CA1263788A - Thermoplastic polyester-linear low density polyethylene molding compositions - Google Patents
Thermoplastic polyester-linear low density polyethylene molding compositionsInfo
- Publication number
- CA1263788A CA1263788A CA000441456A CA441456A CA1263788A CA 1263788 A CA1263788 A CA 1263788A CA 000441456 A CA000441456 A CA 000441456A CA 441456 A CA441456 A CA 441456A CA 1263788 A CA1263788 A CA 1263788A
- Authority
- CA
- Canada
- Prior art keywords
- composition
- low density
- density polyethylene
- linear low
- poly
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 110
- 229920000092 linear low density polyethylene Polymers 0.000 title claims abstract description 42
- 239000004707 linear low-density polyethylene Substances 0.000 title claims abstract description 40
- 229920001169 thermoplastic Polymers 0.000 title claims description 24
- 239000004416 thermosoftening plastic Substances 0.000 title claims description 24
- 238000000465 moulding Methods 0.000 title claims description 16
- 229920000728 polyester Polymers 0.000 claims abstract description 56
- -1 polyethylene terephthalate Polymers 0.000 claims abstract description 41
- 125000003118 aryl group Chemical group 0.000 claims abstract description 19
- 229920000139 polyethylene terephthalate Polymers 0.000 claims abstract description 12
- 239000005020 polyethylene terephthalate Substances 0.000 claims abstract description 12
- 239000003381 stabilizer Substances 0.000 claims abstract description 12
- 239000002667 nucleating agent Substances 0.000 claims abstract description 10
- 239000012744 reinforcing agent Substances 0.000 claims abstract description 9
- 239000003063 flame retardant Substances 0.000 claims abstract description 8
- 239000000654 additive Substances 0.000 claims abstract description 7
- 239000007822 coupling agent Substances 0.000 claims abstract description 7
- 239000000945 filler Substances 0.000 claims abstract description 7
- 239000003086 colorant Substances 0.000 claims abstract description 6
- 238000009757 thermoplastic moulding Methods 0.000 claims abstract description 3
- 230000000996 additive effect Effects 0.000 claims abstract 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 17
- 239000004609 Impact Modifier Substances 0.000 claims description 16
- 125000001931 aliphatic group Chemical group 0.000 claims description 16
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 13
- 239000005977 Ethylene Substances 0.000 claims description 12
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 11
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims description 11
- 229920001577 copolymer Polymers 0.000 claims description 9
- 239000000178 monomer Substances 0.000 claims description 9
- 229920001634 Copolyester Polymers 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 7
- 150000002334 glycols Chemical class 0.000 claims description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 5
- 125000002947 alkylene group Chemical group 0.000 claims description 4
- 150000001991 dicarboxylic acids Chemical class 0.000 claims description 4
- 239000000155 melt Substances 0.000 claims description 4
- 239000004711 α-olefin Substances 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
- 239000004431 polycarbonate resin Substances 0.000 claims description 3
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 claims description 3
- XFEGRFIENDJTCK-UHFFFAOYSA-N 2-phenyl-2,3-dihydroindene-1,1-dicarboxylic acid Chemical class C1C2=CC=CC=C2C(C(=O)O)(C(O)=O)C1C1=CC=CC=C1 XFEGRFIENDJTCK-UHFFFAOYSA-N 0.000 claims description 2
- 125000001118 alkylidene group Chemical group 0.000 claims description 2
