BR112014018998A8 - Catalisador de hidrogenação para a conversão de uma mistura; e processo - Google Patents

Catalisador de hidrogenação para a conversão de uma mistura; e processo

Info

Publication number
BR112014018998A8
BR112014018998A8 BR112014018998A BR112014018998A BR112014018998A8 BR 112014018998 A8 BR112014018998 A8 BR 112014018998A8 BR 112014018998 A BR112014018998 A BR 112014018998A BR 112014018998 A BR112014018998 A BR 112014018998A BR 112014018998 A8 BR112014018998 A8 BR 112014018998A8
Authority
BR
Brazil
Prior art keywords
temperature
catalyst
mixture
ethyl acetate
hydrogenation catalyst
Prior art date
Application number
BR112014018998A
Other languages
English (en)
Portuguese (pt)
Other versions
BR112014018998A2 (https=
Inventor
Zhou Zhenhua
Weiner Heiko
Kumar Dheeraj
Tu Xiuoyan
J Johnston Victor
Wollrab Radmila
Original Assignee
Celanese Int Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese Int Corp filed Critical Celanese Int Corp
Publication of BR112014018998A2 publication Critical patent/BR112014018998A2/pt
Publication of BR112014018998A8 publication Critical patent/BR112014018998A8/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8993—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8966—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • C07C31/08—Ethanol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/56—Separation; Purification; Stabilisation; Use of additives by solid-liquid treatment; by chemisorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/898—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with vanadium, tantalum, niobium or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
BR112014018998A 2012-02-10 2012-11-27 Catalisador de hidrogenação para a conversão de uma mistura; e processo BR112014018998A8 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US13/371,064 US9050585B2 (en) 2012-02-10 2012-02-10 Chemisorption of ethyl acetate during hydrogenation of acetic acid to ethanol
PCT/US2012/066644 WO2013119306A1 (en) 2012-02-10 2012-11-27 A hydrogenation catalyst for converting a mixture comprising acetic acid and ethyl acetate to ethanol

Publications (2)

Publication Number Publication Date
BR112014018998A2 BR112014018998A2 (https=) 2017-06-20
BR112014018998A8 true BR112014018998A8 (pt) 2017-07-11

Family

ID=47351988

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112014018998A BR112014018998A8 (pt) 2012-02-10 2012-11-27 Catalisador de hidrogenação para a conversão de uma mistura; e processo

Country Status (6)

Country Link
US (2) US9050585B2 (https=)
EP (1) EP2812112A1 (https=)
CN (1) CN104093484A (https=)
BR (1) BR112014018998A8 (https=)
MX (1) MX2014009636A (https=)
WO (1) WO2013119306A1 (https=)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9024090B2 (en) * 2012-12-19 2015-05-05 Celanese International Corporation Catalysts and processes for producing butanol
US8962897B2 (en) * 2012-12-19 2015-02-24 Celanese International Corporation Catalysts and processes for producing butanol
US9018426B1 (en) 2013-12-19 2015-04-28 Celanese International Corporation Processes for producing multi-carbon alcohols
CN103772143A (zh) * 2014-01-08 2014-05-07 上海海源化工科技有限公司 一种由醋酸制备工业乙醇的方法
SG11201606554VA (en) * 2014-02-21 2016-09-29 Univ Nanyang Tech Supported nanowire catalysts
