TWI434976B - 增進熱安定性之方法 - Google Patents

增進熱安定性之方法 Download PDF

Info

Publication number
TWI434976B
TWI434976B TW096114178A TW96114178A TWI434976B TW I434976 B TWI434976 B TW I434976B TW 096114178 A TW096114178 A TW 096114178A TW 96114178 A TW96114178 A TW 96114178A TW I434976 B TWI434976 B TW I434976B
Authority
TW
Taiwan
Prior art keywords
group
alkyl
acid
component
formula
Prior art date
Application number
TW096114178A
Other languages
English (en)
Other versions
TW200741060A (en
Inventor
Edvard Ham
Claudius Brinkmann
Byron Scott Bailey
Axel Pierach
Pius Paracchini
Original Assignee
Huntsman Adv Mat Switzerland
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huntsman Adv Mat Switzerland filed Critical Huntsman Adv Mat Switzerland
Publication of TW200741060A publication Critical patent/TW200741060A/zh
Application granted granted Critical
Publication of TWI434976B publication Critical patent/TWI434976B/zh

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325—Amines
    • D06M13/338—Organic hydrazines; Hydrazinium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/63—Esters of sulfonic acids
    • C07C309/64—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to acyclic carbon atoms
    • C07C309/69—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to acyclic carbon atoms of a carbon skeleton substituted by nitrogen atoms, not being part of nitro or nitroso groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D06M13/148—Polyalcohols, e.g. glycerol or glucose
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165—Ethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D06M13/2243—Mono-, di-, or triglycerides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325—Amines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325—Amines
    • D06M13/332—Di- or polyamines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/368—Hydroxyalkylamines; Derivatives thereof, e.g. Kritchevsky bases
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/372—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen containing etherified or esterified hydroxy groups ; Polyethers of low molecular weight
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/422—Hydrazides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/435—Semicarbazides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D06P1/6425—Compounds containing hydrazine or azo groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D06P1/645—Aliphatic, araliphatic or cycloaliphatic compounds containing amino groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
    • D06P1/6495—Compounds containing carbonamide -RCON= (R=H or hydrocarbons)
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02—After-treatment
    • D06P5/04—After-treatment with organic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02—After-treatment
    • D06P5/04—After-treatment with organic compounds
    • D06P5/06—After-treatment with organic compounds containing nitrogen

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Coloring (AREA)

