BR112016021154A2 - Polímeros e copolímeros de ácido itacônico - Google Patents
Polímeros e copolímeros de ácido itacônico Download PDFInfo
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- BR112016021154A2 BR112016021154A2 BR112016021154-5A BR112016021154A BR112016021154A2 BR 112016021154 A2 BR112016021154 A2 BR 112016021154A2 BR 112016021154 A BR112016021154 A BR 112016021154A BR 112016021154 A2 BR112016021154 A2 BR 112016021154A2
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- Prior art keywords
- polymer
- acid
- mol
- sodium
- solution
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- 229920000642 polymer Polymers 0.000 title claims abstract description 251
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 title claims abstract description 127
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 title claims abstract description 117
- 229920001577 copolymer Polymers 0.000 title claims abstract description 74
- 239000000178 monomer Substances 0.000 claims abstract description 142
- -1 tri-substituted vinyl Chemical group 0.000 claims abstract description 123
- 239000003599 detergent Substances 0.000 claims abstract description 119
- 239000002253 acid Substances 0.000 claims abstract description 39
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000000203 mixture Substances 0.000 claims description 229
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 116
- 229910001868 water Inorganic materials 0.000 claims description 105
- 238000000034 method Methods 0.000 claims description 88
- 230000008569 process Effects 0.000 claims description 65
- 239000002002 slurry Substances 0.000 claims description 64
- 238000009472 formulation Methods 0.000 claims description 57
- 150000003839 salts Chemical class 0.000 claims description 57
- 239000004094 surface-active agent Substances 0.000 claims description 57
- 238000006116 polymerization reaction Methods 0.000 claims description 48
- 239000002904 solvent Substances 0.000 claims description 43
- 239000000843 powder Substances 0.000 claims description 40
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 claims description 38
- 229920000536 2-Acrylamido-2-methylpropane sulfonic acid Polymers 0.000 claims description 36
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 36
- 239000003795 chemical substances by application Substances 0.000 claims description 36
- 239000007844 bleaching agent Substances 0.000 claims description 35
- 239000003999 initiator Substances 0.000 claims description 35
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 34
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 33
- 102000004190 Enzymes Human genes 0.000 claims description 32
- 108090000790 Enzymes Proteins 0.000 claims description 32
- 239000002738 chelating agent Substances 0.000 claims description 31
- 150000002148 esters Chemical class 0.000 claims description 30
- 239000004615 ingredient Substances 0.000 claims description 29
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 28
- 239000007788 liquid Substances 0.000 claims description 28
- 239000002585 base Substances 0.000 claims description 25
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 24
- 239000000654 additive Substances 0.000 claims description 21
- MNCGMVDMOKPCSQ-UHFFFAOYSA-M sodium;2-phenylethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=CC1=CC=CC=C1 MNCGMVDMOKPCSQ-UHFFFAOYSA-M 0.000 claims description 19
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 claims description 18
- 239000000499 gel Substances 0.000 claims description 17
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 claims description 16
- 238000005260 corrosion Methods 0.000 claims description 16
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims description 16
- 229920002125 Sokalan® Polymers 0.000 claims description 15
- 239000003638 chemical reducing agent Substances 0.000 claims description 15
- 230000007797 corrosion Effects 0.000 claims description 15
- 238000004851 dishwashing Methods 0.000 claims description 15
- 229910052751 metal Inorganic materials 0.000 claims description 15
- 239000002184 metal Substances 0.000 claims description 15
- 230000000996 additive effect Effects 0.000 claims description 13
