MX363805B - Preparacion de acrilato de metilo a traves de un proceso de esterificacion oxidativa. - Google Patents
Preparacion de acrilato de metilo a traves de un proceso de esterificacion oxidativa.Info
- Publication number
- MX363805B MX363805B MX2016000767A MX2016000767A MX363805B MX 363805 B MX363805 B MX 363805B MX 2016000767 A MX2016000767 A MX 2016000767A MX 2016000767 A MX2016000767 A MX 2016000767A MX 363805 B MX363805 B MX 363805B
- Authority
- MX
- Mexico
- Prior art keywords
- preparation
- methyl acrylate
- esterification process
- oxidative esterification
- acrylate via
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/39—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/644—Arsenic, antimony or bismuth
- B01J23/6447—Bismuth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/648—Vanadium, niobium or tantalum or polonium
- B01J23/6484—Niobium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/652—Chromium, molybdenum or tungsten
- B01J23/6525—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/031—Precipitation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/038—Precipitation; Co-precipitation to form slurries or suspensions, e.g. a washcoat
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/62—Use of additives, e.g. for stabilisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
La presente invención se refiere a un proceso para producir metacrilato de metilo, el proceso comprende poner en contacto reactivos que comprenden metacroleína, metanol y un gas que contiene oxígeno, bajo condiciones de reacción en la presencia de un catalizador sólido que comprende paladio, bismuto y al menos un tercer elemento X, donde X se selecciona del grupo que consiste de P, S, Sc, V, Ga, Se, Y, Nb, Mo, La, Ce, y Nd, en donde el catalizador sólido comprende además un soporte seleccionado de al menos un miembro del grupo que consiste de sílice, alúmina, carbonato de calcio, carbón activo, óxido de zinc, óxido de titanio y óxido de magnesio.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201361859551P | 2013-07-29 | 2013-07-29 | |
PCT/US2014/048667 WO2015017437A1 (en) | 2013-07-29 | 2014-07-29 | Preparation of methyl acrylate via an oxidative esterification process |
Publications (2)
Publication Number | Publication Date |
---|---|
MX2016000767A MX2016000767A (es) | 2016-04-19 |
MX363805B true MX363805B (es) | 2019-04-03 |
Family
ID=51303130
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2016000767A MX363805B (es) | 2013-07-29 | 2014-07-29 | Preparacion de acrilato de metilo a traves de un proceso de esterificacion oxidativa. |
Country Status (12)
Country | Link |
---|---|
US (1) | US9676699B2 (es) |
EP (1) | EP2989077B1 (es) |
JP (1) | JP6506281B2 (es) |
KR (1) | KR102287643B1 (es) |
CN (1) | CN105377806B (es) |
BR (1) | BR112016001127B1 (es) |
CA (1) | CA2918403C (es) |
MX (1) | MX363805B (es) |
SA (1) | SA516370404B1 (es) |
SG (1) | SG11201600702VA (es) |
TW (1) | TW201509901A (es) |
WO (1) | WO2015017437A1 (es) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW201509522A (zh) * | 2013-07-29 | 2015-03-16 | Rohm & Haas | 氧化酯化催化劑 |
BR112016008906B1 (pt) | 2013-10-28 | 2021-12-07 | Rohm And Haas Company | Processo para preparar metil metacrilato |
SG11202000676UA (en) * | 2017-07-28 | 2020-02-27 | Rohm & Haas | Heterogeneous catalyst |
EP3587390A1 (de) | 2018-06-26 | 2020-01-01 | Röhm GmbH | Verfahren zur herstellung von mma in hohen ausbeuten |
CN113477252B (zh) * | 2021-06-30 | 2023-06-30 | 常州大学 | 一种同时含钛及其它过渡金属的复合多孔催化剂的制备方法和应用 |
Family Cites Families (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5368718A (en) * | 1976-11-27 | 1978-06-19 | Nippon Kayaku Co Ltd | Simultaneous preparation of methacrylic acid and its ester or acrylicacid and its ester |
DE2848978A1 (de) | 1978-11-11 | 1980-05-22 | Bayer Ag | Traegerkatalysatoren, ihre herstellung und verwendung |
JPS55151533A (en) * | 1979-05-17 | 1980-11-26 | Asahi Chem Ind Co Ltd | Preparation of carboxylic acid ester |
DE3018071C2 (de) | 1979-05-17 | 1985-06-05 | Asahi Kasei Kogyo K.K., Osaka | Verfahren zur Herstellung von Carbonsäureestern |
JPS5687530A (en) | 1979-12-19 | 1981-07-16 | Asahi Chem Ind Co Ltd | Dehydrating method of gas containing unsaturated aldehyde |