Description

增進熱安定性之方法
本發明係關於一種助劑組成物，以及一種改善未染色、經螢光增白或經染色的天然或合成紡織纖維材料之熱安定性的方法。
在各種紡織處理的步驟中(預處理、螢光增白劑的施用、染色、加工)，紡織纖維材料係暴露於熱處理。尤其就未染色且可能已經螢光增白的產品而言，此經常導致不想要的黃化。
在染色之前或之後，熱的作用亦常導致不想要的影響。例如，熱預處理可能導致對聚醯胺的氧化傷害，其自身表露在例如增加的黃化或者張力強度的損失，或者其亦可在染色性上產生負作用。
染色步驟後的熱處理可同樣地導致無法接受的色澤變樣。
已發現上述不利影響可藉特定紡織助劑的使用而實質地減少。
本發明係關於一種組成物，包含(A)以總組成物計，從5至95重量%的至少一種式(1a)或(1b)化合物Y1 －X－Y2 (1a) A1 A2 N－OH (1b)其中X為二價的脂肪族、芳香族、芳脂族或環脂族基，Y1 及Y2 係各彼此獨立為－OH、－CO－OR1 －、NR1 R2 、－CO－NH－NR1 R2 或－NH－CO－NH－NR1 R2 ，其中R1 及R2 係各彼此獨立為氫、C1 －C20 烷基、C1 －C20 烷氧基、C5 －C24 環烷基、C5 －C30 芳基或C6 －C36 芳烷基，且該烷基、烷氧基、環烷基、芳基或芳烷基可能為未取代，或被一或多個羥基、胺基、磺酸基或羧基或鹵素原子所取代，A1 及A2 係各彼此獨立為C1 －C20 烷基或C6 －C36 芳烷基；(B)以總組成物計，從0至95重量%的一或多種陰離子或非離子界面活性劑或分散劑；以及(C)以總組成物計，從0至85重量%的固體無機或有機酸；在各例中，組份A＋B＋C的總量為100重量%。
式(1a)中，脂肪族基X係例如為伸乙基、伸丙基、三亞甲基、丙烷－1,1－二基、四亞甲基、六亞甲基、八亞甲基或十亞甲基，或者直鏈或支鏈的被一或多個氧原子或－NH－、－N－烷基－或－N－伸烷基－NH2 －基團所中斷的伸烷基。
適合的環脂族基X係例如為環己烷－1,2－二基、環己烷－1,3－二基、環己烷－1,4－二基，以及與。
芳香族基X之實例為1,2－伸苯基、1,3－伸苯基、1,4－伸苯基、伸聯苯基、1,2－萘二基、1,3－萘二基、1,4－萘二基、1,5－萘二基、1,6－萘二基、1,8－萘二基、2,3－萘二基、2,6－萘二基、2,7－萘二基，以及與。
二價芳脂族基係例如為及。
作為基團R1 、R2 、A1 或A2 之C1 －C20 烷基可例如為甲基、乙基、正丙基、異丙基、正丁基、異丁基、第二丁基、第三丁基、正戊基、新戊基、正己基、正辛基或者正十二烷基。
作為基團R1 或R2 之C1 －C20 烷氧基實例為甲氧基、乙氧基、正丙氧基、異丙氧基、正丁氧基、異丁氧基、第二丁氧基、第三丁氧基、正戊氧基、新戊氧基、正己氧基、正辛氧基或者正十二烷氧基。
適合的C5 －C24 環烷基係例如為環戊基、環己基及十氫萘基。
作為基團R1 或R2 之C5 －C30 芳基係例如為苯基、甲苯基、2,4,6－三甲基苯基、2,4,6－三異丙基苯基、萘基或蒽基。
適合的C6 －C36 芳烷基係例如為苄基及2－苯基乙基。
較佳者為式(1a)化合物的使用，其中X為伸乙基、伸丙基、三亞甲基、四亞甲基、五亞甲基、六亞甲基、八亞甲基、伸苯基或亞甲基－對－二伸苯基。
較佳者係進一步為式(1a)化合物，其中Y1 及Y2 為NR1 R2 、－CO－NH－NR1 R2 或－NH－CO－NH－NR1 R2 ，其中R1 及R2 為氫、C1 －C12 烷基或C5 －C24 芳基。
尤其較佳者為式(1a)化合物，其中Y1 及Y2 為NR1 R2 、－CO－NH－NR1 R2 或－NH－CO－NH－NR1 R2 ，其中R1 及R2 為氫、甲基或苯基。
適合的通式(1a)化合物之實例為式(101)－(105)之化合物：
式(1a)化合物為已知，且可藉已知方法合成。
適合的式(1b)化合物為N,N－二甲基羥基胺、N,N－二乙基羥基胺、N,N－二正丁基羥基胺、N,N－二苄基羥基胺，及N－苄基－N－甲基羥基胺。
原則上，任何陰離子或非離子界面活性劑或分散劑皆可在根據本發明之組成物中用作組份B。
