JPS5770836A - Preparation of cinnamic acid ester - Google Patents
Preparation of cinnamic acid esterInfo
- Publication number
- JPS5770836A JPS5770836A JP55146334A JP14633480A JPS5770836A JP S5770836 A JPS5770836 A JP S5770836A JP 55146334 A JP55146334 A JP 55146334A JP 14633480 A JP14633480 A JP 14633480A JP S5770836 A JPS5770836 A JP S5770836A
- Authority
- JP
- Japan
- Prior art keywords
- pref
- carbon monoxide
- salt
- cocatalyst
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
PURPOSE: To prepare the titled substance useful as perfumery, etc., economically, by contacting styrene and an alcohol with carbon monoxide and oxgen in a specific solvent in the presence of a platinum group metal as a catalyst, a copper salt, etc. as a cocatalyst, and an alkali metal hydroxide, etc. as a reaction accelerator.
CONSTITUTION: The objective compound is prepared by contacting styrene, an alcohol, carbon monoxide, and oxygen with each other, in an ethylene glycol ether solvent such as ethylene methyl ether, etc.,o in the presence of a catalyst comprising a platinum group metal or its salt, pref. palladium or palladium chloride, a cocatalyst comprising a copper or an iron salt, and a reaction accelerator selected from hydroxide, carbonate or acetate of an alkali metal or an alkaline earth metal. The partial pressure of carbon monoxide is pref. maintained at ≤30kg/cm2, esp. 0.05W25kg/cm2. The reaction temperature is 30W200°C, pref. 50W150°C.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP55146334A JPS5770836A (en) | 1980-10-21 | 1980-10-21 | Preparation of cinnamic acid ester |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP55146334A JPS5770836A (en) | 1980-10-21 | 1980-10-21 | Preparation of cinnamic acid ester |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS5770836A true JPS5770836A (en) | 1982-05-01 |
Family
ID=15405331
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP55146334A Pending JPS5770836A (en) | 1980-10-21 | 1980-10-21 | Preparation of cinnamic acid ester |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5770836A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6092243A (en) * | 1983-10-24 | 1985-05-23 | Mitsubishi Chem Ind Ltd | Preparation of cinnamic ester |
JPS6094940A (en) * | 1983-10-28 | 1985-05-28 | Mitsubishi Chem Ind Ltd | Production of cinnamic acid ester |
JPS6097935A (en) * | 1983-11-02 | 1985-05-31 | Mitsubishi Chem Ind Ltd | Production of cinnamic acid ester |
JPS60126245A (en) * | 1983-12-14 | 1985-07-05 | Mitsubishi Chem Ind Ltd | Production of cinnamic acid ester |
US5179224A (en) * | 1986-04-11 | 1993-01-12 | Mitsui Toatsu Chemicals, Incorporated | Preparation process of cinnamate ester |
-
1980
- 1980-10-21 JP JP55146334A patent/JPS5770836A/en active Pending
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6092243A (en) * | 1983-10-24 | 1985-05-23 | Mitsubishi Chem Ind Ltd | Preparation of cinnamic ester |
JPS6094940A (en) * | 1983-10-28 | 1985-05-28 | Mitsubishi Chem Ind Ltd | Production of cinnamic acid ester |
JPS6097935A (en) * | 1983-11-02 | 1985-05-31 | Mitsubishi Chem Ind Ltd | Production of cinnamic acid ester |
JPS60126245A (en) * | 1983-12-14 | 1985-07-05 | Mitsubishi Chem Ind Ltd | Production of cinnamic acid ester |
US5179224A (en) * | 1986-04-11 | 1993-01-12 | Mitsui Toatsu Chemicals, Incorporated | Preparation process of cinnamate ester |
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