- 239000012736 aqueous medium Substances 0.000 claims description 13
- 239000003112 inhibitor Substances 0.000 claims description 13
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 13
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 12
- 239000012190 activator Substances 0.000 claims description 12
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 12
- 239000002689 soil Substances 0.000 claims description 12
- 239000000975 dye Substances 0.000 claims description 11
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 claims description 10
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 10
- 229920002472 Starch Polymers 0.000 claims description 10
- 239000007800 oxidant agent Substances 0.000 claims description 10
- 239000002304 perfume Substances 0.000 claims description 10
- 235000019698 starch Nutrition 0.000 claims description 10
- 239000002562 thickening agent Substances 0.000 claims description 10
- 230000002378 acidificating effect Effects 0.000 claims description 9
- 229910021645 metal ion Inorganic materials 0.000 claims description 9
- 150000002978 peroxides Chemical class 0.000 claims description 9
- 239000007921 spray Substances 0.000 claims description 9
- 239000003995 emulsifying agent Substances 0.000 claims description 8
- 239000000945 filler Substances 0.000 claims description 8
- 239000011521 glass Substances 0.000 claims description 8
- 239000008235 industrial water Substances 0.000 claims description 8
- 150000005846 sugar alcohols Polymers 0.000 claims description 8
- 229920001400 block copolymer Polymers 0.000 claims description 7
- 239000003054 catalyst Substances 0.000 claims description 7
- 230000009920 chelation Effects 0.000 claims description 7
- 238000005553 drilling Methods 0.000 claims description 7
- 229920003023 plastic Polymers 0.000 claims description 7
- 239000004033 plastic Substances 0.000 claims description 7
- 239000011541 reaction mixture Substances 0.000 claims description 7
- 239000000872 buffer Substances 0.000 claims description 6
- 239000012459 cleaning agent Substances 0.000 claims description 6
- 239000006260 foam Substances 0.000 claims description 6
- 239000008187 granular material Substances 0.000 claims description 6
- 239000012535 impurity Substances 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 230000001590 oxidative effect Effects 0.000 claims description 6
- 239000000049 pigment Substances 0.000 claims description 6
- 239000002356 single layer Substances 0.000 claims description 6
- 235000010265 sodium sulphite Nutrition 0.000 claims description 6
- 239000008107 starch Substances 0.000 claims description 6
- 230000003472 neutralizing effect Effects 0.000 claims description 5
- 239000003505 polymerization initiator Substances 0.000 claims description 5
- 238000000746 purification Methods 0.000 claims description 5
- 238000000518 rheometry Methods 0.000 claims description 5
- 229920000388 Polyphosphate Polymers 0.000 claims description 4
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- 239000000919 ceramic Substances 0.000 claims description 4
- 239000002270 dispersing agent Substances 0.000 claims description 4
- 239000002609 medium Substances 0.000 claims description 4
- 230000004048 modification Effects 0.000 claims description 4
- 238000012986 modification Methods 0.000 claims description 4
- 239000004584 polyacrylic acid Substances 0.000 claims description 4
- 239000001205 polyphosphate Substances 0.000 claims description 4
- 235000011176 polyphosphates Nutrition 0.000 claims description 4
- 239000002455 scale inhibitor Substances 0.000 claims description 4
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 claims description 3
- 239000003082 abrasive agent Substances 0.000 claims description 3
- 239000003963 antioxidant agent Substances 0.000 claims description 3
- 239000006172 buffering agent Substances 0.000 claims description 3
- 150000001735 carboxylic acids Chemical group 0.000 claims description 3
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000003755 preservative agent Substances 0.000 claims description 3
- 239000006254 rheological additive Substances 0.000 claims description 3