適合的陰離子界面活性劑實例為烷基磺酸鹽、烷基苯磺酸鹽、烷基萘磺酸鹽、烷基硫酸鹽、烷基醚硫酸鹽、乙氧化或丙氧化的芳基硫酸鹽、乙氧化或丙氧化的芳基磷酸鹽、乙氧化或丙氧化的芳烷基硫酸鹽，及乙氧化或丙氧化的芳烷基磷酸鹽。
適合的非離子界面活性劑係例如為脂肪醇聚乙二醇醚、烷基酚聚乙二醇醚、脂肪酸去水山梨醇酯、脂肪酸聚乙二醇酯、氧化乙烯/氧化丙烯嵌段聚合物，以及脂肪酸聚甘油酯。
根據本發明之組成物中，作為組份B，較佳者為式(2)化合物之使用：R－Z－SO3 M (2)其中Z為二價芳香族基，R1 為C1 －C20 烷基、C1 －C20 烷氧基、C5 －C24 環烷基、C5 －C30 芳基、C6 －C36 芳烷基、－NHR3 、－NR4 R5 、－NHCOR6 或－NR7 COR8 ，其中R3 、R4 、R5 、R6 、R7 及R8 係各彼此獨立為C1 －C20 烷基、C1 －C20 烷氧基、C5 －C24 環烷基、C5 －C30 芳基或C6 －C36 芳烷基，該烷基、烷氧基、環烷基、芳基或芳烷基可能為未取代，或被一或多個羥基，胺基、磺酸基或羧基或鹵素原子所取代，且M為氫、鹼金屬陽離子或未取代的銨離子，或被一或多個C1 －C20 烷基所取代的銨離子。
式(2)中，Z係較佳為伸苯基或伸萘基，且R係較佳為C1 －C20 烷基。
尤其較佳之組份B為式(2a)、(2b)、(2c)及(2d)化合物， 其中R9 為C1 －C20 烷基，R10 、R11 、R12 、R13 、R14 及R15 係各彼此獨立為氫或C1 －C20 烷基，n為從1至10之數字，且M係如前文所定義。
適合的式(2a)化合物係例如為辛基苯磺酸鈉、壬基苯磺酸鈉，以及十二烷基苯磺酸鈉。
在根據本發明之組成物中，作為組份B，較佳者為烷基苯磺酸鹽或烷基硫酸鹽之使用。
在本發明上下文中，適合作為根據本發明之組成物的組份C之固體無機或有機酸，應理解為具有熔點F>40℃的化合物。
多元鹼無機酸及其酸式鹽兩者，例如H3 PO4 、NaH2 PO4 、H4 P2 O7 、Na2 H2 P2 O7 及Na2 H4 P3 O10 ，以及未取代或取代的有機單、二元或三元羧酸或磺酸，皆適合用於該目的。
適合的固體有機酸之實例為單羧酸，例如苯甲酸、水楊酸、抗壞血酸及甲苯甲酸；二元羧酸，例如草酸、丙二酸、丁二酸、戊二酸、己二酸、庚二酸、辛二酸、壬二酸、癸二酸、順丁烯二酸、反丁烯二酸、杏仁酸、蘋果酸、酒石酸、檸檬酸及消旋酒石酸；以及三元羧酸，例如偏苯三甲酸。
適合作為本發明上下文中的組份C之額外有機酸，為分子量(重量平均)Mw>200的含羧基寡聚物或聚合物，例如不飽和羧酸如丙烯酸、甲基丙烯酸或丁烯酸的同元或共聚物。
α－羥基羧酸係較佳用作組份C。
特別較佳者為酒石酸、草酸、己二酸及檸檬酸。
根據本發明之組成物中，組份A、B及C的量可在廣範圍內變化。
較佳者為以總組成物計，包含從10至50重量%，尤其是從20至40重量%的組份A，從44至85重量%，尤其是從55至75重量%的組份B，以及從0至75重量%，尤其是從10至60重量%的組份C之組成物。
本發明係關於一種改善未染色、經螢光增白或經反應性酸、金屬錯合物或分散性染料染色的天然或合成紡織纖維材料之熱安定性的方法，其中該纖維材料係以包含一種包含上述組份A、B及C的組成物之藥液處理。
可使用根據本發明之方法處理的紡織纖維材料可為天然或合成纖維，且亦可為其混合物。天然纖維之實例為植物纖維，例如棉花、黏液纖維、亞麻、嫘縈或亞麻；以及動物纖維，例如羊毛、馬海羊毛、喀什米爾羊毛、安哥拉羊毛以及絲。合成纖維係例如為聚酯、聚醯胺、聚胺甲酸酯，以及聚丙烯腈纖維。
根據本發明之方法尤其適合用於聚醯胺纖維材料之處理。
作為聚醯胺纖維材料，可考慮天然的聚醯胺纖維材料，例如羊毛或絲；或者合成的聚醯胺纖維材料，例如聚醯胺6或聚醯胺6.6；或者纖維混合物，例如羊毛/纖維素、聚醯胺/纖維素、聚醯胺/羊毛、聚醯胺/聚酯，或尤其是聚醯胺/彈性纖維混合物。該纖維材料係較佳為合成的聚醯胺纖維材料。
紡織材料可以任何型式使用，例如以纖維、紗、編織纖維或針織纖維之型式。
用於根據本發明之方法、包含定義於上的組份A、B、C之助劑組成物，係有利地以從0.1克/升至100克/升，較佳從0.5克/升至50克/升，且尤其是從1.0克/升至40克/升的量存在於藥液中。
