JPS5473716A - Production of carboxylic ester - Google Patents

Production of carboxylic ester

Info

Publication number
JPS5473716A
JPS5473716A JP13726977A JP13726977A JPS5473716A JP S5473716 A JPS5473716 A JP S5473716A JP 13726977 A JP13726977 A JP 13726977A JP 13726977 A JP13726977 A JP 13726977A JP S5473716 A JPS5473716 A JP S5473716A
Authority
JP
Japan
Prior art keywords
acetate
compound
carboxylic ester
aldehyde
nitrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP13726977A
Other languages
Japanese (ja)
Other versions
JPS5735858B2 (en
Inventor
Nobuhiro Tamura
Yohei Fukuoka
Yoshio Suzuki
Hiroaki Watanabe
Setsuo Yamamatsu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Asahi Chemical Industry Co Ltd
Original Assignee
Asahi Chemical Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Chemical Industry Co Ltd filed Critical Asahi Chemical Industry Co Ltd
Priority to JP13726977A priority Critical patent/JPS5473716A/en
Publication of JPS5473716A publication Critical patent/JPS5473716A/en
Publication of JPS5735858B2 publication Critical patent/JPS5735858B2/ja
Granted legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PURPOSE: An aldehyde and an alcohol are oxidized with molecular oxygen in the presence of a specific catalyst to produce a carboxylic ester with one step procedure in high yield and selectivity.
CONSTITUTION: An aldehyde such as propionaldehyde or methacrolein and an alcohol such as methanol are oxidized with molecular oxygene in the presence of a catalyst consisting of at least one of Pd and its compounds, at least one selected from T1 and Hg and their compounds at 0W100°C under atmospheric pressure to form the objective ester such as ethyl propionate or methyl methacrylate. The Pd compound is, e.g., its acetate, formate or sulfate, the T1 compound is e.g., its acetate, nitrate, thallous chloride, and the Hg compound is, e.g., its acetate, nitrate or oxide. The above catalyst can be supported on a carrier such as alumina, activited carbon or calcium carbonate or may be supported with each other.
COPYRIGHT: (C)1979,JPO&Japio
JP13726977A 1977-11-17 1977-11-17 Production of carboxylic ester Granted JPS5473716A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP13726977A JPS5473716A (en) 1977-11-17 1977-11-17 Production of carboxylic ester

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP13726977A JPS5473716A (en) 1977-11-17 1977-11-17 Production of carboxylic ester

Publications (2)

Publication Number Publication Date
JPS5473716A true JPS5473716A (en) 1979-06-13
JPS5735858B2 JPS5735858B2 (en) 1982-07-31

Family

ID=15194713

Family Applications (1)

Application Number Title Priority Date Filing Date
JP13726977A Granted JPS5473716A (en) 1977-11-17 1977-11-17 Production of carboxylic ester

Country Status (1)

Country Link
JP (1) JPS5473716A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5750941A (en) * 1980-09-12 1982-03-25 Japan Synthetic Rubber Co Ltd Preparation of carboxylic ester
JPH04117333A (en) * 1990-05-31 1992-04-17 Daikin Ind Ltd Production of 1-chloro-1,2,-trifluoroethylene and 1,2,2-trifluoroethylene

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0543880Y2 (en) * 1988-07-23 1993-11-05

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5750941A (en) * 1980-09-12 1982-03-25 Japan Synthetic Rubber Co Ltd Preparation of carboxylic ester
JPS6340416B2 (en) * 1980-09-12 1988-08-11 Japan Synthetic Rubber Co Ltd
JPH04117333A (en) * 1990-05-31 1992-04-17 Daikin Ind Ltd Production of 1-chloro-1,2,-trifluoroethylene and 1,2,2-trifluoroethylene

Also Published As

Publication number Publication date
JPS5735858B2 (en) 1982-07-31

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