CN105582956B (zh) * 2014-10-21 2018-07-31 中国石油化工股份有限公司 加氢催化剂及其制备方法和应用以及加氢反应的方法
CN105618062A (zh) * 2014-11-26 2016-06-01 江苏海普功能材料有限公司 一种乙酸仲丁酯加氢催化剂及其制备方法和应用
CN105561993B (zh) * 2016-02-23 2018-07-27 上海华谊（集团）公司 醋酸加氢制乙醇联产乙酸乙酯催化剂及制备方法
CN105597762A (zh) * 2016-03-04 2016-05-25 重庆工商大学 用于乙酸乙酯加氢脱氧的负载型介孔Ni催化剂及其制备方法
CN107282044B (zh) * 2016-04-12 2020-02-04 中国石油化工股份有限公司 1,4-环己烷二甲酸合成用催化剂
CN107282104B (zh) * 2016-04-12 2020-02-07 中国石油化工股份有限公司 用于1,4-环己烷二甲醇合成的催化剂
CN106423201A (zh) * 2016-09-14 2017-02-22 中溶科技股份有限公司 醋酸加氢制乙醇的TiO2负载的铑基催化剂的制备方法
CN106423202A (zh) * 2016-09-14 2017-02-22 中溶科技股份有限公司 一种醋酸加氢制备乙醇的铑钌复合催化剂的制备方法
CN107011107A (zh) * 2017-05-16 2017-08-04 中国科学技术大学 一种采用负载型金属催化剂制备醇的方法
CN109305883B (zh) * 2017-07-28 2021-11-30 中国石油化工股份有限公司 1,4-环己烷二甲醇的生产方法
CN108358752A (zh) * 2018-04-18 2018-08-03 肖锦 一种乙酸加氢制乙醇的方法
CN108586196A (zh) * 2018-04-18 2018-09-28 肖锦 一种乙酸乙酯加氢制乙醇的方法
US11498059B2 (en) * 2018-07-30 2022-11-15 Saudi Arabian Oil Company Catalysts that include iron, cobalt, and copper, and methods for making the same
CN109622025B (zh) * 2019-01-17 2021-08-17 陕西延长石油（集团）有限责任公司 一种用于制备羟基乙酸甲酯的催化剂及其制备方法与应用
CN110302816B (zh) * 2019-06-20 2021-11-09 广西科技大学鹿山学院 ZnO@SiO2负载介孔磷酸铌催化剂的合成方法及其在制备5-羟甲基糠醛中的应用
CN114452982B (zh) * 2020-10-22 2023-06-30 陕西科技大学 一种W18O49/CoO/CoWO4/NF自支撑电催化材料及其制备方法
CN114618509A (zh) * 2022-03-21 2022-06-14 上海尼普敦环境科技有限公司 一种二氧化碳加氢还原催化剂及其制备方法
CN114773196B (zh) * 2022-05-19 2024-02-13 辽宁华星日化产业技术研究院有限公司 一种甲基丙烯酸高碳酯的提纯方法
CN118002121A (zh) * 2022-10-27 2024-05-10 中国石油化工股份有限公司 加氢催化剂及其制备方法和在醋酸乙酯加氢制备乙醇中的应用

Family Cites Families (170)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US35377A (en) 1862-05-27 Improved heel for boots or shoes
US2549416A (en) 1948-02-04 1951-04-17 Du Pont Preparation of alcohols
US2607807A (en) 1950-02-24 1952-08-19 Du Pont Preparation of alcohols from carboxylic acids
US2882244A (en) 1953-12-24 1959-04-14 Union Carbide Corp Molecular sieve adsorbents
US3130007A (en) 1961-05-12 1964-04-21 Union Carbide Corp Crystalline zeolite y
US3361769A (en) 1964-01-22 1968-01-02 Synergistics Inc Bi-metallic salts of gluconic, glucuronic, or galacturonic acid
DE1235879B (de) 1964-03-17 1967-03-09 Basf Ag Verfahren zur Herstellung von Alkoholen durch katalytische Hydrierung von Carbonsaeuren
GB1168785A (en) 1965-09-24 1969-10-29 British Petroleum Co Graphite
US3981923A (en) 1969-06-11 1976-09-21 Shell Oil Company Dehydrogenation of alcohols to ketones
US3661769A (en) 1970-11-23 1972-05-09 Mobil Oil Corp Process for reforming a naphtha feedstock in the presence of a platinumtungsten-alumina catalyst
US3864284A (en) 1971-04-26 1975-02-04 Chevron Res Platinum-tin catalyst on an alumina carrier
CH576926A5 (https=) 1973-03-21 1976-06-30 Hoffmann La Roche
US3990952A (en) 1974-10-10 1976-11-09 Raphael Katzen Associates International, Inc. Alcohol distillation process
US4048096A (en) 1976-04-12 1977-09-13 E. I. Du Pont De Nemours And Company Surface impregnated catalyst
US4199438A (en) 1978-05-15 1980-04-22 Uop Inc. Hydrocarbon conversion with an acidic multimetallic catalytic composite
US4317918A (en) 1979-11-05 1982-03-02 Sumitomo Chemical Co., Ltd. Process for preparing alcohols
US4514521A (en) 1980-04-21 1985-04-30 National Distillers And Chemical Corporation Manufacture of oxygenated compounds
NL8003405A (nl) 1980-06-12 1982-01-04 Shell Int Research Werkwijze voor het bereiden van ethanol.
