CA2128064C - High melt strength, propylene polymer, process for making it, and use thereof - Google Patents
High melt strength, propylene polymer, process for making it, and use thereof Download PDFInfo
- Publication number
- CA2128064C CA2128064C CA002128064A CA2128064A CA2128064C CA 2128064 C CA2128064 C CA 2128064C CA 002128064 A CA002128064 A CA 002128064A CA 2128064 A CA2128064 A CA 2128064A CA 2128064 C CA2128064 C CA 2128064C
- Authority
- CA
- Canada
- Prior art keywords
- ethylene
- propylene
- olefin
- alpha
- copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 192
- 238000000034 method Methods 0.000 title claims abstract description 56
- 230000008569 process Effects 0.000 title claims abstract description 45
- 239000002861 polymer material Substances 0.000 claims abstract description 142
- 239000007787 solid Substances 0.000 claims abstract description 62
- 239000000463 material Substances 0.000 claims abstract description 52
- 229920000642 polymer Polymers 0.000 claims abstract description 36
- 238000005482 strain hardening Methods 0.000 claims abstract description 26
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000001301 oxygen Substances 0.000 claims abstract description 24
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 24
- 238000004519 manufacturing process Methods 0.000 claims abstract description 6
- 238000007765 extrusion coating Methods 0.000 claims abstract description 4
- 238000003856 thermoforming Methods 0.000 claims abstract description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 220
- 239000005977 Ethylene Substances 0.000 claims description 220
- 239000004711 α-olefin Substances 0.000 claims description 199
- 229920001577 copolymer Polymers 0.000 claims description 143
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 112
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 98
- 239000000203 mixture Substances 0.000 claims description 66
- -1 propylene, ethylene Chemical group 0.000 claims description 63
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 57
- 239000008096 xylene Substances 0.000 claims description 57
- 150000001993 dienes Chemical class 0.000 claims description 23
- 239000000155 melt Substances 0.000 claims description 19
- 239000004743 Polypropylene Substances 0.000 claims description 18
- 229920001384 propylene homopolymer Polymers 0.000 claims description 17
- 238000000113 differential scanning calorimetry Methods 0.000 claims description 15
- 229920001519 homopolymer Polymers 0.000 claims description 15
- 230000005865 ionizing radiation Effects 0.000 claims description 15
- 150000001336 alkenes Chemical class 0.000 claims description 14
- 229910052799 carbon Inorganic materials 0.000 claims description 14
- 125000000217 alkyl group Chemical group 0.000 claims description 13
- 229920005684 linear copolymer Polymers 0.000 claims description 13
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 13
- 229920000098 polyolefin Polymers 0.000 claims description 13
- 238000001125 extrusion Methods 0.000 claims description 8
- 239000011324 bead Substances 0.000 claims description 6
- 238000010894 electron beam technology Methods 0.000 claims description 6
- 238000001879 gelation Methods 0.000 claims description 6
- 239000004604 Blowing Agent Substances 0.000 claims description 5
- 238000012668 chain scission Methods 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- 230000001678 irradiating effect Effects 0.000 claims description 4
- 239000012768 molten material Substances 0.000 claims description 4
- 239000000758 substrate Substances 0.000 claims description 4
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical compound F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 claims description 2
- 239000004088 foaming agent Substances 0.000 claims description 2
- 230000009477 glass transition Effects 0.000 claims description 2
- 238000002844 melting Methods 0.000 claims description 2
- 230000008018 melting Effects 0.000 claims description 2
- 229920005606 polypropylene copolymer Polymers 0.000 claims 2
- 231100000987 absorbed dose Toxicity 0.000 claims 1
- 238000007707 calorimetry Methods 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 238000002156 mixing Methods 0.000 claims 1
- 229920005629 polypropylene homopolymer Polymers 0.000 claims 1
- 230000005855 radiation Effects 0.000 abstract description 17
- 238000005187 foaming Methods 0.000 abstract 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 17
- 239000003381 stabilizer Substances 0.000 description 17
- 229920001971 elastomer Polymers 0.000 description 14
- 239000000654 additive Substances 0.000 description 13
- 150000003254 radicals Chemical class 0.000 description 12
- 238000012546 transfer Methods 0.000 description 11
- 239000006260 foam Substances 0.000 description 9
- 239000007789 gas Substances 0.000 description 9
- 239000002245 particle Substances 0.000 description 9
- 239000005060 rubber Substances 0.000 description 9
