CA1081578A - Process for removing foam from aqueous systems - Google Patents
Process for removing foam from aqueous systemsInfo
- Publication number
- CA1081578A CA1081578A CA254,681A CA254681A CA1081578A CA 1081578 A CA1081578 A CA 1081578A CA 254681 A CA254681 A CA 254681A CA 1081578 A CA1081578 A CA 1081578A
- Authority
- CA
- Canada
- Prior art keywords
- carbon atoms
- reaction product
- percent
- process according
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000006260 foam Substances 0.000 title claims abstract description 66
- 238000000034 method Methods 0.000 title claims abstract description 57
- 239000007795 chemical reaction product Substances 0.000 claims abstract description 88
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 59
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 52
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims abstract description 44
- 229920002545 silicone oil Polymers 0.000 claims abstract description 36
- 238000009736 wetting Methods 0.000 claims abstract description 32
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 21
- 239000000194 fatty acid Substances 0.000 claims abstract description 21
- 229930195729 fatty acid Natural products 0.000 claims abstract description 21
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 21
- 239000000203 mixture Substances 0.000 claims abstract description 21
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 14
- 125000002947 alkylene group Chemical group 0.000 claims abstract description 14
- 239000000463 material Substances 0.000 claims abstract description 14
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 11
- 229920001451 polypropylene glycol Polymers 0.000 claims abstract description 11
- 239000004753 textile Substances 0.000 claims abstract description 11
- 150000001991 dicarboxylic acids Chemical class 0.000 claims abstract description 7
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims abstract description 6
- 239000004743 Polypropylene Substances 0.000 claims abstract description 4
- 150000002334 glycols Chemical class 0.000 claims abstract description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 53
- -1 alkali metal cation Chemical group 0.000 claims description 37
- 239000002253 acid Substances 0.000 claims description 27
- 239000000080 wetting agent Substances 0.000 claims description 25
- 150000001875 compounds Chemical class 0.000 claims description 21
- 239000002518 antifoaming agent Substances 0.000 claims description 15
- 229920006395 saturated elastomer Polymers 0.000 claims description 10
- 150000001298 alcohols Chemical class 0.000 claims description 9
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 9
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 8
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 6
- 239000000835 fiber Substances 0.000 claims description 5
- 229920001296 polysiloxane Polymers 0.000 claims description 5
- 229930195734 saturated hydrocarbon Natural products 0.000 claims description 5
- 229930195735 unsaturated hydrocarbon Natural products 0.000 claims description 5
- 229910052783 alkali metal Inorganic materials 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
- 239000003973 paint Substances 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 150000007522 mineralic acids Chemical class 0.000 claims description 3
