BR112015019704A2 - método e sistema de destilação reativa, e, método de separar uma corrente de fase orgânica e aquosa mista - Google Patents
método e sistema de destilação reativa, e, método de separar uma corrente de fase orgânica e aquosa mistaInfo
- Publication number
- BR112015019704A2 BR112015019704A2 BR112015019704A BR112015019704A BR112015019704A2 BR 112015019704 A2 BR112015019704 A2 BR 112015019704A2 BR 112015019704 A BR112015019704 A BR 112015019704A BR 112015019704 A BR112015019704 A BR 112015019704A BR 112015019704 A2 BR112015019704 A2 BR 112015019704A2
- Authority
- BR
- Brazil
- Prior art keywords
- reactive distillation
- separating
- mixed organic
- aqueous phase
- feed stream
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/009—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping in combination with chemical reactions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/72—Copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/86—Chromium
- B01J23/868—Chromium copper and chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
- B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
- B01J27/1802—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates
- B01J27/1806—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates with alkaline or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0207—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly horizontal
- B01J8/0221—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly horizontal in a cylindrical shaped bed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0242—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
- B01J8/025—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical in a cylindrical shaped bed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0278—Feeding reactive fluids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0285—Heating or cooling the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0446—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
- B01J8/0449—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds
- B01J8/0453—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds the beds being superimposed one above the other
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0446—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
- B01J8/0449—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds
- B01J8/0457—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds the beds being placed in separate reactors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0492—Feeding reactive fluids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0496—Heating or cooling the reactor
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/32—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups
- C07C29/34—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups by condensation involving hydroxy groups or the mineral ester groups derived therefrom, e.g. Guerbet reaction
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00176—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles outside the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00247—Reflux columns
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00265—Part of all of the reactants being heated or cooled outside the reactor while recycling
- B01J2208/00274—Part of all of the reactants being heated or cooled outside the reactor while recycling involving reactant vapours
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00265—Part of all of the reactants being heated or cooled outside the reactor while recycling
