MX2016000767A - Preparacion de acrilato de metilo a traves de un proceso de esterificacion oxidativa. - Google Patents

Preparacion de acrilato de metilo a traves de un proceso de esterificacion oxidativa.

Info

Publication number
MX2016000767A
MX2016000767A MX2016000767A MX2016000767A MX2016000767A MX 2016000767 A MX2016000767 A MX 2016000767A MX 2016000767 A MX2016000767 A MX 2016000767A MX 2016000767 A MX2016000767 A MX 2016000767A MX 2016000767 A MX2016000767 A MX 2016000767A
Authority
MX
Mexico
Prior art keywords
preparation
methyl acrylate
esterification process
oxidative esterification
acrylate via
Prior art date
Application number
MX2016000767A
Other languages
English (en)
Other versions
MX363805B (es
Inventor
Kirk Limbach
Dmitri A Kraptchetov
Christopher D Frick
Original Assignee
Rohm & Haas
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rohm & Haas filed Critical Rohm & Haas
Publication of MX2016000767A publication Critical patent/MX2016000767A/es
Publication of MX363805B publication Critical patent/MX363805B/es

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/39—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/644—Arsenic, antimony or bismuth
    • B01J23/6447—Bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/648—Vanadium, niobium or tantalum or polonium
    • B01J23/6484—Niobium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6525—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/038—Precipitation; Co-precipitation to form slurries or suspensions, e.g. a washcoat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/62—Use of additives, e.g. for stabilisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La presente invención se refiere a un proceso para producir metacrilato de metilo, el proceso comprende poner en contacto reactivos que comprenden metacroleína, metanol y un gas que contiene oxígeno, bajo condiciones de reacción en la presencia de un catalizador sólido que comprende paladio, bismuto y al menos un tercer elemento X, donde X se selecciona del grupo que consiste de P, S, Sc, V, Ga, Se, Y, Nb, Mo, La, Ce, y Nd, en donde el catalizador sólido comprende además un soporte seleccionado de al menos un miembro del grupo que consiste de sílice, alúmina, carbonato de calcio, carbón activo, óxido de zinc, óxido de titanio y óxido de magnesio.
MX2016000767A 2013-07-29 2014-07-29 Preparacion de acrilato de metilo a traves de un proceso de esterificacion oxidativa. MX363805B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201361859551P 2013-07-29 2013-07-29
PCT/US2014/048667 WO2015017437A1 (en) 2013-07-29 2014-07-29 Preparation of methyl acrylate via an oxidative esterification process

Publications (2)

Publication Number Publication Date
MX2016000767A true MX2016000767A (es) 2016-04-19
MX363805B MX363805B (es) 2019-04-03

Family

ID=51303130

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2016000767A MX363805B (es) 2013-07-29 2014-07-29 Preparacion de acrilato de metilo a traves de un proceso de esterificacion oxidativa.

Country Status (12)

Country Link
US (1) US9676699B2 (es)
EP (1) EP2989077B1 (es)
JP (1) JP6506281B2 (es)
KR (1) KR102287643B1 (es)
CN (1) CN105377806B (es)
BR (1) BR112016001127B1 (es)
CA (1) CA2918403C (es)
MX (1) MX363805B (es)
SA (1) SA516370404B1 (es)
SG (1) SG11201600702VA (es)
TW (1) TW201509901A (es)
WO (1) WO2015017437A1 (es)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW201509522A (zh) * 2013-07-29 2015-03-16 Rohm & Haas 氧化酯化催化劑
CN105683142B (zh) 2013-10-28 2018-11-13 罗门哈斯公司 用于分离甲基丙烯醛的方法
BR112020001575B1 (pt) * 2017-07-28 2023-03-14 Rohm And Haas Company Catalisador heterogêneo, e, leito de catalisador
EP3587390A1 (de) 2018-06-26 2020-01-01 Röhm GmbH Verfahren zur herstellung von mma in hohen ausbeuten
CN113477252B (zh) * 2021-06-30 2023-06-30 常州大学 一种同时含钛及其它过渡金属的复合多孔催化剂的制备方法和应用

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JPS5368718A (en) * 1976-11-27 1978-06-19 Nippon Kayaku Co Ltd Simultaneous preparation of methacrylic acid and its ester or acrylicacid and its ester
DE2848978A1 (de) 1978-11-11 1980-05-22 Bayer Ag Traegerkatalysatoren, ihre herstellung und verwendung
DE3018071C2 (de) 1979-05-17 1985-06-05 Asahi Kasei Kogyo K.K., Osaka Verfahren zur Herstellung von Carbonsäureestern
JPS55151533A (en) * 1979-05-17 1980-11-26 Asahi Chem Ind Co Ltd Preparation of carboxylic acid ester
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ATE280750T1 (de) 1995-07-18 2004-11-15 Asahi Kasei Chemicals Corp Verfahren zur herstellung von carbonsäureestern
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TW385304B (en) 1996-09-10 2000-03-21 Asahi Chemical Ind Process for producing methacrylic acid ester or acrylic acid ester
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JP3511350B2 (ja) * 1997-03-25 2004-03-29 旭化成ケミカルズ株式会社 カルボン酸エステル製造用触媒
SG71815A1 (en) 1997-07-08 2000-04-18 Asahi Chemical Ind Method of producing methyl methacrylate
CN1122569C (zh) 1997-08-07 2003-10-01 三菱丽阳株式会社 用于制造羧酸酯的催化剂和羧酸酯的制造方法
US6506930B1 (en) * 1997-11-17 2003-01-14 Rohm And Haas Company Process for preparing alkyl (meth)acrylates
AU7556400A (en) 1999-10-05 2001-05-10 Showa Denko Kabushiki Kaisha Process for producing alkyd resin
JP4339681B2 (ja) * 2000-09-29 2009-10-07 中国石油化工股▲分▼有限公司 不飽和オレフィンの選択的水素化のための選択的水素化触媒、及びその使用
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JP4145621B2 (ja) 2002-10-16 2008-09-03 旭化成ケミカルズ株式会社 不飽和カルボン酸エステル合成反応の反応開始方法
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Also Published As

Publication number Publication date
SG11201600702VA (en) 2016-02-26
CA2918403A1 (en) 2015-02-05
EP2989077A1 (en) 2016-03-02
CN105377806A (zh) 2016-03-02
EP2989077B1 (en) 2017-12-27
JP2016525578A (ja) 2016-08-25
TW201509901A (zh) 2015-03-16
SA516370404B1 (ar) 2017-05-29
JP6506281B2 (ja) 2019-04-24
US9676699B2 (en) 2017-06-13
BR112016001127B1 (pt) 2020-12-29
US20160159728A1 (en) 2016-06-09
BR112016001127A8 (pt) 2019-10-01
CA2918403C (en) 2021-07-06
KR20160035590A (ko) 2016-03-31
CN105377806B (zh) 2017-09-05
WO2015017437A1 (en) 2015-02-05
MX363805B (es) 2019-04-03
KR102287643B1 (ko) 2021-08-06

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