JP2009534551A - 熱安定性の強化方法 - Google Patents
熱安定性の強化方法 Download PDFInfo
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- JP2009534551A JP2009534551A JP2009507031A JP2009507031A JP2009534551A JP 2009534551 A JP2009534551 A JP 2009534551A JP 2009507031 A JP2009507031 A JP 2009507031A JP 2009507031 A JP2009507031 A JP 2009507031A JP 2009534551 A JP2009534551 A JP 2009534551A
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Abstract
【解決手段】本発明は、
(A)全組成に基づき5ないし95質量%の、式(1a)又は(1b)
Y1−X−Y2 (1a)
A1A2N−OH (1b)
[式中、
Xは、2価の脂肪族、芳香族、芳香脂肪族又は脂環式の基を表わし、
Y1及びY2は、各々互いに独立して、−OH、−CO−OR1、−NR1R2、−CO−NH−NR1R2又は−NH−CO−NH−NR1R2(式中、R1及びR2は、各々互いに独立して、水素原子、炭素原子数1ないし20のアルキル基、炭素原子数1ないし20のアルコキシ基、炭素原子数5ないし24のシクロアルキル基、炭素原子数5ないし30のアリール基又は炭素原子数6ないし36のアラルキル基を表わし、該アルキル基、アルコキシ基、シクロアルキル基、アリール基又はアラルキル基は、未置換であるか、又は、ヒドロキシ基、アミノ基、スルホ基又はカルボキシル基又はハロゲン原子の1つ以上によって置換され得る。)を表わし、
A1及びA2は、各々互いに独立して、炭素原子数1ないし20のアルキル基又は炭素原子数6ないし36のアラルキル基を表わす。]で表わされる少なくとも1種の化合物、
(B)全組成に基づき0ないし95質量%の、1種以上のアニオン性又は非イオン性界面活性剤もしくは分散剤;及び、
(C)全組成に基づき0ないし85質量%の、固体の無機酸又は有機酸
を含み、
各場合において、成分A+B+Cの合計量が100質量%となる補助組成物、及びまた、染色されていない、蛍光増白された又は染色された、天然又は合成織物繊維材料の熱安定性を改善する方法に関する。
【選択図】なし
Description
染色工程後の熱処理も同様に、許容できない色調の変化を引き起こし得る。
(A)全組成に基づき5ないし95質量%の、式(1a)又は(1b)
Y1−X−Y2 (1a)
A1A2N−OH (1b)
[式中、
Xは、2価の脂肪族、芳香族、芳香脂肪族又は脂環式の基を表わし、
Y1及びY2は、各々互いに独立して、−OH、−CO−OR1、−NR1R2、−CO−NH−NR1R2又は−NH−CO−NH−NR1R2(式中、R1及びR2は、各々互いに独立して、水素原子、炭素原子数1ないし20のアルキル基、炭素原子数1ないし20のアルコキシ基、炭素原子数5ないし24のシクロアルキル基、炭素原子数5ないし30のアリール基又は炭素原子数6ないし36のアラルキル基を表わし、該アルキル基、アルコキシ基、シクロアルキル基、アリール基又はアラルキル基は、未置換であるか、又は、ヒドロキシ基、アミノ基、スルホ基又はカルボキシル基又はハロゲン原子の1つ以上によって置換され得る。)を表わし、
A1及びA2は、各々互いに独立して、炭素原子数1ないし20のアルキル基又は炭素原子数6ないし36のアラルキル基を表わす。]で表わされる少なくとも1種の化合物、
(B)全組成に基づき0ないし95質量%の、1種以上のアニオン性又は非イオン性界面活性剤もしくは分散剤;及び、
(C)全組成に基づき0ないし85質量%の、固体の無機酸又は有機酸
を含み、
各場合において、成分A+B+Cの合計量が100質量%となる組成物に関する。
−p−ジフェニレン基を表わすところの式(1a)で表わされる化合物の使用である。
R−Z−SO3M (2)
[式中、
Zは、2価の芳香族基を表わし、