- B01J2208/00283—Part of all of the reactants being heated or cooled outside the reactor while recycling involving reactant liquids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/02—Processes carried out in the presence of solid particles; Reactors therefor with stationary particles
- B01J2208/023—Details
- B01J2208/024—Particulate material
- B01J2208/025—Two or more types of catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Abstract
1 / 1 resumo âmãtodo e sistema de destilaãão reativa, e, mãtodo de separar uma corrente de fase orgãnica e aquosa mistaâ um mã©todo de destilaã§ã£o reativa compreende introduzir uma corrente de alimentaã§ã£o a uma coluna de destilaã§ã£o reativa, contactar a corrente de alimentaã§ã£o com uma ou mais catã¡lises na coluna de destilaã§ã£o reativa durante uma destilaã§ã£o e remoã§ã£o de um ou mais ã¡lcoois superiores durante a destilaã§ã£o da coluna de destilaã§ã£o reativa como uma corrente inferior. a corrente de alimentaã§ã£o compreende um ou mais alfa hidrogãªnio ã¡lcoois e a corrente de alimentaã§ã£o reage na presenã§a do um ou mais catalisadores para produzir um produto de reaã§ã£o que compreende o um ou mais ã¡lcoois superiores.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201361766484P | 2013-02-19 | 2013-02-19 | |
US61/766,484 | 2013-02-19 | ||
US201361912235P | 2013-12-05 | 2013-12-05 | |
US61/912,235 | 2013-12-05 | ||
PCT/US2014/016957 WO2014130465A1 (en) | 2013-02-19 | 2014-02-18 | Production of higher alcohols |
Publications (3)
Publication Number | Publication Date |
---|---|
BR112015019704A2 true BR112015019704A2 (pt) | 2017-07-18 |
BR112015019704A8 BR112015019704A8 (pt) | 2021-02-09 |
BR112015019704B1 BR112015019704B1 (pt) | 2021-09-14 |
Family
ID=51351683
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112015019704-3A BR112015019704B1 (pt) | 2013-02-19 | 2014-02-18 | Método e sistema de destilação reativa |
Country Status (7)
Country | Link |
---|---|
US (1) | US9018427B2 (pt) |
EP (1) | EP2958881A4 (pt) |
CN (1) | CN105073697B (pt) |
BR (1) | BR112015019704B1 (pt) |
CA (1) | CA2899318C (pt) |
MY (1) | MY170550A (pt) |
WO (1) | WO2014130465A1 (pt) |
Families Citing this family (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9447018B2 (en) | 2009-10-20 | 2016-09-20 | Greenyug, Llc | Ethyl acetate production |
CN105393312B (zh) * | 2013-07-23 | 2018-01-02 | 旭化成株式会社 | 铜和/或铜氧化物分散体、以及使用该分散体形成的导电膜 |
WO2015085002A1 (en) | 2013-12-04 | 2015-06-11 | Greenyug, Llc | Production of butyl acetate from ethanol |
ES2570231B1 (es) * | 2014-11-14 | 2017-04-19 | Abengoa Bioenergia Nuevas Tecnologias, S.A. | Proceso para la preparación de alcoholes superiores a partir de etanol y n-hexanol mediante condensación de guerbet |
ES2570233B1 (es) * | 2014-11-14 | 2017-02-22 | Abengoa Bioenergía Nuevas Tecnologías, S.A. | Procedimiento de obtención de 1-octanol |
ES2570227B1 (es) * | 2014-11-14 | 2017-04-19 | Abengoa Bioenergia Nuevas Tecnologias, S.A. | Proceso para la preparación de alcoholes superiores a partir de etanol y n-hexanol mediante condensación de guerbet |
RU2601426C1 (ru) * | 2015-05-18 | 2016-11-10 | Федеральное государственное бюджетное учреждение науки Ордена Трудового Красного Знамени Институт нефтехимического синтеза им. А.В. Топчиева Российской академии наук (ИНХС РАН) | Катализатор и способ переработки этанола в линейные альфа-спирты |
BR112018003036B1 (pt) * | 2015-08-19 | 2021-11-09 | Rescurve, Llc | Método para produção de um álcool superior |
