JPS5473723A - Production of alpha,beta-unsaturated carboxylic ester - Google Patents

Production of alpha,beta-unsaturated carboxylic ester

Info

Publication number
JPS5473723A
JPS5473723A JP13726777A JP13726777A JPS5473723A JP S5473723 A JPS5473723 A JP S5473723A JP 13726777 A JP13726777 A JP 13726777A JP 13726777 A JP13726777 A JP 13726777A JP S5473723 A JPS5473723 A JP S5473723A
Authority
JP
Japan
Prior art keywords
carboxylic ester
unsaturated carboxylic
catalyst
beta
alpha
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP13726777A
Other languages
Japanese (ja)
Other versions
JPS5735856B2 (en
Inventor
Nobuhiro Tamura
Yohei Fukuoka
Setsuo Yamamatsu
Yoshio Suzuki
Ryoichi Mitsui
Tadayuki Ibuki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Asahi Chemical Industry Co Ltd
Original Assignee
Asahi Chemical Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Chemical Industry Co Ltd filed Critical Asahi Chemical Industry Co Ltd
Priority to JP13726777A priority Critical patent/JPS5473723A/en
Priority to GB7843668A priority patent/GB2008430B/en
Priority to DE2848369A priority patent/DE2848369C3/en
Priority to US05/960,324 priority patent/US4249019A/en
Priority to CA316,324A priority patent/CA1103272A/en
Priority to FR7832370A priority patent/FR2409253A1/en
Priority to IT51927/78A priority patent/IT1111364B/en
Publication of JPS5473723A publication Critical patent/JPS5473723A/en
Publication of JPS5735856B2 publication Critical patent/JPS5735856B2/ja
Granted legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

PURPOSE: The oxidation reaction of an α,β-unsaturated aliphatic aldehyde and an alcohol with molecular oxygen in conducted in the presence of a specific catalyst to produce in one step an α,β-unsaturated carboxylic ester in high yield and selectivity.
CONSTITUTION: The oxidation reaction of an α,β-unsaturated apliphatic aldehyde of formual I (R1-3 are H or alkyl) such as methacrolein and an alcohol of formula: R4-OH (R4 is 1W20C alkyl) with molecular oxygen is conducted in the presence of a catalyst consisting of (a) at least one from Pd or its compounds, (b) at least one from Pd and its compounds and (c) calcium carbonate at 0W100°C to produce the objective compound of formula II such as methyl methacrylate. The component Pd in the catalyst is preferably metal Pd and the component Pd is preferably lead oxide, hydroxide or acetate. These components may be supported on activated carbon and others; however, most preferably Pd metal and lead acetate are supported on calcium carbonate.
COPYRIGHT: (C)1979,JPO&Japio
JP13726777A 1977-11-17 1977-11-17 Production of alpha,beta-unsaturated carboxylic ester Granted JPS5473723A (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
JP13726777A JPS5473723A (en) 1977-11-17 1977-11-17 Production of alpha,beta-unsaturated carboxylic ester
GB7843668A GB2008430B (en) 1977-11-17 1978-11-08 Process for producing carboxylic esters
DE2848369A DE2848369C3 (en) 1977-11-17 1978-11-08 Process for the preparation of carboxylic acid esters
US05/960,324 US4249019A (en) 1977-11-17 1978-11-13 Process for producing carboxylic esters
CA316,324A CA1103272A (en) 1977-11-17 1978-11-16 Process for producing carboxylic esters
FR7832370A FR2409253A1 (en) 1977-11-17 1978-11-16 CARBOXYL ESTER PRODUCTION PROCESS
IT51927/78A IT1111364B (en) 1977-11-17 1978-11-16 PROCEDURE FOR PRODUCING CARBOXYL ESTERS FROM ALDEHYDES AND ALCOHOLS

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP13726777A JPS5473723A (en) 1977-11-17 1977-11-17 Production of alpha,beta-unsaturated carboxylic ester

Publications (2)

Publication Number Publication Date
JPS5473723A true JPS5473723A (en) 1979-06-13
JPS5735856B2 JPS5735856B2 (en) 1982-07-31

Family

ID=15194667

Family Applications (1)

Application Number Title Priority Date Filing Date
JP13726777A Granted JPS5473723A (en) 1977-11-17 1977-11-17 Production of alpha,beta-unsaturated carboxylic ester

Country Status (1)

Country Link
JP (1) JPS5473723A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5750941A (en) * 1980-09-12 1982-03-25 Japan Synthetic Rubber Co Ltd Preparation of carboxylic ester
WO1998042653A1 (en) * 1997-03-24 1998-10-01 Mitsubishi Rayon Co., Ltd. Process for producing carboxylic acid esters and catalyst
JP2003048863A (en) * 2001-08-03 2003-02-21 Asahi Kasei Corp Method for controlling ph in reactor for synthesis of carboxylic acid ester

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG71815A1 (en) * 1997-07-08 2000-04-18 Asahi Chemical Ind Method of producing methyl methacrylate
US7696125B2 (en) 2005-07-06 2010-04-13 Lee Chang Yung Chemical Industry Corporation Catalyst and process for preparing carboxylic acid esters

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5750941A (en) * 1980-09-12 1982-03-25 Japan Synthetic Rubber Co Ltd Preparation of carboxylic ester
JPS6340416B2 (en) * 1980-09-12 1988-08-11 Japan Synthetic Rubber Co Ltd
WO1998042653A1 (en) * 1997-03-24 1998-10-01 Mitsubishi Rayon Co., Ltd. Process for producing carboxylic acid esters and catalyst
CN1113052C (en) * 1997-03-24 2003-07-02 三菱丽阳株式会社 Process for producing carboxylic acid esters and catalyst
JP2003048863A (en) * 2001-08-03 2003-02-21 Asahi Kasei Corp Method for controlling ph in reactor for synthesis of carboxylic acid ester

Also Published As

Publication number Publication date
JPS5735856B2 (en) 1982-07-31

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