物材料的方法 |
Family Cites Families (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4977219A (en) * | 1983-02-24 | 1990-12-11 | Union Carbide Chemicals And Plastics Company, Inc. | Low temperature crosslinking of water-borne resins |
JPS61103912A (ja) * | 1984-10-25 | 1986-05-22 | Nitto Electric Ind Co Ltd | 樹脂水性エマルジヨン |
US5117059A (en) † | 1989-06-01 | 1992-05-26 | Union Carbide Chemicals & Plastics Technology Corporation | Monodisperse multifunctional carbodiimides |
DE3937610A1 (de) * | 1989-11-11 | 1991-05-16 | Hoechst Ag | Verfahren zur gewinnung von phosphorigsaeure-bis-(2,4-di-tert.-butyl-phenyl)ester-halogeniden |
US5008363A (en) * | 1990-03-23 | 1991-04-16 | Union Carbide Chemicals And Plastics Technology Corporation | Low temperature active aliphatic aromatic polycarbodiimides |
DE4126359A1 (de) † | 1991-08-09 | 1993-02-11 | Basf Ag | Oligomere carbodiimide |
US5574083A (en) * | 1993-06-11 | 1996-11-12 | Rohm And Haas Company | Aromatic polycarbodiimide crosslinkers |
US5859166A (en) * | 1994-06-10 | 1999-01-12 | Nisshinbo Industries, Inc. | Hydrophilic resin composition |
JP3629041B2 (ja) * | 1994-06-10 | 2005-03-16 | 日清紡績株式会社 | 水性テトラメチルキシリレンカルボジイミド |
JP3438957B2 (ja) * | 1994-08-11 | 2003-08-18 | 日清紡績株式会社 | 補強材用の水性表面処理剤、該水性表面処理剤で処理された補強材及び補強材により強化された複合材 |
KR100304475B1 (ko) * | 1996-01-18 | 2001-11-22 | 야마모토 히데키 | 방향족폴리카보디이미드및이로부터제조된필름 |
JP3518149B2 (ja) † | 1996-02-29 | 2004-04-12 | 日清紡績株式会社 | 水性プレコートメタル用塗料 |
US5929188A (en) * | 1996-04-30 | 1999-07-27 | Dainichiseika Color & Chemicals Mfg. Co., Ltd. | Polycarbodiimide compound, production process thereof, resin composition, and treatment method of article |
US5998543A (en) * | 1996-05-28 | 1999-12-07 | Eastman Chemical Company | Stable amino-containing polymer latex blends |
WO1999006459A1 (fr) * | 1997-07-31 | 1999-02-11 | Basf Aktiengesellschaft | Dispersions aqueuses contenant des polyurethanes avec des groupes carbodiimide |
CN1265682A (zh) † | 1997-07-31 | 2000-09-06 | 巴斯福股份公司 | 包含聚氨酯的隐性交联水性分散体 |
US6005035A (en) * | 1997-09-18 | 1999-12-21 | Eastman Chemical Company | Stable waterborne polymer compositions containing poly(alkylenimines) |
JPH11140164A (ja) * | 1997-11-05 | 1999-05-25 | Jsr Corp | 熱硬化性樹脂組成物およびその硬化物 |
JP3715464B2 (ja) * | 1998-04-20 | 2005-11-09 | 日清紡績株式会社 | 水性ジシクロヘキシルメタンカルボジイミド組成物 |
US6184410B1 (en) * | 1998-05-14 | 2001-02-06 | Basf Aktiengesellschaft | Carbodiimides based on 1,3-bis(1-methyl-1-isocyanatoethyl)benzene |
DE19837377A1 (de) * | 1998-08-18 | 2000-02-24 | Basf Ag | Latent vernetzende wässerige Dispersionen enthaltend ein Polyurethan |
US6248857B1 (en) * | 1998-10-01 | 2001-06-19 | Nitto Denko Corporation | Aromatic polycarbodiimide and polycarbodiimide sheet |
JP4318828B2 (ja) * | 1999-04-30 | 2009-08-26 | 日本ペイント株式会社 | 親水化変性ポリカルボジイミド化合物の製造方法および親水化変性ポリカルボジイミド化合物、ならびにこれを含んだ常温硬化型水性塗料組成物 |