- 235000010292 orthophenyl phenol Nutrition 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 239000000725 suspension Substances 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical group N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 2
- 239000001361 adipic acid Substances 0.000 claims description 2
- 235000011037 adipic acid Nutrition 0.000 claims description 2
- 150000001340 alkali metals Chemical class 0.000 claims description 2
- 239000008199 coating composition Substances 0.000 claims description 2
- 239000000306 component Substances 0.000 claims 24
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 4
- 150000001735 carboxylic acids Chemical class 0.000 claims 2
- 229960003903 oxygen Drugs 0.000 claims 1
- 238000004043 dyeing Methods 0.000 abstract description 29
- 230000003254 anti-foaming effect Effects 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 description 81
- 239000004094 surface-active agent Substances 0.000 description 49
- IGFHQQFPSIBGKE-UHFFFAOYSA-N 4-nonylphenol Chemical compound CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 21
- 239000003795 chemical substances by application Substances 0.000 description 20
- 238000005187 foaming Methods 0.000 description 19
- 150000003863 ammonium salts Chemical class 0.000 description 17
- 239000004744 fabric Substances 0.000 description 17
- 238000003756 stirring Methods 0.000 description 17
- 239000001117 sulphuric acid Substances 0.000 description 17
- 235000011149 sulphuric acid Nutrition 0.000 description 17
- 229920000742 Cotton Polymers 0.000 description 13
- GLDOVTGHNKAZLK-UHFFFAOYSA-N n-octadecyl alcohol Natural products CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 13
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 10
- 230000015572 biosynthetic process Effects 0.000 description 10
- 239000000975 dye Substances 0.000 description 8
- 230000002401 inhibitory effect Effects 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 238000000746 purification Methods 0.000 description 8
- 210000002268 wool Anatomy 0.000 description 8
- 230000035515 penetration Effects 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 239000000758 substrate Substances 0.000 description 7
- 241000196324 Embryophyta Species 0.000 description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 150000002148 esters Chemical class 0.000 description 6
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 6
- BXWNKGSJHAJOGX-UHFFFAOYSA-N n-hexadecyl alcohol Natural products CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 6
- 239000004952 Polyamide Substances 0.000 description 5
- 239000003112 inhibitor Substances 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 229920002647 polyamide Polymers 0.000 description 5
- 159000000000 sodium salts Chemical class 0.000 description 5
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N 1-Tetradecanol Natural products CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- 239000002351 wastewater Substances 0.000 description 4
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- LQZZUXJYWNFBMV-UHFFFAOYSA-N ethyl butylhexanol Natural products CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 3
- 238000007730 finishing process Methods 0.000 description 3
- 230000005764 inhibitory process Effects 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 3
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 3
- IPCSVZSSVZVIGE-UHFFFAOYSA-N palmitic acid group Chemical group C(CCCCCCCCCCCCCCC)(=O)O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 3
