BR112013005849A2 - método para a produção de álcool por reação de guerbet - Google Patents

método para a produção de álcool por reação de guerbet

Info

Publication number
BR112013005849A2
BR112013005849A2 BR112013005849A BR112013005849A BR112013005849A2 BR 112013005849 A2 BR112013005849 A2 BR 112013005849A2 BR 112013005849 A BR112013005849 A BR 112013005849A BR 112013005849 A BR112013005849 A BR 112013005849A BR 112013005849 A2 BR112013005849 A2 BR 112013005849A2
Authority
BR
Brazil
Prior art keywords
production
reaction
alcohol
guerbet reaction
alcohols
Prior art date
Application number
BR112013005849A
Other languages
English (en)
Other versions
BR112013005849B1 (pt
Inventor
Jun Kubo
Shuji Sakuma
Takashi Tsuchida
Tetsuya Yoshioka
Original Assignee
Sangi Kk
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sangi Kk filed Critical Sangi Kk
Publication of BR112013005849A2 publication Critical patent/BR112013005849A2/pt
Publication of BR112013005849B1 publication Critical patent/BR112013005849B1/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/32Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups
    • C07C29/34Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups by condensation involving hydroxy groups or the mineral ester groups derived therefrom, e.g. Guerbet reaction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/10Magnesium; Oxides or hydroxides thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/007Mixed salts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14Phosphorus; Compounds thereof
    • B01J27/16Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B01J27/18Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/082X-type faujasite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/03Precipitation; Co-precipitation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

método para a produção de álcool por reação de guerbet. a presente invenção refere-se a um método para o aumento do rendimento de alcoóis por uma reação de guerbet em uma fase gasosa e redução do custo de produção. um método para a produção de alcoóis por uma reação de guebet, em que a reação é realizada em uma fase gasosa e a uma pressão total de menos do que 1 atm e de preferência de 0,01 a 0,5 atm, usando-se um ou mais alcoóis como matéria-prima.
BR112013005849-8A 2010-09-15 2011-09-14 Método para a produção de álcool por reação de guerbet. BR112013005849B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2010206803 2010-09-15
JP2010-206803 2010-09-15
PCT/JP2011/005191 WO2012035772A1 (en) 2010-09-15 2011-09-14 Method for producing alcohol by guerbet reaction

Publications (2)

Publication Number Publication Date
BR112013005849A2 true BR112013005849A2 (pt) 2016-05-17
BR112013005849B1 BR112013005849B1 (pt) 2019-04-24

Family

ID=45831258

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112013005849-8A BR112013005849B1 (pt) 2010-09-15 2011-09-14 Método para a produção de álcool por reação de guerbet.

Country Status (6)

Country Link
US (1) US9056811B2 (pt)
EP (1) EP2616418B1 (pt)
JP (1) JP5786234B2 (pt)
CN (1) CN103119013B (pt)
BR (1) BR112013005849B1 (pt)
WO (1) WO2012035772A1 (pt)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL2010393C2 (en) 2013-03-05 2014-09-08 Stichting Energie Process for preparing bã¨ta-alkylated alcohols.
DE102013106787A1 (de) * 2013-06-28 2014-12-31 Oxea Gmbh Verfahren zur Herstellung von n-Butanderivaten
CN103588621B (zh) * 2013-10-21 2015-09-30 北京化工大学 一种正丁醇的合成方法
CN105562046B (zh) * 2015-12-22 2018-03-02 中国科学院山西煤炭化学研究所 甲醇与乙醇缩合制备丙醇和丁醇的催化剂及制法和应用
US10745330B2 (en) 2017-07-27 2020-08-18 Battelle Memorial Institute Method of converting ethanol to higher alcohols
CN108043432B (zh) * 2017-12-07 2020-12-01 中国科学院山西煤炭化学研究所 一种合成支链醇的催化剂及制备方法和应用
BR102019024934B1 (pt) * 2019-11-26 2022-02-22 Petróleo Brasileiro S.A. - Petrobras Processo para obtenção de compostos, dentre os quais o triptano por reação de acoplamento de álcoois

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5068469A (en) 1990-02-07 1991-11-26 Exxon Chemical Patents Inc. Process for preparation of condensed alcohols by alkoxide catalysts
JP3862775B2 (ja) * 1996-02-28 2006-12-27 花王株式会社 分枝二量化アルコールの製造方法
DE19734673A1 (de) * 1997-08-11 1999-02-18 Rwe Dea Ag Verfahren zur Herstellung von metallfreien Guerbetalkoholen
DE10046434A1 (de) 2000-09-20 2002-04-04 Cognis Deutschland Gmbh Verfahren zur Herstellung von verzweigten Alkoholen und/oder Kohlenwasserstoffen
DE10046433A1 (de) 2000-09-20 2002-04-04 Cognis Deutschland Gmbh Verfahren zur Herstellung von Guerbetalkoholen
CN1926173A (zh) 2004-03-08 2007-03-07 萨索尔德国股份有限公司 包含醇烷氧基化物的组合物及其用途
KR101113050B1 (ko) 2004-12-03 2012-03-14 가부시키가이샤 상기 고분자 알코올의 합성방법
JP2008088140A (ja) * 2006-10-05 2008-04-17 Sangi Co Ltd 化学工業原料及び燃料組成物の合成方法
JP2008303160A (ja) 2007-06-06 2008-12-18 Mitsubishi Chemicals Corp アルコールの製造方法
JP5487537B2 (ja) 2007-07-24 2014-05-07 三菱化学株式会社 アルコールの製造方法
US8603201B2 (en) * 2007-08-24 2013-12-10 Kabushiki Kaisha Sangi Method of synthesizing chemical industry raw materials and fuel compositions
JP5382902B2 (ja) * 2007-08-24 2014-01-08 株式会社サンギ 化学工業原料及び燃料組成物の合成方法
BRPI0819659B1 (pt) 2007-12-20 2018-01-02 Mitsubishi Chemical Corporation Processo para produção de álcool
JP2009167129A (ja) * 2008-01-17 2009-07-30 Daicel Chem Ind Ltd アルコールの製造法
JP2009173611A (ja) 2008-01-28 2009-08-06 Kao Corp β分岐アルコールの製造法
JP5849259B2 (ja) * 2008-02-21 2016-01-27 国立大学法人高知大学 触媒およびアルコールの合成法
BRPI0903506B1 (pt) * 2009-08-17 2017-12-19 Kabushiki Kaisha Sangi A method of synthesis of alcohol for the synthesis of butanol from ethanol ??
ES2621807T3 (es) * 2009-11-06 2017-07-05 Cognis Ip Management Gmbh Procedimiento para la preparación de alcoholes de Guerbet

Also Published As

Publication number Publication date
US20130172634A1 (en) 2013-07-04
EP2616418B1 (en) 2016-11-02
WO2012035772A1 (en) 2012-03-22
EP2616418A1 (en) 2013-07-24
JP5786234B2 (ja) 2015-09-30
CN103119013B (zh) 2015-06-17
CN103119013A (zh) 2013-05-22
EP2616418A4 (en) 2015-11-25
JP2013540690A (ja) 2013-11-07
US9056811B2 (en) 2015-06-16
BR112013005849B1 (pt) 2019-04-24

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Legal Events

Date Code Title Description
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 14/09/2011, OBSERVADAS AS CONDICOES LEGAIS. (CO) 20 (VINTE) ANOS CONTADOS A PARTIR DE 14/09/2011, OBSERVADAS AS CONDICOES LEGAIS