BR112016001127A8 - preparação de acrilato de metil através de um processo de esterificação oxidativa - Google Patents

preparação de acrilato de metil através de um processo de esterificação oxidativa

Info

Publication number
BR112016001127A8
BR112016001127A8 BR112016001127A BR112016001127A BR112016001127A8 BR 112016001127 A8 BR112016001127 A8 BR 112016001127A8 BR 112016001127 A BR112016001127 A BR 112016001127A BR 112016001127 A BR112016001127 A BR 112016001127A BR 112016001127 A8 BR112016001127 A8 BR 112016001127A8
Authority
BR
Brazil
Prior art keywords
preparation
methyl acrylate
oxidative esterification
esterification process
group
Prior art date
Application number
BR112016001127A
Other languages
English (en)
Other versions
BR112016001127B1 (pt
Inventor
D Frick Christopher
A Kraptchetov Dmitri
Limbach Kirk
Original Assignee
Rohm & Haas
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rohm & Haas filed Critical Rohm & Haas
Publication of BR112016001127A8 publication Critical patent/BR112016001127A8/pt
Publication of BR112016001127B1 publication Critical patent/BR112016001127B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/39—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/644—Arsenic, antimony or bismuth
    • B01J23/6447—Bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/648—Vanadium, niobium or tantalum or polonium
    • B01J23/6484—Niobium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6525—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/038—Precipitation; Co-precipitation to form slurries or suspensions, e.g. a washcoat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/62—Use of additives, e.g. for stabilisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

preparação de acrilato de metil através de um processo de esterificação oxidativa um processo para a produção de metacrilato de metil, o processo compreendendo contatar reagentes compreendendo metacroleína, metanol e um gás contendo oxigênio, sob condições de reação na presença de um catalisador sólido compreendendo paládio, bismuto e pelo menos um terceiro elemento x, onde x é selecionado do grupo que consiste em p, s, sc, v, ga, se, y , nb, mo, la, ce e nd, em que o catalisador sólido ainda compreende um suporte selecionado a partir de pelo menos um membro do grupo que consiste em sílica, alumina, carbonato de cálcio, carvão ativado, óxido de zinco, óxido de titânio e óxido de magnésio.
BR112016001127-9A 2013-07-29 2014-07-29 processo para a produção de metacrilato de metil BR112016001127B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201361859551P 2013-07-29 2013-07-29
US61/859,551 2013-07-29
PCT/US2014/048667 WO2015017437A1 (en) 2013-07-29 2014-07-29 Preparation of methyl acrylate via an oxidative esterification process

Publications (2)

Publication Number Publication Date
BR112016001127A8 true BR112016001127A8 (pt) 2019-10-01
BR112016001127B1 BR112016001127B1 (pt) 2020-12-29

Family

ID=51303130

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112016001127-9A BR112016001127B1 (pt) 2013-07-29 2014-07-29 processo para a produção de metacrilato de metil

Country Status (12)

Country Link
US (1) US9676699B2 (pt)
EP (1) EP2989077B1 (pt)
JP (1) JP6506281B2 (pt)
KR (1) KR102287643B1 (pt)
CN (1) CN105377806B (pt)
BR (1) BR112016001127B1 (pt)
CA (1) CA2918403C (pt)
MX (1) MX363805B (pt)
SA (1) SA516370404B1 (pt)
SG (1) SG11201600702VA (pt)
TW (1) TW201509901A (pt)
WO (1) WO2015017437A1 (pt)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW201509522A (zh) * 2013-07-29 2015-03-16 Rohm & Haas 氧化酯化催化劑
CN105683142B (zh) 2013-10-28 2018-11-13 罗门哈斯公司 用于分离甲基丙烯醛的方法
EP3587390A1 (de) 2018-06-26 2020-01-01 Röhm GmbH Verfahren zur herstellung von mma in hohen ausbeuten
CN113477252B (zh) * 2021-06-30 2023-06-30 常州大学 一种同时含钛及其它过渡金属的复合多孔催化剂的制备方法和应用

