CA1228275A - Soil release promoting liquid detergent - Google Patents
Soil release promoting liquid detergentInfo
- Publication number
- CA1228275A CA1228275A CA000451222A CA451222A CA1228275A CA 1228275 A CA1228275 A CA 1228275A CA 000451222 A CA000451222 A CA 000451222A CA 451222 A CA451222 A CA 451222A CA 1228275 A CA1228275 A CA 1228275A
- Authority
- CA
- Canada
- Prior art keywords
- fatty alcohol
- soil release
- terephthalate
- detergent
- higher fatty
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003599 detergent Substances 0.000 title claims abstract description 156
- 239000007788 liquid Substances 0.000 title claims abstract description 92
- 230000001737 promoting effect Effects 0.000 title claims abstract description 70
- 239000002689 soil Substances 0.000 title claims abstract description 60
- -1 polyethylene terephthalate Polymers 0.000 claims abstract description 80
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 61
- 102000004190 Enzymes Human genes 0.000 claims abstract description 60
- 108090000790 Enzymes Proteins 0.000 claims abstract description 60
- 239000000203 mixture Substances 0.000 claims abstract description 34
- 238000005406 washing Methods 0.000 claims abstract description 26
- 150000003839 salts Chemical class 0.000 claims abstract description 22
- 239000000463 material Substances 0.000 claims abstract description 21
- 239000004744 fabric Substances 0.000 claims abstract description 17
- 239000005020 polyethylene terephthalate Substances 0.000 claims abstract description 14
- 239000003381 stabilizer Substances 0.000 claims abstract description 13
- 125000000129 anionic group Chemical group 0.000 claims abstract description 10
- 229920000139 polyethylene terephthalate Polymers 0.000 claims abstract description 10
- 239000002979 fabric softener Substances 0.000 claims abstract description 5
- 230000003578 releasing effect Effects 0.000 claims abstract description 3
- 239000012736 aqueous medium Substances 0.000 claims abstract 5
- 230000000087 stabilizing effect Effects 0.000 claims abstract 3
- 229920000642 polymer Polymers 0.000 claims description 74
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 46
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 39
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 36
- 150000002191 fatty alcohols Chemical class 0.000 claims description 35
- 125000004432 carbon atom Chemical group C* 0.000 claims description 25
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 24
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 18
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 16
- 108091005804 Peptidases Proteins 0.000 claims description 12
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- 239000007859 condensation product Substances 0.000 claims description 12
- 239000002304 perfume Substances 0.000 claims description 12
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 11
- 239000004280 Sodium formate Substances 0.000 claims description 11
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 11
- 229910052708 sodium Inorganic materials 0.000 claims description 11
- 239000011734 sodium Substances 0.000 claims description 11
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical group [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 claims description 11
- 235000019254 sodium formate Nutrition 0.000 claims description 11
- 230000003625 amylolytic effect Effects 0.000 claims description 9
- 229910052799 carbon Inorganic materials 0.000 claims description 9
- CNGYZEMWVAWWOB-VAWYXSNFSA-N 5-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-[(e)-2-[4-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound N=1C(NC=2C=C(C(\C=C\C=3C(=CC(NC=4N=C(N=C(NC=5C=CC=CC=5)N=4)N(CCO)CCO)=CC=3)S(O)(=O)=O)=CC=2)S(O)(=O)=O)=NC(N(CCO)CCO)=NC=1NC1=CC=CC=C1 CNGYZEMWVAWWOB-VAWYXSNFSA-N 0.000 claims description 8
- 239000000243 solution Substances 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- IQDGSYLLQPDQDV-UHFFFAOYSA-N dimethylazanium;chloride Chemical compound Cl.CNC IQDGSYLLQPDQDV-UHFFFAOYSA-N 0.000 claims description 7
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 claims description 5
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical group C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 claims description 5
