CA1170256A - Stable hypochlorite solution suspendable dyes - Google Patents
Stable hypochlorite solution suspendable dyesInfo
- Publication number
- CA1170256A CA1170256A CA000395395A CA395395A CA1170256A CA 1170256 A CA1170256 A CA 1170256A CA 000395395 A CA000395395 A CA 000395395A CA 395395 A CA395395 A CA 395395A CA 1170256 A CA1170256 A CA 1170256A
- Authority
- CA
- Canada
- Prior art keywords
- dye
- amino
- hydrogens
- auxochrome
- set forth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 title claims abstract description 47
- 239000000975 dye Substances 0.000 title abstract description 83
- 239000002245 particle Substances 0.000 claims abstract description 28
- 229920000126 latex Polymers 0.000 claims abstract description 23
- 239000004816 latex Substances 0.000 claims abstract description 19
- 239000007844 bleaching agent Substances 0.000 claims abstract description 14
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 13
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 239000007788 liquid Substances 0.000 claims abstract description 8
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 26
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 21
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 15
- 125000000217 alkyl group Chemical group 0.000 claims description 15
- 229910052739 hydrogen Inorganic materials 0.000 claims description 13
- 239000001257 hydrogen Substances 0.000 claims description 13
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 claims description 13
- 229910052757 nitrogen Inorganic materials 0.000 claims description 9
- 150000004056 anthraquinones Chemical class 0.000 claims description 8
- 150000002431 hydrogen Chemical class 0.000 claims description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 8
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 7
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 7
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 claims description 7
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 7
- 229910052794 bromium Inorganic materials 0.000 claims description 7
- 229910052801 chlorine Inorganic materials 0.000 claims description 7
- 239000000460 chlorine Substances 0.000 claims description 7
- 229910052731 fluorine Inorganic materials 0.000 claims description 7
- 239000011737 fluorine Substances 0.000 claims description 7
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 5
- 125000003118 aryl group Chemical group 0.000 claims description 5
- 229910052736 halogen Inorganic materials 0.000 claims description 5
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical group II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 4
- 150000002367 halogens Chemical class 0.000 claims 3
- 125000001309 chloro group Chemical group Cl* 0.000 claims 2
- 125000005843 halogen group Chemical group 0.000 claims 2
- 238000004061 bleaching Methods 0.000 abstract description 5
- 238000004043 dyeing Methods 0.000 abstract description 2
- 229920000642 polymer Polymers 0.000 description 14
- 239000000243 solution Substances 0.000 description 12
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 11
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 230000000694 effects Effects 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000004744 fabric Substances 0.000 description 6
- -1 hydroxyls halogens Chemical class 0.000 description 6
- 230000003287 optical effect Effects 0.000 description 6
- 239000004793 Polystyrene Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 229920002223 polystyrene Polymers 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000004042 decolorization Methods 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- YYROPELSRYBVMQ-UHFFFAOYSA-N 4-toluenesulfonyl chloride Chemical compound CC1=CC=C(S(Cl)(=O)=O)C=C1 YYROPELSRYBVMQ-UHFFFAOYSA-N 0.000 description 2
- RZVHIXYEVGDQDX-UHFFFAOYSA-N 9,10-anthraquinone Chemical group C1=CC=C2C(=O)C3=CC=CC=C3C(=O)C2=C1 RZVHIXYEVGDQDX-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000001000 anthraquinone dye Substances 0.000 description 2
- 230000000903 blocking effect Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- GUEIZVNYDFNHJU-UHFFFAOYSA-N quinizarin Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(O)=CC=C2O GUEIZVNYDFNHJU-UHFFFAOYSA-N 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- UEIREGKJDNBMLZ-UHFFFAOYSA-N 1,4-dihydroxy-2,3-dimethylanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=C(O)C(C)=C(C)C(O)=C3C(=O)C2=C1 UEIREGKJDNBMLZ-UHFFFAOYSA-N 0.000 description 1
