BR9808032A - Cerâmica composta reforçada por fibra e processo para preparação de uma tal cerâmica - Google Patents
Cerâmica composta reforçada por fibra e processo para preparação de uma tal cerâmicaInfo
- Publication number
- BR9808032A BR9808032A BR9808032-6A BR9808032A BR9808032A BR 9808032 A BR9808032 A BR 9808032A BR 9808032 A BR9808032 A BR 9808032A BR 9808032 A BR9808032 A BR 9808032A
- Authority
- BR
- Brazil
- Prior art keywords
- fibers
- fiber
- composite ceramics
- prepared
- ceramic
- Prior art date
Links
- 239000000919 ceramic Substances 0.000 title abstract 7
- 238000004519 manufacturing process Methods 0.000 title abstract 3
- 239000003733 fiber-reinforced composite Substances 0.000 title abstract 2
- 239000000835 fiber Substances 0.000 abstract 5
- 239000011230 binding agent Substances 0.000 abstract 3
- 239000002131 composite material Substances 0.000 abstract 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 238000000197 pyrolysis Methods 0.000 abstract 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 abstract 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 abstract 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 230000001143 conditioned effect Effects 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 229910002804 graphite Inorganic materials 0.000 abstract 1
- 239000010439 graphite Substances 0.000 abstract 1
- 239000012210 heat-resistant fiber Substances 0.000 abstract 1
- 239000011159 matrix material Substances 0.000 abstract 1
- 239000005011 phenolic resin Substances 0.000 abstract 1
- 229920001568 phenolic resin Polymers 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 230000001681 protective effect Effects 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 239000004071 soot Substances 0.000 abstract 1
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16D—COUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
- F16D69/00—Friction linings; Attachment thereof; Selection of coacting friction substances or surfaces
- F16D69/02—Composition of linings ; Methods of manufacturing
- F16D69/023—Composite materials containing carbon and carbon fibres or fibres made of carbonizable material
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
- C04B35/56—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides
- C04B35/565—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on silicon carbide
- C04B35/573—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on silicon carbide obtained by reaction sintering or recrystallisation
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/628—Coating the powders or the macroscopic reinforcing agents
- C04B35/62844—Coating fibres
- C04B35/62857—Coating fibres with non-oxide ceramics
- C04B35/6286—Carbides
- C04B35/62863—Silicon carbide
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/71—Ceramic products containing macroscopic reinforcing agents
- C04B35/78—Ceramic products containing macroscopic reinforcing agents containing non-metallic materials
- C04B35/80—Fibres, filaments, whiskers, platelets, or the like
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/71—Ceramic products containing macroscopic reinforcing agents
- C04B35/78—Ceramic products containing macroscopic reinforcing agents containing non-metallic materials
- C04B35/80—Fibres, filaments, whiskers, platelets, or the like
- C04B35/83—Carbon fibres in a carbon matrix
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16D—COUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
- F16D69/00—Friction linings; Attachment thereof; Selection of coacting friction substances or surfaces
- F16D69/02—Composition of linings ; Methods of manufacturing
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/38—Non-oxide ceramic constituents or additives
- C04B2235/3817—Carbides
- C04B2235/3821—Boron carbides
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/38—Non-oxide ceramic constituents or additives
- C04B2235/3817—Carbides
- C04B2235/3839—Refractory metal carbides
- C04B2235/3843—Titanium carbides
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/52—Constituents or additives characterised by their shapes
- C04B2235/5208—Fibers
- C04B2235/5216—Inorganic