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- 239000008188 pellet Substances 0.000 description 8
- 239000012530 fluid Substances 0.000 description 7
- 230000000996 additive effect Effects 0.000 description 6
- 239000007795 chemical reaction product Substances 0.000 description 6
- 238000004132 cross linking Methods 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 239000012298 atmosphere Substances 0.000 description 5
- 239000000806 elastomer Substances 0.000 description 5
- 239000012299 nitrogen atmosphere Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 4
- 238000010276 construction Methods 0.000 description 4
- 239000011261 inert gas Substances 0.000 description 4
- 238000010128 melt processing Methods 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 230000005012 migration Effects 0.000 description 4
- 238000013508 migration Methods 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 101000618467 Hypocrea jecorina (strain ATCC 56765 / BCRC 32924 / NRRL 11460 / Rut C-30) Endo-1,4-beta-xylanase 2 Proteins 0.000 description 3
- BEIOEBMXPVYLRY-UHFFFAOYSA-N [4-[4-bis(2,4-ditert-butylphenoxy)phosphanylphenyl]phenyl]-bis(2,4-ditert-butylphenoxy)phosphane Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(C=1C=CC(=CC=1)C=1C=CC(=CC=1)P(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C BEIOEBMXPVYLRY-UHFFFAOYSA-N 0.000 description 3
- 238000013019 agitation Methods 0.000 description 3
- 238000010924 continuous production Methods 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- PWWSSIYVTQUJQQ-UHFFFAOYSA-N distearyl thiodipropionate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCCCCCC PWWSSIYVTQUJQQ-UHFFFAOYSA-N 0.000 description 3
- 239000012634 fragment Substances 0.000 description 3
- 238000001746 injection moulding Methods 0.000 description 3
- 238000010791 quenching Methods 0.000 description 3
- 230000000171 quenching effect Effects 0.000 description 3
- 230000000717 retained effect Effects 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 238000012993 chemical processing Methods 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 235000008504 concentrate Nutrition 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 229920005653 propylene-ethylene copolymer Polymers 0.000 description 2
- 229920005604 random copolymer Polymers 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- DDMOUSALMHHKOS-UHFFFAOYSA-N 1,2-dichloro-1,1,2,2-tetrafluoroethane Chemical compound FC(F)(Cl)C(F)(F)Cl DDMOUSALMHHKOS-UHFFFAOYSA-N 0.000 description 1
- 241000531891 Alburnus alburnus Species 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- 101100168117 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) con-8 gene Proteins 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000010504 bond cleavage reaction Methods 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000002523 gelfiltration Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Ethene-propene or ethene-propene-diene copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/48—Isomerisation; Cyclisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/28—Treatment by wave energy or particle radiation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2201/00—Foams characterised by the foaming process
- C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
- C08J2201/03—Extrusion of the foamable blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
- C08J2323/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
- C08J2323/14—Copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/16—Ethene-propene or ethene-propene-diene copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L2023/40—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with compounds changing molecular weight
- C08L2023/42—Depolymerisation, vis-breaking or degradation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/02—Heterophasic composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
- C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S522/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S522/911—Specified treatment involving megarad or less
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/092,344 | 1993-07-15 | ||
| US08/092,344 US5414027A (en) | 1993-07-15 | 1993-07-15 | High melt strength, propylene polymer, process for making it, and use thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2128064A1 CA2128064A1 (en) | 1995-01-16 |
| CA2128064C true CA2128064C (en) | 2002-12-31 |
Family
ID=22232774
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002128064A Expired - Fee Related CA2128064C (en) | 1993-07-15 | 1994-07-14 | High melt strength, propylene polymer, process for making it, and use thereof |
Country Status (10)
| Country | Link |
|---|---|
| US (3) | US5414027A (cg-RX-API-DMAC10.html) |
| EP (1) | EP0634441B1 (cg-RX-API-DMAC10.html) |
| JP (1) | JP3392947B2 (cg-RX-API-DMAC10.html) |
| KR (1) | KR100311290B1 (cg-RX-API-DMAC10.html) |
| CN (1) | CN1087019C (cg-RX-API-DMAC10.html) |
