JPS55151533A - Preparation of carboxylic acid ester - Google Patents

Preparation of carboxylic acid ester

Info

Publication number
JPS55151533A
JPS55151533A JP5963179A JP5963179A JPS55151533A JP S55151533 A JPS55151533 A JP S55151533A JP 5963179 A JP5963179 A JP 5963179A JP 5963179 A JP5963179 A JP 5963179A JP S55151533 A JPS55151533 A JP S55151533A
Authority
JP
Japan
Prior art keywords
compound
metal compound
catalyst
alkali
earth
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP5963179A
Other languages
Japanese (ja)
Other versions
JPS627902B2 (en
Inventor
Atsushi Aoshima
Yoshio Suzuki
Setsuo Yamamatsu
Tatsuo Yamaguchi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Asahi Chemical Industry Co Ltd
Original Assignee
Asahi Chemical Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Chemical Industry Co Ltd filed Critical Asahi Chemical Industry Co Ltd
Priority to JP5963179A priority Critical patent/JPS55151533A/en
Priority to IN529/CAL/80A priority patent/IN151805B/en
Priority to DE3018071A priority patent/DE3018071C2/en
Priority to US06/149,387 priority patent/US4518796A/en
Priority to BR8002986A priority patent/BR8002986A/en
Priority to NL8002829A priority patent/NL181356C/en
Priority to GB8016070A priority patent/GB2051056B/en
Priority to SU802923551A priority patent/SU1190985A3/en
Priority to AU58483/80A priority patent/AU518930B2/en
Priority to BE2/58568A priority patent/BE883331A/en
Priority to AR28110480A priority patent/AR220625A1/en
Priority to MX18235580A priority patent/MX153577A/en
Priority to FR8011051A priority patent/FR2456723B1/en
Priority to PH24037A priority patent/PH15826A/en
Priority to NZ19374280A priority patent/NZ193742A/en
Publication of JPS55151533A publication Critical patent/JPS55151533A/en
Publication of JPS627902B2 publication Critical patent/JPS627902B2/ja
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/644—Arsenic, antimony or bismuth
    • B01J23/6447—Bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
    • B01J31/30—Halides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/39—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester

Abstract

PURPOSE: To obtain the title compound by the reaction of an aldehyde and an alcohol in the presence of oxygen, using a catalyst comprising a metal compound containing Pd and at least one element selected from Pb, Hg, Tl and Bi, or the above compound and an alkali(ne earth) metal compound.
CONSTITUTION: An aldehyde is made to react with an alcohol in the presence of O2, using a catalyst which comprises a metal compound containing Pd and at least one element selected from Pb, Hg, Tl and Bi (e.g. Pd3Pb1), or the above compound and an alkali(ne earth) metal compound, to give the title compound. The above-mentioned catalyst can be prepared as follows: An aqueous solution, which contains a soluble Pd, Hg, Tl or Bi compound and, if necessary, an alkali(ne earth) metal compound, is impregnated into a carrier and dried. Then the carrier is immersed in an acidic aqueous solution of PdCl2 etc. with heating and reduced.
EFFECT: The above catalyst has a long as well as high activity and high selectivity.
COPYRIGHT: (C)1980,JPO&Japio
JP5963179A 1979-05-17 1979-05-17 Preparation of carboxylic acid ester Granted JPS55151533A (en)

Priority Applications (15)

