JPS5473717A - Production of carboxylic ester - Google Patents

Production of carboxylic ester

Info

Publication number
JPS5473717A
JPS5473717A JP13727077A JP13727077A JPS5473717A JP S5473717 A JPS5473717 A JP S5473717A JP 13727077 A JP13727077 A JP 13727077A JP 13727077 A JP13727077 A JP 13727077A JP S5473717 A JPS5473717 A JP S5473717A
Authority
JP
Japan
Prior art keywords
compound
carboxylic ester
aldehyde
sulfate
acetate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP13727077A
Other languages
Japanese (ja)
Other versions
JPS5735859B2 (en
Inventor
Nobuhiro Tamura
Yohei Fukuoka
Yoshio Suzuki
Hiroaki Watanabe
Setsuo Yamamatsu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Asahi Chemical Industry Co Ltd
Original Assignee
Asahi Chemical Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Chemical Industry Co Ltd filed Critical Asahi Chemical Industry Co Ltd
Priority to JP13727077A priority Critical patent/JPS5473717A/en
Publication of JPS5473717A publication Critical patent/JPS5473717A/en
Publication of JPS5735859B2 publication Critical patent/JPS5735859B2/ja
Granted legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

PURPOSE: The oxidation of an aldehyde and an alcohol with molecular oxygen is conducted in the presence of a specific catalyst to produce a carboxylic ester in one-stage procedure in high yield and selectivity.
CONSTITUTION: An aldehyde such as isobutyladehyde or methacrolein and an alcohol such as methanol are oxidized with molecular oxygen in the presence of a catalyst consisting of at least one of Pd and its compounds and at least one of lead and its compounds at 0W100°C under atmospheric pressure to porduce the objective compound such as ethyl isobutyrate or methyl methacrylate. The Pd compound is, e.g., its acetate, formate, sulfate or others; the lead compound is, e.g., its acetate, sulfate, stearate, naphthenate, oxide or hydroxide. The above catalyst can be supported on a carrier such as alumina, activated carbon, calcium carbonate or two catalysts can be supported with each other with no use of usual carrier.
COPYRIGHT: (C)1979,JPO&Japio
JP13727077A 1977-11-17 1977-11-17 Production of carboxylic ester Granted JPS5473717A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP13727077A JPS5473717A (en) 1977-11-17 1977-11-17 Production of carboxylic ester

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP13727077A JPS5473717A (en) 1977-11-17 1977-11-17 Production of carboxylic ester

Publications (2)

Publication Number Publication Date
JPS5473717A true JPS5473717A (en) 1979-06-13
JPS5735859B2 JPS5735859B2 (en) 1982-07-31

Family

ID=15194738

Family Applications (1)

Application Number Title Priority Date Filing Date
JP13727077A Granted JPS5473717A (en) 1977-11-17 1977-11-17 Production of carboxylic ester

Country Status (1)

Country Link
JP (1) JPS5473717A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5750941A (en) * 1980-09-12 1982-03-25 Japan Synthetic Rubber Co Ltd Preparation of carboxylic ester
US4520125A (en) * 1983-02-26 1985-05-28 Basf Aktiengesellschaft Catalyst for the preparation of methyl methacrylate
JPH04117333A (en) * 1990-05-31 1992-04-17 Daikin Ind Ltd Production of 1-chloro-1,2,-trifluoroethylene and 1,2,2-trifluoroethylene
US6348619B1 (en) 1997-03-24 2002-02-19 Mitsubishi Rayon Co., Ltd. Process for producing a carboxylic acid ester by reacting an aldehyde and an alcohol using a palladium type catalyst
JP2003048863A (en) * 2001-08-03 2003-02-21 Asahi Kasei Corp Method for controlling ph in reactor for synthesis of carboxylic acid ester

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG71815A1 (en) * 1997-07-08 2000-04-18 Asahi Chemical Ind Method of producing methyl methacrylate
TWI257925B (en) 2001-12-21 2006-07-11 Asahi Kasei Corp Oxide catalyst composition

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5750941A (en) * 1980-09-12 1982-03-25 Japan Synthetic Rubber Co Ltd Preparation of carboxylic ester
JPS6340416B2 (en) * 1980-09-12 1988-08-11 Japan Synthetic Rubber Co Ltd
US4520125A (en) * 1983-02-26 1985-05-28 Basf Aktiengesellschaft Catalyst for the preparation of methyl methacrylate
JPH04117333A (en) * 1990-05-31 1992-04-17 Daikin Ind Ltd Production of 1-chloro-1,2,-trifluoroethylene and 1,2,2-trifluoroethylene
US6348619B1 (en) 1997-03-24 2002-02-19 Mitsubishi Rayon Co., Ltd. Process for producing a carboxylic acid ester by reacting an aldehyde and an alcohol using a palladium type catalyst
JP2003048863A (en) * 2001-08-03 2003-02-21 Asahi Kasei Corp Method for controlling ph in reactor for synthesis of carboxylic acid ester

Also Published As

Publication number Publication date
JPS5735859B2 (en) 1982-07-31

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