- 238000001694 spray drying Methods 0.000 claims description 3
- 238000012546 transfer Methods 0.000 claims description 3
- 239000004599 antimicrobial Substances 0.000 claims description 2
- 238000004061 bleaching Methods 0.000 claims description 2
- 150000007529 inorganic bases Chemical class 0.000 claims description 2
- 125000005395 methacrylic acid group Chemical group 0.000 claims description 2
- 230000000379 polymerizing effect Effects 0.000 claims description 2
- 229920005604 random copolymer Polymers 0.000 claims description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 claims description 2
- 239000000306 component Substances 0.000 claims 4
- 239000003248 enzyme activator Substances 0.000 claims 2
- 239000003752 hydrotrope Substances 0.000 claims 2
- 239000002518 antifoaming agent Substances 0.000 claims 1
- 238000005469 granulation Methods 0.000 claims 1
- 230000003179 granulation Effects 0.000 claims 1
- 239000003607 modifier Substances 0.000 claims 1
- 230000002794 monomerizing effect Effects 0.000 claims 1
- 238000005516 engineering process Methods 0.000 abstract description 10
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 abstract description 7
- 229940018557 citraconic acid Drugs 0.000 abstract description 7
- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 abstract description 6
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 abstract description 6
- 239000000243 solution Substances 0.000 description 117
- 239000000523 sample Substances 0.000 description 88
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 71
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 56
- 239000000047 product Substances 0.000 description 54
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 46
- 125000004432 carbon atom Chemical group C* 0.000 description 44
- 235000019441 ethanol Nutrition 0.000 description 44
- 239000002736 nonionic surfactant Substances 0.000 description 35
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 34
- 239000011734 sodium Substances 0.000 description 34
- 229910052708 sodium Inorganic materials 0.000 description 34
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 31
- 239000000463 material Substances 0.000 description 31
- 229940088598 enzyme Drugs 0.000 description 30
- 125000000217 alkyl group Chemical group 0.000 description 29
- 150000001875 compounds Chemical class 0.000 description 27
- 235000019832 sodium triphosphate Nutrition 0.000 description 27
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical group [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 25
- 238000004140 cleaning Methods 0.000 description 25
- 235000011121 sodium hydroxide Nutrition 0.000 description 24
- 238000012360 testing method Methods 0.000 description 24
- 238000007792 addition Methods 0.000 description 23
- 239000012071 phase Substances 0.000 description 23
- 229920001296 polysiloxane Polymers 0.000 description 23
- 229910052783 alkali metal Inorganic materials 0.000 description 22
- 229910000029 sodium carbonate Inorganic materials 0.000 description 22
- 235000017550 sodium carbonate Nutrition 0.000 description 22
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 21
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 20
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 20
- 239000011572 manganese Substances 0.000 description 20
- 239000000126 substance Substances 0.000 description 20
- 229920000742 Cotton Polymers 0.000 description 19
- 239000007864 aqueous solution Substances 0.000 description 19
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 18
- 239000002453 shampoo Substances 0.000 description 18
- 239000010457 zeolite Substances 0.000 description 18
- 102000035195 Peptidases Human genes 0.000 description 17
- 108091005804 Peptidases Proteins 0.000 description 17
- 229910021536 Zeolite Inorganic materials 0.000 description 17
- 238000006243 chemical reaction Methods 0.000 description 17
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 17
- 229910052938 sodium sulfate Inorganic materials 0.000 description 17
- 235000011152 sodium sulphate Nutrition 0.000 description 17
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 16
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 16
