TW200702053A - Catalyst and process for preparing carboxylic acid esters - Google Patents

Catalyst and process for preparing carboxylic acid esters

Info

Publication number
TW200702053A
TW200702053A TW095110656A TW95110656A TW200702053A TW 200702053 A TW200702053 A TW 200702053A TW 095110656 A TW095110656 A TW 095110656A TW 95110656 A TW95110656 A TW 95110656A TW 200702053 A TW200702053 A TW 200702053A
Authority
TW
Taiwan
Prior art keywords
catalyst
carboxylic acid
acid esters
preparing
preparing carboxylic
Prior art date
Application number
TW095110656A
Other languages
Chinese (zh)
Other versions
TWI318583B (en
Inventor
Kindtoken H Liu
Man-Yin Lo
Wen-Chyi Lin
Mei-Yuan Chang
Original Assignee
Lee Chang Yung Chemical Industry Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lee Chang Yung Chemical Industry Corp filed Critical Lee Chang Yung Chemical Industry Corp
Publication of TW200702053A publication Critical patent/TW200702053A/en
Application granted granted Critical
Publication of TWI318583B publication Critical patent/TWI318583B/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C07B41/12—Formation or introduction of functional groups containing oxygen of carboxylic acid ester groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/628—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/648—Vanadium, niobium or tantalum or polonium
    • B01J23/6484—Niobium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/39—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

A catalyst and a process for preparing carboxylic acid esters from an aldehyde and an alcohol in the presence of molecular oxygen are disclosed. The catalyst comprises metals supported on a silica-containing support, wherein the metals consist essentially of palladium, lead, an alkali or alkaline earth metal, and at least one of niobium and zirconium. The process for preparing a carboxylic acid ester comprises reacting an aldehyde with an alcohol in the presence of molecular oxygen and the aforementioned catalyst.
TW95110656A 2005-07-01 2006-03-28 Catalyst and process for preparing carboxylic acid esters TWI318583B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE200510030882 DE102005030882A1 (en) 2005-07-01 2005-07-01 New catalyst for the catalysis reaction of carboxylic acid-ester from an aldehyde and an alcohol in presence of molecular oxygen exhibiting a silicate containing matrix-applied metals

Publications (2)

Publication Number Publication Date
TW200702053A true TW200702053A (en) 2007-01-16
TWI318583B TWI318583B (en) 2009-12-21

Family

ID=37562406

Family Applications (1)

Application Number Title Priority Date Filing Date
TW95110656A TWI318583B (en) 2005-07-01 2006-03-28 Catalyst and process for preparing carboxylic acid esters

Country Status (4)

Country Link
JP (1) JP4235202B2 (en)
CN (1) CN1891336B (en)
DE (1) DE102005030882A1 (en)
TW (1) TWI318583B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI633933B (en) * 2014-04-10 2018-09-01 日商三菱瓦斯化學股份有限公司 Catalyst molded body for producing methyl methacrylate, and method for producing methyl methacrylate using the same

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5645050B2 (en) * 2009-02-06 2014-12-24 三菱レイヨン株式会社 Palladium-containing supported catalyst, method for producing the same, and method for producing α, β-unsaturated carboxylic acid
US9988363B2 (en) 2014-09-02 2018-06-05 Eni S.P.A. Process for preparing organic esters
CN105498769B (en) * 2014-09-25 2018-06-08 中国石油化工股份有限公司 3- acetoxyl group propionic aldehyde catalyst and preparation method
JP7265754B2 (en) * 2019-03-08 2023-04-27 国立大学法人金沢大学 Method for producing polysaccharide derivative and method for producing lignin derivative

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI633933B (en) * 2014-04-10 2018-09-01 日商三菱瓦斯化學股份有限公司 Catalyst molded body for producing methyl methacrylate, and method for producing methyl methacrylate using the same
US10131615B2 (en) 2014-04-10 2018-11-20 Mitsubishi Gas Chemical Company, Inc. Molded catalyst for use in manufacture of methyl methacrylate, and method for manufacture of methyl methacrylate using same

Also Published As

Publication number Publication date
TWI318583B (en) 2009-12-21
CN1891336A (en) 2007-01-10
JP2007007635A (en) 2007-01-18
DE102005030882A1 (en) 2007-01-11
CN1891336B (en) 2011-10-05
JP4235202B2 (en) 2009-03-11

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