DE3101750A1 (de) 1981-01-21 1982-08-26 Basf Ag, 6700 Ludwigshafen Verfahren zur kontinuierlichen herstellung von ethanol
US4337351A (en) 1981-01-30 1982-06-29 Eastman Kodak Company Preparation of ethylidene diacetate
US4443639A (en) 1981-05-18 1984-04-17 The Standard Oil Company (Indiana) Hydrogenation of carboxylic acids
US4398039A (en) 1981-05-18 1983-08-09 The Standard Oil Company Hydrogenation of carboxylic acids
US4374265A (en) 1981-07-31 1983-02-15 Eastman Kodak Company Preparation of ethylidene diacetate
DE3303571C2 (de) 1982-03-11 1984-07-26 Buckau-Walther AG, 4048 Grevenbroich Verfahren und Anlage zur Herstellung von Äthanol
US4426541A (en) 1982-03-16 1984-01-17 Exxon Research & Engineering Co. Process for production of aliphatic alcohols
EP0104197B1 (en) 1982-03-26 1986-05-28 DAVY McKEE (LONDON) LIMITED Process for the production of ethanol
FR2527200A1 (fr) 1982-05-24 1983-11-25 Inst Francais Du Petrole Procede catalytique de production d'alcools par hydrogenolyse d'esters d'acides carboxyliques
DE3221077A1 (de) 1982-06-04 1983-12-08 Basf Ag, 6700 Ludwigshafen Verfahren zur kontinuierlichen herstellung von ethanol
US4421939A (en) 1982-10-15 1983-12-20 Union Carbide Corporation Production of ethanol from acetic acid
US4476326A (en) 1983-02-03 1984-10-09 Texaco Inc. Process for the synthesis of ethanol and acetaldehyde using cobalt compounds with novel promoters
US4480115A (en) 1983-03-17 1984-10-30 Celanese Corporation Direct hydrogenation of carboxylic acids to alcohol and esters
US5124004A (en) 1983-08-22 1992-06-23 Trustees Of Dartmouth College Distillation process for ethanol
US4550185A (en) 1983-12-22 1985-10-29 E. I. Du Pont De Nemours And Company Process for making tetrahydrofuran and 1,4-butanediol using Pd/Re hydrogenation catalyst
US5026908A (en) 1984-05-03 1991-06-25 Hoechst Celanese Corporation Methanol carbonylation process
US5144068A (en) 1984-05-03 1992-09-01 Hoechst Celanese Corporation Methanol carbonylation process
US5001259A (en) 1984-05-03 1991-03-19 Hoechst Celanese Corporation Methanol carbonylation process
EP0167300A1 (en) 1984-06-06 1986-01-08 Humphreys & Glasgow Limited Process for the production of alcohols
US4497967A (en) 1984-06-15 1985-02-05 The Halcon Sd Group, Inc. Process for the preparation of ethanol from methanol, carbon monoxide _and hydrogen
FR2568873B1 (fr) 1984-08-08 1987-01-09 Inst Francais Du Petrole Procede de production d'alcools par hydrogenolyse d'esters d'acides carboxyliques en presence d'un catalyseur contenant du nickel et de l'etain, du germanium ou du plomb