CN105251431A (zh) * | 2015-11-17 | 2016-01-20 | 苏州市金翔钛设备有限公司 | 螺旋式反应装置 |
CN105562046B (zh) * | 2015-12-22 | 2018-03-02 | 中国科学院山西煤炭化学研究所 | 甲醇与乙醇缩合制备丙醇和丁醇的催化剂及制法和应用 |
CN106076344B (zh) * | 2016-06-06 | 2018-08-21 | 浙江工业大学 | 活性炭负载型铜-金属氧化物催化剂及其制备方法和应用 |
WO2018039609A1 (en) * | 2016-08-25 | 2018-03-01 | Rescurve, Llc | Production of higher alcohols |
CN106622283A (zh) * | 2016-11-30 | 2017-05-10 | 山东玉皇化工有限公司 | 乙醇一步法合成乙酸乙酯联产正丁醇所用催化剂制备方法 |
FR3065174B1 (fr) * | 2017-04-14 | 2022-01-14 | Ifp Energies Now | Procede de transformation d'alcool par des catalyseurs metalliques solides a base de cuivre de cerium et de barium |
FR3065175A1 (fr) * | 2017-04-14 | 2018-10-19 | IFP Energies Nouvelles | Procede de transformation d'alcools par des catalyseurs solides a base de cuivre et d'un element choisi parmi na, ca, ba et k |
US10745330B2 (en) * | 2017-07-27 | 2020-08-18 | Battelle Memorial Institute | Method of converting ethanol to higher alcohols |
CN107362563A (zh) * | 2017-08-22 | 2017-11-21 | 南通泰利达化工有限公司 | 一种硝化棉的乙醇蒸馏工艺及装置 |
CN107983328B (zh) * | 2017-12-07 | 2020-12-25 | 中国科学院山西煤炭化学研究所 | 一种醇醇缩合反应的催化剂及其制备方法和应用 |
CN108043403B (zh) * | 2017-12-07 | 2020-12-01 | 中国科学院山西煤炭化学研究所 | 一种合成高级醇类催化剂及制备方法和应用 |
CN107983356B (zh) * | 2017-12-07 | 2020-12-25 | 中国科学院山西煤炭化学研究所 | 一种合成高级支链醇的催化剂及制备方法和应用 |
US10882807B2 (en) * | 2018-03-21 | 2021-01-05 | Massachusetts Institute Of Technology | Methods and compositions for the catalytic upgrading of alcohols |
CN109111343B (zh) * | 2018-09-10 | 2021-05-07 | 大连理工大学 | 一种低碳醇催化转化制备苄醇及同系物的方法及所用催化剂 |
CN109111345B (zh) * | 2018-09-10 | 2020-08-14 | 大连理工大学 | 一种乙醇催化转化制备甲基苯甲醇的方法 |
BR102019024934B1 (pt) | 2019-11-26 | 2022-02-22 | Petróleo Brasileiro S.A. - Petrobras | Processo para obtenção de compostos, dentre os quais o triptano por reação de acoplamento de álcoois |
WO2021236915A1 (en) * | 2020-05-20 | 2021-11-25 | Exxonmobil Research And Engineering Company | Processes for producing ethers and olefins from primary alcohols |
US11518725B2 (en) | 2020-05-20 | 2022-12-06 | Exxonmobil Research And Engineering Company | Processes for producing alcohols from biomass and further products derived therefrom |
JP2023537890A (ja) * | 2020-08-06 | 2023-09-06 | エアー カンパニー ホールディングス インコーポレイテッド | 蒸留プロセスにおける不純物除去を増強するための合金及び方法 |
CN114177908B (zh) * | 2021-08-25 | 2023-09-15 | 广东工业大学 | 一种固体碱协同碳包覆镍基两亲性相转移催化剂及其制备方法和应用 |
CN114558581A (zh) * | 2022-03-08 | 2022-05-31 | 中国科学院青岛生物能源与过程研究所 | 一种Cu/Cr基催化剂及其制备方法和用于制备1,2-戊二醇的用途 |
CN115779908A (zh) * | 2022-12-13 | 2023-03-14 | 浙江工业大学 | 用于乙醇脱氢缩合制高级醇反应的氧化铝负载铜-氧化锌催化剂及其制备和应用 |
CN117101673A (zh) * | 2023-06-19 | 2023-11-24 | 广东工业大学 | 一种Ni-Re双金属基催化剂及其制备方法和应用 |
Family Cites Families (53)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1708460A (en) | 1927-03-26 | 1929-04-09 | Du Pont | Process of manufacturing esters and other valuable organic compounds |
GB312345A (en) | 1928-05-26 | 1930-08-05 | Du Pont | Improvements in catalytic dehydrogenation |
US1992480A (en) | 1930-07-26 | 1935-02-26 | Degussa | Process for the production of higher alcohols, particularly butyl alcohol, from ethyl alcohol |
FR798842A (fr) | 1935-02-27 | 1936-05-27 | Melle Usines Sa | Procédé de fabrication d'éthers-sels et notamment d'acétate d'éthyle |
US2525829A (en) | 1946-12-04 | 1950-10-17 | Koppers Co Inc | Recovery of ethyl acetate from butadiene crude by-product oils |
US2645667A (en) * | 1951-10-01 | 1953-07-14 | Phillips Petroleum Co | Condensation of alcohols in the presence of calcium hydroxide |