| AT (1) | ATE166368T1 (cg-RX-API-DMAC10.html) |
| CA (1) | CA2128064C (cg-RX-API-DMAC10.html) |
| DE (1) | DE69410357T2 (cg-RX-API-DMAC10.html) |
| MX (1) | MX9405377A (cg-RX-API-DMAC10.html) |
| TW (1) | TW304969B (cg-RX-API-DMAC10.html) |
Families Citing this family (184)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5508319A (en) * | 1991-06-21 | 1996-04-16 | Montell North America Inc. | High melt strength, ethylene polymer, process for making it, and use thereof |
| IT1260495B (it) * | 1992-05-29 | 1996-04-09 | Himont Inc | Concentrati adatti alla preparazione di poliolefine funzionalizzate e processo di funzionalizzazione mediante detti concentrati |
| US5414027A (en) * | 1993-07-15 | 1995-05-09 | Himont Incorporated | High melt strength, propylene polymer, process for making it, and use thereof |
| JP2793482B2 (ja) * | 1993-10-13 | 1998-09-03 | 昭和電工株式会社 | ポリオレフィン系樹脂組成物およびその成形体 |
| US5773515A (en) * | 1994-08-25 | 1998-06-30 | Solvay Engineered Polymers | Engineered polyolefin materials |
| US5763534A (en) * | 1994-08-25 | 1998-06-09 | Solvay Engineered Polymers | Thermoplastic polypropylene blends with mixtures of ethylene/butene and ethylene/octene copolymer elastomers |
| CN1160412A (zh) * | 1994-10-12 | 1997-09-24 | 金伯利-克拉克环球有限公司 | 可熔融挤出的热塑性聚丙烯组合物及由此所制备的非织造织物 |
| IT1274503B (it) * | 1995-05-15 | 1997-07-17 | Montell North America Inc | Fibre poliolefiniche ad elevata tenacita' |
| US5738745A (en) * | 1995-11-27 | 1998-04-14 | Kimberly-Clark Worldwide, Inc. | Method of improving the photostability of polypropylene compositions |
| DE19544828A1 (de) * | 1995-12-01 | 1997-06-05 | Hoechst Ag | Hochmolekulare Copolymere |
| US6211295B1 (en) * | 1995-12-01 | 2001-04-03 | Montell Technology Company By Hoofddorp | Polyolefin compositions and blown films obtained therefrom |
| US5820981A (en) * | 1996-04-02 | 1998-10-13 | Montell North America Inc. | Radiation visbroken polypropylene and fibers made therefrom |
| CA2208337C (en) * | 1996-06-22 | 2002-05-14 | Clifford P. Ronden | Process for the production of lightweight cellular composites of wood waste and thermoplastic polymers |
| IT1287179B1 (it) * | 1996-11-15 | 1998-08-04 | Montell North America Inc | Miscela polimerica per slush moulding |
| TW442528B (en) * | 1996-12-02 | 2001-06-23 | Chisso Corp | Polypropylene composition |
| US5947944A (en) * | 1996-12-30 | 1999-09-07 | Kimberly-Clark Worldwide, Inc. | Stretched-thinned films comprising low crystallinity polymers and laminates thereof |
| DE69836415T3 (de) | 1997-02-07 | 2014-03-27 | Exxonmobil Chemical Patents Inc. | Herstellung von vinyl enthaltenden polymeren |
| CA2277111A1 (en) | 1997-02-07 | 1998-08-13 | Exxon Chemical Patents, Inc. | Thermoplastic elastomer compositions from branched olefin copolymers |
| EP0872516A1 (en) * | 1997-04-15 | 1998-10-21 | Dsm N.V. | Foamable polymeric composition |
| US6218023B1 (en) | 1997-04-21 | 2001-04-17 | Montell North America, Inc. | Co-extruded laminate comprising at least one propylene graft copolymer layer |
| US5916929A (en) * | 1997-06-23 | 1999-06-29 | E-Beam Services, Inc. | Method for irradiating organic polymers |
| US5986009A (en) * | 1997-12-03 | 1999-11-16 | The Dow Chemical Company | Blends of polypropylenes |
| US6197910B1 (en) | 1997-12-10 | 2001-03-06 | Exxon Chemical Patents, Inc. | Propylene polymers incorporating macromers |
| US6184327B1 (en) | 1997-12-10 | 2001-02-06 | Exxon Chemical Patents, Inc. | Elastomeric propylene polymers |
| US6060533A (en) * | 1998-01-09 | 2000-05-09 | Montell North America Inc. | Process for making foam articles having good low temperature toughness from high melt strength propyline polymer materials |
| US6486246B1 (en) * | 1998-02-03 | 2002-11-26 | Montell Technology Company Bv | Polyolefin based hot melt adhesive composition |
| DE19815045B4 (de) * | 1998-04-03 | 2004-04-08 | Borealis Gmbh | Verbunde mit textilem Charakter und Verfahren zu deren Herstellung sowie deren Verwendung |
| DE19815046A1 (de) * | 1998-04-03 | 1999-10-14 | Borealis Ag | Polyolefinfolien und Polyolefinbeschichtungen von Substraten |
| US6306960B1 (en) | 1998-05-13 | 2001-10-23 | Exxonmobil Chemical Patents Inc. | Articles formed from foamable polypropylene polymer |
| US6692679B1 (en) * | 1998-06-10 | 2004-02-17 | Depuy Orthopaedics, Inc. | Cross-linked molded plastic bearings |
| EP1522553B1 (en) | 1998-07-01 | 2007-04-11 | ExxonMobil Chemical Patents Inc. | Elastic blends comprising crystalline polymer and crystallizable polymers of propylene |
| JP5407099B2 (ja) | 1998-08-26 | 2014-02-05 | エクソンモービル・ケミカル・パテンツ・インク | 分枝ポリプロピレン組成物 |
| US6720362B1 (en) | 1998-09-17 | 2004-04-13 | The Dow Chemical Company | Perforated foams |
| AU2476600A (en) | 1998-12-08 | 2000-06-26 | Dow Chemical Company, The | Mel-bondable polypropylene/ethylene polymer fiber and composition for making thesame |
| MXPA01006372A (es) | 1998-12-21 | 2002-06-04 | Exxonmobil Chem Patents Inc | Composiciones de etileno-propileno semi-cristalinas, ramificadas. |