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical class C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 claims description 2
- 229920005668 polycarbonate resin Polymers 0.000 claims description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims 4
- 230000003014 reinforcing effect Effects 0.000 claims 2
- 229920000515 polycarbonate Polymers 0.000 abstract description 15
- 239000004417 polycarbonate Substances 0.000 abstract description 15
- WSQZNZLOZXSBHA-UHFFFAOYSA-N 3,8-dioxabicyclo[8.2.2]tetradeca-1(12),10,13-triene-2,9-dione Chemical compound O=C1OCCCCOC(=O)C2=CC=C1C=C2 WSQZNZLOZXSBHA-UHFFFAOYSA-N 0.000 abstract description 10
- 229920006230 thermoplastic polyester resin Polymers 0.000 abstract description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 17
- 238000000034 method Methods 0.000 description 17
- 229920000642 polymer Polymers 0.000 description 15
- 239000003054 catalyst Substances 0.000 description 10
- 229920001684 low density polyethylene Polymers 0.000 description 10
- 239000004702 low-density polyethylene Substances 0.000 description 10
- 239000011521 glass Substances 0.000 description 9
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 9
- 239000004615 ingredient Substances 0.000 description 9
- 229940099514 low-density polyethylene Drugs 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- 230000006872 improvement Effects 0.000 description 6
- 239000007924 injection Substances 0.000 description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 239000011258 core-shell material Substances 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- 238000002347 injection Methods 0.000 description 5
- 238000001746 injection moulding Methods 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 229920003232 aliphatic polyester Polymers 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 4
- 239000004700 high-density polyethylene Substances 0.000 description 4
- 229940063583 high-density polyethylene Drugs 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000002530 phenolic antioxidant Substances 0.000 description 4
- 150000002989 phenols Chemical class 0.000 description 4
- 229920001707 polybutylene terephthalate Polymers 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- SYJPAKDNFZLSMV-HYXAFXHYSA-N (Z)-2-methylpropanal oxime Chemical compound CC(C)\C=N/O SYJPAKDNFZLSMV-HYXAFXHYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 150000004820 halides Chemical class 0.000 description 3
- 229920001903 high density polyethylene Polymers 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229920001225 polyester resin Polymers 0.000 description 3
- 239000004645 polyester resin Substances 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 230000000087 stabilizing effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- 229910014033 C-OH Inorganic materials 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910014570 C—OH Inorganic materials 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 229920004142 LEXAN™ Polymers 0.000 description 2
- 239000004418 Lexan Substances 0.000 description 2
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 229910010066 TiC14 Inorganic materials 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 150000004982 aromatic amines Chemical class 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000012757 flame retardant agent Substances 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 229920000578 graft copolymer Polymers 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 150000002430 hydrocarbons Chemical group 0.000 description 2
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 239000012764 mineral filler Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 238000010561 standard procedure Methods 0.000 description 2