- 235000021286 stilbenes Nutrition 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical group [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims description 3
- 230000003472 neutralizing effect Effects 0.000 claims description 3
- ROSDSFDQCJNGOL-UHFFFAOYSA-N protonated dimethyl amine Natural products CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims description 3
- 159000000000 sodium salts Chemical class 0.000 claims description 3
- LLLVZDVNHNWSDS-UHFFFAOYSA-N 4-methylidene-3,5-dioxabicyclo[5.2.2]undeca-1(9),7,10-triene-2,6-dione Chemical compound C1(C2=CC=C(C(=O)OC(=C)O1)C=C2)=O LLLVZDVNHNWSDS-UHFFFAOYSA-N 0.000 claims 11
- 102000035195 Peptidases Human genes 0.000 claims 8
- 238000006386 neutralization reaction Methods 0.000 claims 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical group OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims 1
- 150000003467 sulfuric acid derivatives Polymers 0.000 claims 1
- 230000001502 supplementing effect Effects 0.000 claims 1
- 238000003860 storage Methods 0.000 abstract description 11
- 229920000728 polyester Polymers 0.000 abstract description 8
- 229920001577 copolymer Polymers 0.000 abstract description 4
- 230000014759 maintenance of location Effects 0.000 abstract 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 44
- 235000019198 oils Nutrition 0.000 description 44
- 239000000047 product Substances 0.000 description 34
- 238000012360 testing method Methods 0.000 description 17
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 16
- 239000000306 component Substances 0.000 description 15
- 150000002500 ions Chemical class 0.000 description 15
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 14
- 229960004418 trolamine Drugs 0.000 description 14
- 244000228957 Ferula foetida Species 0.000 description 12
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
- 238000011068 loading method Methods 0.000 description 9
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 8
- 238000004140 cleaning Methods 0.000 description 7
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 230000003247 decreasing effect Effects 0.000 description 6
- 238000000926 separation method Methods 0.000 description 6
- 229910052938 sodium sulfate Inorganic materials 0.000 description 6
- 235000011152 sodium sulphate Nutrition 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 5
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- 230000002255 enzymatic effect Effects 0.000 description 5
- YGUMVDWOQQJBGA-VAWYXSNFSA-N 5-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-[(e)-2-[4-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound C=1C=C(\C=C\C=2C(=CC(NC=3N=C(N=C(NC=4C=CC=CC=4)N=3)N3CCOCC3)=CC=2)S(O)(=O)=O)C(S(=O)(=O)O)=CC=1NC(N=C(N=1)N2CCOCC2)=NC=1NC1=CC=CC=C1 YGUMVDWOQQJBGA-VAWYXSNFSA-N 0.000 description 4
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- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 4
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- 239000002285 corn oil Substances 0.000 description 3
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- 239000007850 fluorescent dye Substances 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- OHMBHFSEKCCCBW-UHFFFAOYSA-N hexane-2,5-diol Chemical compound CC(O)CCC(C)O OHMBHFSEKCCCBW-UHFFFAOYSA-N 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 101150085091 lat-2 gene Proteins 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000008206 lipophilic material Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 230000003340 mental effect Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- STEPQTYSZVCJPV-UHFFFAOYSA-N metazachlor Chemical compound CC1=CC=CC(C)=C1N(C(=O)CCl)CN1N=CC=C1 STEPQTYSZVCJPV-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- APVPOHHVBBYQAV-UHFFFAOYSA-N n-(4-aminophenyl)sulfonyloctadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NS(=O)(=O)C1=CC=C(N)C=C1 APVPOHHVBBYQAV-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 239000002674 ointment Substances 0.000 description 1
- 229950004864 olamine Drugs 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 235000009991 pite Nutrition 0.000 description 1
- 244000293655 pite Species 0.000 description 1