Application Number Priority Date Filing Date Title
JP5963179A JPS55151533A (en) 1979-05-17 1979-05-17 Preparation of carboxylic acid ester
IN529/CAL/80A IN151805B (en) 1979-05-17 1980-05-06
DE3018071A DE3018071C2 (en) 1979-05-17 1980-05-10 Process for the preparation of carboxylic acid esters
US06/149,387 US4518796A (en) 1979-05-17 1980-05-13 Method for preparing carboxylic esters
BR8002986A BR8002986A (en) 1979-05-17 1980-05-14 PROCESS FOR THE PRODUCTION OF CARBOXYL ESTERS
NL8002829A NL181356C (en) 1979-05-17 1980-05-14 PROCESS FOR PREPARING A CARBONIC ACID ESTER.
GB8016070A GB2051056B (en) 1979-05-17 1980-05-15 Method of preparing carboxylic esters
SU802923551A SU1190985A3 (en) 1979-05-17 1980-05-15 Method of producing esters of carboxylic acid
AU58483/80A AU518930B2 (en) 1979-05-17 1980-05-16 Esters
BE2/58568A BE883331A (en) 1979-05-17 1980-05-16 WERKWIJZE VOOR HET BEREIDEN VAN CARBONZURE ESTERS
AR28110480A AR220625A1 (en) 1979-05-17 1980-05-16 CARBOXYL ESTER PREPARATION PROCEDURE
MX18235580A MX153577A (en) 1979-05-17 1980-05-16 PROCEDURE FOR PREPARING ESTERS OF CARBOXYL ACIDS
FR8011051A FR2456723B1 (en) 1979-05-17 1980-05-16 PROCESS FOR PRODUCING CARBOXYL ESTERS
PH24037A PH15826A (en) 1979-05-17 1980-05-16 Method for producing carboxylic esters
NZ19374280A NZ193742A (en) 1979-05-17 1980-05-16 Production of carboxylic acid esters by reaction of an aldehyde with an alcohol in the presence of oxygen and an intermetallic compound catalyst

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP5963179A JPS55151533A (en) 1979-05-17 1979-05-17 Preparation of carboxylic acid ester

Publications (2)

Publication Number Publication Date
JPS55151533A true JPS55151533A (en) 1980-11-26
JPS627902B2 JPS627902B2 (en) 1987-02-19

Family

ID=13118766

Family Applications (1)

Application Number Title Priority Date Filing Date
JP5963179A Granted JPS55151533A (en) 1979-05-17 1979-05-17 Preparation of carboxylic acid ester

Country Status (2)

Country Link
JP (1) JPS55151533A (en)
BE (1) BE883331A (en)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58166936A (en) * 1982-03-24 1983-10-03 バスフ　アクチエンゲゼルシヤフト Catalyst for producing carboxylic ester and use thereof
JPS59162947A (en) * 1983-02-26 1984-09-13 バスフ　アクチエンゲゼルシヤフト Catalyst and use thereof for producing methyl methacrylate
WO1998042653A1 (en) * 1997-03-24 1998-10-01 Mitsubishi Rayon Co., Ltd. Process for producing carboxylic acid esters and catalyst
US20100130648A1 (en) * 2007-05-25 2010-05-27 Evonik Roehm Gmbh Process for preparation of methyl methacrylate by esterification during oxidation
JP2013527966A (en) * 2010-03-26 2013-07-04 ユニバーシティ、オブ、サウサンプトン Fuel cell, catalyst and method
JP2016505046A (en) * 2013-01-22 2016-02-18 サウディ ベーシック インダストリーズ コーポレイション Production of methyl methacrylate from propionaldehyde and formaldehyde by oxidative esterification
JP2016525578A (en) * 2013-07-29 2016-08-25 ローム アンド ハース カンパニーＲｏｈｍ Ａｎｄ Ｈａａｓ Ｃｏｍｐａｎｙ Preparation of methyl acrylate via oxidative esterification method
JP2017504607A (en) * 2013-12-20 2017-02-09 エボニック レーム ゲゼルシャフト ミット ベシュレンクテル ハフツングＥｖｏｎｉｋ Ｒｏｅｈｍ ＧｍｂＨ Process for the preparation of unsaturated esters by direct oxidative esterification starting from aldehydes
JP2017507903A (en) * 2013-12-20 2017-03-23 エボニック レーム ゲゼルシャフト ミット ベシュレンクテル ハフツングＥｖｏｎｉｋ Ｒｏｅｈｍ ＧｍｂＨ Method for producing methyl methacrylate
JP2020528422A (en) * 2017-07-28 2020-09-24 ローム アンド ハース カンパニーＲｏｈｍ Ａｎｄ Ｈａａｓ Ｃｏｍｐａｎｙ Method for producing methyl methacrylate by oxidative esterification using a heterogeneous catalyst
CN111804291A (en) * 2020-07-20 2020-10-23 中国科学技术大学 Small-size Pd3Pb intermetallic compound and preparation method and application thereof

