JPS5473715A - Production of carboxylic ester - Google Patents

Production of carboxylic ester

Info

Publication number
JPS5473715A
JPS5473715A JP13726877A JP13726877A JPS5473715A JP S5473715 A JPS5473715 A JP S5473715A JP 13726877 A JP13726877 A JP 13726877A JP 13726877 A JP13726877 A JP 13726877A JP S5473715 A JPS5473715 A JP S5473715A
Authority
JP
Japan
Prior art keywords
mercury
lead
reaction
carboxylic ester
aldehyde
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP13726877A
Other languages
Japanese (ja)
Other versions
JPS5735857B2 (en
Inventor
Nobuhiro Tamura
Yohei Fukuoka
Setsuo Yamamatsu
Yoshio Suzuki
Ryoichi Mitsui
Tadayuki Ibuki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Asahi Chemical Industry Co Ltd
Original Assignee
Asahi Chemical Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Chemical Industry Co Ltd filed Critical Asahi Chemical Industry Co Ltd
Priority to JP13726877A priority Critical patent/JPS5473715A/en
Priority to GB7843668A priority patent/GB2008430B/en
Priority to DE2848369A priority patent/DE2848369C3/en
Priority to US05/960,324 priority patent/US4249019A/en
Priority to FR7832370A priority patent/FR2409253A1/en
Priority to CA316,324A priority patent/CA1103272A/en
Priority to IT51927/78A priority patent/IT1111364B/en
Publication of JPS5473715A publication Critical patent/JPS5473715A/en
Publication of JPS5735857B2 publication Critical patent/JPS5735857B2/ja
Granted legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

PURPOSE: In the reaction between an aldehyde and an alcohol in the presence of oxygen, a catalyst consisting of Pd that is active even at lower temperatures, lead or mercury and an alkaline earth metal is used to produce readily title compound in high yield with no side reaction.
CONSTITUTION: In the reaction between an aldehyde such as acrolein or methcarolein and an alcohol such as methanol or ethanol in the presence of oxygen, a catalyst consisting of a Pd compoud selected from metal Pd, its acetate, sulfate and others, a compound selected from lead, mercury or thallium or their acetates, carbonates oxides and another compound selected from alkaline earth metals, zinc or cadmium or their oxides, hydroxides carbontaes or sulfates, is used to form an carboxylic ester. The amount of Pd is 0.5W20wt%, lead or mercury is 0.01W 20wt% and the third component is preferably 2W95wt% in the catalyst.
COPYRIGHT: (C)1979,JPO&Japio
JP13726877A 1977-11-17 1977-11-17 Production of carboxylic ester Granted JPS5473715A (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
JP13726877A JPS5473715A (en) 1977-11-17 1977-11-17 Production of carboxylic ester
GB7843668A GB2008430B (en) 1977-11-17 1978-11-08 Process for producing carboxylic esters
DE2848369A DE2848369C3 (en) 1977-11-17 1978-11-08 Process for the preparation of carboxylic acid esters
US05/960,324 US4249019A (en) 1977-11-17 1978-11-13 Process for producing carboxylic esters
FR7832370A FR2409253A1 (en) 1977-11-17 1978-11-16 CARBOXYL ESTER PRODUCTION PROCESS
CA316,324A CA1103272A (en) 1977-11-17 1978-11-16 Process for producing carboxylic esters
IT51927/78A IT1111364B (en) 1977-11-17 1978-11-16 PROCEDURE FOR PRODUCING CARBOXYL ESTERS FROM ALDEHYDES AND ALCOHOLS

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP13726877A JPS5473715A (en) 1977-11-17 1977-11-17 Production of carboxylic ester

Publications (2)

Publication Number Publication Date
JPS5473715A true JPS5473715A (en) 1979-06-13
JPS5735857B2 JPS5735857B2 (en) 1982-07-31

Family

ID=15194692

Family Applications (1)

Application Number Title Priority Date Filing Date
JP13726877A Granted JPS5473715A (en) 1977-11-17 1977-11-17 Production of carboxylic ester

Country Status (1)

Country Link
JP (1) JPS5473715A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6348619B1 (en) 1997-03-24 2002-02-19 Mitsubishi Rayon Co., Ltd. Process for producing a carboxylic acid ester by reacting an aldehyde and an alcohol using a palladium type catalyst
JP2016505046A (en) * 2013-01-22 2016-02-18 サウディ ベーシック インダストリーズ コーポレイション Production of methyl methacrylate from propionaldehyde and formaldehyde by oxidative esterification

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5982522U (en) * 1982-11-29 1984-06-04 三菱重工業株式会社 dust collection device
US4615715A (en) * 1985-03-15 1986-10-07 Foster Wheeler Energy Corporation Water-cooled cyclone separator
EP0298671A3 (en) * 1987-07-06 1990-03-28 Foster Wheeler Energy Corporation Cyclone separator having water-steam cooled walls
SG71815A1 (en) * 1997-07-08 2000-04-18 Asahi Chemical Ind Method of producing methyl methacrylate

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6348619B1 (en) 1997-03-24 2002-02-19 Mitsubishi Rayon Co., Ltd. Process for producing a carboxylic acid ester by reacting an aldehyde and an alcohol using a palladium type catalyst
JP2016505046A (en) * 2013-01-22 2016-02-18 サウディ ベーシック インダストリーズ コーポレイション Production of methyl methacrylate from propionaldehyde and formaldehyde by oxidative esterification

Also Published As

Publication number Publication date
JPS5735857B2 (en) 1982-07-31

Similar Documents

Publication Publication Date Title
JPS5384933A (en) Preparation of terephthalic acid
JPS5473715A (en) Production of carboxylic ester
JPS55151533A (en) Preparation of carboxylic acid ester
JPS53105417A (en) Preparation of acrylic acid esters or methacrylic acid esters
JPS5422319A (en) Prepaeation of methacrylic acid
JPS5473723A (en) Production of alpha,beta-unsaturated carboxylic ester
JPS5473717A (en) Production of carboxylic ester
JPS5524106A (en) Preparation of methyl methacrylate
JPS56123946A (en) Preparation of unsaturated carboxylic acid ester
JPS5382715A (en) Preparation of unsaturated compound
JPS53105413A (en) Preparation of alpha-branched aliphatic carboxylic acid
JPS5473716A (en) Production of carboxylic ester
JPS53105411A (en) Preparation of alpha-branched aliphatic carboxylic acid
JPS5473724A (en) Production of alpha,beta-unsaturated carboxylic ester
JPS5424810A (en) Synthesis of carboxylic acid ester
JPS549203A (en) Preparation of alpha-branched aliphatic carboxylic acid
JPS5233614A (en) Process for preparation of acetic acid
JPS5365388A (en) Carboxylation of ethylene-vinyl acetate copolymer saponified product
JPS53112808A (en) Preparation of malonic esters
JPS52122336A (en) Preparation of beta-orcyl carboxylic acid esters
JPS52153908A (en) Preparation of allyl acetic acid
JPS5473725A (en) Production of alpha,beta-unsaturated carboxylic ester
JPS53147021A (en) Preparation of glycerol esters
JPS53141232A (en) Preparation of formylated phenols
JPS537614A (en) Preparation of acrylic acid