BR112015017306A2 - processo para a formação de metacrilato de metila - Google Patents

processo para a formação de metacrilato de metila

Info

Publication number
BR112015017306A2
BR112015017306A2 BR112015017306A BR112015017306A BR112015017306A2 BR 112015017306 A2 BR112015017306 A2 BR 112015017306A2 BR 112015017306 A BR112015017306 A BR 112015017306A BR 112015017306 A BR112015017306 A BR 112015017306A BR 112015017306 A2 BR112015017306 A2 BR 112015017306A2
Authority
BR
Brazil
Prior art keywords
methyl methacrylate
reaction
reaction product
propionaldehyde
methacrolein
Prior art date
Application number
BR112015017306A
Other languages
English (en)
Inventor
Kauffman James
Malcolm Allman James
Original Assignee
Saudi Basic Ind Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=50031639&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=BR112015017306(A2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Saudi Basic Ind Corp filed Critical Saudi Basic Ind Corp
Publication of BR112015017306A2 publication Critical patent/BR112015017306A2/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/44—Preparation of carboxylic acid esters by oxidation-reduction of aldehydes, e.g. Tishchenko reaction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/39—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • C07C45/75—Reactions with formaldehyde

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

resumo processo para a formação de metacrilato de metila um processo para formação de metacrilato de metila pode compreender: reação de etileno, monóxido de carbono e hidrogênio na presença de um primeiro catalisador que compreende uma carbonila de metal; remoção de um primeiro produto de reação que compreende propionaldeído; reação do primeiro produto de reação com formaldeído; remoção de um segundo produto de reação que compreende metacroleína; reação do segundo produto de reação com oxigênio e metanol na presença de um segundo catalisador para formar um terceiro produto de reação que compreende metacrilato de metila. outro processo para formação de metacrilato de metila pode compreender: reação de etileno com monóxido de carbono para formar propionaldeído; reação do propionaldeído com formaldeído para formar metacroleína; e reação da metacroleína com metanol e oxigênio para formar o metacrilato de metila. 1/1
BR112015017306A 2013-01-22 2014-01-21 processo para a formação de metacrilato de metila BR112015017306A2 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201361755260P 2013-01-22 2013-01-22
PCT/US2014/012333 WO2014116588A1 (en) 2013-01-22 2014-01-21 Method for making methyl methacrylate from propionaldehyde and formaldehyde via oxidative esterification

Publications (1)

Publication Number Publication Date
BR112015017306A2 true BR112015017306A2 (pt) 2017-07-11

Family

ID=50031639

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112015017306A BR112015017306A2 (pt) 2013-01-22 2014-01-21 processo para a formação de metacrilato de metila

Country Status (9)

Country Link
US (2) US20140206897A1 (pt)
EP (1) EP2948425A1 (pt)
JP (1) JP2016505046A (pt)
KR (1) KR20150107762A (pt)
CN (1) CN104936940B (pt)
AR (1) AR094543A1 (pt)
BR (1) BR112015017306A2 (pt)
CA (1) CA2896634C (pt)
WO (1) WO2014116588A1 (pt)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9890105B2 (en) * 2013-04-19 2018-02-13 Evonik Roehm Gmbh Method for producing methylmethacrylate
CN105683142B (zh) * 2013-10-28 2018-11-13 罗门哈斯公司 用于分离甲基丙烯醛的方法
SG11201703339UA (en) 2014-10-31 2017-05-30 Rohm & Haas Oxidative esterification process for making methyl methacrylate
EP3144291A1 (de) * 2015-09-16 2017-03-22 Evonik Röhm GmbH Synthese von methacrylsäure aus auf methacrolein basierenden alkylmethacrylat
WO2018217963A1 (en) * 2017-05-25 2018-11-29 Rohm And Haas Company Process for preparing methacrolein
EP3608305A1 (en) 2018-08-10 2020-02-12 Röhm GmbH Process for producing methacrylic acid or methacrylic acid esters
CN109395732B (zh) * 2018-11-29 2020-11-03 中国科学院大连化学物理研究所 一种低成本高效生产甲基丙烯酸甲酯的催化剂及其制备方法
CN110882722A (zh) * 2019-11-22 2020-03-17 淄博诺奥化工股份有限公司 一种酸碱复合催化剂以及使用其制备甲基丙烯醛的方法
EP3945088A1 (de) * 2020-07-30 2022-02-02 Röhm GmbH Vorgehen zur minimierung des aktivitätsverlusts bei im kreislaufbetrieb ausgeführten reaktionsschritten
EP4255880A1 (en) * 2020-12-01 2023-10-11 Rohm and Haas Company Integrated process to produce aldehydes from synthesis gas
JP2024500012A (ja) * 2020-12-01 2024-01-04 ローム アンド ハース カンパニー メタノールからアルデヒドを製造する統合プロセス
CN115141099A (zh) * 2021-03-31 2022-10-04 中国石油天然气集团有限公司 甲基丙烯酸甲酯的生产装置和工艺
WO2023059675A1 (en) * 2021-10-08 2023-04-13 Rohm And Haas Company Process for methyl methacrylate production
WO2023059679A1 (en) * 2021-10-08 2023-04-13 Rohm And Haas Company Process for methyl methacrylate production from ethanol