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- 150000007970 thio esters Chemical class 0.000 description 2
- 238000005809 transesterification reaction Methods 0.000 description 2
- 238000001721 transfer moulding Methods 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- HCNHNBLSNVSJTJ-UHFFFAOYSA-N 1,1-Bis(4-hydroxyphenyl)ethane Chemical compound C=1C=C(O)C=CC=1C(C)C1=CC=C(O)C=C1 HCNHNBLSNVSJTJ-UHFFFAOYSA-N 0.000 description 1
- VSKSUBSGORDMQX-UHFFFAOYSA-N 1,2-dichloro-3-phenoxybenzene Chemical compound ClC1=CC=CC(OC=2C=CC=CC=2)=C1Cl VSKSUBSGORDMQX-UHFFFAOYSA-N 0.000 description 1
- VNAFWALXWOAPCK-UHFFFAOYSA-N 1-phenyl-2,3-dihydro-1h-indene Chemical compound C1CC2=CC=CC=C2C1C1=CC=CC=C1 VNAFWALXWOAPCK-UHFFFAOYSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 1
- FQMIAEWUVYWVNB-UHFFFAOYSA-N 3-prop-2-enoyloxybutyl prop-2-enoate Chemical compound C=CC(=O)OC(C)CCOC(=O)C=C FQMIAEWUVYWVNB-UHFFFAOYSA-N 0.000 description 1
- XOJWAAUYNWGQAU-UHFFFAOYSA-N 4-(2-methylprop-2-enoyloxy)butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCOC(=O)C(C)=C XOJWAAUYNWGQAU-UHFFFAOYSA-N 0.000 description 1
- 125000004203 4-hydroxyphenyl group Chemical group [H]OC1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- ZYUVGYBAPZYKSA-UHFFFAOYSA-N 5-(3-hydroxybutan-2-yl)-4-methylbenzene-1,3-diol Chemical compound CC(O)C(C)C1=CC(O)=CC(O)=C1C ZYUVGYBAPZYKSA-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 241001522296 Erithacus rubecula Species 0.000 description 1
- 229910010199 LiAl Inorganic materials 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 1
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 150000001279 adipic acids Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229940058905 antimony compound for treatment of leishmaniasis and trypanosomiasis Drugs 0.000 description 1
- 150000001463 antimony compounds Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- ZPOLOEWJWXZUSP-WAYWQWQTSA-N bis(prop-2-enyl) (z)-but-2-enedioate Chemical compound C=CCOC(=O)\C=C/C(=O)OCC=C ZPOLOEWJWXZUSP-WAYWQWQTSA-N 0.000 description 1
- 239000005388 borosilicate glass Substances 0.000 description 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 229940000425 combination drug Drugs 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- NHADDZMCASKINP-HTRCEHHLSA-N decarboxydihydrocitrinin Natural products C1=C(O)C(C)=C2[C@H](C)[C@@H](C)OCC2=C1O NHADDZMCASKINP-HTRCEHHLSA-N 0.000 description 1
- 238000013461 design Methods 0.000 description 1
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- 150000001993 dienes Chemical class 0.000 description 1
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- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 239000005042 ethylene-ethyl acrylate Substances 0.000 description 1
- KVFIJIWMDBAGDP-UHFFFAOYSA-N ethylpyrazine Chemical compound CCC1=CN=CC=N1 KVFIJIWMDBAGDP-UHFFFAOYSA-N 0.000 description 1
- 239000012632 extractable Substances 0.000 description 1
- 238000010101 extrusion blow moulding Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical class [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 238000010102 injection blow moulding Methods 0.000 description 1
- 150000002531 isophthalic acids Chemical class 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- BBKPDHOKNRMWQN-UHFFFAOYSA-N nonane-1,4-diol Chemical compound CCCCCC(O)CCCO BBKPDHOKNRMWQN-UHFFFAOYSA-N 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- DMCTVRQBJMBEDT-UHFFFAOYSA-N phenol;1,1,1,2-tetrachloroethane Chemical compound ClCC(Cl)(Cl)Cl.OC1=CC=CC=C1 DMCTVRQBJMBEDT-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 150000007519 polyprotic acids Polymers 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 1