- UFCPKEVUMYMOMJ-UHFFFAOYSA-N 2,3-dimethyl-1,4-bis-(4-methylphenyl)sulfonylanthracene-9,10-dione Chemical compound C1=CC(C)=CC=C1S(=O)(=O)C1=C(C)C(C)=C(S(=O)(=O)C=2C=CC(C)=CC=2)C2=C1C(=O)C1=CC=CC=C1C2=O UFCPKEVUMYMOMJ-UHFFFAOYSA-N 0.000 description 1
- KIJPZYXCIHZVGP-UHFFFAOYSA-N 2,3-dimethylanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=C(C)C(C)=C2 KIJPZYXCIHZVGP-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004908 Emulsion polymer Substances 0.000 description 1
- 101000913968 Ipomoea purpurea Chalcone synthase C Proteins 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 101000907988 Petunia hybrida Chalcone-flavanone isomerase C Proteins 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000001253 acrylic acids Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- BKNBVEKCHVXGPH-UHFFFAOYSA-N anthracene-1,4,9,10-tetrol Chemical compound C1=CC=C2C(O)=C3C(O)=CC=C(O)C3=C(O)C2=C1 BKNBVEKCHVXGPH-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 125000003636 chemical group Chemical group 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- WBLIXGSTEMXDSM-UHFFFAOYSA-N chloromethane Chemical compound Cl[CH2] WBLIXGSTEMXDSM-UHFFFAOYSA-N 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 125000000332 coumarinyl group Chemical class O1C(=O)C(=CC2=CC=CC=C12)* 0.000 description 1
- 238000007405 data analysis Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- GRWZHXKQBITJKP-UHFFFAOYSA-L dithionite(2-) Chemical compound [O-]S(=O)S([O-])=O GRWZHXKQBITJKP-UHFFFAOYSA-L 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 229920001477 hydrophilic polymer Polymers 0.000 description 1
- 229920001600 hydrophobic polymer Polymers 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000004900 laundering Methods 0.000 description 1
- 238000003760 magnetic stirring Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 239000000992 solvent dye Substances 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- DZLFLBLQUQXARW-UHFFFAOYSA-N tetrabutylammonium Chemical compound CCCC[N+](CCCC)(CCCC)CCCC DZLFLBLQUQXARW-UHFFFAOYSA-N 0.000 description 1
- 125000002088 tosyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1C([H])([H])[H])S(*)(=O)=O 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B1/00—Dyes with anthracene nucleus not condensed with any other ring
- C09B1/16—Amino-anthraquinones
- C09B1/20—Preparation from starting materials already containing the anthracene nucleus
- C09B1/26—Dyes with amino groups substituted by hydrocarbon radicals
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B1/00—Dyes with anthracene nucleus not condensed with any other ring
- C09B1/50—Amino-hydroxy-anthraquinones; Ethers and esters thereof
- C09B1/51—N-substituted amino-hydroxy anthraquinone
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3956—Liquid compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Detergent Compositions (AREA)
- Coloring (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US271,159 | 1981-06-08 | ||
| US06/271,159 US4457855A (en) | 1981-06-08 | 1981-06-08 | Stable hypochlorite solution suspendable dyes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1170256A true CA1170256A (en) | 1984-07-03 |
Family
ID=23034435
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000395395A Expired CA1170256A (en) | 1981-06-08 | 1982-02-02 | Stable hypochlorite solution suspendable dyes |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4457855A (enExample) |
| JP (1) | JPS57212260A (enExample) |
| AR (1) | AR231545A1 (enExample) |
| CA (1) | CA1170256A (enExample) |
| ES (1) | ES513372A0 (enExample) |
| FR (1) | FR2507193B1 (enExample) |
| GB (1) | GB2100307B (enExample) |
| IT (1) | IT1148185B (enExample) |
| MX (1) | MX158138A (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7686892B2 (en) | 2004-11-19 | 2010-03-30 | The Procter & Gamble Company | Whiteness perception compositions |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8315838D0 (en) * | 1983-06-09 | 1983-07-13 | Unilever Plc | Coloured bleaching compositions |
| JPS6013853A (ja) * | 1983-07-06 | 1985-01-24 | Motoyasu Uehara | 螢光漂白剤組成 |