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2497303A (en) * 1945-05-23 1950-02-14 Du Pont Reaction between olefinic compounds, carbon monoxide, and hydrogen in the presence of a metal carbonyl catalyst
US3168553A (en) * 1961-08-25 1965-02-02 Shell Oil Co Reactions of olefins with carbon monoxide
US3547964A (en) * 1968-07-24 1970-12-15 Union Oil Co Group viii noble metal catalyst recovery
JPS5473715A (en) * 1977-11-17 1979-06-13 Asahi Chem Ind Co Ltd Production of carboxylic ester
GB2008430B (en) * 1977-11-17 1982-04-28 Asahi Chemical Ind Process for producing carboxylic esters
DE2855504B2 (de) * 1978-12-22 1981-02-19 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur Herstellung von Methacrolein
DE3018071C2 (de) * 1979-05-17 1985-06-05 Asahi Kasei Kogyo K.K., Osaka Verfahren zur Herstellung von Carbonsäureestern
JPS55151533A (en) * 1979-05-17 1980-11-26 Asahi Chem Ind Co Ltd Preparation of carboxylic acid ester
DE3213681A1 (de) * 1982-04-14 1983-10-27 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von (alpha)-alkylacroleinen
KR100259743B1 (ko) * 1995-07-18 2000-07-01 야마모토 카즈모토 카르복실산 에스테르 제조용 촉매
TW377306B (en) * 1996-12-16 1999-12-21 Asahi Chemical Ind Noble metal support
SG71815A1 (en) * 1997-07-08 2000-04-18 Asahi Chemical Ind Method of producing methyl methacrylate
JP3681285B2 (ja) * 1997-07-08 2005-08-10 旭化成ケミカルズ株式会社 メタクリル酸メチルの製造方法
CN1202064C (zh) * 2002-01-25 2005-05-18 四川大学 一种乙烯制丙醛的方法
WO2005063668A1 (en) * 2003-12-31 2005-07-14 Council Of Scientific & Industrial Research Process for synthesis of alpha-substituted acroleins
JP4954952B2 (ja) * 2007-08-14 2012-06-20 ローム アンド ハース カンパニー エチレンおよび一酸化炭素混合物をエタンから製造する方法
CN101376629B (zh) * 2007-08-27 2012-05-30 中国石油天然气股份有限公司 一种氧化酯化生产不饱和脂肪酸酯的方法
FR2940801B1 (fr) * 2009-01-06 2012-08-17 Arkema France Procede de fabrication d'un methacrylate de methyle derive de la biomasse
KR101487352B1 (ko) * 2010-09-16 2015-01-29 아사히 가세이 케미칼즈 가부시키가이샤 실리카계 재료 및 그 제조 방법, 및 귀금속 담지물 및 그것을 촉매로서 이용하는 카르복실산류의 제조 방법
US9234064B2 (en) * 2011-05-11 2016-01-12 Archer Daniels Midland Company Processes for making acrylic-type monomers and products made therefrom

Also Published As

Publication number Publication date
CN104936940B (zh) 2018-12-21
AR094543A1 (es) 2015-08-12
KR20150107762A (ko) 2015-09-23
US20160068465A1 (en) 2016-03-10
CA2896634A1 (en) 2014-07-31
CA2896634C (en) 2020-06-02
JP2016505046A (ja) 2016-02-18
EP2948425A1 (en) 2015-12-02
WO2014116588A1 (en) 2014-07-31
US20140206897A1 (en) 2014-07-24
CN104936940A (zh) 2015-09-23

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Legal Events

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B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]

Free format text: REFERENTE A 5A ANUIDADE.

B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: EM VIRTUDE DO ARQUIVAMENTO PUBLICADO NA RPI 2497 DE 13-11-2018 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDO O ARQUIVAMENTO DO PEDIDO DE PATENTE, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.