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 150000003839 salts Chemical group 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- 229940087291 tridecyl alcohol Drugs 0.000 description 3
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 2
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- LPZOCVVDSHQFST-UHFFFAOYSA-N 2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-3-ethylpyrazol-1-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C=1C(=NN(C=1)CC(=O)N1CC2=C(CC1)NN=N2)CC LPZOCVVDSHQFST-UHFFFAOYSA-N 0.000 description 2
- YJLUBHOZZTYQIP-UHFFFAOYSA-N 2-[5-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-1,3,4-oxadiazol-2-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1=NN=C(O1)CC(=O)N1CC2=C(CC1)NN=N2 YJLUBHOZZTYQIP-UHFFFAOYSA-N 0.000 description 2
- GJYCVCVHRSWLNY-UHFFFAOYSA-N 2-butylphenol Chemical compound CCCCC1=CC=CC=C1O GJYCVCVHRSWLNY-UHFFFAOYSA-N 0.000 description 2
- CYEJMVLDXAUOPN-UHFFFAOYSA-N 2-dodecylphenol Chemical compound CCCCCCCCCCCCC1=CC=CC=C1O CYEJMVLDXAUOPN-UHFFFAOYSA-N 0.000 description 2
- AOHAPDDBNAPPIN-UHFFFAOYSA-N 3-Methoxy-4,5-methylenedioxybenzoic acid Chemical compound COC1=CC(C(O)=O)=CC2=C1OCO2 AOHAPDDBNAPPIN-UHFFFAOYSA-N 0.000 description 2
- NTDQQZYCCIDJRK-UHFFFAOYSA-N 4-octylphenol Chemical compound CCCCCCCCC1=CC=C(O)C=C1 NTDQQZYCCIDJRK-UHFFFAOYSA-N 0.000 description 2
- CNGYZEMWVAWWOB-VAWYXSNFSA-N 5-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-[(e)-2-[4-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound N=1C(NC=2C=C(C(\C=C\C=3C(=CC(NC=4N=C(N=C(NC=5C=CC=CC=5)N=4)N(CCO)CCO)=CC=3)S(O)(=O)=O)=CC=2)S(O)(=O)=O)=NC(N(CCO)CCO)=NC=1NC1=CC=CC=C1 CNGYZEMWVAWWOB-VAWYXSNFSA-N 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 240000002129 Malva sylvestris Species 0.000 description 2
- 235000006770 Malva sylvestris Nutrition 0.000 description 2
- 229920002302 Nylon 6,6 Polymers 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000000980 acid dye Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 2
- 229940073608 benzyl chloride Drugs 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 235000013351 cheese Nutrition 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 239000000986 disperse dye Substances 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 244000144992 flock Species 0.000 description 2
- 230000003165 hydrotropic effect Effects 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- 229940055577 oleyl alcohol Drugs 0.000 description 2
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 2
- 239000000985 reactive dye Substances 0.000 description 2
- 230000002940 repellent Effects 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 2
- 238000009988 textile finishing Methods 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- HFVMEOPYDLEHBR-UHFFFAOYSA-N (2-fluorophenyl)-phenylmethanol Chemical compound C=1C=CC=C(F)C=1C(O)C1=CC=CC=C1 HFVMEOPYDLEHBR-UHFFFAOYSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- ATNNLHXCRAAGJS-QZQOTICOSA-N (e)-docos-2-enoic acid Chemical compound CCCCCCCCCCCCCCCCCCC\C=C\C(O)=O ATNNLHXCRAAGJS-QZQOTICOSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 1
- QQGRFMIMXPWKPM-UHFFFAOYSA-N 2,3,4-tributylphenol Chemical compound CCCCC1=CC=C(O)C(CCCC)=C1CCCC QQGRFMIMXPWKPM-UHFFFAOYSA-N 0.000 description 1
- PQSMEVPHTJECDZ-UHFFFAOYSA-N 2,3-dimethylheptan-2-ol Chemical compound CCCCC(C)C(C)(C)O PQSMEVPHTJECDZ-UHFFFAOYSA-N 0.000 description 1
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical class CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 1