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5368718A (en) * 1976-11-27 1978-06-19 Nippon Kayaku Co Ltd Simultaneous preparation of methacrylic acid and its ester or acrylicacid and its ester
DE2848978A1 (de) 1978-11-11 1980-05-22 Bayer Ag Traegerkatalysatoren, ihre herstellung und verwendung
JPS55151533A (en) * 1979-05-17 1980-11-26 Asahi Chem Ind Co Ltd Preparation of carboxylic acid ester
DE3018071C2 (de) * 1979-05-17 1985-06-05 Asahi Kasei Kogyo K.K., Osaka Verfahren zur Herstellung von Carbonsäureestern
JPS5687530A (en) 1979-12-19 1981-07-16 Asahi Chem Ind Co Ltd Dehydrating method of gas containing unsaturated aldehyde
US4714695A (en) 1985-04-18 1987-12-22 The Standard Oil Company Method for the preparation of high activity palladium based catalysts
JP3258354B2 (ja) * 1991-11-28 2002-02-18 三井化学株式会社 カルボン酸エステルの製造法
KR100259743B1 (ko) 1995-07-18 2000-07-01 야마모토 카즈모토 카르복실산 에스테르 제조용 촉매
JPH09216850A (ja) * 1996-02-09 1997-08-19 Mitsubishi Rayon Co Ltd カルボン酸エステルの製造方法
TW385304B (en) 1996-09-10 2000-03-21 Asahi Chemical Ind Process for producing methacrylic acid ester or acrylic acid ester
TW377306B (en) 1996-12-16 1999-12-21 Asahi Chemical Ind Noble metal support
JP3511350B2 (ja) * 1997-03-25 2004-03-29 旭化成ケミカルズ株式会社 カルボン酸エステル製造用触媒
SG71815A1 (en) 1997-07-08 2000-04-18 Asahi Chemical Ind Method of producing methyl methacrylate
CN1122569C (zh) 1997-08-07 2003-10-01 三菱丽阳株式会社 用于制造羧酸酯的催化剂和羧酸酯的制造方法
US6506930B1 (en) * 1997-11-17 2003-01-14 Rohm And Haas Company Process for preparing alkyl (meth)acrylates
WO2001024924A1 (en) 1999-10-05 2001-04-12 Showa Denko K. K. Catalyst for acetic acid production, process for producing the same, and process for producing acetic acid with the same
KR100605467B1 (ko) * 2000-09-29 2006-07-28 차이나 페트로리움 앤드 케미컬 코포레이션 불포화 탄화수소의 선택적 수소화 촉매, 및 그의 제법 및용도
US7326806B2 (en) 2001-06-04 2008-02-05 Nippon Shokubai Co., Ltd. Catalyst for the preparation of carboxylic esters and method for producing carboxylic esters
JP4145621B2 (ja) 2002-10-16 2008-09-03 旭化成ケミカルズ株式会社 不飽和カルボン酸エステル合成反応の反応開始方法
CN1214865C (zh) 2003-01-22 2005-08-17 中国科学院过程工程研究所 一种用于甲基丙烯醛一步氧化酯化生产甲基丙烯酸甲酯的新型催化剂
JP2004345973A (ja) 2003-05-20 2004-12-09 Asahi Kasei Chemicals Corp 不飽和カルボン酸エステルの製造方法
DE102004038013A1 (de) * 2004-08-04 2006-03-16 Basf Ag Verfahren zur Herstellung von (Meth)acrylsäureestern
GB2428014B (en) * 2005-07-08 2010-02-10 Lee Chang Yung Chemical Indust Catalyst and process for preparing carboxylic acid esters
MY152280A (en) 2007-08-13 2014-09-15 Asahi Kasei Chemicals Corp Catalyst for producing carboxylic acid esters, process for producing same and process for producing carboxylic acid esters
JP2011104457A (ja) * 2009-11-12 2011-06-02 Mitsubishi Rayon Co Ltd パラジウム含有担持触媒、その製造方法、およびα，β−不飽和カルボン酸の製造方法
KR101487352B1 (ko) 2010-09-16 2015-01-29 아사히 가세이 케미칼즈 가부시키가이샤 실리카계 재료 및 그 제조 방법, 및 귀금속 담지물 및 그것을 촉매로서 이용하는 카르복실산류의 제조 방법
US8802588B2 (en) 2012-01-23 2014-08-12 Celanese International Corporation Bismuth catalyst composition and process for manufacturing ethanol mixture