- 229920000636 poly(norbornene) polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- PCNRQYHSJVEIGH-ASTDGNLGSA-M sodium;5-benzo[e]benzotriazol-2-yl-2-[(e)-2-phenylethenyl]benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC(N2N=C3C4=CC=CC=C4C=CC3=N2)=CC=C1\C=C\C1=CC=CC=C1 PCNRQYHSJVEIGH-ASTDGNLGSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 108010075550 termamyl Proteins 0.000 description 1
- UMFCIIBZHQXRCJ-NSCUHMNNSA-N trans-anol Chemical compound C\C=C\C1=CC=C(O)C=C1 UMFCIIBZHQXRCJ-NSCUHMNNSA-N 0.000 description 1
- KRTNITDCKAVIFI-UHFFFAOYSA-N tridecyl benzenesulfonate Chemical compound CCCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 KRTNITDCKAVIFI-UHFFFAOYSA-N 0.000 description 1
- 229940080117 triethanolamine sulfate Drugs 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38618—Protease or amylase in liquid compositions only
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C11D3/0015—Softening compositions liquid
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38663—Stabilised liquid enzyme compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US48190483A | 1983-04-04 | 1983-04-04 | |
| US481,904 | 1983-04-04 | ||
| US53907983A | 1983-10-05 | 1983-10-05 | |
| US53908083A | 1983-10-05 | 1983-10-05 | |
| US539,079 | 1983-10-05 | ||
| US539,080 | 1983-10-05 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1228275A true CA1228275A (en) | 1987-10-20 |
Family
ID=27413589
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000451222A Expired CA1228275A (en) | 1983-04-04 | 1984-04-03 | Soil release promoting liquid detergent |
Country Status (23)
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4661287A (en) * | 1983-10-05 | 1987-04-28 | Colgate-Palmolive Company | Stable soil release promoting enzymatic liquid detergent composition |
| US4702857A (en) * | 1984-12-21 | 1987-10-27 | The Procter & Gamble Company | Block polyesters and like compounds useful as soil release agents in detergent compositions |
| US4571303A (en) * | 1985-01-23 | 1986-02-18 | Colgate-Palmolive Company | Built nonionic detergent composition containing stabilized polyethylene terephthalate-polyoxyethylene terephthalate soil release promoting polymer |
| EP0194127B1 (en) * | 1985-03-06 | 1990-03-28 | The Procter & Gamble Company | Articles and methods for treating fabrics |
| US4711730A (en) * | 1986-04-15 | 1987-12-08 | The Procter & Gamble Company | Capped 1,2-propylene terephthalate-polyoxyethylene terephthalate polyesters useful as soil release agents |
| US4785060A (en) * | 1986-08-28 | 1988-11-15 | Colgate-Palmolive Company | Soil release promoting pet-poet copolymer, method of producing same and use thereof in detergent composition having soil release promoting property |
| CA1323280C (en) * | 1987-07-31 | 1993-10-19 | Mario Bulfari | Liquid detergent compositions |
| AU616190B2 (en) * | 1987-08-10 | 1991-10-24 | Colgate-Palmolive Company, The | Nonionic detergent composition of increased soil release promoting properties |
| US5082585A (en) * | 1989-02-02 | 1992-01-21 | Lever Brothers Company, Division Of Conopco, Inc. | Enzymatic liquid detergent compositions containing nonionic copolymeric stabilizing agents for included lipolytic enzymes |
| US4908150A (en) * | 1989-02-02 | 1990-03-13 | Lever Brothers Company | Stabilized lipolytic enzyme-containing liquid detergent composition |
| DE4344357A1 (de) * | 1993-12-24 | 1995-06-29 | Henkel Kgaa | Flüssiges Wasch- und Reinigungsmittel |
| DE4400637A1 (de) * | 1994-01-12 | 1995-07-13 | Henkel Kgaa | Oberflächenaktive Mittel |
| US5466394A (en) * | 1994-04-25 | 1995-11-14 | The Procter & Gamble Co. | Stable, aqueous laundry detergent composition having improved softening properties |
| AU713996B2 (en) * | 1995-01-12 | 1999-12-16 | Unilever Plc | Detergent composition |
| FI972969A7 (fi) * | 1995-01-12 | 1997-07-11 | Procter & Gamble | Stabiloituja nestemäisiä kankaan pehmenninkoostumuksia |
| EP0776965A3 (en) | 1995-11-30 | 1999-02-03 | Unilever N.V. | Polymer compositions |
| DE19735715A1 (de) | 1997-08-18 | 1999-02-25 | Huels Chemische Werke Ag | Amphiphile Polymere auf Basis von Polyestern mit einkondensierten acetalischen Gruppen, die bei Raumtemperatur flüssig sind, sowie ihr Einsatz in Wasch- und Reinigungsmitteln |
| HUE025312T2 (en) | 2010-04-01 | 2016-02-29 | Unilever Nv | Structure of detergent fluids with hydrogenated castor oil |
| EP2495300A1 (en) | 2011-03-04 | 2012-09-05 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Structuring detergent liquids with hydrogenated castor oil |