- HMWIHOZPGQRZLR-UHFFFAOYSA-N 2-hexadecylphenol Chemical compound CCCCCCCCCCCCCCCCC1=CC=CC=C1O HMWIHOZPGQRZLR-UHFFFAOYSA-N 0.000 description 1
- BNCADMBVWNPPIZ-UHFFFAOYSA-N 2-n,2-n,4-n,4-n,6-n,6-n-hexakis(methoxymethyl)-1,3,5-triazine-2,4,6-triamine Chemical compound COCN(COC)C1=NC(N(COC)COC)=NC(N(COC)COC)=N1 BNCADMBVWNPPIZ-UHFFFAOYSA-N 0.000 description 1
- DUIOKRXOKLLURE-UHFFFAOYSA-N 2-octylphenol Chemical compound CCCCCCCCC1=CC=CC=C1O DUIOKRXOKLLURE-UHFFFAOYSA-N 0.000 description 1
- RGDDVTHQUAQTIE-UHFFFAOYSA-N 2-pentadecylphenol Chemical compound CCCCCCCCCCCCCCCC1=CC=CC=C1O RGDDVTHQUAQTIE-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- PIFPCDRPHCQLSJ-WYIJOVFWSA-N 4,8,12,15,19-Docosapentaenoic acid Chemical compound CC\C=C\CC\C=C\C\C=C\CC\C=C\CC\C=C\CCC(O)=O PIFPCDRPHCQLSJ-WYIJOVFWSA-N 0.000 description 1
- CYYZDBDROVLTJU-UHFFFAOYSA-N 4-n-Butylphenol Chemical compound CCCCC1=CC=C(O)C=C1 CYYZDBDROVLTJU-UHFFFAOYSA-N 0.000 description 1
- QPHPUQJVKQXISS-UHFFFAOYSA-N 4-oxo-4-sulfanylbutanoic acid Chemical compound OC(=O)CCC(S)=O QPHPUQJVKQXISS-UHFFFAOYSA-N 0.000 description 1
- ISAVYTVYFVQUDY-UHFFFAOYSA-N 4-tert-Octylphenol Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(O)C=C1 ISAVYTVYFVQUDY-UHFFFAOYSA-N 0.000 description 1
- REHWHBNZBAXRIT-UHFFFAOYSA-N 6,6-diethyloctan-1-ol Chemical compound C(C)C(CCCCCO)(CC)CC REHWHBNZBAXRIT-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- PIFPCDRPHCQLSJ-UHFFFAOYSA-N Clupanodonic acid Natural products CCC=CCCC=CCC=CCCC=CCCC=CCCC(O)=O PIFPCDRPHCQLSJ-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
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Classifications
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-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/01—Silicones
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Dispersion Chemistry (AREA)
- Toxicology (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Emergency Medicine (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Degasification And Air Bubble Elimination (AREA)
- Coloring (AREA)
- Paper (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Detergent Compositions (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH7695/75 | 1975-06-13 | ||
CH769575A CH604813A5 (en) | 1975-06-13 | 1975-06-13 | Low foaming wetting agent compsns. |
CH1301175 | 1975-10-07 | ||
CH13011/75 | 1975-10-07 |
Publications (1)
Publication Number | Publication Date |
---|---|
CA1081578A true CA1081578A (en) | 1980-07-15 |
Family
ID=25701944
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA254,681A Expired CA1081578A (en) | 1975-06-13 | 1976-06-11 | Process for removing foam from aqueous systems |
CA254,671A Expired CA1069016A (en) | 1975-06-13 | 1976-06-11 | Wetting and anti-foaming agents |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA254,671A Expired CA1069016A (en) | 1975-06-13 | 1976-06-11 | Wetting and anti-foaming agents |
Country Status (17)
Families Citing this family (51)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4075118A (en) * | 1975-10-14 | 1978-02-21 | The Procter & Gamble Company | Liquid detergent compositions containing a self-emulsified silicone suds controlling agent |
LU76633A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1977-01-24 | 1978-09-13 | ||
LU76632A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1977-01-24 | 1978-09-13 | ||
CH637304A5 (de) * | 1978-11-03 | 1983-07-29 | Ciba Geigy Ag | Schaumdaempfungsmittel fuer waessrige systeme. |