EP0175558A1 (en) 1984-09-17 1986-03-26 EASTMAN KODAK COMPANY (a New Jersey corporation) Process for the vapor phase hydrogenation of carboxylic acids to esters and alcohols
FR2577217B1 (fr) 1985-02-08 1987-02-20 Rhone Poulenc Chim Base Procede d'hydrogenation de l'acide acetique
GB8509530D0 (en) 1985-04-13 1985-05-15 Bp Chem Int Ltd Hydrogenation of carboxylic acids
CA1299195C (en) 1986-06-16 1992-04-21 G. Paull Torrence Addition of hydrogen to carbon monoxide feed gas in producing acetic acid by carbonylation of methanol
JPS63145242A (ja) 1986-12-10 1988-06-17 Agency Of Ind Science & Technol エタノ−ルの製造法
JPS6415136A (en) 1987-03-03 1989-01-19 Japan Tobacco Inc Catalyst for reducing carboxylic acid or its ester to alcohol compound
US5149680A (en) 1987-03-31 1992-09-22 The British Petroleum Company P.L.C. Platinum group metal alloy catalysts for hydrogenation of carboxylic acids and their anhydrides to alcohols and/or esters
GB8707595D0 (en) 1987-03-31 1987-05-07 British Petroleum Co Plc Chemical process
US5250271A (en) 1987-07-24 1993-10-05 Minister Of International Trade & Industry Apparatus to concentrate and purify alcohol
US4837368A (en) 1988-02-01 1989-06-06 Eastman Kodak Company Low pressure catalytic hydrogenation of carbonyl-containing compounds and supported catalysts therefor
US5198592A (en) 1987-12-11 1993-03-30 Engelhard De Meern B.V. Hydrogenolysis reaction and catalyst suitable therefor
US5185476A (en) 1988-07-15 1993-02-09 Eastman Kodak Company Low pressure catalytic hydrogenation of carbonyl-containing compounds and supported catalysts therefor
GB8828616D0 (en) 1988-12-07 1989-01-11 Bp Chem Int Ltd Chemical process
US5176897A (en) 1989-05-01 1993-01-05 Allied-Signal Inc. Catalytic destruction of organohalogen compounds
GB8917157D0 (en) 1989-07-27 1989-09-13 Bp Chem Int Ltd Chemical process
JP2806391B2 (ja) 1989-07-11 1998-09-30 田中貴金属工業株式会社 有害気体酸化触媒
US5008235A (en) 1989-12-21 1991-04-16 Union Carbide Chemicals And Plastics Technology Corporation Catalysts of Cu-Al-third metal for hydrogenation
JPH0635403B2 (ja) 1990-04-16 1994-05-11 通商産業省基礎産業局長 粗製エタノール水溶液中の不純物の分離方法
DE4025525A1 (de) 1990-08-11 1992-02-20 Hoechst Ag Traegerkatalysatoren und ein verfahren zu ihrer herstellung
US5292916A (en) 1990-09-28 1994-03-08 Ube Industries, Ltd. Method of producing carbonic acid diester
US5137861A (en) 1991-01-22 1992-08-11 Mobil Oil Corp. Catalyst comprising a hydrogenation metal and a delaminated layered silicate
ES2071419T3 (es) 1991-06-21 1995-06-16 Shell Int Research Catalizador y procedimiento de hidrogenacion.
FR2682949B1 (fr) 1991-10-24 1993-12-17 Rhone Poulenc Chimie Procede de synthese d'aldehydes.