根據本發明之組成物可藉常用的染色或印花方法施用至紡織纖維材料，例如藉噴灑施用或泡沫施用、藉染料吸盡法，或者較佳藉壓染法。
特殊裝置並非為必須。舉例來說，可使用常用的染色裝置，例如開放浴、繩狀染槽、交捲染色機，或者漿翼式、噴射或循環裝置。
除了包含水及根據本發明之紡織助劑外，藥液可包含額外的添加劑，例如潤濕劑、抗發泡劑、均染劑、螢光增白劑，或可影響紡織材料性質的藥劑，例如軟化劑、防火劑或防塵、水及油劑，亦及軟水劑及天然或合成稠化劑，例如褐藻酸鹽及纖維素醚。
如上所述，根據本發明之方法可有利地用於可能已使用螢光增白劑處理的未染色紡織纖維材料(增白織物)以及已染色的紡織纖維材料兩者之熱安定化。
至於未染色或經螢光增白的紡織纖維材料，因熱定型期間(熱風)或模製程序期間(接觸熱)之熱處理導致的黃化被預防或降低。
根據本發明之方法在經螢光增白的紡織纖維材料之處理中尤其有效。
在經染色的紡織纖維材料之熱安定化中，根據本發明之組成物可在染色之前、期間或之後施用。
當組成物在染色之前使用時，可預防或降低未染色產品在所謂預定型期間之黃化。
根據本發明之組成物係較佳在紡織纖維材料經反應性酸、金屬錯合物或分散性染料染色後施用。
使用根據本發明之紡織助劑的經染色紡織纖維材料之後處理，尤其在後定型(熱定型)期間引起了某種程度的纖維保護作用，且有效地降低在該處理步驟中常發生的色澤改變，亦即色澤維持不變，且無消光及色彩強度的損失。
至於未染色或經螢光增白的紡織纖維材料，在使用根據本發明之組成物處理後，未觀察到可見的白度降低。
令人驚訝地，已發現使用根據本發明之組成物處理紡織纖維材料亦引起耐臭氧、NOx 及氯堅牢度之改善。
本發明相應地亦關於一種改善未染色、經螢光增白或經反應性酸、金屬錯合物或分散性染料染色的天然或合成紡織纖維材料之耐臭氧、NOx 及氯堅牢度之方法，其中該纖維材料係以包含一種包含上述組份A、B及C的組成物之藥液處理。
所謂的儲存黃化，亦即在紡織材料儲存期間發生的黃化，出乎意料地亦可藉根據本發明之組成物處理而有效地降低。對儲存黃化的抵抗性一般係使用Courtauld黃化測試而測量。
由Courtauld公司開發且進一步由Mark&Spencer發展的Courtauld測試，為一種在紡織工業中已建立用於評估對由酚抗氧化劑所導致黃化之敏感性的測試。
以根據本發明之組成物處理的紡織纖維材料具有高的Courtauld堅牢度。
根據本發明之組成物可包含例如潤濕劑、分散劑或pH調節劑作為額外的添加劑。
以下實施例係用以解釋本發明。除非另有指示，溫度係以攝氏度數提供，”份”及”重量份”以及”百分率”係相關於”重量百分率”。”重量份”以公斤對公升的同樣比例相關於”體積份”。
 實施例1－13 ：經螢光增白的聚醯胺之處理
(a)漂白方法以含2.0% UvitexNFW液(螢光增白劑，汽巴(Ciba)特用化學)及1.0克/升UltravonEL(分散劑，汽巴特用化學)的藥液水溶液，藉染料吸盡法處理聚醯胺6.6締捲經編物。以醋酸調整pH至4.5。
藥液比1：20，30分鐘/95℃。
(b)助劑的施用以包含表1規定的助劑組成物之藥液水溶液，藉壓染法處理增白織物。
藥液浸吸量100%；在70℃下乾燥根據Ganz之白度：230
接著將該織物進行熱定型測試(60秒/210℃)以及模製測試(60秒/210℃)；與未處理材料相比之結果列於表2：
實施例14－16： 染色的聚醯胺/彈性纖維之處理
以pH 4.5、含1.7% LanasetBlue 2R(汽巴特用化學)及1.0% LanasetViolet B(汽巴特用化學)之藥液水溶液，以染料吸盡法將聚醯胺6.6/彈性纖維織物(82：18)染色。
在各例中，以含30克/升由30%己二醯二肼與70%IrgasolDAM(分散劑，汽巴特用化學)(實施例14)，或30%己二醯二肼與70% TamolNN 904(分散劑)(實施例15)，或30%己二醯二肼與70%十二烷基苯磺酸鈉(實施例16)組成之助劑組成物的藥液水溶液，以壓染法(藥液浸吸量約70%)在70℃下將以該方法預染色的織物處理2分鐘，然後熱定型(60秒/180℃)。接著對染色的織物進行氯水浴測試(100 ppm Cl2 )。表3顯示與參照物相比(未處理的染色織物)之色澤偏差(DEF值)。