| US4464281A (en) * | 1983-07-28 | 1984-08-07 | Lever Brothers Company | Stabilized bleach-sensitive dyes in automatic dishwasher detergent compositions |
| US4661293A (en) * | 1983-12-01 | 1987-04-28 | The Clorox Company | Method for preparing 1,4-diaminoanthraquinones and intermediates thereof |
| US4929383A (en) * | 1984-01-27 | 1990-05-29 | The Clorox Company | Stable emulstified bleaching compositions |
| US5075029A (en) * | 1984-01-27 | 1991-12-24 | The Clorox Company | Stable emulsified bleaching compositions |
| EP0206718B1 (en) * | 1984-01-27 | 1990-08-08 | The Clorox Company | Bleaching and brightening composition and method |
| US4931207A (en) * | 1984-01-27 | 1990-06-05 | The Clorox Company | Bleaching and bluing composition and method |
| US5104571A (en) * | 1984-01-27 | 1992-04-14 | The Clorox Company | Bleaching and brightening composition and method |
| US4952333A (en) * | 1984-01-27 | 1990-08-28 | The Clorox Company | Bleaching and brightening composition and method |
| US4623476A (en) * | 1984-03-30 | 1986-11-18 | The Procter & Gamble Company | Stable suspension of pigments in aqueous hypochlorite bleach compositions |
| GB8431256D0 (en) * | 1984-12-11 | 1985-01-23 | Unilever Plc | Coloured bleaching compositions |
| US4746461A (en) * | 1986-05-23 | 1988-05-24 | The Clorox Company | Method for preparing 1,4-diaminoanthraquinones and intermediates thereof |
| CH670912A5 (enExample) * | 1986-07-30 | 1989-07-14 | Ciba Geigy Ag | |
| US5139695A (en) * | 1988-01-14 | 1992-08-18 | Ciba-Geigy Corporation | Stable bleaching compositions containing fluorescent whitening agents |
| US5049385A (en) * | 1988-06-30 | 1991-09-17 | Ppg Industries, Inc. | Solid halogen-containing composition and method for producing same |
| US5106559A (en) * | 1988-06-30 | 1992-04-21 | Ppg Industries, Inc. | Solid halogen-containing composition and method for producing same |
| US4917814A (en) * | 1988-08-11 | 1990-04-17 | The Drackett Company | Pigmented hypochlorite compositions |
| US20030198892A1 (en) * | 2002-04-22 | 2003-10-23 | General Electric Company | Limited play data storage media and method for limiting access to data thereon |
| US20030205323A1 (en) * | 2002-04-22 | 2003-11-06 | General Electric Company | Method for making limited play data storage media |
| US7087282B2 (en) * | 2003-07-15 | 2006-08-08 | General Electric Company | Limited play optical storage medium, method for making the same |
| US7202292B2 (en) * | 2003-07-15 | 2007-04-10 | General Electric Company | Colored polymeric resin composition with 1,8-diaminoanthraquinone derivative, article made therefrom, and method for making the same |
| USD494615S1 (en) * | 2003-09-30 | 2004-08-17 | Pitney Bowes Inc. | Mailing machine |
| US7875359B2 (en) | 2005-01-13 | 2011-01-25 | Akzo Nobel N.V. | Opacifying polymers |
| US8048837B2 (en) * | 2005-01-13 | 2011-11-01 | The Clorox Company | Stable bleaches with coloring agents |
| US8642527B2 (en) | 2007-06-18 | 2014-02-04 | The Clorox Company | Oxidizing bleach composition |
| JP2011046921A (ja) * | 2009-07-30 | 2011-03-10 | Canon Inc | 着色粒子 |
| CN102802421B (zh) | 2010-01-21 | 2014-11-05 | 南达科他大学 | 用于输送次卤酸盐的聚合物系统 |
| JP7162468B2 (ja) * | 2018-08-09 | 2022-10-28 | ライオン株式会社 | 液体漂白剤組成物及び液体漂白剤組成物製品 |
Family Cites Families (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3393153A (en) * | 1965-12-20 | 1968-07-16 | Procter & Gamble | Novel liquid bleaching compositions |
| NL6805464A (enExample) * | 1967-05-24 | 1968-11-25 | ||
| GB1230438A (enExample) * | 1968-10-15 | 1971-05-05 | ||
| US3663442A (en) * | 1970-02-09 | 1972-05-16 | Purex Corp Ltd | Household bleach having stable opacifier |
| US3666680A (en) * | 1970-03-05 | 1972-05-30 | Purex Corp Ltd | Method of combining optical brighteners with polymers for stability in bleach and encapsulated product |
| US3655566A (en) * | 1970-03-05 | 1972-04-11 | Purex Corp Ltd | Bleach having stable brighteners |
| US3762859A (en) * | 1971-03-15 | 1973-10-02 | Colgate Palmolive Co | Enhancing the apparent whiteness of fabrics by applying an effective amount of an alkali and heat stable water soluble disazo blue dyestuff fabric softening and detergent composition therefor |
| US3689421A (en) * | 1971-04-09 | 1972-09-05 | Purex Corp Ltd | Household hypochlorite bleach with stable latex opacifier |