CH624257GA3 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1979-01-10 | 1981-07-31 | ||
EP0014689A1 (de) * | 1979-02-13 | 1980-08-20 | Ciba-Geigy Ag | Hilfsmittel und seine Verwendung beim Färben oder optischen Aufhellen von Polyesterfasermaterialien |
DE2943902A1 (de) * | 1979-10-31 | 1981-05-14 | Hoechst Ag, 6000 Frankfurt | Verwendung von veresterten oxalkylaten als praeparationsmittel fuer farbstoffe und entsprechende farbstoffzubereitungen |
DE3021712A1 (de) * | 1980-06-10 | 1982-01-07 | Hoechst Ag, 6000 Frankfurt | Verwendung von veresterten oxalkylaten aromatischer hydroxyverbindungen zum praeparieren von farbmitteln und entsprechende farbmittelzubereitungen |
US4612109A (en) * | 1980-10-28 | 1986-09-16 | Nl Industries, Inc. | Method for controlling foaming in delayed coking processes |
US4426203A (en) * | 1981-01-06 | 1984-01-17 | Ciba-Geigy Corporation | Stable anhydrous textile assistant |
CH651581A5 (de) * | 1981-03-10 | 1985-09-30 | Ciba Geigy Ag | Waessrige zusammensetzungen enthaltend polymere auf acrylsaeurebasis, sowie verfahren zu deren herstellung. |
US4943390A (en) * | 1983-11-02 | 1990-07-24 | Petroleum Fermentations N.V. | Bioemulsifier-stabilized hydrocarbosols |
DE3400009A1 (de) * | 1984-01-02 | 1985-07-11 | Henkel KGaA, 4000 Düsseldorf | Entschaeumer fuer waessrige dispersionen und loesungen von kunstharzen |
DE3400014A1 (de) * | 1984-01-02 | 1985-07-18 | Henkel KGaA, 4000 Düsseldorf | Entschaeumer fuer waessrige dispersionen und loesungen von kunstharzen |
US4584125A (en) * | 1984-08-10 | 1986-04-22 | Sws Silicones Corporation | Antifoam compositions |
USRE34584E (en) * | 1984-11-09 | 1994-04-12 | The Procter & Gamble Company | Shampoo compositions |
DE3660964D1 (en) * | 1985-03-07 | 1988-11-24 | Ciba Geigy Ag | Auxiliary mixture and its use as a dyeing auxiliary or textile auxiliary |
MX2781A (es) * | 1985-06-27 | 1993-09-01 | Ciba Geigy Ag | Inhibidor de espuma para sistemas acuosos |
GB8518871D0 (en) * | 1985-07-25 | 1985-08-29 | Dow Corning Ltd | Detergent foam control agents |
US4880564A (en) * | 1986-09-29 | 1989-11-14 | Ciba-Geigy Corporation | Antifoams for aqueous systems and their use |
JPH0679075B2 (ja) * | 1986-09-30 | 1994-10-05 | 株式会社日立製作所 | 界面活性剤含有放射性廃液の処理方法および設備 |
JPH0790127B2 (ja) * | 1987-08-31 | 1995-10-04 | ダウコーニングアジア株式会社 | 固形シリコ−ン消泡剤 |
US5273684A (en) * | 1988-07-27 | 1993-12-28 | Ciba-Geigy Corporation | Composition for wetting hydrophobic capillary materials and the use thereof |
US4950420A (en) * | 1988-08-31 | 1990-08-21 | Nalco Chemical Company | Antifoam/defoamer composition |
US5223177A (en) * | 1989-01-09 | 1993-06-29 | Ciba-Geigy Corporation | Alkali-resistant foam suppressant which is free from silicone oil |
US4956119A (en) * | 1989-04-20 | 1990-09-11 | Friel Jr Thomas C | Particulate defoaming compositions |
DE4038608A1 (de) * | 1990-12-04 | 1992-06-11 | Henkel Kgaa | Verwendung von esterpolyole enthaltenden reaktionsmischungen als schaumdaempfende zusatzstoffe |
DE69201241T2 (de) * | 1992-07-20 | 1995-09-14 | Kao Corp | Waschmittelzusammensetzungen. |
EP0593841A1 (en) * | 1992-10-23 | 1994-04-27 | The Procter & Gamble Company | Detergent composition with suds suppressing system |
US5668095A (en) * | 1992-10-23 | 1997-09-16 | The Procter & Gamble Company | Detergent composition with suds suppressing system |
DE4308140A1 (de) * | 1993-03-15 | 1994-09-22 | Henkel Kgaa | Schaumbekämpfungsmittel für die Nahrungsmittel-, Lack- und Papierindustrie |