- QTECDUFMBMSHKR-UHFFFAOYSA-N prop-2-enyl prop-2-enoate Chemical compound C=CCOC(=O)C=C QTECDUFMBMSHKR-UHFFFAOYSA-N 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 150000003504 terephthalic acids Chemical class 0.000 description 1
- 150000003608 titanium Chemical class 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000004260 weight control Methods 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/444,228 US4564658A (en) | 1982-11-24 | 1982-11-24 | Thermoplastic polyester-linear low density polyethylene molding compositions |
| US444,228 | 1982-11-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1263788A true CA1263788A (en) | 1989-12-05 |
Family
ID=23764016
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000441456A Expired CA1263788A (en) | 1982-11-24 | 1983-11-18 | Thermoplastic polyester-linear low density polyethylene molding compositions |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4564658A (en, 2012) |
| EP (1) | EP0111179B1 (en, 2012) |
| JP (1) | JPS59131645A (en, 2012) |
| AU (1) | AU569266B2 (en, 2012) |
| CA (1) | CA1263788A (en, 2012) |
| DE (1) | DE3373821D1 (en, 2012) |
Families Citing this family (44)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59129254A (ja) * | 1983-01-17 | 1984-07-25 | Idemitsu Petrochem Co Ltd | ポリカ−ボネ−ト樹脂組成物 |
| JPS6195063A (ja) * | 1984-10-15 | 1986-05-13 | Mitsubishi Gas Chem Co Inc | 熱可塑性樹脂組成物 |
| US4554303A (en) * | 1984-12-14 | 1985-11-19 | Eastman Kodak Company | Copolyester compositions |
| JPS61293252A (ja) * | 1985-06-21 | 1986-12-24 | Teijin Chem Ltd | 樹脂組成物 |
| JPS62543A (ja) * | 1985-06-26 | 1987-01-06 | Teijin Chem Ltd | 樹脂組成物 |
| US4607075A (en) * | 1986-01-06 | 1986-08-19 | Gaf Corporation | Polyester compostions |
| JPS62227947A (ja) * | 1986-03-31 | 1987-10-06 | Teijin Ltd | ポリエステルシ−ト |
| EP0291065A3 (en) * | 1987-05-14 | 1989-06-07 | Reynolds Consumer Products, Inc. | Nonoriented polyester films for lidding stock |
| US4946743A (en) * | 1987-06-26 | 1990-08-07 | Reynolds Consumer Products, Inc. | Nonoriented polyester films for lidding stock with modified heat seal layer |
| JPH0721103B2 (ja) * | 1988-03-02 | 1995-03-08 | ポリプラスチックス株式会社 | 難燃性ポリブチレンテレフタレート樹脂組成物及び電気部品用成形品 |
| US5189091A (en) * | 1989-05-04 | 1993-02-23 | The Dow Chemical Company | Polycarbonate/aromatic polyester blends modified with a grafted olefin copolymer |
| US5369173A (en) * | 1989-06-13 | 1994-11-29 | Sumitomo Chemical Company, Limited | Glass fiber-reinforced resin composition |
| US5087665A (en) * | 1989-12-20 | 1992-02-11 | Mobay Corporation | Toughened, hydrolysis resistant polycarbonate/polyester blends |
| US5137973A (en) * | 1990-09-10 | 1992-08-11 | Allied-Signal Inc. | Polyolefins containing polyester nucleating agent and articles formed therefrom |
| US5830940A (en) * | 1993-12-28 | 1998-11-03 | Toray Industries, Inc. | Shaped article of liquid crystalline polymer |
| TW340130B (en) * | 1993-12-28 | 1998-09-11 | Toray Industries | Shaped article of liquid crystalline resin |
| US5602195A (en) * | 1994-07-27 | 1997-02-11 | Skc Limited | Polymeric film and process for the preparation thereof |
| JP3571725B2 (ja) * | 1994-08-31 | 2004-09-29 | イー・アイ・デュポン・ドゥ・ヌムール・アンド・カンパニー | 液晶ポリマー組成物 |
| MX9707587A (es) * | 1995-04-07 | 1997-12-31 | Dow Chemical Co | Mezclas de policarbonato y polimeros lineales de etileno. |
| DE69636614T2 (de) * | 1995-05-17 | 2007-08-30 | Mitsubishi Engineering-Plastics Corp. | Polycarbonatmischung für die Profilextrusion |
| US6187848B1 (en) | 1998-02-20 | 2001-02-13 | General Electric Company | Glass filled polyester compositions with improved color stability |