- 150000001298 alcohols Chemical class 0.000 description 16
- 150000001340 alkali metals Chemical class 0.000 description 16
- 239000011976 maleic acid Substances 0.000 description 16
- 238000002156 mixing Methods 0.000 description 16
- 239000002245 particle Substances 0.000 description 16
- 239000004365 Protease Substances 0.000 description 15
- 238000004453 electron probe microanalysis Methods 0.000 description 15
- UFZOPKFMKMAWLU-UHFFFAOYSA-N ethoxy(methyl)phosphinic acid Chemical compound CCOP(C)(O)=O UFZOPKFMKMAWLU-UHFFFAOYSA-N 0.000 description 15
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 15
- 238000006386 neutralization reaction Methods 0.000 description 15
- 238000005406 washing Methods 0.000 description 15
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 14
- 239000000460 chlorine Substances 0.000 description 14
- 229910052801 chlorine Inorganic materials 0.000 description 14
- 150000002191 fatty alcohols Chemical class 0.000 description 14
- 239000003921 oil Substances 0.000 description 14
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 13
- 235000019198 oils Nutrition 0.000 description 13
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 12
- 238000001035 drying Methods 0.000 description 12
- 229910019142 PO4 Inorganic materials 0.000 description 11
- 239000004115 Sodium Silicate Substances 0.000 description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 11
- 239000004744 fabric Substances 0.000 description 11
- 229910052760 oxygen Inorganic materials 0.000 description 11
- 239000001301 oxygen Substances 0.000 description 11
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 11
- 239000007787 solid Substances 0.000 description 11
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
- 238000005481 NMR spectroscopy Methods 0.000 description 10
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 10
- LPTWEDZIPSKWDG-UHFFFAOYSA-N benzenesulfonic acid;dodecane Chemical compound OS(=O)(=O)C1=CC=CC=C1.CCCCCCCCCCCC LPTWEDZIPSKWDG-UHFFFAOYSA-N 0.000 description 10
- 235000014113 dietary fatty acids Nutrition 0.000 description 10
- 239000006185 dispersion Substances 0.000 description 10
- 239000000194 fatty acid Substances 0.000 description 10
- 229930195729 fatty acid Natural products 0.000 description 10
- 239000012530 fluid Substances 0.000 description 10
- 230000006870 function Effects 0.000 description 10
- 239000012299 nitrogen atmosphere Substances 0.000 description 10
- 229920005862 polyol Polymers 0.000 description 10
- 239000011591 potassium Substances 0.000 description 10
- 229910052700 potassium Inorganic materials 0.000 description 10
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 10
- 229910052911 sodium silicate Inorganic materials 0.000 description 10
- 229920001897 terpolymer Polymers 0.000 description 10
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 9
- 125000000129 anionic group Chemical group 0.000 description 9
- 239000006229 carbon black Substances 0.000 description 9
- 150000001732 carboxylic acid derivatives Chemical group 0.000 description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
- 229910021641 deionized water Inorganic materials 0.000 description 9
- 230000036961 partial effect Effects 0.000 description 9
- 239000010452 phosphate Substances 0.000 description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 9
- 235000021317 phosphate Nutrition 0.000 description 9
- 150000003077 polyols Chemical class 0.000 description 9
- 229920001451 polypropylene glycol Polymers 0.000 description 9
- 239000000344 soap Substances 0.000 description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 8
- 101000740449 Bacillus subtilis (strain 168) Biotin/lipoyl attachment protein Proteins 0.000 description 8
- 102000016938 Catalase Human genes 0.000 description 8
- 108010053835 Catalase Proteins 0.000 description 8
- 125000001931 aliphatic group Chemical group 0.000 description 8
- 150000008051 alkyl sulfates Chemical class 0.000 description 8
- 229910000019 calcium carbonate Inorganic materials 0.000 description 8
- 235000010216 calcium carbonate Nutrition 0.000 description 8