EP0906986A3 (de) * | 1997-10-01 | 1999-12-22 | Ciba SC Holding AG | Färbeverfahren für polyesterhaltige Fasermaterialien |
JPH11152691A (ja) * | 1997-10-01 | 1999-06-08 | Ciba Specialty Chem Holding Inc | ポリエステル−含有繊維材料のための染色方法 |
CA2410179A1 (en) * | 2000-06-16 | 2001-12-27 | Tommy Lee Mills | Bilobal cross-section fibers and fabrics prepared therefrom |
US20070210476A1 (en) * | 2004-03-23 | 2007-09-13 | Sanyo Chemical Industries, Ltd. | Machinable Resin Molded Product, Material For Forming The Same, And Model Made Of The Same |
US7662317B2 (en) * | 2005-06-30 | 2010-02-16 | Samsung Electronics Co., Ltd. | Dispersant, paste composition including the dispersant, inorganic device using the paste composition, and display apparatus including the inorganic device |
KR101178053B1 (ko) * | 2005-09-27 | 2012-08-30 | 삼성전자주식회사 | 카르복실 에스테르계 분산제 및 그를 포함하는 황화물계 형광체 페이스트 조성물 |
KR101146667B1 (ko) * | 2005-11-07 | 2012-05-24 | 삼성에스디아이 주식회사 | 금속산화물 페이스트 조성물 및 그를 이용한 반도체 전극의제조방법 |
DE102006057373B3 (de) * | 2006-12-04 | 2007-10-18 | Byk-Chemie Gmbh | Entschäumer für wässrige Medien |
EP2301645A1 (en) * | 2009-09-28 | 2011-03-30 | Cytec Surface Specialties Austria GmbH | Defoamers for airless paint spray application |
EP2426177A1 (de) * | 2010-09-07 | 2012-03-07 | Cognis IP Management GmbH | Entschäumende Netzmittel für wässrige Beschichtungssysteme |
US10414955B2 (en) * | 2011-09-06 | 2019-09-17 | Flint Trading, Inc. | Anti-foaming agents for hot-melt adhesives |
CN107034727B (zh) * | 2017-04-26 | 2018-09-25 | 威尔(福建)生物有限公司 | 一种消泡剂及其合成方法 |
CN108342903A (zh) * | 2018-02-02 | 2018-07-31 | 哈尔滨工程大学 | 碳纤维上浆工艺中消泡剂的制备方法和上浆方法 |
AU2020296116B2 (en) | 2019-06-21 | 2023-09-21 | Ecolab Usa Inc. | Solid nonionic surfactant compositions |
CN110964755B (zh) * | 2019-12-06 | 2020-11-20 | 鹤山市东古调味食品有限公司 | 一种微生物发酵过程中泡沫的处理方法 |
WO2022087765A1 (en) * | 2020-10-26 | 2022-05-05 | Dow Global Technologies Llc | Industrial and institutional cleaning foam control agent |
CN113583646B (zh) * | 2021-08-13 | 2022-12-27 | 四川瑞冬科技有限公司 | 脂肪醇烯醚羧酸酯作为修复液在油田油藏修复中的应用 |
CN114669090B (zh) * | 2022-04-07 | 2023-07-21 | 湖北鑫钰鸿成科技有限公司 | 一种磷石膏水洗用消泡剂及其制备方法 |
CN114855480A (zh) * | 2022-05-24 | 2022-08-05 | 中山市好本意新材料有限公司 | 一种无磷润湿除气剂及其制备方法 |
EP4506049A1 (en) * | 2023-08-08 | 2025-02-12 | Hindustan Petroleum Corporation Limited | An antifoam / defoam formulation |
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Publication number | Priority date | Publication date | Assignee | Title |
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US2147415A (en) * | 1937-05-11 | 1939-02-14 | Eastman Kodak Co | Electroplating |
US2390212A (en) * | 1942-09-22 | 1945-12-04 | Nat Oil Prod Co | Antifoaming agents |
US2575276A (en) * | 1948-08-03 | 1951-11-13 | Nat Aluminate Corp | Process of minimizing foam production in steam generation |
US2751358A (en) * | 1949-11-28 | 1956-06-19 | Shell Dev | Non-foaming detergents |
US2753309A (en) * | 1951-10-27 | 1956-07-03 | Pioneer Chemical Works Inc | Defoaming agents |
US2748086A (en) * | 1951-12-18 | 1956-05-29 | Petrolite Corp | Process for inhibiting foam |
IT500132A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1952-01-16 | |||
US2948757A (en) * | 1953-12-07 | 1960-08-09 | Dow Chemical Co | Trihydroxy polyoxyalkylene ethers of glycerol |
US2849405A (en) * | 1953-12-28 | 1958-08-26 | Nopco Chem Co | Liquid defoaming compositions |