US5243095A (en) 1992-04-24 1993-09-07 Engelhard Corporation Hydrogenation catalyst, process for preparing and process for using said catalyst
US5414161A (en) 1992-06-30 1995-05-09 Korea Institute Of Science And Technology Process for the preparation of ethanol from methanol
JPH06116182A (ja) 1992-10-09 1994-04-26 Mitsubishi Kasei Corp 有機カルボン酸及び／又は有機カルボン酸エステルの水素化方法
US5821111A (en) 1994-03-31 1998-10-13 Bioengineering Resources, Inc. Bioconversion of waste biomass to useful products
US5350504A (en) 1992-12-18 1994-09-27 Mobil Oil Corporation Shape selective hydrogenation of aromatics over modified non-acidic platinum/ZSM-5 catalysts
US5672743A (en) 1993-09-10 1997-09-30 Bp Chemicals Limited Process for the production of acetic acid
USRE35377E (en) 1993-05-27 1996-11-12 Steinberg; Meyer Process and apparatus for the production of methanol from condensed carbonaceous material
US5719097A (en) 1993-07-22 1998-02-17 Chang; Clarence D. Catalyst comprising a modified solid oxide
JP3381804B2 (ja) 1993-07-27 2003-03-04 荒川化学工業株式会社 カルボン酸直接還元用触媒および該触媒の製造方法ならびにアルコール化合物の製造方法
BR9404315A (pt) 1993-11-04 1995-07-04 Shell Int Research Catalisador, processo para sua preparação e processo para hidroconversão de hidrocarboneto.
DE4431987A1 (de) 1994-09-08 1996-03-28 Hoechst Ag Verfahren zur Herstellung von Aldehyden durch katalytische Gasphasenhydrierung von Carbonsäuren oder ihre Derivate mit Hilfe eines Zinnkatalysators
US5831133A (en) 1994-10-19 1998-11-03 Firmenich Sa Process for the preparation of alcohols
DE59508645D1 (de) 1994-11-29 2000-09-21 Degussa Katalysator für die Dehydrierung von C6-bis C15-Paraffinen
US5599976A (en) 1995-04-07 1997-02-04 Hoechst Celanese Corporation Recovery of acetic acid from dilute aqueous streams formed during a carbonylation process
US5977010A (en) 1995-06-15 1999-11-02 Engelhard Corporation Shaped hydrogenation catalyst and processes for their preparation and use
US5767307A (en) 1996-05-21 1998-06-16 Air Products And Chemicals, Inc. Heterogeneous catalyst for the production of ethylidene diacetate from acetic anhydride
IN192600B (https=) 1996-10-18 2004-05-08 Hoechst Celanese Corp
FR2755378B1 (fr) 1996-11-07 1999-01-08 Inst Francais Du Petrole Catalyseurs d'hydrogenation selective contenant du palladium et au moins un metal du groupe iva
JPH10306047A (ja) 1997-03-04 1998-11-17 Mitsubishi Chem Corp １，６−ヘキサンジオールの製造方法
DE19720657A1 (de) 1997-05-16 1998-11-19 Basf Ag Verfahren zur Herstellung von aliphatischen Alkoholen
FR2770421B1 (fr) 1997-10-31 1999-12-10 Inst Francais Du Petrole Procede de preparation de catalyseurs utilisables dans les reactions de transformation de composes organiques
JP3780669B2 (ja) 1997-11-17 2006-05-31 三菱化学株式会社 アルデヒド類及び、又はアルコール類の製造方法
FR2777562B1 (fr) 1998-04-16 2002-07-19 Rhone Poulenc Fibres Procede de purification d'aminonitriles aliphatiques
US6121498A (en) 1998-04-30 2000-09-19 Eastman Chemical Company Method for producing acetaldehyde from acetic acid
US6294703B1 (en) 1998-06-22 2001-09-25 Mitsubishi Chemical Company Process for the manufacture of cycloalkyldimethanol
EP0992484A1 (en) 1998-10-01 2000-04-12 Kvaerner Process Technology Limited Process
EP0992482A1 (en) 1998-10-01 2000-04-12 Kvaerner Process Technology Limited Process