SU362814A1 (ru) | 1970-03-02 | 1972-12-30 | Способ получения этилацетата | |
US3714236A (en) | 1970-08-07 | 1973-01-30 | Eastman Kodak Co | Process for producing mixed esters from aldehydes |
US4052424A (en) | 1976-09-01 | 1977-10-04 | Celanese Corporation | Production of esters from alcohols |
US4220803A (en) | 1978-06-27 | 1980-09-02 | Union Carbide Corporation | Catalytic dehydrogenation of ethanol for the production of acetaldehyde and acetic acid |
US4379028A (en) | 1982-03-30 | 1983-04-05 | Lloyd Berg | Separation of ethyl acetate from ethanol and water by extractive distillation |
US4435595A (en) | 1982-04-26 | 1984-03-06 | Eastman Kodak Company | Reactive distillation process for the production of methyl acetate |
US4440946A (en) | 1982-07-26 | 1984-04-03 | Celanese Corporation | Production of esters from aldehydes using a silver/cadmium/zinc/zirconium catalyst |
JPS5925334A (ja) | 1982-07-30 | 1984-02-09 | Nippon Shirika Kogyo Kk | 亜臭素酸およびその塩によるエステル化合物の製造法 |
DE3228500A1 (de) | 1982-07-30 | 1984-02-02 | Basf Ag, 6700 Ludwigshafen | Verfahren zur reinigung von aldehyde, acetale und/oder ungesaettigte verbindungen enthaltenden carbonsaeureestern |
DE3338439A1 (de) | 1983-10-22 | 1985-05-02 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur destillativen aufarbeitung von wasser und methanol enthaltenden hoeheren alokoholen mit 6 bis 20 c-atomen |
GB8400785D0 (en) | 1984-01-12 | 1984-02-15 | Davy Mckee Ltd | Process |
US4569726A (en) | 1984-07-19 | 1986-02-11 | Lloyd Berg | Process for the separation of ethyl acetate from ethanol and water by extractive distillation |
US4825013A (en) | 1984-11-05 | 1989-04-25 | The Dow Chemical Company | Preparation of ethanol and higher alcohols from lower carbon number alcohols |
AU574809B2 (en) * | 1984-11-05 | 1988-07-14 | Dow Chemical Company, The | Homologation of lower alcohols in a fischer-tropsch process |
CA1281739C (en) | 1985-05-10 | 1991-03-19 | Brian T. Keen | Method to convert primary alkanols to their corresponding esters |
JPH0753676B2 (ja) * | 1987-04-01 | 1995-06-07 | 三菱化学株式会社 | 高級アルコ−ルの精製方法 |
DE3806304A1 (de) | 1988-02-27 | 1989-09-07 | Basf Ag | Verfahren zur reinigung von aldehyde, acetale und/oder ungesaettigte verbindungen enthaltenden carbonsaeureestern |
DE3936854A1 (de) | 1989-11-06 | 1991-05-08 | Basf Ag | Verfahren zur herstellung von methylformiat |
US4996007A (en) | 1990-01-19 | 1991-02-26 | Shell Oil Company | Process for the oxidation of alcohols to aldehydes/acids/esters |
BR9105300A (pt) | 1990-12-10 | 1992-08-18 | Standard Oil Co Ohio | Processo para fabricacao de acetato de etilo |
BR9104652A (pt) | 1991-10-23 | 1993-04-27 | Pai Cheng Cha | Sistema de codificacao |
JP3160983B2 (ja) | 1992-01-10 | 2001-04-25 | 昭和電工株式会社 | 酢酸エチルの精製方法 |
FR2743060B1 (fr) | 1995-12-27 | 1998-02-06 | Inst Francais Du Petrole | Procede de synthese d'hydrogene par utilisation d'une zone de distillation reactive |
DE19842371A1 (de) * | 1998-09-16 | 2000-03-23 | Oxeno Oelfinchemie Gmbh | Verfahren zur Herstellung von höheren Oxo-Alkoholen aus Olefingemischen |
EP0990638A1 (en) | 1998-10-01 | 2000-04-05 | Kvaerner Process Technology Limited | Process |
EP0992484A1 (en) | 1998-10-01 | 2000-04-12 | Kvaerner Process Technology Limited | Process |
CA2589125C (en) * | 2004-12-03 | 2010-10-19 | Kabushiki Kaisha Sangi | Method of synthesizing higher-molecular alcohol |
US8080684B2 (en) | 2007-06-27 | 2011-12-20 | H R D Corporation | Method of producing ethyl acetate |