US4714695A (en) | 1985-04-18 | 1987-12-22 | The Standard Oil Company | Method for the preparation of high activity palladium based catalysts |
JP3258354B2 (ja) * | 1991-11-28 | 2002-02-18 | 三井化学株式会社 | カルボン酸エステルの製造法 |
MY119415A (en) | 1995-07-18 | 2005-05-31 | Asahi Chemical Ind | Catalyst for use in producing carboxylic esters |
JPH09216850A (ja) * | 1996-02-09 | 1997-08-19 | Mitsubishi Rayon Co Ltd | カルボン酸エステルの製造方法 |
TW385304B (en) | 1996-09-10 | 2000-03-21 | Asahi Chemical Ind | Process for producing methacrylic acid ester or acrylic acid ester |
TW377306B (en) | 1996-12-16 | 1999-12-21 | Asahi Chemical Ind | Noble metal support |
JP3511350B2 (ja) * | 1997-03-25 | 2004-03-29 | 旭化成ケミカルズ株式会社 | カルボン酸エステル製造用触媒 |
SG71815A1 (en) | 1997-07-08 | 2000-04-18 | Asahi Chemical Ind | Method of producing methyl methacrylate |
CN1122569C (zh) | 1997-08-07 | 2003-10-01 | 三菱丽阳株式会社 | 用于制造羧酸酯的催化剂和羧酸酯的制造方法 |
US6506930B1 (en) * | 1997-11-17 | 2003-01-14 | Rohm And Haas Company | Process for preparing alkyl (meth)acrylates |
EP1226868B1 (en) | 1999-10-05 | 2005-12-28 | Showa Denko K.K. | Catalyst for producing acetic acid |
RU2278731C2 (ru) * | 2000-09-29 | 2006-06-27 | Чайна Петролеум Энд Кемикал Корпорейшн | Катализатор селективного гидрирования ненасыщенных олефинов, способ получения и применения катализатора |
US7326806B2 (en) | 2001-06-04 | 2008-02-05 | Nippon Shokubai Co., Ltd. | Catalyst for the preparation of carboxylic esters and method for producing carboxylic esters |
JP4145621B2 (ja) | 2002-10-16 | 2008-09-03 | 旭化成ケミカルズ株式会社 | 不飽和カルボン酸エステル合成反応の反応開始方法 |
CN1214865C (zh) | 2003-01-22 | 2005-08-17 | 中国科学院过程工程研究所 | 一种用于甲基丙烯醛一步氧化酯化生产甲基丙烯酸甲酯的新型催化剂 |
JP2004345973A (ja) | 2003-05-20 | 2004-12-09 | Asahi Kasei Chemicals Corp | 不飽和カルボン酸エステルの製造方法 |
DE102004038013A1 (de) * | 2004-08-04 | 2006-03-16 | Basf Ag | Verfahren zur Herstellung von (Meth)acrylsäureestern |
GB2428014B (en) * | 2005-07-08 | 2010-02-10 | Lee Chang Yung Chemical Indust | Catalyst and process for preparing carboxylic acid esters |
BRPI0815166A8 (pt) | 2007-08-13 | 2016-12-20 | Asahi Kasei Chemicals Corp | Catalisador para uso na produção de éster de ácido carboxílico, processos para produzir o mesmo, e, para produzir éster de ácido carboxílico |
JP2011104457A (ja) * | 2009-11-12 | 2011-06-02 | Mitsubishi Rayon Co Ltd | パラジウム含有担持触媒、その製造方法、およびα,β−不飽和カルボン酸の製造方法 |
US9120085B2 (en) | 2010-09-16 | 2015-09-01 | Asahi Kasei Chemicals Corporation | Silica-based material and process for producing the same, noble metal supported material and process for producing carboxylic acids by using the same as catalyst |
US8802588B2 (en) | 2012-01-23 | 2014-08-12 | Celanese International Corporation | Bismuth catalyst composition and process for manufacturing ethanol mixture |
-
2014
- 2014-07-28 TW TW103125654A patent/TW201509901A/zh unknown
- 2014-07-29 KR KR1020167003900A patent/KR102287643B1/ko active IP Right Grant
- 2014-07-29 WO PCT/US2014/048667 patent/WO2015017437A1/en active Application Filing
- 2014-07-29 CA CA2918403A patent/CA2918403C/en active Active
- 2014-07-29 EP EP14750669.5A patent/EP2989077B1/en active Active
- 2014-07-29 JP JP2016531829A patent/JP6506281B2/ja active Active
- 2014-07-29 SG SG11201600702VA patent/SG11201600702VA/en unknown
- 2014-07-29 MX MX2016000767A patent/MX363805B/es active IP Right Grant
- 2014-07-29 US US14/906,310 patent/US9676699B2/en active Active
- 2014-07-29 CN CN201480040179.1A patent/CN105377806B/zh active Active
- 2014-07-29 BR BR112016001127-9A patent/BR112016001127B1/pt active IP Right Grant
-
2016
- 2016-01-14 SA SA516370404A patent/SA516370404B1/ar unknown
Also Published As
Publication number | Publication date |
---|---|
CN105377806B (zh) | 2017-09-05 |
JP6506281B2 (ja) | 2019-04-24 |
KR20160035590A (ko) | 2016-03-31 |
MX2016000767A (es) | 2016-04-19 |
CN105377806A (zh) | 2016-03-02 |
BR112016001127B1 (pt) | 2020-12-29 |
CA2918403C (en) | 2021-07-06 |
WO2015017437A1 (en) | 2015-02-05 |
SA516370404B1 (ar) | 2017-05-29 |
SG11201600702VA (en) | 2016-02-26 |
US9676699B2 (en) | 2017-06-13 |
EP2989077A1 (en) | 2016-03-02 |
JP2016525578A (ja) | 2016-08-25 |
BR112016001127A8 (pt) | 2019-10-01 |
CA2918403A1 (en) | 2015-02-05 |
TW201509901A (zh) | 2015-03-16 |
US20160159728A1 (en) | 2016-06-09 |
EP2989077B1 (en) | 2017-12-27 |
KR102287643B1 (ko) | 2021-08-06 |
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