US5945570A (en) 1998-10-29 1999-08-31 Arhancet; Juan Pedro Catalyst and process for preparing 1,3-propanediol
ATE405665T1 (de) 1999-03-11 2008-09-15 Zeachem Inc Verfahren zur herstellung von äthanol
US7074603B2 (en) 1999-03-11 2006-07-11 Zeachem, Inc. Process for producing ethanol from corn dry milling
JP4282829B2 (ja) 1999-06-16 2009-06-24 株式会社クラレ カルボン酸及びアルコールの製造方法
PT1204722E (pt) 1999-07-28 2003-12-31 Sued Chemie Inc Catalisadores de hidrogenacao
JP2001046874A (ja) 1999-08-17 2001-02-20 Mitsubishi Chemicals Corp 水素化用触媒、及びこれを用いるカルボン酸類からのアルコール類の製造方法
DE19942895A1 (de) 1999-09-08 2001-03-15 Basf Ag Katalysator und Verfahren zur Hydrierung von Carbonylverbindungen
JP4472109B2 (ja) 1999-09-21 2010-06-02 旭化成ケミカルズ株式会社 カルボン酸水添用触媒
AU7318900A (en) 1999-09-21 2001-04-24 Asahi Kasei Kabushiki Kaisha Catalysts for hydrogenation of carboxylic acid
US6232352B1 (en) 1999-11-01 2001-05-15 Acetex Limited Methanol plant retrofit for acetic acid manufacture
WO2001049771A1 (fr) 2000-01-05 2001-07-12 Toyo Boseki Kabushiki Kaisha Catalyseur de polymerisation pour polyesters, polyesters obtenus et leur procede de production
DE10009817A1 (de) 2000-03-01 2001-09-06 Basf Ag Verfahren zur Herstellung von Alkoholen an rheniumhaltigen Aktivkohle-Trägerkatalysatoren
US6627770B1 (en) 2000-08-24 2003-09-30 Celanese International Corporation Method and apparatus for sequesting entrained and volatile catalyst species in a carbonylation process
CN1487911A (zh) 2000-12-23 2004-04-07 �������¹ɷ����޹�˾ 通过氢化羰基化合物生产醇的方法
US6657078B2 (en) 2001-02-07 2003-12-02 Celanese International Corporation Low energy carbonylation process
US6685754B2 (en) 2001-03-06 2004-02-03 Alchemix Corporation Method for the production of hydrogen-containing gaseous mixtures
JP3786007B2 (ja) 2001-05-29 2006-06-14 住友金属鉱山株式会社 炭化水素油中に含む芳香族化合物の水素化処理用触媒
US6903045B2 (en) 2001-06-19 2005-06-07 Eastman Chemical Company Tin promoted platinum catalyst for carbonylation of lower alkyl alcohols
EP1277826A1 (en) 2001-07-18 2003-01-22 ATOFINA Research Hydrogenation and dehydrogenation processes and catalysts therefor
GB0119327D0 (en) 2001-08-08 2001-10-03 Johnson Matthey Plc Catalyst
AU2002363534A1 (en) 2001-11-08 2003-05-19 Conoco Inc. Modified zirconia support for catalyst for fischer-tropsch process
US7115772B2 (en) 2002-01-11 2006-10-03 Celanese International Corporation Integrated process for producing carbonylation acetic acid, acetic anhydride, or coproduction of each from a methyl acetate by-product stream
WO2004050591A1 (ja) 2002-12-04 2004-06-17 Mitsubishi Chemical Corporation アルコールの製造方法
US7005541B2 (en) 2002-12-23 2006-02-28 Celanese International Corporation Low water methanol carbonylation process for high acetic acid production and for water balance control
US6670490B1 (en) 2002-12-23 2003-12-30 E. I. Du Pont De Nemours And Company Platinum-rhenium-tin catalyst for hydrogenation in aqueous solution
CN1938257A (zh) 2004-01-29 2007-03-28 齐凯姆公司 有机酸的回收
US7208624B2 (en) 2004-03-02 2007-04-24 Celanese International Corporation Process for producing acetic acid
WO2005102513A1 (en) 2004-04-26 2005-11-03 Hte Aktiengesellschaft The High Throughput Experimentation Company Catalysts for the simultaneous removal of carbon monoxide and hydrocarbons from oxygen-rich exhaust gases and processes for the manufacture thereof