Also Published As

Publication number Publication date
EP2989077A1 (en) 2016-03-02
CA2918403C (en) 2021-07-06
MX363805B (es) 2019-04-03
US9676699B2 (en) 2017-06-13
KR102287643B1 (ko) 2021-08-06
MX2016000767A (es) 2016-04-19
US20160159728A1 (en) 2016-06-09
SA516370404B1 (ar) 2017-05-29
SG11201600702VA (en) 2016-02-26
JP6506281B2 (ja) 2019-04-24
EP2989077B1 (en) 2017-12-27
WO2015017437A1 (en) 2015-02-05
CA2918403A1 (en) 2015-02-05
KR20160035590A (ko) 2016-03-31
TW201509901A (zh) 2015-03-16
CN105377806B (zh) 2017-09-05
BR112016001127B1 (pt) 2020-12-29
JP2016525578A (ja) 2016-08-25
CN105377806A (zh) 2016-03-02

Similar Documents

Publication Publication Date Title
BR112016001127A8 (pt) preparação de acrilato de metil através de um processo de esterificação oxidativa
BRPI0910458A2 (pt) catalisador para preparar acroleína ou ácido acrílico por reação de desidratação de glicerina e método para produzir o mesmo
ES2661081T3 (es) Reactivo de liberación para compuestos de vitamina D
BR112012031918A2 (pt) processo de transesterificação usando catalisadores de sais mistos acetilacetonatos.
BR112015019704A8 (pt) método e sistema de destilação reativa
BR112015027794A2 (pt) Processo para a produção de 1,3-butadieno
AR094543A1 (es) Método para producir metacrilato de metilo a partir de propionaldehído y formaldehído mediante esterificación oxidativa
BR112015018532A8 (pt) processo de preparação de uma olefina, processo de preparação seletiva de but-2-eno, processo de preparação de isobuteno, processo de preparação de uma mistura de olefinas, processo de preparação de uma mistura de pelo menos duas olefinas, processo de fabricação de propeno, processo de fabricação de butadieno, processo de fabricação de acroleína e processo de fabricação de aldeído-3-(metíltio)propiônico”
AR066574A1 (es) Un sistema reactor, un proceso de produccion de oxido de olefina 1,2-diol 1,2-diol eter , 1,2-carbonato o alcanolamina
BR112014001365A2 (pt) processo aperfeiçoado de reações de desidratação
CL2013000163A1 (es) Proceso para la preparacion de material de carbonato de calcio que comprende proveer al menos un material que contenga carbonato de calcio, proveer al menos una sal de un acido graso c5-c28, tratar el material poniendolo en contacto con dicho acido graso y obtener dicho material tratado superficialmente; material de carbonato de calcio; y su uso en el control de material organico en un medio acuoso.
BR112015021850A2 (pt) processo e catalisador de carbonilação
BR112019001305A2 (pt) métodos para produzir ácido acrílico a partir de ácido láctico ou seus derivados em fase líquida
IN2015DN00251A (pt)
BRPI0906766A2 (pt) Sistema do catalisador, reator de oxidação contendo o mesmo, e método de preparação para acroleíne e ácido acrílico empregando o mesmo
MX2016000765A (es) Preparacion de metacrilato de metilo a traves de un proceso de esterificacion oxidativa.
WO2014210416A8 (en) Helicase suppression of non-template amplification
BR112014014552A2 (pt) Método para acoplamento ou condensação catalítica
BR112017005344A2 (pt) método para a produção de um álcool alifático tendo 8 ou mais e 22 ou menos átomos de carbono por meio de hidrogenação de um ácido graxo ou um éster de ácido graxo usando um catalisador
MX2016000764A (es) Preparacion de metacrilato de metilo a traves de un proceso de esterificacion oxidativa.
BR112015007821A2 (pt) processo para a preparação de voriconazol e análogos do mesmo
AR081730A1 (es) Composicion de control de fitoenfermedades y metodo para controlar fitoenfermedades
BR112018009801A2 (pt) métodos para preparar um éster de ácido 3-hidroxipropiônico e um éster de ácido acrílico.
BR112012014718A2 (pt) método para a produção de óxido de propileno
MY178884A (en) A catalyst for oxidation reactions, a method for its preparation and the use thereof

Legal Events

Date Code Title Description
B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 29/07/2014, OBSERVADAS AS CONDICOES LEGAIS.