GB808805A (en) * | 1954-05-18 | 1959-02-11 | Chemical Developments Canada | Improvements in aqueous detergent compositions |
US3198744A (en) * | 1960-09-15 | 1965-08-03 | Nalco Chemical Co | Process for controlling foaming of an aqueous system |
GB964837A (en) * | 1962-07-09 | 1964-07-22 | Armour & Co | Improved defoamer compositions and processes for preparing them |
GB967883A (en) * | 1962-09-24 | 1964-08-26 | Dearborn Chemicals Co | Improvements in or relating to foam control |
NO121968C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1966-06-23 | 1977-06-13 | Mo Och Domsjoe Ab | |
DE1519967B2 (de) * | 1966-11-09 | 1975-08-21 | Basf Ag, 6700 Ludwigshafen | Schaumdämpfer |
US3925242A (en) * | 1970-06-17 | 1975-12-09 | Rhone Poulenc Sa | Process for reducing foaming of liquids susceptible to foaming |
DE2115082C3 (de) * | 1971-03-29 | 1980-05-14 | Henkel Kgaa, 4000 Duesseldorf | Antischaummittel für Spülmaschinen |
US3785935A (en) * | 1971-05-17 | 1974-01-15 | Dow Corning | Distillation process of monomers with the addition of an antifoam composition |
BE791209A (fr) * | 1971-11-17 | 1973-05-10 | Basf Ag | Emulsions aqueuses anti-mousse |
-
1976
- 1976-06-01 IE IE1260/76A patent/IE42854B1/en unknown
- 1976-06-02 MX MX164917A patent/MX143986A/es unknown
- 1976-06-02 MX MX164918A patent/MX148203A/es unknown
- 1976-06-07 US US05/693,585 patent/US4092266A/en not_active Expired - Lifetime
- 1976-06-07 US US05/693,584 patent/US4071468A/en not_active Expired - Lifetime
- 1976-06-09 DE DE2625706A patent/DE2625706B2/de not_active Ceased
- 1976-06-09 DE DE2625707A patent/DE2625707C3/de not_active Expired
- 1976-06-09 FR FR7617379A patent/FR2314245A1/fr active Granted
- 1976-06-09 FR FR7617380A patent/FR2313958A1/fr active Granted
- 1976-06-10 LU LU75135A patent/LU75135A1/xx unknown
- 1976-06-10 LU LU75136A patent/LU75136A1/xx unknown
- 1976-06-11 CA CA254,681A patent/CA1081578A/en not_active Expired
- 1976-06-11 AU AU14820/76A patent/AU502541B2/en not_active Expired
- 1976-06-11 IL IL49768A patent/IL49768A/xx unknown
- 1976-06-11 DK DK264376A patent/DK156124C/da not_active IP Right Cessation
- 1976-06-11 IL IL49767A patent/IL49767A/xx unknown
- 1976-06-11 GB GB24355/76A patent/GB1522121A/en not_active Expired
- 1976-06-11 NL NLAANVRAGE7606349,A patent/NL184049C/xx not_active IP Right Cessation
- 1976-06-11 AT AT0429276A patent/AT375559B/de not_active IP Right Cessation
- 1976-06-11 AR AR263592A patent/AR224716A1/es active
- 1976-06-11 AT AT0429176A patent/AT376581B/de not_active IP Right Cessation
- 1976-06-11 AR AR263591A patent/AR217402A1/es active
- 1976-06-11 NL NLAANVRAGE7606348,A patent/NL185447C/xx not_active IP Right Cessation
- 1976-06-11 AU AU14821/76A patent/AU505279B2/en not_active Expired
- 1976-06-11 CA CA254,671A patent/CA1069016A/en not_active Expired
- 1976-06-11 GB GB24356/76A patent/GB1523509A/en not_active Expired
- 1976-06-11 BR BR7603810A patent/BR7603810A/pt unknown
- 1976-06-11 IE IE1261/76A patent/IE43382B1/en unknown
- 1976-06-11 BR BR7603799A patent/BR7603799A/pt unknown
- 1976-06-11 DK DK264276A patent/DK156123C/da not_active IP Right Cessation
- 1976-06-12 JP JP51068251A patent/JPS6036803B2/ja not_active Expired
- 1976-06-12 ES ES448834A patent/ES448834A1/es not_active Expired
- 1976-06-12 JP JP51068250A patent/JPS5918089B2/ja not_active Expired
- 1976-06-12 ES ES448833A patent/ES448833A1/es not_active Expired
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Legal Events
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MKEX | Expiry |