US20060102520A1 (en) 2004-11-12 2006-05-18 Lapinski Mark P Reforming process using high density catalyst
DE102005004604A1 (de) 2005-02-01 2006-08-10 Basf Ag Verfahren zur Steuerung einer Hydrierung
DE112006001685A5 (de) 2005-04-20 2008-04-03 White Fox Technologies Ltd. Trennverfahren
RU2007143051A (ru) 2005-04-21 2009-05-27 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) Катализатор гидрирования и способ гидрирования
EP1741692A1 (en) 2005-07-06 2007-01-10 BP Chemicals Limited Process for the conversion of hydrocarbons to C2-oxygenates
US20080207953A1 (en) 2005-07-13 2008-08-28 Basf Aktiengesellschaft Catalyst and Method for Hyrogenating Carbonyl Compounds
EP1923380A1 (en) 2006-10-20 2008-05-21 BP Chemicals Limited Process for the conversion of hydrocarbons to alcohols
FR2910346B1 (fr) 2006-12-22 2010-10-15 Inst Francais Du Petrole Procede de deshydrogenation en presence d'un catalyseur bimetallique ou multi-metallique ayant un indice de bimetallicite et une capacite d'adsorption d'hydrogene optimises
CN101646776A (zh) 2007-02-09 2010-02-10 齐凯姆公司 制造产物的高能效方法
US7538060B2 (en) 2007-02-14 2009-05-26 Eastman Chemical Company Palladium-copper chromite hydrogenation catalysts
CN101610838B (zh) 2007-02-16 2012-05-23 花王株式会社 醇制造用催化剂
US7700814B2 (en) 2007-03-27 2010-04-20 Exxonmobil Chemical Patents Inc. Manufacture of alcohols
US7425657B1 (en) 2007-06-06 2008-09-16 Battelle Memorial Institute Palladium catalyzed hydrogenation of bio-oils and organic compounds
WO2009009322A1 (en) 2007-07-06 2009-01-15 Best Energies, Inc. Integrated facility for producing alcohol using homoacidogenic fermentation
WO2009009320A1 (en) 2007-07-06 2009-01-15 Best Energies Inc. Improved indirect process for producing ethanol
GB0714460D0 (en) 2007-07-25 2007-09-05 Johnson Matthey Plc Catalyst
EP2027917A1 (en) 2007-07-31 2009-02-25 Shell Internationale Researchmaatschappij B.V. Catalyst composition, its preparation and use
DE102007041380A1 (de) 2007-08-31 2009-03-05 Evonik Oxeno Gmbh Hydrierkatalysator und Verfahren zur Herstellung von Alkoholen durch Hydrierung von Carbonylverbindungen
US7923405B2 (en) 2007-09-07 2011-04-12 Range Fuels, Inc. Cobalt-molybdenum sulfide catalyst materials and methods for ethanol production from syngas
SG186001A1 (en) 2007-11-14 2012-12-28 Bp Plc An improved process for the production of alcohol from a carbonaceous feedstock
EP2060553A1 (en) 2007-11-14 2009-05-20 BP p.l.c. Process for the conversion of hydrocarbons into alcohol
EA017325B1 (ru) 2007-11-14 2012-11-30 Бп П.Л.К. Способ получения спирта из углеродсодержащего сырья
EP2072486A1 (en) 2007-12-17 2009-06-24 BP p.l.c. Process for the conversion of hydrocarbons to ethanol
EP2072489A1 (en) 2007-12-17 2009-06-24 BP p.l.c. Process for the conversion of hydrocarbons into ethanol
EP2072487A1 (en) 2007-12-17 2009-06-24 BP p.l.c. Process for the conversion of hydrocarbons to ethanol
EP2072488A1 (en) 2007-12-17 2009-06-24 BP p.l.c. Process for the conversion of hydrocarbon to ethanol
EP2072492A1 (en) 2007-12-17 2009-06-24 BP p.l.c. Process for the conversion of hydrocarbons to ethanol