- 239000003093 cationic surfactant Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- 230000032050 esterification Effects 0.000 description 8
- 238000005886 esterification reaction Methods 0.000 description 8
- 150000002500 ions Chemical class 0.000 description 8
- 239000003002 pH adjusting agent Substances 0.000 description 8
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate group Chemical group S(=O)(=O)([O-])[O-] QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 8
- 239000003826 tablet Substances 0.000 description 8
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 7
- 102000013142 Amylases Human genes 0.000 description 7
- 108010065511 Amylases Proteins 0.000 description 7
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- 150000007513 acids Chemical class 0.000 description 7
- 150000004996 alkyl benzenes Chemical class 0.000 description 7
- 150000008052 alkyl sulfonates Chemical class 0.000 description 7
- 150000001412 amines Chemical class 0.000 description 7
- 235000012216 bentonite Nutrition 0.000 description 7
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 7
- 239000012467 final product Substances 0.000 description 7
- 150000002596 lactones Chemical group 0.000 description 7
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 7
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 7
- 230000006641 stabilisation Effects 0.000 description 7
- 238000011105 stabilization Methods 0.000 description 7
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 7
- ODHCTXKNWHHXJC-UHFFFAOYSA-N 5-oxoproline Chemical compound OC(=O)C1CCC(=O)N1 ODHCTXKNWHHXJC-UHFFFAOYSA-N 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical class CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 6
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
- WDJHALXBUFZDSR-UHFFFAOYSA-N acetoacetic acid Chemical compound CC(=O)CC(O)=O WDJHALXBUFZDSR-UHFFFAOYSA-N 0.000 description 6
- 125000003545 alkoxy group Chemical group 0.000 description 6
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 6
- INJRKJPEYSAMPD-UHFFFAOYSA-N aluminum;silicic acid;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O INJRKJPEYSAMPD-UHFFFAOYSA-N 0.000 description 6
- 239000011575 calcium Substances 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 229910052802 copper Inorganic materials 0.000 description 6
- 239000010949 copper Substances 0.000 description 6
- 239000008367 deionised water Substances 0.000 description 6
- 150000004665 fatty acids Chemical class 0.000 description 6
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- IWMMSZLFZZPTJY-UHFFFAOYSA-M sodium;3-(dodecylamino)propane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCNCCCS([O-])(=O)=O IWMMSZLFZZPTJY-UHFFFAOYSA-M 0.000 description 1
- HWCHICTXVOMIIF-UHFFFAOYSA-M sodium;3-(dodecylamino)propanoate Chemical compound [Na+].CCCCCCCCCCCCNCCC([O-])=O HWCHICTXVOMIIF-UHFFFAOYSA-M 0.000 description 1
- FTZNYGSHSMZEIA-UHFFFAOYSA-M sodium;hydrogen carbonate;sulfuric acid Chemical compound [Na+].OC([O-])=O.OS(O)(=O)=O FTZNYGSHSMZEIA-UHFFFAOYSA-M 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- NPAWNPCNZAPTKA-UHFFFAOYSA-M sodium;propane-1-sulfonate Chemical compound [Na+].CCCS([O-])(=O)=O NPAWNPCNZAPTKA-UHFFFAOYSA-M 0.000 description 1
- WGRULTCAYDOGQK-UHFFFAOYSA-M sodium;sodium;hydroxide Chemical compound [OH-].[Na].[Na+] WGRULTCAYDOGQK-UHFFFAOYSA-M 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 229920006301 statistical copolymer Polymers 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 description 1
- DIORMHZUUKOISG-UHFFFAOYSA-N sulfoformic acid Chemical compound OC(=O)S(O)(=O)=O DIORMHZUUKOISG-UHFFFAOYSA-N 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 230000037072 sun protection Effects 0.000 description 1
- 239000000829 suppository Substances 0.000 description 1
- 108010038851 tannase Proteins 0.000 description 1
- 238000005494 tarnishing Methods 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 108010075550 termamyl Proteins 0.000 description 1
- NMOALOSNPWTWRH-UHFFFAOYSA-N tert-butyl 7,7-dimethyloctaneperoxoate Chemical compound CC(C)(C)CCCCCC(=O)OOC(C)(C)C NMOALOSNPWTWRH-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 150000004026 tertiary sulfonium compounds Chemical class 0.000 description 1
