BR112014017585A8 - processo para produção de hexametileno diamina a partir de materiais contendo carboidrato e intermediários para os mesmos - Google Patents

processo para produção de hexametileno diamina a partir de materiais contendo carboidrato e intermediários para os mesmos

Info

Publication number
BR112014017585A8
BR112014017585A8 BR112014017585A BR112014017585A BR112014017585A8 BR 112014017585 A8 BR112014017585 A8 BR 112014017585A8 BR 112014017585 A BR112014017585 A BR 112014017585A BR 112014017585 A BR112014017585 A BR 112014017585A BR 112014017585 A8 BR112014017585 A8 BR 112014017585A8
Authority
BR
Brazil
Prior art keywords
hexanediol
hexamethylene diamine
carbohydrate
containing materials
hmda
Prior art date
Application number
BR112014017585A
Other languages
English (en)
Other versions
BR112014017585B1 (pt
BR112014017585A2 (pt
Inventor
L Dias Eric
A W Shoemaker James
R Boussie Thomas
j murphy Vincent
Original Assignee
Rennovia Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rennovia Inc filed Critical Rennovia Inc
Publication of BR112014017585A2 publication Critical patent/BR112014017585A2/pt
Publication of BR112014017585A8 publication Critical patent/BR112014017585A8/pt
Publication of BR112014017585B1 publication Critical patent/BR112014017585B1/pt

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/156—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof
    • C07C29/157—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
    • C07C209/14—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups
    • C07C209/16—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups with formation of amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C07C29/175—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with simultaneous reduction of an oxo group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C07D307/48—Furfural
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C07D307/48—Furfural
    • C07D307/50—Preparation from natural products

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

resumo da patente de invenção para: "processo para produção de hexametileno diamina a partir de materiais contendo carboidrato e intermediários para os mesmos". são revelados processos para a conversão de uma fonte de carboidrato em hexametileno diamina (hmda) e a intermediários úteis para a produção de hexametileno diamina e outros produtos químicos industriais. hmda é produzido por redução direta de um substrato de furfural em 1,6-hexanodiol na presença de hidrogênio e um catalisador de redução heterogênea compreendendo pt ou por redução indireta de um substrato de furfural em 1,6-hexanodiol em que 1,2,6-hexanotriol é produzido por redução do substrato de furfural na presença de hidrogênio e um catalisador compreendendo pt e 1,2,6-hexanodiol é então convertido por hidrogenação na presença de um catalisador compreendendo pt em 1,6 hexanodiol, cada processo prosseguindo então para a produção de hmda por rotas conhecidas, como aminação de 1,6 hexanodiol. catalisadores úteis para a produção direta e indireta de 1,6-hexanodiol são também revelados.
BR112014017585-3A 2012-01-18 2013-01-11 processo para produção de hexametileno diamina a partir de materiais contendo carboidrato e intermediários para os mesmos BR112014017585B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261588093P 2012-01-18 2012-01-18
US61/588,093 2012-01-18
PCT/US2013/021315 WO2013109477A1 (en) 2012-01-18 2013-01-11 Process for production of hexamethylenediamine from 5 - hydroxymethylfurfural

Publications (3)

Publication Number Publication Date
BR112014017585A2 BR112014017585A2 (pt) 2017-06-13
BR112014017585A8 true BR112014017585A8 (pt) 2017-07-04
BR112014017585B1 BR112014017585B1 (pt) 2020-11-24

Family

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Family Applications (1)

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BR112014017585-3A BR112014017585B1 (pt) 2012-01-18 2013-01-11 processo para produção de hexametileno diamina a partir de materiais contendo carboidrato e intermediários para os mesmos

Country Status (18)

Country Link
US (7) US8853458B2 (pt)
EP (2) EP2804848B1 (pt)
JP (1) JP6253203B2 (pt)
KR (1) KR20140113706A (pt)
CN (2) CN106008163B (pt)
AR (1) AR089707A1 (pt)
AU (2) AU2013210005B2 (pt)
BR (1) BR112014017585B1 (pt)
CA (1) CA2860886A1 (pt)
EA (1) EA025555B1 (pt)
HK (1) HK1204318A1 (pt)
IN (1) IN2014DN06596A (pt)
MX (1) MX336933B (pt)
MY (1) MY165219A (pt)
SA (2) SA113340200B1 (pt)
SG (3) SG10201700153WA (pt)
WO (1) WO2013109477A1 (pt)
ZA (2) ZA201405258B (pt)

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US20170050906A1 (en) 2017-02-23
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