Rは、炭素原子数1ないし20のアルキル基、炭素原子数1ないし20のアルコキシ基、炭素原子数5ないし24のシクロアルキル基、炭素原子数5ないし30のアリール基、炭素原子数6ないし36のアラルキル基、−NHR3、−NR4R5、−NHCOR6又は−NR7COR8(式中、R3、R4、R5、R6、R7及びR8は、各々互いに独立して、炭素原子数1ないし20のアルキル基、炭素原子数1ないし20のアルコキシ基、炭素原子数5ないし24のシクロアルキル基、炭素原子数5ないし30のアリール基又は炭素原子数6ないし36のアラルキル基を表わし、該アルキル基、アルコキシ基、シクロアルキル基、アリール基又はアラルキル基は、未置換であるか、又は、ヒドロキシ基、アミノ基、スルホ基又はカルボキシル基又はハロゲン原子の1つ以上によって置換され得る。)を表わし、及び、
Mは、水素原子、アルカリ金属カチオン又は未置換のアンモニウムイオン又は1つ以上の炭素原子数1ないし20のアルキル基によって置換されたアンモニウムイオンを表わす。]で表わされる化合物の使用である。
多価性無機酸及びそれらの酸塩、例えば、H3PO4、NaH2PO4、H4P2O7、Na2H2P2O7及びNa2H4P3O10、及び、未置換の又は置換された有機モノ−、ジ−又はトリ−カルボン酸又は−スルホン酸が、目的のために好適である。
ポリアミド繊維材料としては、天然ポリアミド繊維材料、例えば、羊毛又は絹、又は合成ポリアミド繊維材料、例えば、ポリアミド6又はポリアミド6.6、又はブレンド、例えば、羊毛/セルロース、ポリアミド/セルロース、ポリアミド/羊毛、ポリアミド/ポリエステル又は、特に、ポリアミド/エラスタン ブレンドが考慮される。繊維材料は、好
ましくは、合成ポリアミド繊維材料である。
コートールド社によって開発され、マークス&スペンサー社によって更に改良されたコートールド試験は、フェノール系抗酸化剤によってもたらされる黄変に対する感度を評価するために織物工業において確立された試験である。
本発明に従った組成物で処理された織物繊維材料は、高いコートールド堅牢度を有する。
(a)増白工程
PA6.6(ポリアミド6.6)のテクスチャード加工されたトリコットを、2.0%ユビテックス(登録商標:Uvitex)NFW液(蛍光増白剤、チバスペシャルティケミカルズ社製)及びウルトラボン(登録商標:Ultravon)EL(分散剤、チバスペシャルティケミカルズ社製)1.0g/Lを含む水溶液で浸染法(exhaust process)により処理した。pHは酢酸で4.5に調整した。
溶液比 1:20、30分/95℃
(b)助剤の適用
増白された繊維を、表1に示した補助組成物を含む水溶液でパッド染色法により処理した。
溶液含浸量 100%;70℃で乾燥
ガンツ(Ganz)に従う白色度:230
該繊維をその後、ヒートセット試験(60秒/210℃)成形試験(60秒/210℃)に付した;未処理の材料と比較した結果を表2に示す。
表1:補助組成物
PA6.6/エラスタン繊維(82:18)を、pH 4.5において、1.7% ラナセット ブルー 2R(登録商標:Lanaset)(チバスペシャルティケミカルズ社製)及び1.0% ラナセット バイオレット B(登録商標:Lanaset)(チバスペシャルティケミカルズ社製)を含む水溶液を用いて、浸染法により染色した。
該方法において予め染色した繊維を、70℃において2分間、30% アジピン酸ジヒドラジド及び70% イルガソル DAM(登録商標:Irgasol)(分散剤、チバスペシャルティケミカルズ社製)(実施例14)、又は、30% アジピン酸ジヒドラジド及び70% タモル NN904(登録商標:Tamol)(分散剤)(実施例15)、又は、30% アジピン酸ジヒドラジド及び70% ドデシルベンゼンスルホン酸ナトリウム(実施例16)(液含浸率 70%)からなる補助組成物 30g/Lを含む各場合の水溶液を用いてパッド染色法により処理し、その後、ヒートセットした(60秒/180℃)。その後、染色繊維を、塩素浴水試験(chlorine bath water test)(100ppm Cl2)に付した。
表3は、対照(未処理の染色繊維)との比較における色調(DEF値)の差を示す。
表3
Claims (14)
- (A)全組成に基づき5ないし95質量%の、式(1a)又は(1b)
Y1−X−Y2 (1a)
A1A2N−OH (1b)
[式中、
Xは、2価の脂肪族、芳香族、芳香脂肪族又は脂環式の基を表わし、
Y1及びY2は、各々互いに独立して、−OH、−CO−OR1、−NR1R2、−CO−NH−NR1R2又は−NH−CO−NH−NR1R2(式中、R1及びR2は、各々互いに独立して、水素原子、炭素原子数1ないし20のアルキル基、炭素原子数1ないし20のアルコキシ基、炭素原子数5ないし24のシクロアルキル基、炭素原子数5ないし30のアリール基又は炭素原子数6ないし36のアラルキル基を表わし、該アルキル基、アルコキシ基、シクロアルキル基、アリール基又はアラルキル基は、未置換であるか、又は、ヒドロキシ基、アミノ基、スルホ基又はカルボキシル基又はハロゲン原子の1つ以上によって置換され得る。)を表わし、
A1及びA2は、各々互いに独立して、炭素原子数1ないし20のアルキル基又は炭素原子数6ないし36のアラルキル基を表わす。]で表わされる少なくとも1種の化合物、
(B)全組成に基づき0ないし95質量%の、1種以上のアニオン性又は非イオン性界面活性剤もしくは分散剤;及び、
(C)全組成に基づき0ないし85質量%の、固体の無機酸又は有機酸
を含み、
各場合において、成分A+B+Cの合計量が100質量%となる組成物。 - 成分(A)として、Xが、エチレン基、プロピレン基、トリメチレン基、テトラメチレン基、ペンタメチレン基、ヘキサメチレン基、オクタメチレン基、フェニレン基又はメチレン−p−ジフェニレン基を表わすところの式(1a)で表わされる化合物を含む請求項1に記載の組成物。
- 成分(A)として、Y1及びY2が、−NR1R2、−CO−NH−NR1R2又は−NH−CO−NH−NR1R2(式中、R1及びR2は、水素原子、炭素原子数1ないし12のアルキル基又は炭素原子数5ないし24のアリール基を表わす。)を表わすところの式(1a)で表わされる化合物を含む請求項1に記載の組成物。
- 成分(A)として、Y1及びY2が、−NR1R2、−CO−NH−NR1R2又は−NH−CO−NH−NR1R2(式中、R1及びR2は、水素原子、メチル基又はフェニル基を表わす。)を表わすところの式(1a)で表わされる化合物を含む請求項1に記載の組成物。
- 成分(A)として、A1及びA2がエチル基を表わすところの式(1b)で表わされる化合物を含む請求項1に記載の組成物。
- 成分(B)として、式(2)
R−Z−SO3M (2)
[式中、
Zは、2価の芳香族基を表わし、
Rは、炭素原子数1ないし20のアルキル基、炭素原子数1ないし20のアルコキシ基、炭素原子数5ないし24のシクロアルキル基、炭素原子数5ないし30のアリール基、炭素原子数6ないし36のアラルキル基、−NHR3、−NR4R5、−NHCOR6又は−NR7COR8(式中、R3、R4、R5、R6、R7及びR8は、各々互いに独立して、炭素原子数1ないし20のアルキル基、炭素原子数1ないし20のアルコキシ基、炭素原子数5ないし24のシクロアルキル基、炭素原子数5ないし30のアリール基又は炭素原子数6ないし36のアラルキル基を表わし、該アルキル基、アルコキシ基、シクロアルキル基、アリール基又はアラルキル基は、未置換であるか、又は、ヒドロキシ基、アミノ基、スルホ基又はカルボキシル基又はハロゲン原子の1つ以上によって置換され得る。)を表わし、及び、
Mは、水素原子、アルカリ金属カチオン又は未置換のアンモニウムイオン又は1つ以上の炭素原子数1ないし20のアルキル基によって置換されたアンモニウムイオンを表わす。]で表わされる化合物を含む請求項1に記載の組成物。 - 成分(B)として、Zが、フェニレン基又はナフチレン基を表わし、かつRが炭素原子数1ないし20のアルキル基を表わすところの式(2)で表わされる化合物を含む請求項7に記載の組成物。
- 成分(B)として、アルキルベンゼンスルホネート又はアルキルスルフェートを含む請求項7に記載の組成物。
- 成分(C)として、α−ヒドロキシカルボン酸を含む請求項1に記載の組成物。
- 成分(C)として、酒石酸、蓚酸、アジピン酸又はクエン酸を含む請求項1に記載の組成物。
- 染色されていない、蛍光増白された又は反応染料、酸性染料、金属錯体染料又は分散染料で染色された、天然又は合成織物繊維材料の熱安定性を改善する方法であって、該繊維材料が請求項1に記載の組成物を含む液で処理されるところの方法。
- 染色されていない、蛍光増白された又は反応染料、酸性染料、金属錯体染料又は分散染料で染色された、天然又は合成織物繊維材料のオゾン堅牢度、NOx堅牢度又は塩素堅牢度を改善する方法であって、該繊維材料が請求項1に記載の組成物を含む液で処理されるところの方法。
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KR20090014278A (ko) | 2009-02-09 |
WO2007122142A2 (en) | 2007-11-01 |
US20090165215A1 (en) | 2009-07-02 |
CN101426973A (zh) | 2009-05-06 |
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WO2007122142A3 (en) | 2008-05-15 |
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