- DCQJDRNKCUQEMA-UHFFFAOYSA-N tetradecanediperoxoic acid Chemical compound OOC(=O)CCCCCCCCCCCCC(=O)OO DCQJDRNKCUQEMA-UHFFFAOYSA-N 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Chemical class 0.000 description 1
- 230000000699 topical effect Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 229960002622 triacetin Drugs 0.000 description 1
- 125000005270 trialkylamine group Chemical group 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical class [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- ZMANZCXQSJIPKH-UHFFFAOYSA-O triethylammonium ion Chemical compound CC[NH+](CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-O 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 description 1
- 229960000281 trometamol Drugs 0.000 description 1
- 239000012588 trypsin Substances 0.000 description 1
- 230000001810 trypsinlike Effects 0.000 description 1
- OUYCCCASQSFEME-UHFFFAOYSA-N tyrosine Natural products OC(=O)C(N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-UHFFFAOYSA-N 0.000 description 1
- 229940124543 ultraviolet light absorber Drugs 0.000 description 1
- KJIOQYGWTQBHNH-UHFFFAOYSA-N undecanol Chemical class CCCCCCCCCCCO KJIOQYGWTQBHNH-UHFFFAOYSA-N 0.000 description 1
- 206010048828 underweight Diseases 0.000 description 1
- 239000004474 valine Substances 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- OXQKEKGBFMQTML-KVTDHHQDSA-N volemitol Chemical compound OC[C@@H](O)[C@@H](O)C(O)[C@H](O)[C@H](O)CO OXQKEKGBFMQTML-KVTDHHQDSA-N 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
- 150000003752 zinc compounds Chemical class 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/02—Acids; Metal salts or ammonium salts thereof, e.g. maleic acid or itaconic acid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/14—Monomers containing only one unsaturated aliphatic radical containing one ring substituted by heteroatoms or groups containing heteroatoms
- C08F212/30—Sulfur
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Detergent Compositions (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201461953239P | 2014-03-14 | 2014-03-14 | |
| US61/953,239 | 2014-03-14 | ||
| PCT/US2015/020408 WO2015138872A1 (en) | 2014-03-14 | 2015-03-13 | Itaconic acid polymers and copolymers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR112016021154A2 true BR112016021154A2 (pt) | 2021-08-24 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112016021154-5A BR112016021154A2 (pt) | 2014-03-14 | 2015-03-13 | Polímeros e copolímeros de ácido itacônico |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US11214758B2 (https=) |
| EP (1) | EP3116924B1 (https=) |
| JP (2) | JP7071039B2 (https=) |
| KR (1) | KR102350475B1 (https=) |
| CN (1) | CN106574018A (https=) |
| BR (1) | BR112016021154A2 (https=) |
| ES (1) | ES2823562T3 (https=) |
| TW (1) | TWI637053B (https=) |
| WO (1) | WO2015138872A1 (https=) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2026006892A1 (pt) * | 2024-07-03 | 2026-01-08 | Chemyunion Ltda | Composição de lavagem de fibras têxteis, métodos e usos relacionados |
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| BR112016021154A2 (pt) * | 2014-03-14 | 2021-08-24 | Lubrizol Advanced Materials, Inc. | Polímeros e copolímeros de ácido itacônico |
| WO2016202582A1 (de) | 2015-06-17 | 2016-12-22 | Clariant International Ltd | Wasserlösliche oder wasserquellbare polymere als wasserverlustreduzierer in zementschlämmen |
| BR112019011780B1 (pt) | 2016-12-12 | 2023-03-07 | Clariant International Ltd | Polímero compreendendo carbono de material biológico, seu processo de obtenção e seu uso |
| WO2018108611A1 (en) | 2016-12-12 | 2018-06-21 | Clariant International Ltd | Use of bio-based polymer in a cosmetic, dermatological or pharmaceutical composition |
| EP3554644B1 (en) | 2016-12-15 | 2025-03-19 | Clariant International Ltd | Water-soluble and/or water-swellable hybrid polymer |
| EP3554646B1 (en) | 2016-12-15 | 2025-03-19 | Clariant International Ltd | Water-soluble and/or water-swellable hybrid polymer |
| ES3017507T3 (en) | 2016-12-15 | 2025-05-13 | Clariant Int Ltd | Water-soluble and/or water-swellable hybrid polymer |