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0166207U (en) * 1987-10-22 1989-04-27
SG71815A1 (en) * 1997-07-08 2000-04-18 Asahi Chemical Ind Method of producing methyl methacrylate
US7696125B2 (en) 2005-07-06 2010-04-13 Lee Chang Yung Chemical Industry Corporation Catalyst and process for preparing carboxylic acid esters

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5459634A (en) * 1977-10-19 1979-05-14 Ishikawajima Harima Heavy Ind Co Ltd Improved vapor generating method for dry cooling system of cokes and other materials

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5459634A (en) * 1977-10-19 1979-05-14 Ishikawajima Harima Heavy Ind Co Ltd Improved vapor generating method for dry cooling system of cokes and other materials

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58166936A (en) * 1982-03-24 1983-10-03 バスフ　アクチエンゲゼルシヤフト Catalyst for producing carboxylic ester and use thereof
JPH0446618B2 (en) * 1982-03-24 1992-07-30 Basf Ag
JPS59162947A (en) * 1983-02-26 1984-09-13 バスフ　アクチエンゲゼルシヤフト Catalyst and use thereof for producing methyl methacrylate
JPH0472578B2 (en) * 1983-02-26 1992-11-18 Basf Ag
WO1998042653A1 (en) * 1997-03-24 1998-10-01 Mitsubishi Rayon Co., Ltd. Process for producing carboxylic acid esters and catalyst
CN1113052C (en) * 1997-03-24 2003-07-02 三菱丽阳株式会社 Process for producing carboxylic acid esters and catalyst
US20100130648A1 (en) * 2007-05-25 2010-05-27 Evonik Roehm Gmbh Process for preparation of methyl methacrylate by esterification during oxidation
US8829235B2 (en) * 2007-05-25 2014-09-09 Evonk Röhm GmbH Process for preparation of methyl methacrylate by esterification during oxidation
JP2013527966A (en) * 2010-03-26 2013-07-04 ユニバーシティ、オブ、サウサンプトン Fuel cell, catalyst and method
JP2016505046A (en) * 2013-01-22 2016-02-18 サウディ ベーシック インダストリーズ コーポレイション Production of methyl methacrylate from propionaldehyde and formaldehyde by oxidative esterification
JP2016525578A (en) * 2013-07-29 2016-08-25 ローム アンド ハース カンパニーＲｏｈｍ Ａｎｄ Ｈａａｓ Ｃｏｍｐａｎｙ Preparation of methyl acrylate via oxidative esterification method
JP2017504607A (en) * 2013-12-20 2017-02-09 エボニック レーム ゲゼルシャフト ミット ベシュレンクテル ハフツングＥｖｏｎｉｋ Ｒｏｅｈｍ ＧｍｂＨ Process for the preparation of unsaturated esters by direct oxidative esterification starting from aldehydes
JP2017507903A (en) * 2013-12-20 2017-03-23 エボニック レーム ゲゼルシャフト ミット ベシュレンクテル ハフツングＥｖｏｎｉｋ Ｒｏｅｈｍ ＧｍｂＨ Method for producing methyl methacrylate
JP2020528422A (en) * 2017-07-28 2020-09-24 ローム アンド ハース カンパニーＲｏｈｍ Ａｎｄ Ｈａａｓ Ｃｏｍｐａｎｙ Method for producing methyl methacrylate by oxidative esterification using a heterogeneous catalyst
CN111804291A (en) * 2020-07-20 2020-10-23 中国科学技术大学 Small-size Pd3Pb intermetallic compound and preparation method and application thereof

Also Published As

Publication number Publication date
BE883331A (en) 1980-09-15
JPS627902B2 (en) 1987-02-19

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