| JP4310832B2 (ja) * | 1999-01-13 | 2009-08-12 | チッソ株式会社 | プロピレン系樹脂シートおよびそれを用いた成形体 |
| US6630231B2 (en) * | 1999-02-05 | 2003-10-07 | 3M Innovative Properties Company | Composite articles reinforced with highly oriented microfibers |
| US6110588A (en) | 1999-02-05 | 2000-08-29 | 3M Innovative Properties Company | Microfibers and method of making |
| EP1038893A1 (en) * | 1999-03-19 | 2000-09-27 | Fina Research S.A. | Production of polypropylene having improved properties |
| US6265037B1 (en) | 1999-04-16 | 2001-07-24 | Andersen Corporation | Polyolefin wood fiber composite |
| US6174930B1 (en) | 1999-04-16 | 2001-01-16 | Exxon Chemical Patents, Inc. | Foamable polypropylene polymer |
| US6225411B1 (en) | 1999-04-19 | 2001-05-01 | Montell Technology Company Bv | Soft propylene polymer blend with high melt strength |
| US6143825A (en) * | 1999-05-14 | 2000-11-07 | Montell Technology Company Bv | Adhesive propylene polymer compositions suitable for coating substrates |
| US6306518B1 (en) * | 1999-05-19 | 2001-10-23 | Montell Technology Company Bv | High surface gloss, co-extruded sheets from propylene polymer materials |
| US6489019B1 (en) * | 1999-05-19 | 2002-12-03 | Basell Poliolefine Italia S.P.A. | High surface gloss, co-extruded sheets from olefin polymer materials |
| CA2377008C (en) | 1999-06-24 | 2008-11-25 | The Dow Chemical Company | Polyolefin composition with improved impact properties |
| US6541105B1 (en) | 1999-09-16 | 2003-04-01 | Dow Global Technologies Inc. | Acoustical open-cell polylefins and process for making |
| US6809168B2 (en) * | 1999-12-10 | 2004-10-26 | Exxonmobil Chemical Patents Inc. | Articles formed from propylene diene copolymers |
| US6977287B2 (en) * | 1999-12-10 | 2005-12-20 | Exxonmobil Chemical Patents Inc. | Propylene diene copolymers |
| CA2393414A1 (en) * | 1999-12-10 | 2001-06-14 | Main Chang | Propylene diene copolymerized polymers |
| WO2001088001A1 (en) * | 1999-12-30 | 2001-11-22 | Opp Petroquímica S.A. | Process for preparing high melt strength polypropylene and crosslinked polypropylene prepared therewith |
| US6593005B2 (en) | 2000-01-24 | 2003-07-15 | Dow Global Technologies Inc. | Composition and films thereof |
| ES2257397T3 (es) | 2000-03-17 | 2006-08-01 | Dow Global Technologies Inc. | Espuma poliolefinica macrocelular que tiene una alta temperatura de servicio para aplicaciones acusticas. |
| MXPA02008939A (es) * | 2000-03-17 | 2004-10-15 | Dow Global Technologies Inc | Espuma de polimero de absorcion acustica que tiene funcionamiento mejorado de aislamiento termico. |
| DE60117536T2 (de) | 2000-05-04 | 2006-11-09 | Dow Global Technologies, Inc., Midland | Molekularschmelze und verfahren zu ihrer herstellung und anwendung |
| DE10023441B4 (de) * | 2000-05-12 | 2006-02-09 | Clariant Gmbh | Verwendung von Wachsmischungen für Lacke |
| WO2001092403A2 (en) * | 2000-05-26 | 2001-12-06 | Dow Global Technologies Inc. | Polyethylene rich/polypropylene blends and their uses |
| US6468451B1 (en) | 2000-06-23 | 2002-10-22 | 3M Innovative Properties Company | Method of making a fibrillated article |
| EP1170322A1 (en) * | 2000-07-04 | 2002-01-09 | ATOFINA Research | Heat sealing polyolefins |
| EP1170307A1 (en) * | 2000-07-05 | 2002-01-09 | ATOFINA Research | Moulding of polyolefins having improved properties |
| EP1170309A1 (en) * | 2000-07-05 | 2002-01-09 | ATOFINA Research | Production of propylene copolymers having improved properties |
| EP1170306A1 (en) * | 2000-07-05 | 2002-01-09 | ATOFINA Research | Production of polypropylene having improved properties |
| EP1170305A1 (en) * | 2000-07-05 | 2002-01-09 | ATOFINA Research | Production of polyolefins having improved properties |
| CA2323307A1 (en) | 2000-10-16 | 2002-04-16 | Peter Jackson | Crosslinked, heat shrinkable polypropylene compositions |
| US6417242B1 (en) | 2000-10-23 | 2002-07-09 | Dow Global Technologies Inc. | Propylene polymer foams |
| US6420024B1 (en) * | 2000-12-21 | 2002-07-16 | 3M Innovative Properties Company | Charged microfibers, microfibrillated articles and use thereof |
| WO2002051890A1 (en) | 2000-12-22 | 2002-07-04 | Dow Global Technologies Inc. | Propylene copolymer foams |
| US6590034B2 (en) | 2001-01-02 | 2003-07-08 | Dow Global Technologies Inc. | Peelable seal and method of making and using same |
| US7537829B2 (en) * | 2001-02-22 | 2009-05-26 | Exxonmobil Oil Corporation | Multi-layer films having improved sealing properties |
| JP4796235B2 (ja) * | 2001-03-27 | 2011-10-19 | 上野製薬株式会社 | ビナフトール誘導体金属塩およびその製法 |
| US6680114B2 (en) | 2001-05-15 | 2004-01-20 | 3M Innovative Properties Company | Fibrous films and articles from microlayer substrates |
| US20030211310A1 (en) * | 2001-06-21 | 2003-11-13 | Haas Christopher K. | Foam and method of making |
| US6620695B2 (en) * | 2001-07-30 | 2003-09-16 | The United States Of America As Represented By The Secretary Of The Navy | Method for increasing fracture toughness and reducing brittleness of semi-crystalline polymer |