| EP3554643B1 (en) | 2016-12-15 | 2025-03-19 | Clariant International Ltd | Water-soluble and/or water-swellable hybrid polymer |
| US10472594B2 (en) | 2017-04-11 | 2019-11-12 | Itaconix Corporation | Sulfonated copolymers for detergent composition |
| EP3418364A1 (en) | 2017-06-19 | 2018-12-26 | The Procter & Gamble Company | Automatic dishwashing cleaning composition |
| EP3418366A1 (en) | 2017-06-19 | 2018-12-26 | The Procter & Gamble Company | Automatic dishwashing cleaning composition |
| EP3441450A1 (en) * | 2017-08-11 | 2019-02-13 | The Procter & Gamble Company | Automatic dishwashing composition |
| PL3676360T3 (pl) * | 2017-08-30 | 2022-01-24 | Dow Global Technologies Llc | Kompozycja do automatycznego mycia naczyń z polimerem dyspergującym |
| WO2019099145A1 (en) * | 2017-11-15 | 2019-05-23 | Dow Global Technologies Llc | Dispersant polymer for autodish formulations |
| GB201809123D0 (en) | 2018-06-04 | 2018-07-18 | Reckitt Benckiser Finish Bv | Composition |
| US11549082B2 (en) * | 2018-09-20 | 2023-01-10 | Baker Hughes Holdings Llc | Cleaning agent comprising a polyacrylate terpolymer for removal of fouling deposits from metal surfaces |
| DE102018133650A1 (de) * | 2018-12-28 | 2020-07-02 | Henkel Ag & Co. Kgaa | Geschirrspülmittel mit verbesserter Klarspülleistung |
| KR20220104737A (ko) | 2019-11-19 | 2022-07-26 | 루브리졸 어드밴스드 머티어리얼스, 인코포레이티드 | 재침착 억제 중합체 및 이를 함유하는 세제 조성물 |
| JP6829754B1 (ja) * | 2019-11-19 | 2021-02-10 | 住友精化株式会社 | 二次電池用結着剤 |
| US20220389349A1 (en) * | 2019-11-25 | 2022-12-08 | Kao Corporation | Liquid detergent composition for textile products |
| CN114867831A (zh) | 2019-12-19 | 2022-08-05 | 路博润先进材料公司 | 再沉积抑制性聚合物和含有所述再沉积抑制性聚合物的洗涤剂组合物 |
| WO2021159146A1 (en) * | 2020-02-05 | 2021-08-12 | Itaconix Corporation | Copolymer formulations of poly (itaconic acid-co-2-acrylamido-2-methylpropane sulfonic acid) for dishwasher detergent compositions |
| US11879111B2 (en) | 2020-03-27 | 2024-01-23 | Ecolab Usa Inc. | Detergent compositions, cleaning systems and methods of cleaning cosmetic and other soils |
| US11827842B2 (en) | 2020-10-26 | 2023-11-28 | Ecolab Usa Inc. | Calcite scale control agent for geothermal wells |
| ES3026558T3 (en) | 2021-03-17 | 2025-06-11 | Akzo Nobel Coatings Int Bv | Alkyd resin, coating composition, and substrate coated with such coating compositon |
| CN113336888B (zh) * | 2021-05-28 | 2022-09-13 | 华南农业大学 | 生物基酸碱响应性超亲水油水分离膜及其制备方法和应用 |
| EP4269548A1 (en) | 2022-04-27 | 2023-11-01 | Dalli-Werke GmbH & Co. KG | Detergent composition with antiscalants |
| CN117624961A (zh) * | 2023-12-11 | 2024-03-01 | 广东卫斯理化工科技有限公司 | 一种脱胶纸剂 |
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-
2015
- 2015-03-13 BR BR112016021154-5A patent/BR112016021154A2/pt not_active Application Discontinuation
- 2015-03-13 WO PCT/US2015/020408 patent/WO2015138872A1/en not_active Ceased
- 2015-03-13 KR KR1020167028558A patent/KR102350475B1/ko active Active
- 2015-03-13 TW TW104108103A patent/TWI637053B/zh active
- 2015-03-13 EP EP15712768.9A patent/EP3116924B1/en not_active Revoked
- 2015-03-13 CN CN201580024475.7A patent/CN106574018A/zh active Pending
- 2015-03-13 ES ES15712768T patent/ES2823562T3/es active Active
- 2015-03-13 US US15/125,820 patent/US11214758B2/en active Active
- 2015-03-13 JP JP2016575634A patent/JP7071039B2/ja active Active
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- 2020-01-17 JP JP2020005968A patent/JP2020063458A/ja active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2026006892A1 (pt) * | 2024-07-03 | 2026-01-08 | Chemyunion Ltda | Composição de lavagem de fibras têxteis, métodos e usos relacionados |
Also Published As
| Publication number | Publication date |
|---|---|
| EP3116924A1 (en) | 2017-01-18 |
| ES2823562T3 (es) | 2021-05-07 |
| TWI637053B (zh) | 2018-10-01 |
| US20170022451A1 (en) | 2017-01-26 |
| EP3116924B1 (en) | 2020-08-19 |
| KR20160135272A (ko) | 2016-11-25 |
| CN106574018A (zh) | 2017-04-19 |
| JP2020063458A (ja) | 2020-04-23 |
| US11214758B2 (en) | 2022-01-04 |
| JP7071039B2 (ja) | 2022-05-18 |
| TW201538717A (zh) | 2015-10-16 |
| WO2015138872A1 (en) | 2015-09-17 |
| JP2017510693A (ja) | 2017-04-13 |
| KR102350475B1 (ko) | 2022-01-11 |
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