US20090166172A1 (en) 2007-12-28 2009-07-02 Leonard Ray Casey Ethanol plant process
US20090221725A1 (en) 2008-02-28 2009-09-03 Enerkem, Inc. Production of ethanol from methanol
KR100922998B1 (ko) 2008-03-06 2009-10-22 한국화학연구원 모노카르복실산 또는 그의 유도체로부터 일가 알콜의 제조방법
AU2009244135A1 (en) 2008-05-07 2009-11-12 Zeachem Inc. Recovery of organic acids
US8338650B2 (en) * 2008-07-31 2012-12-25 Celanese International Corporation Palladium catalysts for making ethanol from acetic acid
US8501652B2 (en) 2008-07-31 2013-08-06 Celanese International Corporation Catalysts for making ethanol from acetic acid
US8309773B2 (en) 2010-02-02 2012-11-13 Calanese International Corporation Process for recovering ethanol
US8304586B2 (en) 2010-02-02 2012-11-06 Celanese International Corporation Process for purifying ethanol
US7608744B1 (en) 2008-07-31 2009-10-27 Celanese International Corporation Ethanol production from acetic acid utilizing a cobalt catalyst
US7863489B2 (en) 2008-07-31 2011-01-04 Celanese International Corporation Direct and selective production of ethanol from acetic acid utilizing a platinum/tin catalyst
US8546622B2 (en) 2008-07-31 2013-10-01 Celanese International Corporation Process for making ethanol from acetic acid using acidic catalysts
US8309772B2 (en) 2008-07-31 2012-11-13 Celanese International Corporation Tunable catalyst gas phase hydrogenation of carboxylic acids
US20100197486A1 (en) 2008-07-31 2010-08-05 Celanese International Corporation Catalysts for making ethyl acetate from acetic acid
US20100030002A1 (en) 2008-07-31 2010-02-04 Johnston Victor J Ethylene production from acetic acid utilizing dual reaction zone process
US8471075B2 (en) 2008-07-31 2013-06-25 Celanese International Corporation Processes for making ethanol from acetic acid
US20100030001A1 (en) 2008-07-31 2010-02-04 Laiyuan Chen Process for catalytically producing ethylene directly from acetic acid in a single reaction zone
EP2186787A1 (en) 2008-11-13 2010-05-19 BP p.l.c. Hydrogenation of ethanoic acid to produce ethanol
MX2011005690A (es) 2008-12-02 2011-10-28 Texas A & M Univ Sys Vias alternas a los alcoholes e hidrocarbonos de biomasa.
US8076508B2 (en) 2008-12-08 2011-12-13 Lyondell Chemical Technology Preparation of acetic acid
US7884253B2 (en) 2008-12-11 2011-02-08 Range Fuels, Inc. Methods and apparatus for selectively producing ethanol from synthesis gas
US8198057B2 (en) 2009-06-08 2012-06-12 Alternative Green Technologies, Llc Ethanol production by fermentation of chinese tallow tree
US8680321B2 (en) 2009-10-26 2014-03-25 Celanese International Corporation Processes for making ethanol from acetic acid using bimetallic catalysts
RU2012121861A (ru) 2009-10-26 2013-12-10 Селаниз Интернэшнл Корпорейшн Способы изготовления этанола из уксусной кислоты
CN102229520B (zh) 2011-04-25 2013-12-11 江苏索普（集团）有限公司 一种由醋酸气相加氢制备乙醇的方法
CN102228831A (zh) 2011-04-25 2011-11-02 中国科学院大连化学物理研究所 一种乙酸气相加氢制取乙醇的催化剂
US8536382B2 (en) * 2011-10-06 2013-09-17 Celanese International Corporation Processes for hydrogenating alkanoic acids using catalyst comprising tungsten

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US20130211150A1 (en) 2013-08-15
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