| CN1276019C (zh) * | 2001-10-01 | 2006-09-20 | 陶氏环球技术公司 | 可吹塑的丙烯聚合物组合物 |
| US20050070673A1 (en) * | 2001-10-01 | 2005-03-31 | Novak Leo R. | Thermoformable propylene polymer compositions |
| PL368462A1 (en) * | 2001-11-27 | 2005-03-21 | Basell Poliolefine Italia S.P.A. | Clear and flexible propylene polymer compositions |
| US6913056B2 (en) | 2002-01-31 | 2005-07-05 | Baxter International Inc. | Apparatus and method for connecting and disconnecting flexible tubing |
| US7226955B2 (en) * | 2002-02-22 | 2007-06-05 | Dow Global Technologies Inc. | Macrocellular acoustic foam containing particulate additive |
| US6869538B2 (en) | 2002-05-24 | 2005-03-22 | Baxter International, Inc. | Method and apparatus for controlling a medical fluid heater |
| US6764761B2 (en) * | 2002-05-24 | 2004-07-20 | Baxter International Inc. | Membrane material for automated dialysis system |
| AU2003234608A1 (en) | 2002-05-24 | 2003-12-12 | Baxter Healthcare S.A. | Automated dialysis system |
| JP4468801B2 (ja) | 2002-05-24 | 2010-05-26 | バクスター・インターナショナル・インコーポレイテッド | 自動化された透析装置のためのハードウエアシステム、方法及び装置 |
| EP2314333B1 (en) | 2002-05-24 | 2012-07-11 | Baxter International Inc. | Dialysis system comprising a display device |
| US20030232210A1 (en) * | 2002-06-18 | 2003-12-18 | 3M Innovative Properties Company | Ink-receptive foam article |
| EP1380613A1 (en) * | 2002-07-09 | 2004-01-14 | ATOFINA Research | Long chain branching polypropylene |
| US6734253B2 (en) * | 2002-07-19 | 2004-05-11 | Dow Global Technologies, Inc. | Scratch and mar resistant propylene polymer composition |
| US7238164B2 (en) * | 2002-07-19 | 2007-07-03 | Baxter International Inc. | Systems, methods and apparatuses for pumping cassette-based therapies |
| WO2005108442A1 (en) | 2002-10-15 | 2005-11-17 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| US6844038B2 (en) * | 2003-01-24 | 2005-01-18 | Baxter International Inc. | Peelable overpouch films |
| US7820282B2 (en) * | 2003-04-10 | 2010-10-26 | 3M Innovative Properties Company | Foam security substrate |
| US7655296B2 (en) | 2003-04-10 | 2010-02-02 | 3M Innovative Properties Company | Ink-receptive foam article |
| US7883769B2 (en) * | 2003-06-18 | 2011-02-08 | 3M Innovative Properties Company | Integrally foamed microstructured article |
| JP2007502338A (ja) * | 2003-08-12 | 2007-02-08 | バーセル ポリオレフィン イタリア ソシエタ ア レスポンサビリタ リミタータ | 照射されたブテン−1ポリマー組成物 |
| DE602004031638D1 (de) * | 2003-09-12 | 2011-04-14 | Kaneka Corp | Harzzusammensetzung auf basis von polypropylen, diese enthaltende expandierte formkörper und herstellungsverfahren dafür |
| CA2539494C (en) | 2003-09-22 | 2011-12-06 | Baxter International Inc. | High-pressure sterilization to terminally sterilize pharmaceutical preparations and medical products |
| US20050085785A1 (en) * | 2003-10-17 | 2005-04-21 | Sherwin Shang | High impact strength film and non-pvc containing container and pouch and overpouch |
| US20050186377A1 (en) * | 2004-02-19 | 2005-08-25 | Hurst William S. | Solventless plastic bonding of medical devices and container components through infrared heating |
| US8076386B2 (en) * | 2004-02-23 | 2011-12-13 | Molecular Imprints, Inc. | Materials for imprint lithography |
| US7226977B2 (en) * | 2004-04-19 | 2007-06-05 | Sunoco, Inc. ( R&M) | High melt flow rate thermoplastic polyolefins produced in-reactor |
| US7378476B2 (en) * | 2004-06-25 | 2008-05-27 | Ineos Usa Llc | Olefin polymerization process in the presence of a radical generating system |
| US7511105B2 (en) * | 2004-07-01 | 2009-03-31 | The Penn State Research Foundation | One-pot process and reagents for preparing long chain branched polymers |
| US20090198031A1 (en) * | 2004-07-01 | 2009-08-06 | The Penn State Research Foundation | One-pot process and reagents for preparing long chain branched polymers |
| CA2577290C (en) * | 2004-08-13 | 2011-03-08 | Srivatsan Srinivas Iyer | Polymeric compositions including their uses and methods of production |
| DE102004040991B4 (de) * | 2004-08-17 | 2006-10-19 | Leibniz-Institut Für Polymerforschung Dresden E.V. | Verfahren zur Erzeugung von langkettenverzweigtem Polypropylen |
| US7456231B2 (en) * | 2005-02-02 | 2008-11-25 | Shawcor Ltd. | Radiation-crosslinked polyolefin compositions |
| WO2006082144A1 (en) | 2005-02-03 | 2006-08-10 | Basell Poliolefine Italia S.R.L. | Propylene polymer composition for injection molding |
| US8076416B2 (en) * | 2005-02-04 | 2011-12-13 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizates and their use |
| US20060255501A1 (en) * | 2005-05-11 | 2006-11-16 | Shawcor Ltd. | Crosslinked chlorinated polyolefin compositions |
| KR20080022101A (ko) | 2005-05-12 | 2008-03-10 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 프로필렌-에틸렌 공중합체 및 그 제조 방법 |
| EP1899415B1 (en) * | 2005-07-01 | 2011-08-10 | Basell Poliolefine Italia S.r.l. | Propylene polymers having broad molecular weight distribution |
| US20070004861A1 (en) * | 2005-07-01 | 2007-01-04 | Kevin Cai | High melt strength polypropylene resins and method for making same |