Claims (13)

  1. 一種組成物，其包含：(A)以總組成物計，從5至95重量%的至少一種式(1a)或(1b)化合物Y1 -X-Y2 (1a) A1 A2 N-OH (1b)其中X為二價的脂肪族、芳香族、芳脂族或環脂族基，Y1 及Y2 係各彼此獨立為-OH、-CO-OR1 -、NR1 R2 、-CO-NH-NR1 R2 或-NH-CO-NH-NR1 R2 ，其中R1 及R2 係各彼此獨立為氫、C1 -C20 烷基、C1 -C20 烷氧基、C5 -C24 環烷基、C5 -C30 芳基或C6 -C36 芳烷基，且該烷基、烷氧基、環烷基、芳基或芳烷基可能為未取代，或被一或多個羥基、胺基、磺酸基或羧基或鹵素原子所取代，A1 及A2 係各彼此獨立為C1 -C20 烷基或C6 -C36 芳烷基；(B)以總組成物計，從0至95重量%的一或多種式(2)化合物作為陰離子或非離子界面活性劑或分散劑，R-Z-SO3 M (2)其中Z為二價芳香族基，R1 為C1 -C20 烷基、C1 -C20 烷氧基、C5 -C24 環烷基、C5 -C30 芳基、C6 -C36 芳烷基、-NHR3 、-NR4 R5 、-NHCOR6 或-NR7 COR8 ，其中R3 、R4 、R5 、R6 、R7 及R8 係各彼此獨立為C1 -C20 烷基、C1 -C20 烷氧基、C5 -C24 環烷基、C5 -C30 芳基或C6 -C36 芳烷基， 該烷基、烷氧基、環烷基、芳基或芳烷基係可能為未取代，或被一或多個羥基、胺基、磺酸基或羧基或鹵素原子所取代，且M為氫、鹼金屬陽離子或未取代的銨離子，或者被一或多個C1 -C20 烷基所取代的銨離子；以及(C)以總組成物計，從0至85重量%的固體無機或有機酸；且在各例中，組份A+B+C的總量為100重量%。
  2. 如申請專利範圍第1項之組成物，其包含式(1a)化合物作為組份A，其中X為伸乙基、伸丙基、三亞甲基、四亞甲基、五亞甲基、六亞甲基、八亞甲基、伸苯基，或者亞甲基-對-二伸苯基。
  3. 如申請專利範圍第1項之組成物，其包含式(1a)化合物作為組份A，其中Y1 及Y2 為NR1 R2 、-CO-NH-NR1 R2 或-NH-CO-NH-NR1 R2 ，其中R1 及R2 為氫、C1 -C12 烷基或C5 -C24 芳基。
  4. 如申請專利範圍第1項之組成物，其包含式(1a)化合物作為組份A，其中Y1 及Y2 為NR1 R2 、-CO-NH-NR1 R2 或-NH-CO-NH-NR1 R2 ，其中R1 及R2 為氫、甲基或苯基。
  5. 如申請專利範圍第1項之組成物，其包含式(101)-(105)化合物作為組份A：
  6. 如申請專利範圍第1項之組成物，其包含式(1b)化合物作為組份A，其中A1 及A2 為乙基。
  7. 如申請專利範圍第1項之組成物，其包含式(2)化合物作為組份B，其中Z為伸苯基或伸萘基，且R為C1 -C20 烷基。
  8. 如申請專利範圍第1項之組成物，其包含式(2a)、(2b)、(2c)或(2d)化合物作為組份B， 其中R9 為C1 -C20 烷基，R10 、R11 、R12 、R13 、R14 及R15 係各彼此獨立為氫或C1 -C20 烷基，n為從1至10之數字，且M係如申請專利範圍第1項中所定義。
  9. 如申請專利範圍第1項之組成物，其包含烷基苯磺酸鹽作為組份B。
  10. 如申請專利範圍第1項之組成物，其包含α-羥基羧酸作為組份C。
  11. 如申請專利範圍第1項之組成物，其包含酒石酸、草酸、己二酸或檸檬酸作為組份C。
  12. 一種方法，其係改善未染色、經螢光增白或經反應性酸、金屬錯合物或分散性染料染色的天然或合成紡織纖維材料之熱安定性，其中該纖維材料係以一種包含如申請專利範圍第1項之組成物的藥液處理。
  13. 一種方法，其係改善未染色、經螢光增白或經反應性酸、金屬錯合物或分散性染料染色的天然或合成紡織纖維材料耐臭氧、NOx 及氯堅牢度，其中該纖維材料係以一種包含如申請專利範圍第1項之組成物的藥液處理。
TW096114178A 2006-04-24 2007-04-23 增進熱安定性之方法 TWI434976B (zh)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP06112948 2006-04-24