WO2009026483A1 (en) | 2007-08-22 | 2009-02-26 | E.I. Du Pont De Nemours And Company | Catalytic conversion of ethanol to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite containing the anion of ethylenediaminetetraacetic acid |
WO2009026501A1 (en) | 2007-08-22 | 2009-02-26 | E. I. Du Pont De Nemours And Company | Catalytic conversion of ethanol and methanol to an isobutanol-containing reaction product using a thermally decomposed hydrotalcite/metal carbonate |
US7705192B2 (en) | 2007-08-22 | 2010-04-27 | E. I. Du Pont De Nemours And Company | Catalytic conversion of ethanol and methanol to an isobutanol-containing reaction product using a thermally decomposed hydrotalcite catalyst |
WO2009026506A1 (en) | 2007-08-22 | 2009-02-26 | E.I. Du Pont De Nemours And Company | Catalytic conversion of ethanol and methanol to an isobutanol-containing reaction product using a thermally decomposed hydrotalcite containing the anion of ethylenediaminetetraacetic acid |
US7700811B2 (en) | 2007-08-22 | 2010-04-20 | E.I. Du Pont De Namours And Company | Catalytic conversion of ethanol to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite/metal carbonate |
US7700810B2 (en) | 2007-08-22 | 2010-04-20 | E.I. Du Pont De Nemours And Company | Catalytic conversion of ethanol to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite catalyst |
WO2009097312A1 (en) | 2008-01-28 | 2009-08-06 | E.I. Du Pont De Nemours And Company | Catalytic conversion of ethanol and hydrogen to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite/metal carbonate |
JP5849259B2 (ja) * | 2008-02-21 | 2016-01-27 | 国立大学法人高知大学 | 触媒およびアルコールの合成法 |
US8318989B2 (en) | 2008-12-22 | 2012-11-27 | E I Du Pont De Nemours And Company | Process for producing guerbet alcohols using water tolerant basic catalysts |
US8962896B2 (en) * | 2009-09-11 | 2015-02-24 | E I Du Pont De Nemours And Company | Conversion of ethanol to a reaction product comprising 1-butanol using hydroxyapatite catalysts |
US8558025B2 (en) * | 2009-10-20 | 2013-10-15 | Greenyug, Llc | Ethyl acetate production |
US9447018B2 (en) | 2009-10-20 | 2016-09-20 | Greenyug, Llc | Ethyl acetate production |
US8575403B2 (en) | 2010-05-07 | 2013-11-05 | Celanese International Corporation | Hydrolysis of ethyl acetate in ethanol separation process |
EP2560945A2 (de) | 2010-04-19 | 2013-02-27 | Basf Se | Reinigung von carbonsäureestern durch extraktivdestillation |
CA2804582A1 (en) * | 2010-07-09 | 2012-01-12 | BP Biofuels UK Limited | Conversion of alcohols |
ES2712067T3 (es) | 2011-10-12 | 2019-05-09 | Greenyug Llc | Producción de acetato de etilo |
US9079851B2 (en) | 2012-02-01 | 2015-07-14 | Greenyug, Llc | Ethyl acetate production |
HUE053582T2 (hu) * | 2012-06-29 | 2021-07-28 | Abengoa Bioenergia Nuevas Tecnologias Sa | Katalizátor és annak elõállítási folyamata hosszabb láncú alkoholok elõállítására |
ES2808989T3 (es) | 2017-05-18 | 2021-03-02 | General Electric Technology Gmbh | Disyuntor que comprende un catalizador basado en ceria para la conversión de CO en CO2 |
-
2014
- 2014-02-18 MY MYPI2015702409A patent/MY170550A/en unknown
- 2014-02-18 CA CA2899318A patent/CA2899318C/en active Active
- 2014-02-18 BR BR112015019704-3A patent/BR112015019704B1/pt active IP Right Grant
- 2014-02-18 US US14/183,273 patent/US9018427B2/en active Active
- 2014-02-18 EP EP14754744.2A patent/EP2958881A4/en active Pending
- 2014-02-18 WO PCT/US2014/016957 patent/WO2014130465A1/en active Application Filing
- 2014-02-18 CN CN201480009376.7A patent/CN105073697B/zh active Active
Also Published As
Publication number | Publication date |