| JP5127711B2 (ja) * | 2005-08-08 | 2013-01-23 | サンアロマー株式会社 | ポリプロピレン樹脂の核化方法 |
| ATE394448T1 (de) * | 2005-08-19 | 2008-05-15 | Borealis Tech Oy | Polyolefin-schaum |
| US7465776B2 (en) * | 2006-06-01 | 2008-12-16 | Sunoco, Inc. (R&M) | High crystallinity, high melt flow rate polypropylene |
| US8012550B2 (en) * | 2006-10-04 | 2011-09-06 | 3M Innovative Properties Company | Ink receptive article |
| US8003176B2 (en) * | 2006-10-04 | 2011-08-23 | 3M Innovative Properties Company | Ink receptive article |
| CN100467521C (zh) * | 2006-10-24 | 2009-03-11 | 秦怀德 | 一种聚丙烯组合物 |
| CA2668397A1 (en) * | 2006-11-01 | 2008-05-15 | Dow Global Technologies Inc. | Articles comprising nonpolar polyolefin and polyurethane, and methods for their preparation and use |
| JP4637157B2 (ja) * | 2006-11-17 | 2011-02-23 | 日本ポリプロ株式会社 | プロピレン系重合体及びその製造方法 |
| EP2527374B1 (en) | 2006-12-21 | 2020-07-01 | Dow Global Technologies LLC | Functionalized olefin polymers, compositions and articles prepared therefrom, and methods for making the same |
| KR101038802B1 (ko) * | 2007-03-02 | 2011-06-03 | 고쿠리츠다이가쿠호진 히로시마다이가쿠 | 고분자 결정체 |
| JP2010523762A (ja) * | 2007-03-30 | 2010-07-15 | ダウ グローバル テクノロジーズ インコーポレイティド | ポリプロピレン組成物、その製造方法、及びそれより製造された物品 |
| EP2167570A1 (en) * | 2007-06-29 | 2010-03-31 | Basell Poliolefine Italia S.R.L. | An irradiated polyolefin composition comprising a non - phenolic stabilizer |
| EP2177544B1 (en) * | 2007-08-06 | 2012-05-02 | Japan Polypropylene Corporation | Propylene polymer, process for producing the same, composition containing the same, and use thereof |
| US7662901B2 (en) * | 2007-11-30 | 2010-02-16 | Sunoco Chemicals, Inc. | High crystallinity, high melt flow rate polypropylene |
| US7867358B2 (en) * | 2008-04-30 | 2011-01-11 | Xyleco, Inc. | Paper products and methods and systems for manufacturing such products |
| AU2013202841B2 (en) * | 2008-04-30 | 2015-05-07 | Xyleco, Inc. | Paper products and methods and systems for manufacturing such products |
| US8212087B2 (en) * | 2008-04-30 | 2012-07-03 | Xyleco, Inc. | Processing biomass |
| SG10201805188YA (en) * | 2008-06-18 | 2018-07-30 | Dow Global Technologies Inc | Processes to control fouling and improve compositions |
| EP2294102B1 (en) * | 2008-06-30 | 2013-08-21 | Dow Global Technologies LLC | Polyolefin compositions and articles prepared therefrom and methods of making the same |
| US7935740B2 (en) * | 2008-12-30 | 2011-05-03 | Basell Poliolefine Italia S.R.L. | Process for producing high melt strength polypropylene |
| US20100227966A1 (en) * | 2009-03-06 | 2010-09-09 | Shawcor Ltd. | Moisture-crosslinked polyolefin compositions |
| US20110111456A1 (en) | 2009-04-03 | 2011-05-12 | Xyleco, Inc. | Processing biomass |
| US8220226B2 (en) | 2009-08-04 | 2012-07-17 | E-Beam Services, Inc. | Electron beam irradiation of bulk material solids |
| WO2011086581A1 (en) | 2010-01-15 | 2011-07-21 | Reliance Industries Limited | Concurrent solid & melt state grafting of coagents for making long chain branched polypropylene via direct reactive extrusion process |
| JP5992907B2 (ja) * | 2010-06-30 | 2016-09-14 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 架橋済みポリオレフィン組成物 |
| EP2426061A1 (en) * | 2010-09-02 | 2012-03-07 | baumhueter extrusion GmbH | Geogrid, non-woven or woven fabric and strapping band |
| KR101559638B1 (ko) | 2010-10-14 | 2015-10-12 | 릴라이언스 인더스트리즈 리미티드 | 고용융장력 프로필렌 폴리머의 제조 과정 |
| US8575252B2 (en) | 2011-02-09 | 2013-11-05 | Equistar Chemicals, Lp | Controlled rheology formulations containing high melt strength polypropylene for extrusion coating |
| US8389632B2 (en) | 2011-02-09 | 2013-03-05 | Equistar Chemicals, Lp | Co-continuous heterophase polymer compositions containing high melt strength polypropylene for extrusion coating |
| US8546504B2 (en) | 2011-02-09 | 2013-10-01 | Equistar Chemicals, Lp | Extrusion processes using high melt strength polypropylene |
| US9067705B2 (en) | 2011-06-17 | 2015-06-30 | Berry Plastics Corporation | Process for forming an insulated container having artwork |
| WO2012174422A2 (en) | 2011-06-17 | 2012-12-20 | Berry Plastics Corporation | Insulated container with molded brim |
| CN103717113B (zh) | 2011-06-17 | 2015-11-25 | 比瑞塑料公司 | 用于杯子的绝热套筒 |
| MX347519B (es) | 2011-06-17 | 2017-04-28 | Berry Plastics Corp | Depósito aislado. |
| BR112014004460A2 (pt) | 2011-08-31 | 2017-03-21 | Berry Plastics Corp | material polimérico para um recipiente isolado |
| WO2014025877A1 (en) | 2012-08-07 | 2014-02-13 | Berry Plastics Corporation | Cup-forming process and machine |
| BR112015009329A2 (pt) | 2012-10-26 | 2017-07-04 | Berry Plastics Corp | material polimérico para um recipiente isolado |
| AR093944A1 (es) | 2012-12-14 | 2015-07-01 | Berry Plastics Corp | Troquelado para envase |
| US9840049B2 (en) | 2012-12-14 | 2017-12-12 | Berry Plastics Corporation | Cellular polymeric material |
| AR093943A1 (es) | 2012-12-14 | 2015-07-01 | Berry Plastics Corp | Reborde de un envase termico |