Publications (2)

Publication Number Publication Date
TW200741060A TW200741060A (en) 2007-11-01
TWI434976B true TWI434976B (zh) 2014-04-21

Family

ID=37897458

Family Applications (1)

Application Number Title Priority Date Filing Date
TW096114178A TWI434976B (zh) 2006-04-24 2007-04-23 增進熱安定性之方法

Country Status (10)

Country Link
US (1) US20090165215A1 (zh)
EP (1) EP2010708A2 (zh)
JP (1) JP2009534551A (zh)
KR (1) KR20090014278A (zh)
CN (1) CN101426973B (zh)
BR (1) BRPI0710831A8 (zh)
MX (1) MX2008013553A (zh)
MY (1) MY174886A (zh)
TW (1) TWI434976B (zh)
WO (1) WO2007122142A2 (zh)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110284327A (zh) * 2019-07-10 2019-09-27 广东湛丰精细化工有限公司 一种用于防止织物酚醛变色的保护剂、制备方法及其应用
CN115819271A (zh) * 2022-12-26 2023-03-21 科凯精细化工（上海）有限公司 一种尼龙织物抗热黄变剂及制备方法、应用
CN116023293A (zh) * 2022-12-26 2023-04-28 科凯精细化工（上海）有限公司 一种萘环尼龙抗热黄变剂及制备方法、应用