JP4278265B2 (ja) * | 1999-04-30 | 2009-06-10 | 日本ペイント株式会社 | 熱硬化性水性塗料組成物およびこれを用いた塗膜形成方法、ならびに、複層塗膜形成方法 |
JP3601766B2 (ja) * | 1999-05-10 | 2004-12-15 | 大日精化工業株式会社 | 乳化性ポリカルボジイミド化合物組成物、架橋性重合体組成物及び物品の処理方法 |
AU775843B2 (en) * | 1999-05-18 | 2004-08-19 | Rohm And Haas Company | Method of improving stability of aromatic polycarbodiimides |
DE10015658A1 (de) * | 2000-03-29 | 2001-10-04 | Rhein Chemie Rheinau Gmbh | Blockcopolymere auf Basis von Polycarbodiimiden, ein Verfahren zu ihrer Herstellung und ihre Verwendung als Hydrolysestabilisatoren |
-
2003
- 2003-07-03 NL NL1023817A patent/NL1023817C2/nl not_active IP Right Cessation
-
2004
- 2004-07-02 RU RU2005141416/04A patent/RU2313541C2/ru not_active IP Right Cessation
- 2004-07-02 PT PT47487004T patent/PT1644428E/pt unknown
- 2004-07-02 WO PCT/NL2004/000470 patent/WO2005003204A2/fr active Application Filing
- 2004-07-02 CN CNB2004800163516A patent/CN100543056C/zh not_active Expired - Lifetime
- 2004-07-02 AU AU2004253814A patent/AU2004253814B2/en not_active Expired
- 2004-07-02 EP EP04748700.4A patent/EP1644428B2/fr not_active Expired - Lifetime
- 2004-07-02 MX MXPA05013947A patent/MXPA05013947A/es active IP Right Grant
- 2004-07-02 BR BRPI0411732-8A patent/BRPI0411732B1/pt active IP Right Grant
- 2004-07-02 PL PL04748700.4T patent/PL1644428T5/pl unknown
- 2004-07-02 ZA ZA200509360A patent/ZA200509360B/en unknown
- 2004-07-02 KR KR1020057022052A patent/KR101132250B1/ko active IP Right Grant
- 2004-07-02 DK DK04748700.4T patent/DK1644428T4/da active
- 2004-07-02 CA CA2531230A patent/CA2531230C/fr not_active Expired - Fee Related
- 2004-07-02 ES ES04748700.4T patent/ES2466382T3/es not_active Expired - Lifetime
- 2004-07-02 JP JP2006516993A patent/JP5035792B2/ja not_active Expired - Lifetime
-
2005
- 2005-12-28 US US11/320,189 patent/US7439316B2/en active Active
-
2006
- 2006-12-22 HK HK06114139.7A patent/HK1094215A1/xx not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
EP1644428A2 (fr) | 2006-04-12 |
US7439316B2 (en) | 2008-10-21 |
NL1023817C2 (nl) | 2005-01-04 |
KR101132250B1 (ko) | 2012-04-02 |
MXPA05013947A (es) | 2006-07-03 |
PL1644428T5 (pl) | 2024-07-15 |
PL1644428T3 (pl) | 2014-09-30 |
RU2005141416A (ru) | 2006-08-10 |
WO2005003204A2 (fr) | 2005-01-13 |
BRPI0411732B1 (pt) | 2014-12-16 |
JP5035792B2 (ja) | 2012-09-26 |
EP1644428B2 (fr) | 2024-05-08 |
CA2531230A1 (fr) | 2005-01-13 |
BRPI0411732A (pt) | 2006-08-08 |
RU2313541C2 (ru) | 2007-12-27 |
AU2004253814A1 (en) | 2005-01-13 |
PT1644428E (pt) | 2014-06-24 |
CN100543056C (zh) | 2009-09-23 |
WO2005003204A3 (fr) | 2005-03-10 |
DK1644428T4 (da) | 2024-05-27 |
ZA200509360B (en) | 2007-04-25 |
HK1094215A1 (en) | 2007-03-23 |
DK1644428T3 (da) | 2014-06-23 |
JP2007521360A (ja) | 2007-08-02 |
US20060106189A1 (en) | 2006-05-18 |