| US9957365B2 (en) | 2013-03-13 | 2018-05-01 | Berry Plastics Corporation | Cellular polymeric material |
| JP2016518289A (ja) | 2013-03-14 | 2016-06-23 | ベリー プラスチックス コーポレイション | 容器 |
| WO2015024018A1 (en) | 2013-08-16 | 2015-02-19 | Berry Plastics Corporation | Polymeric material for an insulated container |
| CA2917818A1 (en) | 2013-08-26 | 2015-03-05 | Berry Plastics Corporation | Polymeric material for container |
| CN104877236B (zh) * | 2014-02-27 | 2020-11-10 | 浙江交联辐照材料股份有限公司 | 辐射交联聚丙烯泡沫塑料及其连续生产方法 |
| US9982099B2 (en) | 2014-04-16 | 2018-05-29 | Costas Tzoganakis | Method for modifying polyolefin to increase long chain branching |
| EP3144365B1 (en) * | 2014-05-16 | 2019-09-11 | Eidai Co., Ltd. | Heat reservoir comprising porous substrate impregnated with latent heat storage material, and method for producing the same |
| US9758655B2 (en) | 2014-09-18 | 2017-09-12 | Berry Plastics Corporation | Cellular polymeric material |
| BR112017005773A2 (pt) | 2014-09-23 | 2017-12-12 | Dart Container | recipiente expandido de espuma, lâmina com múltiplas camadas, método para produção de um recipiente expandido de espuma, e, processo para formação de uma lâmina com múltiplas camadas. |
| US10513589B2 (en) | 2015-01-23 | 2019-12-24 | Berry Plastics Corporation | Polymeric material for an insulated container |
| WO2016141179A1 (en) | 2015-03-04 | 2016-09-09 | Berry Plastics Corporation | Polymeric material for container |
| WO2016173967A1 (en) * | 2015-04-30 | 2016-11-03 | Sabic Global Technologies B.V. | High density polyethylene |
| KR102502942B1 (ko) | 2016-06-10 | 2023-02-22 | 이-빔 서비시스, 인크. | 프로필렌 폴리머 또는 이것의 코폴리머의 용융 강도를 증가시키는 방법 |
| PL3497152T3 (pl) | 2016-08-11 | 2023-10-16 | Sabic Global Technologies B.V. | Kompozycja polipropylenowa |
| KR101859286B1 (ko) | 2016-09-26 | 2018-06-29 | 롯데케미칼 주식회사 | 고용융장력 폴리프로필렌 수지 제조방법 |
| US20180094111A1 (en) * | 2016-09-30 | 2018-04-05 | LCY Chemical Corp. | Linear polypropylene specimen and foam and process of preparing the same |
| CA3013576A1 (en) | 2017-08-08 | 2019-02-08 | Berry Global, Inc. | Insulated multi-layer sheet and method of making the same |
| JP2021501237A (ja) * | 2017-10-27 | 2021-01-14 | ダブリュー・アール・グレース・アンド・カンパニー−コーンW R Grace & Co−Conn | 溶融強度が増加したポリオレフィンポリマー |
| EP3708594A4 (en) | 2017-11-09 | 2021-10-13 | Lotte Chemical Corporation | PROCESS FOR PREPARING A HIGH MELT RESISTANCE POLYPROPYLENE RESIN |
| WO2019199486A1 (en) | 2018-04-10 | 2019-10-17 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizale compositions |
| WO2020109870A2 (en) | 2018-06-28 | 2020-06-04 | Exxonmobil Chemical Patents Inc. | Polyethylene compositions, wires and cables, and methods for making the same |
| EP3850255A1 (en) | 2018-09-14 | 2021-07-21 | ExxonMobil Chemical Patents Inc. | Thermoplastic vulcanizate compositions their preparation and use in flexible tubular pipes |
| KR102671695B1 (ko) | 2018-11-29 | 2024-06-05 | 롯데케미칼 주식회사 | 우수한 용융 특성을 지닌 폴리프로필렌 수지 및 그 제조 방법 |
| CN113853403B (zh) | 2019-06-13 | 2024-04-16 | 国际人造丝公司 | 用热塑性硫化橡胶组合物形成的汽车挡风雨密封件 |
| JP2022536829A (ja) | 2019-06-21 | 2022-08-19 | エクソンモービル・ケミカル・パテンツ・インク | 熱可塑性加硫物組成物 |
| US12486390B2 (en) | 2019-06-26 | 2025-12-02 | Dow Global Technologies Llc | EPDM blends with long chain branching |
| CN112759826B (zh) | 2019-10-21 | 2021-10-22 | 国家能源投资集团有限责任公司 | 可发泡聚丙烯组合物和发泡聚丙烯及其制备方法 |
| CN112759768B (zh) | 2019-10-21 | 2022-01-28 | 国家能源投资集团有限责任公司 | 聚丙烯改性剂及其制备方法和聚丙烯组合物和聚丙烯材料及其制备方法 |
| EP4337705A1 (en) | 2021-05-12 | 2024-03-20 | Borealis AG | High melt strength polypropylene |
| KR20240059091A (ko) * | 2022-10-27 | 2024-05-07 | 에스케이이노베이션 주식회사 | 고용융강도 프로필렌계 중합체 및 이의 제조방법 |
| KR102831045B1 (ko) | 2022-11-30 | 2025-07-04 | 롯데케미칼 주식회사 | 용융강도가 우수한 폴리프로필렌 수지 조성물 및 그 제조방법 |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3717559A (en) * | 1967-02-18 | 1973-02-20 | Toray Industries | Process for the preparation of polypropylene resin foams |
| DE2331933C3 (de) * | 1973-06-26 | 1979-11-08 | Sumitomo Chemical Co., Ltd., Osaka (Japan) | Verschäumbare Formmasse und Verfahren zur Herstellung einer Propylenpolymerisatschaumstofflage |
| US4170664A (en) * | 1978-07-13 | 1979-10-09 | Exxon Research & Engineering Co. | Resilient radiation-curable automotive body components |
| JPS5540739A (en) * | 1978-09-18 | 1980-03-22 | Kanegafuchi Chem Ind Co Ltd | Foamed polypropylene resin article and its manufacturing |
| DE2911719C2 (de) * | 1979-03-24 | 1982-07-01 | Fa. Carl Freudenberg, 6940 Weinheim | Verfahren zur Herstellung von leichtgewichtigen Schaumstoffen aus thermoplastischen kristallinen Kunststoffen |
| US4424293A (en) * | 1980-02-25 | 1984-01-03 | The Furukawa Electric Co., Ltd. | Crosslinkable polypropylene composition |
| US4525257A (en) * | 1982-12-27 | 1985-06-25 | Union Carbide Corporation | Low level irradiated linear low density ethylene/alpha-olefin copolymers and film extruded therefrom |
| IN166935B (cg-RX-API-DMAC10.html) * | 1985-01-31 | 1990-08-11 | Himont Inc | |