---|---|
CN105073697B (zh) | 2017-05-24 |
EP2958881A4 (en) | 2016-12-21 |
MY170550A (en) | 2019-08-16 |
EP2958881A1 (en) | 2015-12-30 |
WO2014130465A1 (en) | 2014-08-28 |
CA2899318A1 (en) | 2014-08-28 |
US20140235901A1 (en) | 2014-08-21 |
BR112015019704B1 (pt) | 2021-09-14 |
BR112015019704A8 (pt) | 2021-02-09 |
CA2899318C (en) | 2019-12-24 |
US9018427B2 (en) | 2015-04-28 |
CN105073697A (zh) | 2015-11-18 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
BR112015019704A2 (pt) | método e sistema de destilação reativa, e, método de separar uma corrente de fase orgânica e aquosa mista | |
BR112014017395A8 (pt) | método e sistema de destilação reativa | |
BR112015000858A2 (pt) | método para preparar ácido acrílico | |
BR112013012876B8 (pt) | processo e sistema para produzir componentes de combustível a partir de um material de origem biológica, componentes de combustível, uso de componentes de combustível, mistura, e, uso de uma mistura | |
AR092596A1 (es) | Sistema de reactor para la produccion de alotropos de carbono | |
BR112014030260A2 (pt) | método para converter um material hidrocarbonáceo em um produto de hidrocarboneto fluido que compreende p-xileno | |
BR112018010229A2 (pt) | sistema catalisador e processo para a produção de glicóis | |
BR112015019100A2 (pt) | processo para a preparação de monoetileno glicol a partir de sacarose, e, processo para a conversão de sacarose em frutose e/ou derivados de frutose | |
BR112015021850A2 (pt) | processo e catalisador de carbonilação | |
IN2014DN03381A (pt) | ||
BR112018011705A2 (pt) | processo para a preparação de glicóis | |
BR112015020497A2 (pt) | processo para remover o formaldeído de uma composição compreendendo glicolaldeído | |
BR112014015123A2 (pt) | processo para a produção de um ou mais alcenos ou compostos aromáticos | |
BR112013032492A2 (pt) | processo para fazer compostos beta-hidroxiamino | |
MX2017009128A (es) | Rechazo de hidrogeno en el proceso de metanol a hidrocarburo. | |
BR112018007719A2 (pt) | método de preparação para substância p-fenilenodiamina substituída por aril | |
WO2014154849A3 (en) | Process for the fluid catalytic cracking of oxygenated hydrocarbon compounds from biological origin | |
MX2015007293A (es) | Proceso para convertir compuestos fenolicos en hidrocarburos aromaticos. | |
BR112018009963A8 (pt) | hidrogenação seletiva com o uso de um índice de fluxo | |
BR112015006233A2 (pt) | extração pré-absorvente de butadieno | |
BR112017028247A2 (pt) | processo para produção de um hidrocarboneto superior a partir de biomassa sólida. | |
BR112012033071A2 (pt) | processo para a oxidação de hidrocarbonetos alquilaromáticos catalisados pelos derivados de n-hidróxi | |
AR099705A1 (es) | Sistema y método para producir hidrógeno | |
BR112016002079A2 (pt) | Processo para preparação de um aditivo ácido de oximorfona, solução aquosa de aditivo ácido de oximorfona, aditivo ácido de oximorfona sólido, e, alcaloide de oximorfona sólido | |
BR112015020388A2 (pt) | processo para a conversão catalítica de uma carga de alimentação contendo sacarídeo |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
B25A | Requested transfer of rights approved |
Owner name: RESCURVE, LLC (US) |
|
B06F | Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette] | ||
B06U | Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette] | ||
B06A | Patent application procedure suspended [chapter 6.1 patent gazette] | ||
B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 18/02/2014, OBSERVADAS AS CONDICOES LEGAIS. |