- C04B2235/524—Non-oxidic, e.g. borides, carbides, silicides or nitrides
- C04B2235/5244—Silicon carbide
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/52—Constituents or additives characterised by their shapes
- C04B2235/5208—Fibers
- C04B2235/5216—Inorganic
- C04B2235/524—Non-oxidic, e.g. borides, carbides, silicides or nitrides
- C04B2235/5248—Carbon, e.g. graphite
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/52—Constituents or additives characterised by their shapes
- C04B2235/5208—Fibers
- C04B2235/526—Fibers characterised by the length of the fibers
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/52—Constituents or additives characterised by their shapes
- C04B2235/5208—Fibers
- C04B2235/5264—Fibers characterised by the diameter of the fibers
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/54—Particle size related information
- C04B2235/5418—Particle size related information expressed by the size of the particles or aggregates thereof
- C04B2235/5436—Particle size related information expressed by the size of the particles or aggregates thereof micrometer sized, i.e. from 1 to 100 micron
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/60—Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
- C04B2235/616—Liquid infiltration of green bodies or pre-forms
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Engineering & Computer Science (AREA)
- Composite Materials (AREA)
- Mechanical Engineering (AREA)
- Inorganic Chemistry (AREA)
- Ceramic Products (AREA)
- Braking Arrangements (AREA)
Abstract
Patente de Invenção: <B>"CERâMICA COMPOSTA REFORçADA POR FIBRA E PROCESSO PARA PREPARAçãO DE UMA TAL CERâMICA"<D>. é indicada uma cerâmica composta reforçada por fibras com fibras altamente resistentes a aquecimento, particularmente à base de Si/C/B/N, que são ligadas por reação a uma matriz à base de Si, que é preparada, por impregnação dos feixes de fibras de Si/C/B/N com um aglutinante apropriado para pirólise e o aglutinante é fixado, opcionalmente o feixe de fibras é condicionado em seguida com uma camada de proteção de silicatação apropriada para pirólise, como resina fenólica ou policarbossilano, prepara-se em seguida uma mistura de feixes de fibras, preenchedores, como SiC e carbono na forma de grafite ou fuligem, e aglutinantes, e a mistura é prensada para preparação de um moldado não-curado, em seguida é pirolisada sob vácuo ou gás de proteção para preparação de um corpo moldado poroso, que então preferentemente é infiltrado sob vácuo com um fundido de silício. Assim são preparadas de maneira racional cerâmicas compostas reforçadas por fibras em uma grande produção em série, que visivelmente apresentam propriedades aperfeiçoadas perante as cerâmicas compostas usuais e particularmente são apropriadas para emprego em sistemas de frenagem com alto desempenho (Fig. 1).
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19711829A DE19711829C1 (de) | 1997-03-21 | 1997-03-21 | Verfahren zur Herstellung einer faserverstärkten Verbundkeramik |
PCT/EP1998/001044 WO1998042635A1 (de) | 1997-03-21 | 1998-02-24 | Faserverstärkte verbundkeramik und verfahren zur herstellung einer solchen |
Publications (1)
Publication Number | Publication Date |
---|---|
BR9808032A true BR9808032A (pt) | 2000-03-08 |
Family
ID=7824131
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR9808032-6A BR9808032A (pt) | 1997-03-21 | 1998-02-24 | Cerâmica composta reforçada por fibra e processo para preparação de uma tal cerâmica |
Country Status (13)
Country | Link |
---|---|
US (1) | US6261981B1 (pt) |
EP (1) | EP0968150B1 (pt) |
JP (1) | JP3502395B2 (pt) |
KR (1) | KR100346256B1 (pt) |
CN (1) | CN1155539C (pt) |
BR (1) | BR9808032A (pt) |
CA (1) | CA2284617C (pt) |
CZ (1) | CZ299421B6 (pt) |
DE (2) | DE19711829C1 (pt) |
ES (1) | ES2162431T3 (pt) |
PL (1) | PL191605B1 (pt) |
RU (1) | RU2184715C2 (pt) |
WO (1) | WO1998042635A1 (pt) |
Families Citing this family (123)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR876M (pt) | 1960-10-12 | 1961-10-16 | ||
DE29724077U1 (de) | 1997-06-28 | 1999-11-11 | DaimlerChrysler AG, 70567 Stuttgart | Bremseinheit |
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JP2000081062A (ja) † | 1998-09-08 | 2000-03-21 | Ngk Insulators Ltd | ブレーキ用部材 |