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE636326C (de) * 1934-12-29 1936-10-09 I G Farbenindustrie Akt Ges Verfahren zur Erhoehung der Echtheit von Celluloseesterkunstseide
US3149998A (en) * 1962-08-01 1964-09-22 Du Pont Color stabilized articles and process for preparing same
CH467381A (de) * 1966-05-06 1968-08-30 Geigy Ag J R Verfahren zum Färben oder Bedrucken von Textilfasern aus natürlichen oder synthetischen Polyamiden
CH1595874A4 (zh) * 1974-12-02 1976-08-31
JPS5982483A (ja) * 1982-11-01 1984-05-12 明成化学工業株式会社 ポリアミド繊維染色物の耐熱性向上法
JPS6081370A (ja) * 1983-10-07 1985-05-09 日華化学株式会社 繊維製品の処理方法
JPS626976A (ja) * 1985-07-01 1987-01-13 日本ヒドラジン工業株式会社 絹の耐候性向上法
JPH02242970A (ja) * 1988-08-04 1990-09-27 Honda Motor Co Ltd 羊毛繊維の耐光耐熱性向上法
DE59108599D1 (de) * 1990-05-31 1997-04-17 Ciba Geigy Stabilisierung von Färbungen auf Polyamidfasern
US5294735A (en) * 1991-03-04 1994-03-15 Ciba-Geigy Corporation Semicarbazides and the use thereof for stabilizing polyamide fibre materials and the dyeings produced thereon
MX9205504A (es) * 1991-11-01 1993-06-01 Ciba Geigy Ag Composicion y proceso para la preparacion de articulos que tienen estabilidad de moldeo
US5319013A (en) * 1992-11-10 1994-06-07 E. I. Du Pont De Nemours And Company Fiber and film of improved flame resistance containing mixed oxides of tungsten
JPH0827674A (ja) * 1994-07-14 1996-01-30 Unitika Ltd 天然ポリアミド系繊維の黄変防止加工方法
JP4407190B2 (ja) * 2003-07-28 2010-02-03 パナソニック電工株式会社 アルデヒドキャッチャー剤
JP2005256213A (ja) * 2004-03-11 2005-09-22 Mitsubishi Paper Mills Ltd インクジェット用記録材料
KR101157417B1 (ko) * 2004-10-28 2012-06-22 훈츠만 어드밴스트 머티리얼스(스위처랜드) 게엠베하 열안정성의 개선방법
CN100556479C (zh) * 2005-09-09 2009-11-04 罗文圣 低游离甲醛释放量地板和家具生产方法

Also Published As

Publication number Publication date
BRPI0710831A2 (pt) 2011-08-23
BRPI0710831A8 (pt) 2016-09-20
CN101426973B (zh) 2013-03-27
US20090165215A1 (en) 2009-07-02
CN101426973A (zh) 2009-05-06
MX2008013553A (es) 2008-10-31
KR20090014278A (ko) 2009-02-09
WO2007122142A2 (en) 2007-11-01
WO2007122142A3 (en) 2008-05-15
EP2010708A2 (en) 2009-01-07
JP2009534551A (ja) 2009-09-24
TW200741060A (en) 2007-11-01
MY174886A (en) 2020-05-20

Similar Documents

Publication Publication Date Title
US3154489A (en) Surface active compositions
CN111826959A (zh) 阻燃助剂、阻燃加工剂组合物、和阻燃性纤维布帛的制造方法
TWI434976B (zh) 增進熱安定性之方法
TW201733971A (zh) 染色助劑及染色纖維製品之製造方法
GB2026566A (en) Stable stilbene fluorescent brightener solution
CN112941938B (zh) 一种锦纶染色防固色斑剂及其应用方法
JP4111624B2 (ja) 洗浄剤組成物
US5601746A (en) Wet-slippage of textile material and wet lubricant therefor
US4880430A (en) Mixtures of an acylated polyamine and an alcohol-ether useful for textile finishing
TWI415995B (zh) 改善熱穩定性的方法
JP4302892B2 (ja) 水性ディスパージョン、それらの製造および使用
JPH01229072A (ja) 合成繊維加工用の低起泡性組成物
JP3930475B2 (ja) テキスタイル繊維脱脂剤、その製造及びその使用
EP1218586B1 (en) Increasing the wet slippage properties of textile material, and wet-acting lubricants for this purpose
US2344260A (en) Alkali salts of fatty amino compounds
WO2008023493A1 (fr) Agent d'amélioration de la qualité dans le bain pour le traitement de fibres et procédé de traitement
JP2022170304A (ja) 繊維処理助剤、及びポリエステル繊維用処理剤
JPH02251676A (ja) 繊維用柔軟平滑剤組成物
CA2305673A1 (en) Finishing for jeans material
JPH0274684A (ja) ソーピング剤および処理法
KR970005208B1 (ko) 폴리에스테르 직물의 발염을 위한 백도촉진제 및 이를 포함하는 가공석 발염제 조성물
ITRM930085A1 (it) Tensioattivi poco schiumogeni, loro preparazione e loro impiego in procedimenti di tintura.
JPH0827667A (ja) 浴中柔軟剤
WO2002079364A1 (en) Softener compositions and their use