| US20020098308A1 (en) * | 1998-08-24 | 2002-07-25 | Frank C. Cesare | Low molecular weight polymers and their use as dispersion aids |
| DE60040011D1 (de) * | 1999-10-19 | 2008-10-02 | Rolic Ag | Topologischstrukturierte polymerbeschichtung |
| US6448334B1 (en) | 2000-12-19 | 2002-09-10 | General Electric Company | Translucent polycarbonate composition, method for preparation thereof, and articles derived therefrom |
| US20030153684A1 (en) * | 2001-11-28 | 2003-08-14 | Hitech Polymers Inc. | Polyester composition |
| ES2368563T3 (es) | 2002-04-09 | 2011-11-18 | Illinois Tool Works Inc. | Bandaje de poliéster de alta integridad. |
| US20040043170A1 (en) * | 2002-06-24 | 2004-03-04 | The Procter & Gamble Company | Food package |
| US7119141B2 (en) * | 2003-08-20 | 2006-10-10 | General Electric Company | Polyester molding composition |
| JP4835438B2 (ja) * | 2004-08-11 | 2011-12-14 | 東レ株式会社 | 光反射体用ポリエステル樹脂組成物 |
| US7541084B2 (en) * | 2007-03-01 | 2009-06-02 | Prs Mediterranean Ltd. | Geotechnical articles |
| US7501174B2 (en) * | 2007-03-01 | 2009-03-10 | Prs Mediterranean Ltd. | High performance geosynthetic article |
| JP5200563B2 (ja) * | 2008-02-01 | 2013-06-05 | 日立電線株式会社 | 絶縁電線 |
| WO2011068074A1 (ja) * | 2009-12-03 | 2011-06-09 | 三菱瓦斯化学株式会社 | 制振性を有する成型材料および成型品 |
| WO2011155366A1 (ja) * | 2010-06-10 | 2011-12-15 | ウィンテックポリマー株式会社 | 接着力改善用変性ポリアルキレンテレフタレート樹脂、接着力改善用変性ポリアルキレンテレフタレート樹脂組成物、樹脂成形体、及び接合体 |
| US20120246873A1 (en) | 2011-04-01 | 2012-10-04 | Rama Konduri | Hollow articles comprising fiber-filled polyester compositions, methods of manufacture, and uses thereof |
| TW201336667A (zh) * | 2011-12-16 | 2013-09-16 | Saudi Basic Ind Corp | 含有熱塑性聚酯的單軸定向膜 |
| US9670313B2 (en) * | 2012-07-30 | 2017-06-06 | Sabic Global Technologies B.V. | Hydrostability of polyester composition |
| EP2880077B1 (en) * | 2012-07-30 | 2021-08-25 | SABIC Global Technologies B.V. | Method for the preparation of polyalkylene terephthalate resin compositions employing titanium-containing catalyst complex |
| US10087323B2 (en) * | 2012-07-30 | 2018-10-02 | Sabic Global Technologies B.V. | Hydrostability of polycarbonate polybutylene terephthalate composition |
| US20140371366A1 (en) * | 2013-06-14 | 2014-12-18 | Sabic Innovative Plastics Ip B.V. | Flame Retardant Polyester Composition |
| US9647256B2 (en) | 2013-10-15 | 2017-05-09 | Sony Corporation | Battery, battery pack, electronic apparatus, electrically driven vehicle, electrical storage device, and power system |
| WO2018110280A1 (ja) * | 2016-12-13 | 2018-06-21 | 株式会社クラレ | 立毛調人工皮革、ポリエステル繊維、及び不織布 |
| KR102769045B1 (ko) * | 2018-05-11 | 2025-02-18 | 사빅 글로벌 테크놀러지스 비.브이. | 보강된 폴리에스테르 구조 부품 |
| CN111363338B (zh) * | 2020-05-07 | 2022-05-10 | 吉林庭然景观材料科技有限公司 | 一种含pet、pc的合金型材及其制备方法 |
Family Cites Families (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4076698A (en) * | 1956-03-01 | 1978-02-28 | E. I. Du Pont De Nemours And Company | Hydrocarbon interpolymer compositions |
| DE2345458A1 (de) * | 1958-07-22 | 1975-03-20 | Basf Ag | Formmassen auf der basis von polybutylenterephthalat |
| DE1273193C2 (de) * | 1965-11-25 | 1976-03-18 | Enko Glanzstoff AG, 5600 Wuppertal | Verwendung von formmassen aus polyaethylenterephthalat und polymeren olefinen fuer spritzgussmassen |
| US4013613A (en) * | 1971-10-01 | 1977-03-22 | General Electric Company | Reinforced intercrystalline thermoplastic polyester compositions |
| US3953394A (en) * | 1971-11-15 | 1976-04-27 | General Electric Company | Polyester alloys and molding compositions containing the same |
| JPS4913428A (en, 2012) * | 1972-06-06 | 1974-02-05 | ||
| US3769260A (en) * | 1972-06-13 | 1973-10-30 | Allied Chem | Impact-resistant polyethylene terephthalate compositions |