DE19805608C2 (de) * | 1998-02-12 | 2000-05-11 | Daimler Chrysler Ag | Verfahren zur Herstellung von endformnahen Formkörpern aus Preßmassen sowie danach erhältlicher Formkörper |
DE19805868C2 (de) * | 1998-02-13 | 2002-09-12 | Daimler Chrysler Ag | Verfahren zur Herstellung eines Faserverbundwerkstoffs |
DE19815309C2 (de) * | 1998-04-06 | 2002-10-31 | Daimler Chrysler Ag | Verfahren zur Herstellung eines Faserverbundwerkstoffes |
DE19861035C2 (de) * | 1998-04-06 | 2000-11-30 | Daimler Chrysler Ag | Faserverbundwerkstoff und Verfahren zu dessen Herstellung |
DE19834571C2 (de) | 1998-07-31 | 2001-07-26 | Daimler Chrysler Ag | Verfahren zur Herstellung von Körpern aus faserverstärkten Verbundwerkstoffen und Verwendung des Verfahrens |
DE19834542C5 (de) * | 1998-07-31 | 2004-07-01 | Daimlerchrysler Ag | Verfahren zur Herstellung von Verstärkungsfasern enthaltenden Körpern, danach erhältliche Körper, Verfahren zum Fügen der so erhaltenen Körper, gefügte Körper und Anwendung des Fügeverfahrens |
ES2185099T3 (es) | 1998-09-15 | 2003-04-16 | Daimler Chrysler Ag | Unidad de freno consistente en disco de freno y forro de freno. |
DE19842926B4 (de) * | 1998-09-18 | 2009-07-09 | Deutsches Zentrum für Luft- und Raumfahrt e.V. | Elektromagnetische Notbremse |
DE19856597B4 (de) * | 1998-10-14 | 2004-07-08 | Industrieanlagen-Betriebsgesellschaft Mbh | Schutzpanzerung |
DE19856721A1 (de) * | 1998-12-09 | 2000-06-15 | Ecm Ingenieur Unternehmen Fuer | Verfahren zur Herstellung eines mittels Kohlenstoffkurzfasern verstärkten Siliciumcarbid-Verbundwerkstoffes |
DE19859840B4 (de) | 1998-12-23 | 2006-01-12 | Daimlerchrysler Ag | Bremseinheit |
DE19859839A1 (de) | 1998-12-23 | 2000-07-06 | Daimler Chrysler Ag | Bremseinheit |
DE19859617C1 (de) | 1998-12-23 | 2000-05-25 | Daimler Chrysler Ag | Verfahren zur Betätigung einer Bremseinheit |
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US20050181209A1 (en) * | 1999-08-20 | 2005-08-18 | Karandikar Prashant G. | Nanotube-containing composite bodies, and methods for making same |
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DE60010845T3 (de) † | 2000-02-09 | 2011-05-05 | Freni Brembo S.P.A., Curno | Geformtes Verbundmaterial für Bremsen und Verfahren zu seiner Herstellung |
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-
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- 1997-03-21 DE DE19711829A patent/DE19711829C1/de not_active Expired - Lifetime
-
1998
- 1998-02-24 CZ CZ0333599A patent/CZ299421B6/cs not_active IP Right Cessation
- 1998-02-24 RU RU99122165/03A patent/RU2184715C2/ru active
- 1998-02-24 CA CA002284617A patent/CA2284617C/en not_active Expired - Lifetime
- 1998-02-24 WO PCT/EP1998/001044 patent/WO1998042635A1/de active IP Right Grant
- 1998-02-24 JP JP54206698A patent/JP3502395B2/ja not_active Expired - Lifetime
- 1998-02-24 KR KR1019997008146A patent/KR100346256B1/ko not_active IP Right Cessation
- 1998-02-24 PL PL335684A patent/PL191605B1/pl unknown
- 1998-02-24 BR BR9808032-6A patent/BR9808032A/pt not_active Application Discontinuation
- 1998-02-24 ES ES98912381T patent/ES2162431T3/es not_active Expired - Lifetime
- 1998-02-24 DE DE59801312T patent/DE59801312D1/de not_active Expired - Lifetime
- 1998-02-24 CN CNB988035758A patent/CN1155539C/zh not_active Expired - Fee Related
- 1998-02-24 EP EP98912381A patent/EP0968150B1/de not_active Expired - Lifetime
- 1998-02-24 US US09/381,465 patent/US6261981B1/en not_active Expired - Lifetime
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DE19711829C1 (de) | 1998-09-03 |
WO1998042635A1 (de) | 1998-10-01 |
JP2000512257A (ja) | 2000-09-19 |
PL191605B1 (pl) | 2006-06-30 |
KR20000076058A (ko) | 2000-12-26 |
CA2284617A1 (en) | 1998-10-01 |
RU2184715C2 (ru) | 2002-07-10 |
CN1251083A (zh) | 2000-04-19 |
CZ299421B6 (cs) | 2008-07-23 |
DE59801312D1 (de) | 2001-10-04 |
EP0968150A1 (de) | 2000-01-05 |
CN1155539C (zh) | 2004-06-30 |
JP3502395B2 (ja) | 2004-03-02 |
EP0968150B1 (de) | 2001-08-29 |
KR100346256B1 (ko) | 2002-07-26 |
CA2284617C (en) | 2002-11-05 |
PL335684A1 (en) | 2000-05-08 |
CZ333599A3 (cs) | 2000-08-16 |
US6261981B1 (en) | 2001-07-17 |
ES2162431T3 (es) | 2001-12-16 |
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