CN1805984A (zh) | 2006-07-19 |
EP1644428B1 (fr) | 2014-04-16 |
ES2466382T3 (es) | 2014-06-10 |
KR20060017609A (ko) | 2006-02-24 |
AU2004253814B2 (en) | 2009-12-17 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CA2531230C (fr) | Procede de preparation de dispersions de polycarbodiimide stables dans l'eau, depourvues de solvants organiques et pouvant etre utilisees en tant qu'agent de reticulation | |
EP1981922B1 (fr) | Procédé d'élaboration de dispersions d'agents de réticulation dans l'eau | |
EP2598555B1 (fr) | Procédé pour la préparation de polycarbodiimides multifonctionnels qui sont utilisés en tant qu'agents de réticulation | |
CA1271775A (fr) | Derives d'isocyanate renfermant des groupes carbodiimides; methode de preparation et utilisation comme additifs pour les solutions ou les dispersions aqueuses de matieres plastiques | |
DE69633036T2 (de) | Aspartat-funktionelle Polyhydantoin-Prepolymere sowie deren Verwendung in Beschichtungszusammensetzungen | |
HUT65861A (en) | Multifunctional water-dispersible crosslinking agent process for producing and using thereof | |
JP5210632B2 (ja) | 乳化性ポリイソシアネート | |
EP1474461B1 (fr) | Procede pour produire des polyurees fortement ramifiees et hautement fonctionnelles | |
DE69606350T2 (de) | Hydroxyfunktionelle Polyhydantoin-Prepolymere sowie deren Verwendung in Beschichtungszusammensetzungen | |
EP3263618A1 (fr) | Allophanates fonctionnalisés avec des alokoxysilanes | |
CA2072902A1 (fr) | Dispersions aqueuses de polyisocyanates bloques | |
KR101080442B1 (ko) | 친수화 블로킹된 폴리이소시아네이트 | |
EP1555276A1 (fr) | Dispersions contenant des coploymères de polysiloxanes organiques et de polyurée | |
AU776231B2 (en) | Aqueous dispersion of a polyurethane containing blocked reactive sites | |
US20050049358A1 (en) | Water dispersible polyisocyanate composition bearing urea and/or biuret and its uses | |
CN114921168B (zh) | 一种碳硅纳米材料改性水性聚氨酯乳液、合成方法及其应用 | |
DE69606910T2 (de) | Blockierte Polyisocyanate mit verbesserter thermischer Stabilität | |
DE69606912T2 (de) | Blockierte Polyisocyanate mit verbesserter thermischer Stabilität | |
DE69608848T2 (de) | Thermoreaktive wässrige Zusammensetzungen auf Basis stabiler Polyurethandispersionen oder Lösungen | |
WO2023148674A1 (fr) | Composition d'isocyanates bloqués, utilisation de composés en tant qu'agents de blocage d'isocyanates | |
WO2023148675A1 (fr) | Composition d'isocyanates bloqués et utilisation de composés en tant qu'agents de blocage d'isocyanates | |
DE19856968A1 (de) | Malonester/Triazolmischblockiertes HDI-Trimerisat/Formaldehydstabilisierung | |
WO2021064056A1 (fr) | Compositions de polyuréthane à base d'isocyanates bloqués utilisant un nouvel agent de blocage, procédé de fabrication et utilisations de celles-ci |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |
Effective date: 20130703 |