| US4046837A (en) * | 1972-09-25 | 1977-09-06 | Eastman Kodak Company | Polyester-polyolefin blend film or coating composition |
| US3944699A (en) * | 1972-10-24 | 1976-03-16 | Imperial Chemical Industries Limited | Opaque molecularly oriented and heat set linear polyester film and process for making same |
| JPS6020405B2 (ja) * | 1976-04-06 | 1985-05-22 | 三井東圧化学株式会社 | 低密度ポリエチレンの製造方法 |
| US4081424A (en) * | 1976-06-07 | 1978-03-28 | Shell Oil Company | Multicomponent polyolefin - block copolymer - polymer blends |
| US4122061A (en) * | 1976-12-23 | 1978-10-24 | General Electric Company | Impact modified polyester compositions |
| US4217426A (en) * | 1977-11-14 | 1980-08-12 | Eastman Kodak Company | Polyester/low-viscosity polyethylene melt blends for powder adhesives or powder coating materials |
| US4185047A (en) * | 1977-12-30 | 1980-01-22 | General Electric Company | Thermoplastic molding compositions |
| CA1104734A (en) * | 1977-12-30 | 1981-07-07 | Stuart C. Cohen | Unfilled thermoplastic molding compositions |
| US4290937A (en) * | 1977-12-30 | 1981-09-22 | General Electric Company | Thermoplastic molding compositions |
| US4302566A (en) * | 1978-03-31 | 1981-11-24 | Union Carbide Corporation | Preparation of ethylene copolymers in fluid bed reactor |
| JPS5550058A (en) * | 1978-10-05 | 1980-04-11 | Mitsubishi Chem Ind Ltd | Preparation of thermoplastic polyester resin composition |
| US4288573A (en) * | 1980-07-28 | 1981-09-08 | Gulf Oil Corporation | Blends of low density ethylene polymers with certain polyesters |
| US4327198A (en) * | 1981-04-24 | 1982-04-27 | Eastman Kodak Company | Polymeric molding compositions having the high impact strength |
| JPS5817148A (ja) * | 1981-07-24 | 1983-02-01 | Toray Ind Inc | ポリエステル組成物 |
| US4354009A (en) * | 1981-07-30 | 1982-10-12 | Union Carbide Corporation | Catalyst composition for copolymerizing ethylene |
| DE3273898D1 (en) * | 1981-08-17 | 1986-11-27 | Basf Ag | Polyethylene terephthalate with hydrolysis resistance, and use thereof |
| US4397982A (en) * | 1981-10-30 | 1983-08-09 | General Electric Company | Compositions |
| US4401785A (en) * | 1982-01-29 | 1983-08-30 | General Electric Company | Polyolefin-poly(ester-carbonate) composition |
| JPS58187448A (ja) * | 1982-04-27 | 1983-11-01 | Mitsubishi Chem Ind Ltd | ポリエステル組成物 |
| US4463121A (en) * | 1982-08-18 | 1984-07-31 | The Goodyear Tire & Rubber Company | Thermoforming partially crystalline polyester articles |
| DE3275557D1 (en) * | 1982-09-23 | 1987-04-09 | Gen Electric | Polycarbonate compositions |
| US4448913A (en) * | 1982-10-29 | 1984-05-15 | Dart Industries Inc. | Fast crystallizing polyethylene terephthalate compositions |
| US4476274A (en) * | 1983-01-03 | 1984-10-09 | General Electric Company | Linear low density polyethylene impact modifier for thermoplastic polyesters |
-
1982
- 1982-11-24 US US06/444,228 patent/US4564658A/en not_active Expired - Lifetime
-
1983
- 1983-11-12 DE DE8383111335T patent/DE3373821D1/de not_active Expired
- 1983-11-12 EP EP83111335A patent/EP0111179B1/en not_active Expired
- 1983-11-18 CA CA000441456A patent/CA1263788A/en not_active Expired
- 1983-11-23 AU AU21601/83A patent/AU569266B2/en not_active Ceased
- 1983-11-24 JP JP58219674A patent/JPS59131645A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| AU2160183A (en) | 1984-05-31 |
| AU569266B2 (en) | 1988-01-28 |
| EP0111179A1 (en) | 1984-06-20 |
| US4564658A (en) | 1986-01-14 |
| JPH0475259B2 (en, 2012) | 1992-11-30 |
| EP0111179B1 (en) | 1987-09-23 |
| JPS59131645A (ja) | 1984-07-28 |
| DE3373821D1 (en) | 1987-10-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKLA | Lapsed |