| EP0190889B2 (en) * | 1985-01-31 | 2000-07-05 | Montell North America Inc. | Polypropylene with free-end long chain branching, process for making it, and use thereof |
| US4626467A (en) * | 1985-12-16 | 1986-12-02 | Hercules Incorporated | Branched polyolefin as a quench control agent for spin melt compositions |
| US5047446A (en) * | 1988-07-22 | 1991-09-10 | Himont Incorporated | Thermal treatment of irradiated propylene polymer material |
| US4940736A (en) * | 1988-09-12 | 1990-07-10 | Amoco Corporation | Production of low density polypropylene foam |
| US5047485A (en) * | 1989-02-21 | 1991-09-10 | Himont Incorporated | Process for making a propylene polymer with free-end long chain branching and use thereof |
| IT1230133B (it) * | 1989-04-28 | 1991-10-14 | Himont Inc | Composizioni polipropileniche plasto-elastiche |
| IT1240417B (it) * | 1990-02-28 | 1993-12-15 | Himont Inc | Procedimento per la produzione di film e corpi laminari polipropilenici e prodotti cosi' ottenuti |
| IT1242305B (it) * | 1990-03-09 | 1994-03-04 | Ausimont Srl | Composizioni di polipropilene reticolato atte alla preparazione di materiali espansi |
| US5116881A (en) * | 1990-03-14 | 1992-05-26 | James River Corporation Of Virginia | Polypropylene foam sheets |
| IT1243188B (it) * | 1990-08-01 | 1994-05-24 | Himont Inc | Composizioni poliolefiniche elastoplastiche |
| US5212246A (en) * | 1990-09-28 | 1993-05-18 | Himont Incorporated | Olefin polymer films |
| TW275636B (cg-RX-API-DMAC10.html) * | 1991-06-21 | 1996-05-11 | Himont Inc | |
| US5414027A (en) * | 1993-07-15 | 1995-05-09 | Himont Incorporated | High melt strength, propylene polymer, process for making it, and use thereof |
-
1993
- 1993-07-15 US US08/092,344 patent/US5414027A/en not_active Expired - Lifetime
-
1994
- 1994-07-14 MX MX9405377A patent/MX9405377A/es not_active IP Right Cessation
- 1994-07-14 CA CA002128064A patent/CA2128064C/en not_active Expired - Fee Related
- 1994-07-15 AT AT94111029T patent/ATE166368T1/de not_active IP Right Cessation
- 1994-07-15 EP EP94111029A patent/EP0634441B1/en not_active Expired - Lifetime
- 1994-07-15 KR KR1019940017250A patent/KR100311290B1/ko not_active Expired - Fee Related
- 1994-07-15 CN CN94116148A patent/CN1087019C/zh not_active Expired - Fee Related
- 1994-07-15 JP JP16431494A patent/JP3392947B2/ja not_active Expired - Fee Related
- 1994-07-15 DE DE69410357T patent/DE69410357T2/de not_active Expired - Fee Related
- 1994-08-10 TW TW083107305A patent/TW304969B/zh active
-
1995
- 1995-01-17 US US08/373,925 patent/US5541236A/en not_active Expired - Lifetime
-
1996
- 1996-03-28 US US08/625,450 patent/US5605936A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US5605936A (en) | 1997-02-25 |
| DE69410357D1 (de) | 1998-06-25 |
| CN1087019C (zh) | 2002-07-03 |
| DE69410357T2 (de) | 1998-10-08 |
| US5541236A (en) | 1996-07-30 |
| JPH07138430A (ja) | 1995-05-30 |
| KR950003325A (ko) | 1995-02-16 |
| TW304969B (cg-RX-API-DMAC10.html) | 1997-05-11 |
| KR100311290B1 (ko) | 2002-08-13 |
| ATE166368T1 (de) | 1998-06-15 |
| CA2128064A1 (en) | 1995-01-16 |
| US5414027A (en) | 1995-05-09 |
| MX9405377A (es) | 1995-01-31 |
| EP0634441B1 (en) | 1998-05-20 |
| JP3392947B2 (ja) | 2003-03-31 |
| EP0634441A1 (en) | 1995-01-18 |
| CN1105033A (zh) | 1995-07-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2128064C (en) | High melt strength, propylene polymer, process for making it, and use thereof | |
| US5508318A (en) | Compositions of irradiated and non-irradiated olefin polymer materials with reduced gloss | |
| US5552104A (en) | High melt strength, ethylene polymer, process for making it, and use thereof | |
| US8076416B2 (en) | Thermoplastic vulcanizates and their use | |
| CN101479334B (zh) | 聚烯烃热塑性硫化产品弹性体 | |
| US4906694A (en) | Thermoplastic elastomer composition and process for preparation thereof | |
| EP1661935B2 (en) | Transparent easy tearable film | |
| EP1534772B1 (en) | Thermoplastic elastomers having enhanced foaming and physical properties | |
| KR20210067265A (ko) | 수축필름용 폴리프로필렌 수지 조성물 및 이를 이용하여 제조된 수축필름 | |
| EP3388483B1 (en) | Propylene resin composition and injection molded article | |
| JP2018503731A (ja) | 半結晶性ポリオレフィンおよびスルホニルアジドを含む組成物、結果的に得られるフォーム、およびそれを製造する方法 | |
| CA2071779C (en) | High melt strength, ethylene polymer, process for making it, and use thereof | |
| EP0519386B1 (en) | High melt strength irradiated ethylene polymer | |
| RU2107701C1 (ru) | Формовочная масса на основе полиолефина и формованные изделия на ее основе | |
| CN114585679A (zh) | 含有无定型聚α-烯烃的聚烯烃共混物 | |
| JP2000327718A (ja) | オレフィン系熱可塑性エラストマーおよび製造方法 | |
| EP0721972B1 (en) | Thermoplastic-elastomeric composition | |
| WO2025247876A1 (en) | Recyclable multilayer films having a raheco/propylene homopolymer-based core layer | |
| KR20190064336A (ko) | 저온 열접착성 및 수축율이 우수한 수축필름용 폴리프로필렌 수지 조성물 | |
| AU2258899A (en) | Process for increasing the melt strength of polypropylene |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |