BRPI0313260B1 - polímero insolúvel em água do mar, processo para a preparação de um polímero insolúvel em água do mar,uso de um polímero insolúvel em água do mar, composições para revestimento antiincrustação e uso de uma composição para revestimento - Google Patents
polímero insolúvel em água do mar, processo para a preparação de um polímero insolúvel em água do mar,uso de um polímero insolúvel em água do mar, composições para revestimento antiincrustação e uso de uma composição para revestimento Download PDFInfo
- Publication number
- BRPI0313260B1 BRPI0313260B1 BRPI0313260A BR0313260A BRPI0313260B1 BR PI0313260 B1 BRPI0313260 B1 BR PI0313260B1 BR PI0313260 A BRPI0313260 A BR PI0313260A BR 0313260 A BR0313260 A BR 0313260A BR PI0313260 B1 BRPI0313260 B1 BR PI0313260B1
- Authority
- BR
- Brazil
- Prior art keywords
- polymer
- groups
- seawater
- hydrocarbon group
- quaternary ammonium
- Prior art date
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- 229920000642 polymer Polymers 0.000 title claims abstract description 71
- 239000013535 sea water Substances 0.000 title claims description 34
- 230000003373 anti-fouling effect Effects 0.000 title claims description 29
- 239000008199 coating composition Substances 0.000 title claims description 24
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 125000001453 quaternary ammonium group Chemical group 0.000 claims abstract description 34
- 125000005496 phosphonium group Chemical group 0.000 claims abstract description 27
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 26
- 239000002253 acid Substances 0.000 claims abstract description 25
- 239000000203 mixture Substances 0.000 claims abstract description 22
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 19
- 125000002877 alkyl aryl group Chemical group 0.000 claims abstract description 15
- 125000003118 aryl group Chemical group 0.000 claims abstract description 15
- 125000000129 anionic group Chemical group 0.000 claims abstract description 13
- 150000002500 ions Chemical class 0.000 claims abstract description 9
- 238000002360 preparation method Methods 0.000 claims abstract description 4
- 125000001183 hydrocarbyl group Chemical group 0.000 claims abstract 12
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 38
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 37
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- 239000004615 ingredient Substances 0.000 claims description 11
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 9
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- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 5
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 claims description 5
- 238000006116 polymerization reaction Methods 0.000 claims description 5
- 238000005956 quaternization reaction Methods 0.000 claims description 5
- 125000006527 (C1-C5) alkyl group Chemical group 0.000 claims description 4
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- 229910019142 PO4 Inorganic materials 0.000 description 2
- 235000021314 Palmitic acid Nutrition 0.000 description 2
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- AMHNZOICSMBGDH-UHFFFAOYSA-L zineb Chemical compound [Zn+2].[S-]C(=S)NCCNC([S-])=S AMHNZOICSMBGDH-UHFFFAOYSA-L 0.000 description 2
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- 125000002837 carbocyclic group Chemical group 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- CRQQGFGUEAVUIL-UHFFFAOYSA-N chlorothalonil Chemical compound ClC1=C(Cl)C(C#N)=C(Cl)C(C#N)=C1Cl CRQQGFGUEAVUIL-UHFFFAOYSA-N 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- WIVXEZIMDUGYRW-UHFFFAOYSA-L copper(i) sulfate Chemical compound [Cu+].[Cu+].[O-]S([O-])(=O)=O WIVXEZIMDUGYRW-UHFFFAOYSA-L 0.000 description 1
- QHNCWVQDOPICKC-UHFFFAOYSA-N copper;1-hydroxypyridine-2-thione Chemical compound [Cu].ON1C=CC=CC1=S.ON1C=CC=CC1=S QHNCWVQDOPICKC-UHFFFAOYSA-N 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- NMCCNOZOBBWFMN-UHFFFAOYSA-N davicil Chemical compound CS(=O)(=O)C1=C(Cl)C(Cl)=NC(Cl)=C1Cl NMCCNOZOBBWFMN-UHFFFAOYSA-N 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
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- 230000008021 deposition Effects 0.000 description 1
- 229960002380 dibutyl phthalate Drugs 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- VUPKGFBOKBGHFZ-UHFFFAOYSA-N dipropyl carbonate Chemical compound CCCOC(=O)OCCC VUPKGFBOKBGHFZ-UHFFFAOYSA-N 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000005670 ethenylalkyl group Chemical group 0.000 description 1
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
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- 125000000524 functional group Chemical group 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- HDHLIWCXDDZUFH-UHFFFAOYSA-N irgarol 1051 Chemical compound CC(C)(C)NC1=NC(SC)=NC(NC2CC2)=N1 HDHLIWCXDDZUFH-UHFFFAOYSA-N 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 229940117955 isoamyl acetate Drugs 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000010907 mechanical stirring Methods 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 235000020638 mussel Nutrition 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- OYDCCWNLILCHDJ-UHFFFAOYSA-N p-sulfooxy cinnamic acid Natural products OC(=O)C=CC1=CC=C(OS(O)(=O)=O)C=C1 OYDCCWNLILCHDJ-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical class OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 150000003141 primary amines Chemical group 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- WJSXSXUHWBSPEP-UHFFFAOYSA-N pyridine;triphenylborane Chemical compound C1=CC=NC=C1.C1=CC=CC=C1B(C=1C=CC=CC=1)C1=CC=CC=C1 WJSXSXUHWBSPEP-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 150000003335 secondary amines Chemical group 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- HYVWIQDYBVKITD-UHFFFAOYSA-N tolylfluanid Chemical compound CN(C)S(=O)(=O)N(SC(F)(Cl)Cl)C1=CC=C(C)C=C1 HYVWIQDYBVKITD-UHFFFAOYSA-N 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- XNFIRYXKTXAHAC-UHFFFAOYSA-N tralopyril Chemical compound BrC1=C(C(F)(F)F)NC(C=2C=CC(Cl)=CC=2)=C1C#N XNFIRYXKTXAHAC-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 150000003752 zinc compounds Chemical class 0.000 description 1
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- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 description 1
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/52—Amides or imides
- C08F20/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F20/60—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing nitrogen in addition to the carbonamido nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/10—Esters
- C08F20/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F30/00—Homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
- C08F30/02—Homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1811—C10or C11-(Meth)acrylate, e.g. isodecyl (meth)acrylate, isobornyl (meth)acrylate or 2-naphthyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/52—Amides or imides
- C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F220/60—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing nitrogen in addition to the carbonamido nitrogen
- C08F220/603—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing nitrogen in addition to the carbonamido nitrogen and containing oxygen in addition to the carbonamido oxygen and nitrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Paints Or Removers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
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| EP02255612 | 2002-08-09 | ||
| PCT/EP2003/007693 WO2004018533A1 (en) | 2002-08-09 | 2003-07-16 | Aci-capped quaternised polymer and compositions comprising such polymer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR0313260A BR0313260A (pt) | 2005-06-14 |
| BRPI0313260B1 true BRPI0313260B1 (pt) | 2015-10-20 |
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Family Applications (1)
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| BRPI0313260A BRPI0313260B1 (pt) | 2002-08-09 | 2003-07-16 | polímero insolúvel em água do mar, processo para a preparação de um polímero insolúvel em água do mar,uso de um polímero insolúvel em água do mar, composições para revestimento antiincrustação e uso de uma composição para revestimento |
Country Status (22)
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| EP (1) | EP1534760B9 (enExample) |
| JP (1) | JP4695390B2 (enExample) |
| KR (1) | KR101045922B1 (enExample) |
| CN (1) | CN1330677C (enExample) |
| AU (1) | AU2003250076B2 (enExample) |
| BR (1) | BRPI0313260B1 (enExample) |
| CA (1) | CA2495549C (enExample) |
| CY (1) | CY1113438T1 (enExample) |
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| ES (1) | ES2394636T3 (enExample) |
| MX (1) | MXPA05001535A (enExample) |
| MY (1) | MY148366A (enExample) |
| NO (1) | NO333476B1 (enExample) |
| NZ (1) | NZ538655A (enExample) |
| PL (1) | PL211454B1 (enExample) |
| PT (1) | PT1534760E (enExample) |
| RU (1) | RU2333920C2 (enExample) |
| TW (1) | TWI335930B (enExample) |
| UA (1) | UA81258C2 (enExample) |
| WO (1) | WO2004018533A1 (enExample) |
| ZA (1) | ZA200501975B (enExample) |
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| EP1641862B1 (en) | 2003-07-07 | 2006-11-15 | Akzo Nobel Coatings International B.V. | Silyl ester copolymer compositions |
| ES2302182T3 (es) | 2004-02-03 | 2008-07-01 | Akzo Nobel Coatings International Bv | Composiciones antiensuciamiento que comprenden un polimero con grupos salinos. |
| US7893047B2 (en) | 2006-03-03 | 2011-02-22 | Arch Chemicals, Inc. | Biocide composition comprising pyrithione and pyrrole derivatives |
| EP2013277A1 (en) * | 2006-04-28 | 2009-01-14 | Albermarle Corporation | Coatings, coating formulations, and compositions containing quaternary ammonium compounds |
| US9365460B2 (en) * | 2006-11-09 | 2016-06-14 | Akzo Nobel N.V. | Pigment dispersion |
| ES2438577T3 (es) * | 2008-08-13 | 2014-01-17 | Akzo Nobel Coatings International B.V. | Polímero con grupos salinos y composición de recubrimiento anti-incrustante que comprende dicho polímero |
| JP2012510511A (ja) * | 2008-12-01 | 2012-05-10 | インヴアスク セラピューテイックス インコーポレイテッド | レニン−アンジオテンシン−アルドステロン系阻害剤及びリポ酸化合物を含有する組成物、並びに、レニン−アンジオテンシン−アルドステロン系に関連した疾患の治療のためのそれらの使用 |
| EP2468825A1 (en) | 2010-12-21 | 2012-06-27 | Akzo Nobel Coatings International B.V. | Antifouling coating composition |
| JP5529832B2 (ja) * | 2010-12-22 | 2014-06-25 | ダウ グローバル テクノロジーズ エルエルシー | Ｄｃｏｉｔまたはｏｉｔまたはｂｂｉｔの１種と、グリホサート化合物との相乗的組み合わせ |
| RU2476206C1 (ru) | 2011-11-22 | 2013-02-27 | Виктор Львович Лимонов | Фармацевтическая композиция для приготовления инфузионных растворов антимикробных препаратов, способ ее получения (варианты) |
| EP2785804B1 (en) | 2011-12-02 | 2015-11-18 | Akzo Nobel Coatings International BV | Waterborne antifouling coating composition |
| JP5860164B2 (ja) | 2011-12-22 | 2016-02-16 | アクゾ ノーベル コーティングス インターナショナル ビー ヴィ | 保護塗料の選択および塗布方法 |
| CN102775870A (zh) * | 2012-06-14 | 2012-11-14 | 天长市银狐漆业有限公司 | 生物杀伤防污油漆 |
| KR20170031140A (ko) * | 2014-07-15 | 2017-03-20 | 아크조노벨코팅스인터내셔널비.브이. | 2개 이상의 염-함유 공중합체들을 포함하는 방오 코팅 조성물 |
| US9580608B1 (en) * | 2014-08-08 | 2017-02-28 | Sandia Corporation | Switchable antifouling coatings and uses thereof |
| AU2015340747A1 (en) * | 2014-10-28 | 2017-04-20 | Akzo Nobel Coatings International B.V. | Fouling control coating compostion comprising a polymer containing silyl ester groups, and a polymer comprising quaternary ammonium/phosphonium sulphonate groups |
| JP6423528B2 (ja) * | 2014-10-28 | 2018-11-14 | アクゾ ノーベル コーティングス インターナショナル ビー ヴィ | シリルエステル官能基及び四級アンモニウム基／ホスホニウム基を含むポリマーを含む付着抑制組成物 |
| US10064273B2 (en) | 2015-10-20 | 2018-08-28 | MR Label Company | Antimicrobial copper sheet overlays and related methods for making and using |
| JP6473275B1 (ja) | 2016-01-20 | 2019-02-20 | アクゾ ノーベル コーティングス インターナショナル ビー ヴィ | 水に浸される基材用の被覆組成物 |
| CA3027588C (en) * | 2016-06-22 | 2024-03-26 | The Lubrizol Corporation | Gas hydrate inhibitors |
| US11279835B2 (en) | 2016-11-11 | 2022-03-22 | Hempel A/S | Antifouling coating composition comprising novel carbon-based hydrolysable polymers |
| KR20200073248A (ko) | 2017-10-23 | 2020-06-23 | 헴펠 에이/에스 | 알콕시실란을 포함하는 자기 연마형 오염방지 코팅 조성물 |
| KR102700117B1 (ko) | 2017-11-06 | 2024-08-28 | 헴펠 에이/에스 | 해양 선박의 유체 동적 프로파일을 개선하는 방법, 개선된 유체 동적 프로파일을 갖는 해양 선박 및 유체 동적 프로파일을 개선하기 위한 코팅 시스템 |
| EP3724278A1 (en) | 2017-12-14 | 2020-10-21 | Hempel A/S | Controlled release antifouling coating composition via biocide interaction |
| JP2019178329A (ja) * | 2019-05-23 | 2019-10-17 | 三菱ケミカル株式会社 | 摩擦低減剤を含有する塗料、および塗料を用いた摩擦低減方法 |
| GB2592921B (en) | 2020-03-09 | 2024-04-17 | Jotun As | Hull cleaning robot |
| GB202107159D0 (en) | 2021-03-23 | 2021-06-30 | Jotun As | Monitoring a vessel |
| JP2024514449A (ja) | 2021-03-23 | 2024-04-02 | ヨツン アクティーゼルスカブ | 水中の静止物体の表面の清浄度の監視 |
Family Cites Families (51)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB231070A (en) | 1924-08-06 | 1925-03-26 | Carl Julius Baer | Improvements in the method and apparatus for dredging and cutting channels |
| GB751129A (en) | 1953-03-10 | 1956-06-27 | Basf Ag | Improvements in the production of quaternary ammonium salts |
| NL296183A (enExample) | 1963-01-30 | |||
| US3522066A (en) | 1966-12-06 | 1970-07-28 | Lithium Corp | Process for preparing aqueous mixed lithium and sodium (and/or potassium) silicate solutions |
| US3620784A (en) | 1968-01-24 | 1971-11-16 | Nasa | Potassium silicate-zinc coatings |
| US3721574A (en) | 1968-08-06 | 1973-03-20 | R Schneider | Silicate coatings compositions |
| US4012437A (en) * | 1972-02-07 | 1977-03-15 | Rohm And Haas Company | Method of producing betaines, monomers and polymers containing betaine-type units and novel and useful copolymers thereby obtained |
| GB1457590A (en) | 1974-04-03 | 1976-12-08 | Int Paint Co | Marine paint |
| US4161169A (en) * | 1977-07-07 | 1979-07-17 | Solar Energy Systems, Inc. | Focussing flat plate solar collector device |
| US4162169A (en) | 1977-12-21 | 1979-07-24 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Alkali-metal silicate binders and methods of manufacture |
| US4230496A (en) | 1978-09-22 | 1980-10-28 | Pq Corporation | Zinc rich paint vehicle |
| US4180643A (en) | 1978-11-16 | 1979-12-25 | Texaco Development Corp. | Acrylamide or methacrylamide quaternary compounds |
| US4212820A (en) | 1979-04-23 | 1980-07-15 | Texaco Development Corporation | Acrylamide or methacrylamide alkoxypropyl quaternary compounds |
| GB2056997B (en) | 1979-07-12 | 1983-04-07 | Kuraray Co | Copolymers containing cationic groups |
| US4426464A (en) | 1981-07-03 | 1984-01-17 | International Paint Public Limited Company | Marine paint |
| US4594365A (en) | 1983-01-17 | 1986-06-10 | M&T Chemicals Inc. | Erodible ship-bottom paints for control of marine fouling |
| FR2540127B1 (enExample) | 1983-01-28 | 1985-03-29 | Rhone Poulenc Spec Chim | |
| US4479824A (en) | 1983-05-04 | 1984-10-30 | Schutt John B | Silicate binders and coatings |
| GB8511144D0 (en) | 1985-05-02 | 1985-06-12 | Int Paint Plc | Marine anti-fouling paint |
| JPH0764985B2 (ja) | 1985-05-17 | 1995-07-12 | 日本ペイント株式会社 | 金属含有樹脂組成物 |
| US4745214A (en) | 1986-06-20 | 1988-05-17 | Norsolor | Process for the preparation of an aqueous solution of unsaturated quaternary ammonium salts |
| WO1988006177A1 (en) | 1987-02-13 | 1988-08-25 | Labofina S.A. | Improved shop primer compositions |
| US4892944A (en) | 1987-05-13 | 1990-01-09 | Mitsubishi Petrochemical Co., Ltd. | Process for producing quaternary salts |
| US5260480A (en) | 1988-02-11 | 1993-11-09 | Norsolor | Quaternization process |
| US5246488A (en) | 1988-03-31 | 1993-09-21 | Nippon Paint Co., Ltd. | Temporary rust resisting coating composition |
| DE3816328A1 (de) | 1988-05-13 | 1989-11-23 | Hoechst Ag | Verfahren zur herstellung von quaternaeren ammoniumsalzen langkettiger aliphatischer carbonsaeuren und verwendung dieser ammoniumsalze |
| US5116407A (en) * | 1988-10-13 | 1992-05-26 | Courtaulds Coatings Limited | Antifouling coatings |
| US4902442A (en) | 1988-10-24 | 1990-02-20 | The Dow Chemical Company | Stabilized mixtures of colloidal silica and soluble silicate and a method of producing porous silica compositions therefrom |
| JP2582418B2 (ja) | 1988-10-28 | 1997-02-19 | 花王株式会社 | 防カビ塗料組成物 |
| US4973639A (en) | 1989-01-25 | 1990-11-27 | Hoechst Celanese Corporation | Polymerizable quaternary ammonium methyl carbonates |
| US4910325A (en) | 1989-01-25 | 1990-03-20 | Hoechst Celanese Corporation | Polymerizable quaternary ammonium methyl carbonates |
| EP0506782B1 (en) | 1989-12-22 | 1996-08-14 | Courtaulds Coatings (Holdings) Limited | Anti-fouling coating compositions |
| GB9006318D0 (en) | 1990-03-21 | 1990-05-16 | Courtaulds Coatings Ltd | Coating compositions |
| DE4242082A1 (de) | 1992-12-14 | 1994-06-16 | Witco Gmbh | Hydrolisierbare polymere Harze und Bindemittel für bewuchsverhindernde Anstriche |
| ZA943999B (en) | 1993-06-09 | 1995-02-03 | Lonza Ag | Quaternary ammonium and waterproofing/preservative compositions |
| US5641726A (en) | 1993-06-09 | 1997-06-24 | Lonza, Inc. | Quaternary ammonium carboxylate and borate compositions and preparation thereof |
| US5520910A (en) * | 1993-07-14 | 1996-05-28 | Nippon Chemical Industrial | Antimicrobial polymer, contact lens and contact lens-care articles |
| JP3062917B2 (ja) | 1994-09-01 | 2000-07-12 | 日本ペイント株式会社 | 加水分解型金属含有樹脂および防汚塗料組成物 |
| JPH09286933A (ja) | 1996-02-21 | 1997-11-04 | Kansai Paint Co Ltd | 防汚塗料組成物 |
| US5674934A (en) * | 1996-02-23 | 1997-10-07 | The Dow Chemical Company | Reversible and irreversible water-based coatings |
| SG60054A1 (en) | 1996-04-17 | 1999-02-22 | Nof Corp | Coating composition |
| FR2757866B1 (fr) * | 1996-12-30 | 2004-12-17 | Catalyse | Polymeres comportant des groupes ammoniums quaternaires, leur utilisation pour la fabrication d'un materiau a propretes antibacteriennes et leurs procedes de preparation |
| JP2919419B2 (ja) | 1997-02-07 | 1999-07-12 | 三菱化学株式会社 | 電解液用の電解質 |
| CN1246397C (zh) | 1999-03-18 | 2006-03-22 | 国际涂料有限公司 | 用于金属底材的涂料组合物 |
| JP2000290317A (ja) * | 1999-04-12 | 2000-10-17 | Hokko Chem Ind Co Ltd | アンモニウム−テトラアリールボレート系重合体、その製造方法、およびそれを含有する水中防汚剤 |
| DE19921904A1 (de) | 1999-05-12 | 2000-11-16 | Creavis Tech & Innovation Gmbh | Verfahren zur Herstellung inhärent mikrobizider Polymeroberflächen |
| AU6564600A (en) | 1999-08-27 | 2001-03-26 | Creavis Gesellschaft Fur Technologie Und Innovation Mbh | Copolymers of acryloyloxyalkylamino compounds |
| JP2001329124A (ja) * | 2000-05-25 | 2001-11-27 | Dai Ichi Kogyo Seiyaku Co Ltd | 水性組成物およびこれを用いた帯電防止膜 |
| DK1299483T3 (da) * | 2000-07-06 | 2005-12-12 | Akzo Nobel Coatings Int Bv | Antibegroningsmaling |
| US8048215B2 (en) | 2000-09-13 | 2011-11-01 | Akzo Nobel N.V. | Primer coating of steel |
| ES2234900T3 (es) | 2000-09-13 | 2005-07-01 | Akzo Nobel Coatings International B.V. | Revestimiento de imprimacion de acero. |
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2003
- 2003-07-16 EP EP03792203.6A patent/EP1534760B9/en not_active Expired - Lifetime
- 2003-07-16 BR BRPI0313260A patent/BRPI0313260B1/pt active IP Right Grant
- 2003-07-16 CN CNB038195119A patent/CN1330677C/zh not_active Expired - Lifetime
- 2003-07-16 NZ NZ538655A patent/NZ538655A/en not_active IP Right Cessation
- 2003-07-16 CA CA2495549A patent/CA2495549C/en not_active Expired - Fee Related
- 2003-07-16 AU AU2003250076A patent/AU2003250076B2/en not_active Ceased
- 2003-07-16 UA UAA200502037A patent/UA81258C2/uk unknown
- 2003-07-16 DK DK03792203.6T patent/DK1534760T3/da active
- 2003-07-16 RU RU2005106212/04A patent/RU2333920C2/ru not_active IP Right Cessation
- 2003-07-16 WO PCT/EP2003/007693 patent/WO2004018533A1/en not_active Ceased
- 2003-07-16 MX MXPA05001535A patent/MXPA05001535A/es active IP Right Grant
- 2003-07-16 ES ES03792203T patent/ES2394636T3/es not_active Expired - Lifetime
- 2003-07-16 KR KR1020057002285A patent/KR101045922B1/ko not_active Expired - Lifetime
- 2003-07-16 JP JP2004530027A patent/JP4695390B2/ja not_active Expired - Lifetime
- 2003-07-16 PT PT37922036T patent/PT1534760E/pt unknown
- 2003-07-16 PL PL373870A patent/PL211454B1/pl unknown
- 2003-07-22 US US10/623,620 patent/US7001933B2/en not_active Ceased
- 2003-08-06 TW TW092121533A patent/TWI335930B/zh not_active IP Right Cessation
- 2003-08-07 MY MYPI20032986A patent/MY148366A/en unknown
-
2005
- 2005-01-31 NO NO20050536A patent/NO333476B1/no not_active IP Right Cessation
- 2005-03-08 ZA ZA200501975A patent/ZA200501975B/en unknown
-
2008
- 2008-02-14 US US12/031,253 patent/USRE41208E1/en not_active Expired - Lifetime
-
2012
- 2012-11-30 CY CY20121101173T patent/CY1113438T1/el unknown
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