JPS55104229A - Preparation of polybasic carboxylic acid alkenyl ester - Google Patents

Preparation of polybasic carboxylic acid alkenyl ester

Info

Publication number
JPS55104229A
JPS55104229A JP1196779A JP1196779A JPS55104229A JP S55104229 A JPS55104229 A JP S55104229A JP 1196779 A JP1196779 A JP 1196779A JP 1196779 A JP1196779 A JP 1196779A JP S55104229 A JPS55104229 A JP S55104229A
Authority
JP
Japan
Prior art keywords
compound
carboxylic acid
alkenyl
polybasic carboxylic
catalyst consisting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP1196779A
Other languages
Japanese (ja)
Other versions
JPS5849536B2 (en
Inventor
Fumiaki Kawamoto
Yoshihiro Honma
Shozo Tanaka
Kazuo Nakao
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHINETSU SAKUSAN BINIRU KK
Japan Vam and Poval Co Ltd
Original Assignee
SHINETSU SAKUSAN BINIRU KK
Shin Etsu Vinyl Acetate Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHINETSU SAKUSAN BINIRU KK, Shin Etsu Vinyl Acetate Co Ltd filed Critical SHINETSU SAKUSAN BINIRU KK
Priority to JP54011967A priority Critical patent/JPS5849536B2/en
Publication of JPS55104229A publication Critical patent/JPS55104229A/en
Publication of JPS5849536B2 publication Critical patent/JPS5849536B2/en
Expired legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

PURPOSE: To prepare the title compound in high yield, by the alkenyl exchange reaction using a catalyst system comprising a main catalyst consisting of Pd and/or a Pd compound and a co-catalyst consisting of a copper compound containing a copper halide and an alkali metal compound.
CONSTITUTION: A polybasic carboxylic acid alkenyl ester (e.g. divinyl adipate) is prepared by the alkenyl exchange reaction of an aliphatic or aromatic polybasic carboxylic acid (e.g. adipic acid) with an ester of formula R1COOR2 (R1 is H or univalent hydrocarbon; R2 is alkenyl) (e.g. vinyl acetate) in the presence of a catalyst consisting of Pd metal and/or a Pd compound (e.g. palladium acetate) and a co-catalyst consisting of an alkali metal compound and a copper compound [at least one of the above two compounds is halide (esp. bromide)], such as the combination of potassium acetate and cupric bromide.
COPYRIGHT: (C)1980,JPO&Japio
JP54011967A 1979-02-05 1979-02-05 Method for producing alkenyl ester of polycarboxylic acid Expired JPS5849536B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP54011967A JPS5849536B2 (en) 1979-02-05 1979-02-05 Method for producing alkenyl ester of polycarboxylic acid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP54011967A JPS5849536B2 (en) 1979-02-05 1979-02-05 Method for producing alkenyl ester of polycarboxylic acid

Publications (2)

Publication Number Publication Date
JPS55104229A true JPS55104229A (en) 1980-08-09
JPS5849536B2 JPS5849536B2 (en) 1983-11-05

Family

ID=11792377

Family Applications (1)

Application Number Title Priority Date Filing Date
JP54011967A Expired JPS5849536B2 (en) 1979-02-05 1979-02-05 Method for producing alkenyl ester of polycarboxylic acid

Country Status (1)

Country Link
JP (1) JPS5849536B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02172946A (en) * 1988-12-26 1990-07-04 Shinetsu Sakusan Vinyl Kk Production of alkenyl carboxylate
WO2007060176A1 (en) * 2005-11-23 2007-05-31 Basf Se Process for preparing vinyl carboxylates

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0510521Y2 (en) * 1985-08-28 1993-03-15

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02172946A (en) * 1988-12-26 1990-07-04 Shinetsu Sakusan Vinyl Kk Production of alkenyl carboxylate
JPH0587059B2 (en) * 1988-12-26 1993-12-15 Shinetsu Sakusan Biniru Kk
WO2007060176A1 (en) * 2005-11-23 2007-05-31 Basf Se Process for preparing vinyl carboxylates
JP2009516723A (en) * 2005-11-23 2009-04-23 ビーエーエスエフ ソシエタス・ヨーロピア Method for producing carboxylic acid vinyl ester
US8044233B2 (en) 2005-11-23 2011-10-25 Basf Aktiengesellschaft Process for preparing vinyl carboxylates

Also Published As

Publication number Publication date
JPS5849536B2 (en) 1983-11-05

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