| US4193888A (en) * | 1971-09-01 | 1980-03-18 | Colgate-Palmolive Company | Color-yielding scouring cleanser compositions |
| JPS497337A (enExample) * | 1972-05-10 | 1974-01-23 | ||
| US3923454A (en) * | 1972-10-20 | 1975-12-02 | American Aniline Prod | Polyester and plastic dyes |
| JPS5149037A (ja) * | 1974-10-09 | 1976-04-27 | Canon Kk | Genzosochi |
| GB1484643A (en) * | 1975-03-27 | 1977-09-01 | Jude Eng Inc | Heat exchange apparatus |
| GB1568836A (en) * | 1975-09-26 | 1980-06-04 | Ciba Geigy Ag | Process for the production and use of readily dispersible prpatations of dyes and polyvinylacrzals |
| FR2328020A1 (fr) * | 1975-10-15 | 1977-05-13 | Ugine Kuhlmann | Nouveaux colorants anthraquinoniques |
| CH619336B (de) * | 1975-11-24 | Ciba Geigy Ag | Verwendung von distyrylbenzol- bzw. -diphenylverbindungen als optische aufhellmittel. | |
| US4235597A (en) * | 1975-11-27 | 1980-11-25 | Ciba-Geigy Corporation | Granules of textile processing agents for use in organic solvent liquors |
| GB1574824A (enExample) * | 1976-03-30 | 1980-09-10 | Unilever Ltd | |
| DE2656408C2 (de) * | 1976-12-13 | 1983-12-15 | CIBA-GEIGY AG, 4002 Basel | Verfahren zur Herstellung von staubarmen Präparaten und deren Verwendung |
| DE2656406C3 (de) * | 1976-12-13 | 1979-12-20 | Ciba-Geigy Ag, Basel (Schweiz) | Verfahren zur Herstellung von staubarmen Präparaten und deren Verwendung |
| DE2656407C3 (de) * | 1976-12-13 | 1981-10-08 | CIBA-GEIGY AG, 4002 Basel | Verfahren zur Herstellung von staubarmen Farbstoff- und optischen Aufhellerpräparaten und deren Verwendung |
| GB1598254A (en) * | 1977-03-21 | 1981-09-16 | Rohner Ag | Process for the preparation of concentrated formulations which can be dispersed in aqueous media |
| DE2712656A1 (de) * | 1977-03-23 | 1978-09-28 | Bayer Ag | Farbstoffpraeparationen |
| US4227880A (en) * | 1977-04-18 | 1980-10-14 | Ciba-Geigy Corporation | Process for the production of dustfree granules of dyes and optical brighteners |
| US4195012A (en) * | 1978-03-29 | 1980-03-25 | American Cyanamid Company | Process for preparing 2-chloro-1-methylaminoanthraquinone and plastics containing the same |
| DE2822041A1 (de) * | 1978-05-20 | 1979-11-29 | Bayer Ag | Verfahren zum faerben von synthetischen fasern mit anthrachinon-farbstoffmischungen |
| DE2930003A1 (de) * | 1978-07-26 | 1980-02-07 | Ciba Geigy Ag | Neue anthrachinonverbindungen |
| JPS5929935B2 (ja) * | 1978-07-28 | 1984-07-24 | 株式会社東芝 | デ−タ入力装置 |
| JPS56835A (en) * | 1979-06-19 | 1981-01-07 | Diafoil Co Ltd | Colored thermoplastic resin composition |
| JPS5638352A (en) * | 1979-09-07 | 1981-04-13 | Mitsubishi Chem Ind Ltd | Preparation of anthraquinone dye |
| JPS58195B2 (ja) * | 1980-06-17 | 1983-01-05 | 航空宇宙技術研究所長 | リング・レ−ザを用いたレ−ザ・ジヤイロ |
-
1981
- 1981-06-08 US US06/271,159 patent/US4457855A/en not_active Expired - Lifetime
-
1982
- 1982-02-02 CA CA000395395A patent/CA1170256A/en not_active Expired
- 1982-03-11 FR FR8204128A patent/FR2507193B1/fr not_active Expired
- 1982-03-16 AR AR288751A patent/AR231545A1/es active
- 1982-05-24 GB GB8215086A patent/GB2100307B/en not_active Expired
- 1982-05-26 ES ES513372A patent/ES513372A0/es active Granted
- 1982-06-03 MX MX192987A patent/MX158138A/es unknown
- 1982-06-04 JP JP57096049A patent/JPS57212260A/ja active Granted
- 1982-06-04 IT IT48585/82A patent/IT1148185B/it active
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7686892B2 (en) | 2004-11-19 | 2010-03-30 | The Procter & Gamble Company | Whiteness perception compositions |
| US7846268B2 (en) | 2004-11-19 | 2010-12-07 | The Procter & Gamble Company | Whiteness perception compositions comprising a dye-polymer conjugate |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2100307B (en) | 1985-04-11 |
| AR231545A1 (es) | 1984-12-28 |
| FR2507193A1 (fr) | 1982-12-10 |
| ES8401125A1 (es) | 1983-12-01 |
| JPS57212260A (en) | 1982-12-27 |
| US4457855A (en) | 1984-07-03 |
| FR2507193B1 (fr) | 1986-11-28 |
| IT8248585A0 (it) | 1982-06-04 |
| ES513372A0 (es) | 1983-12-01 |
| MX158138A (es) | 1989-01-10 |
| JPH0471108B2 (enExample) | 1992-11-12 |
| GB2100307A (en) | 1982-12-22 |
| IT1148185B (it) | 1986-11-26 |
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| Date | Code | Title | Description |
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| MKEX | Expiry |