MX2016000765A - Preparacion de metacrilato de metilo a traves de un proceso de esterificacion oxidativa. - Google Patents

Preparacion de metacrilato de metilo a traves de un proceso de esterificacion oxidativa.

Info

Publication number
MX2016000765A
MX2016000765A MX2016000765A MX2016000765A MX2016000765A MX 2016000765 A MX2016000765 A MX 2016000765A MX 2016000765 A MX2016000765 A MX 2016000765A MX 2016000765 A MX2016000765 A MX 2016000765A MX 2016000765 A MX2016000765 A MX 2016000765A
Authority
MX
Mexico
Prior art keywords
methyl methacrylate
preparation
esterification process
oxidative esterification
methacrylate via
Prior art date
Application number
MX2016000765A
Other languages
English (en)
Inventor
Kirk Limbach
Dmitri A Kraptchetov
Christopher D Frick
Original Assignee
Rohm & Haas
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rohm & Haas filed Critical Rohm & Haas
Publication of MX2016000765A publication Critical patent/MX2016000765A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/39—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/624—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with germanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/644—Arsenic, antimony or bismuth
    • B01J23/6447—Bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8973—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/62—Use of additives, e.g. for stabilisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La presente invención se refiere a un proceso para producir metacrilato de metilo, el proceso comprende poner en contacto reactivos que comprenden metacroleína, metanol y un gas que contiene oxígeno, bajo condiciones de reacción en la presencia de un catalizador sólido que comprende paladio, bismuto y al menos un tercer elemento X seleccionado del grupo que consiste de Fe, Zn, Ge, y Pb, en donde el catalizador sólido comprende además un soporte seleccionado de al menos un miembro del grupo que consiste de sílice y alúmina.
MX2016000765A 2013-07-29 2014-07-29 Preparacion de metacrilato de metilo a traves de un proceso de esterificacion oxidativa. MX2016000765A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201361859544P 2013-07-29 2013-07-29
PCT/US2014/048665 WO2015017436A1 (en) 2013-07-29 2014-07-29 Preparation of methyl methacrylate via an oxidative esterification process

Publications (1)

Publication Number Publication Date
MX2016000765A true MX2016000765A (es) 2016-04-19

Family

ID=51303129

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2016000765A MX2016000765A (es) 2013-07-29 2014-07-29 Preparacion de metacrilato de metilo a traves de un proceso de esterificacion oxidativa.

Country Status (9)

Country Link
US (1) US20160207870A1 (es)
EP (1) EP2989076A1 (es)
JP (1) JP2016527267A (es)
KR (1) KR20160035591A (es)
CN (1) CN105377805A (es)
CA (1) CA2918402A1 (es)
MX (1) MX2016000765A (es)
TW (1) TW201512168A (es)
WO (1) WO2015017436A1 (es)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102291247B1 (ko) 2013-10-28 2021-08-20 롬 앤드 하아스 컴패니 메타크롤레인을 분리하는 방법
KR102567215B1 (ko) * 2017-05-25 2023-08-16 롬 앤드 하아스 컴패니 메타크롤레인을 제조하는 방법
CN109694946B (zh) 2017-10-24 2020-06-23 宝山钢铁股份有限公司 快速加热冷轧带钢的装置与方法
GB201721527D0 (en) * 2017-12-21 2018-02-07 Johnson Matthey Japan Godo Kaisha Oxidation catalyst for a diesel engine exhaust
KR20200105854A (ko) * 2018-01-10 2020-09-09 다우 글로벌 테크놀로지스 엘엘씨 산화적 에스터화에 의한 메틸 메타크릴레이트 생산용 불균일 촉매

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1361206B1 (en) * 1995-07-18 2004-10-27 Asahi Kasei Chemicals Corporation Method for producing carboxylic esters
JPH09216850A (ja) * 1996-02-09 1997-08-19 Mitsubishi Rayon Co Ltd カルボン酸エステルの製造方法
JP3103500B2 (ja) * 1996-02-14 2000-10-30 三菱レイヨン株式会社 カルボン酸エステルの製造方法
TW385304B (en) * 1996-09-10 2000-03-21 Asahi Chemical Ind Process for producing methacrylic acid ester or acrylic acid ester
JPH10158124A (ja) * 1996-11-25 1998-06-16 Pola Chem Ind Inc 発毛・育毛料
JP3313993B2 (ja) * 1996-11-29 2002-08-12 三菱レイヨン株式会社 カルボン酸エステルの製造法
JP3297342B2 (ja) * 1997-03-24 2002-07-02 三菱レイヨン株式会社 カルボン酸エステルの製造法
JP2002241345A (ja) * 2001-02-13 2002-08-28 Asahi Kasei Corp カルボン酸エステルの製造方法
CN101074192A (zh) * 2007-06-20 2007-11-21 天津大学 以甲醛为原料制备甲基丙烯酸甲酯的方法
EP2177267B1 (en) * 2007-08-13 2013-07-31 Asahi Kasei Chemicals Corporation Catalyst for carboxylic acid ester production, method for producing the same, and method for producing carboxylic acid ester

Also Published As

Publication number Publication date
CN105377805A (zh) 2016-03-02
TW201512168A (zh) 2015-04-01
WO2015017436A1 (en) 2015-02-05
KR20160035591A (ko) 2016-03-31
EP2989076A1 (en) 2016-03-02
JP2016527267A (ja) 2016-09-08
US20160207870A1 (en) 2016-07-21
CA2918402A1 (en) 2015-02-05

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