| ES2421162T3 (es) | 2011-04-04 | 2013-08-29 | Unilever Nv | Procedimiento de lavado de telas |
| WO2013139702A1 (en) | 2012-03-21 | 2013-09-26 | Unilever Plc | Laundry detergent particles |
| BR112017019942A2 (pt) | 2015-04-02 | 2018-06-12 | Unilever Nv | composição líquida para lavagem de roupas e uso de polímero para a liberação de sujeira |
| WO2017133879A1 (en) | 2016-02-04 | 2017-08-10 | Unilever Plc | Detergent liquid |
| BR112018075524A2 (pt) | 2016-06-09 | 2019-03-19 | Unilever N.V. | composição detergente, sistema para um usuário formular produtos de lavagem de roupas personalizados sob demanda e aparelho para prover produto de lavagem de roupas |
| EP3469130A1 (en) | 2016-06-09 | 2019-04-17 | Unilever PLC | Laundry products |
| WO2018127390A1 (en) | 2017-01-06 | 2018-07-12 | Unilever N.V. | Stain removing composition |
| CN110998014A (zh) | 2017-06-09 | 2020-04-10 | 荷兰联合利华有限公司 | 洗衣液分配系统 |
| WO2019038187A1 (en) | 2017-08-24 | 2019-02-28 | Unilever Plc | IMPROVEMENTS RELATING TO THE CLEANING OF FABRICS |
| WO2019038186A1 (en) | 2017-08-24 | 2019-02-28 | Unilever Plc | IMPROVEMENTS RELATING TO THE CLEANING OF FABRICS |
| CN111164192B (zh) | 2017-09-29 | 2022-08-26 | 联合利华知识产权控股有限公司 | 洗衣产品 |
| TR202005218U5 (tr) | 2017-10-05 | 2020-08-21 | Unilever Nv | Çamaşır yıkama ürünleri. |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1377092A (en) * | 1971-01-13 | 1974-12-11 | Unilever Ltd | Detergent compositions |
| BE789801A (fr) * | 1971-10-12 | 1973-04-06 | Unilever Nv | Compositions detergentes |
| GB1437076A (en) * | 1972-08-15 | 1976-05-26 | Unilever Ltd | Preparation of components for detergent formulations |
| CA1049367A (en) * | 1974-06-25 | 1979-02-27 | The Procter And Gamble Company | Liquid detergent compositions having soil release properties |
| US3959230A (en) * | 1974-06-25 | 1976-05-25 | The Procter & Gamble Company | Polyethylene oxide terephthalate polymers |
| US4125370A (en) * | 1976-06-24 | 1978-11-14 | The Procter & Gamble Company | Laundry method imparting soil release properties to laundered fabrics |
| US4318818A (en) * | 1979-11-09 | 1982-03-09 | The Procter & Gamble Company | Stabilized aqueous enzyme composition |
| JPS5669609A (en) * | 1979-11-13 | 1981-06-11 | Olympus Optical Co Ltd | Turret condenser of microscope |
| US4411831A (en) * | 1981-12-02 | 1983-10-25 | Purex Industries, Inc. | Stable liquid anionic detergent compositions having soil, release properties |
| DE3324258A1 (de) * | 1982-07-09 | 1984-01-12 | Colgate-Palmolive Co., 10022 New York, N.Y. | Nichtionogene waschmittelzusammensetzung mit verbesserter schmutzauswaschbarkeit |
-
1984
- 1984-03-29 NZ NZ207692A patent/NZ207692A/en unknown
- 1984-03-30 ZW ZW52/84A patent/ZW5284A1/xx unknown
- 1984-03-30 DE DE19843411941 patent/DE3411941A1/de not_active Ceased
- 1984-03-30 SE SE8401765A patent/SE8401765L/ not_active Application Discontinuation
- 1984-04-02 MX MX200876A patent/MX159212A/es unknown
- 1984-04-03 FR FR8405253A patent/FR2543569B1/fr not_active Expired
- 1984-04-03 NO NO841307A patent/NO160217C/no unknown
- 1984-04-03 IT IT47981/84A patent/IT1182704B/it active
- 1984-04-03 PT PT78366A patent/PT78366B/pt not_active IP Right Cessation
- 1984-04-03 AU AU26388/84A patent/AU560819B2/en not_active Ceased
- 1984-04-03 FI FI841326A patent/FI83233C/fi not_active IP Right Cessation
- 1984-04-03 BR BR8401541A patent/BR8401541A/pt not_active IP Right Cessation
- 1984-04-03 CA CA000451222A patent/CA1228275A/en not_active Expired
- 1984-04-03 PH PH30492A patent/PH22091A/en unknown
- 1984-04-03 ES ES531246A patent/ES8609446A1/es not_active Expired
- 1984-04-04 GB GB08408687A patent/GB2137652B/en not_active Expired
- 1984-04-04 DK DK177884A patent/DK161716C/da not_active IP Right Cessation
- 1984-04-04 GR GR74312A patent/GR79578B/el unknown
- 1984-04-04 CH CH1708/84A patent/CH659080A5/de not_active IP Right Cessation
- 1984-04-04 NL NL8401065A patent/NL8401065A/nl not_active Application Discontinuation
- 1984-04-04 AT AT0113484A patent/AT396368B/de not_active IP Right Cessation
-
1987
- 1987-09-29 MY MYPI87002256A patent/MY102609A/en unknown
-
1990
- 1990-04-19 HK HK304/90A patent/HK30490A/xx unknown
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Legal Events
| Date | Code | Title | Description |
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| MKEX | Expiry |