FR3065174B1 - Procede de transformation d'alcool par des catalyseurs metalliques solides a base de cuivre de cerium et de barium - Google Patents

Procede de transformation d'alcool par des catalyseurs metalliques solides a base de cuivre de cerium et de barium Download PDF

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Publication number
FR3065174B1
FR3065174B1 FR1753303A FR1753303A FR3065174B1 FR 3065174 B1 FR3065174 B1 FR 3065174B1 FR 1753303 A FR1753303 A FR 1753303A FR 1753303 A FR1753303 A FR 1753303A FR 3065174 B1 FR3065174 B1 FR 3065174B1
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FR
France
Prior art keywords
barium
catalysts based
solid metallic
metallic catalysts
cerium copper
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1753303A
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English (en)
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FR3065174A1 (fr
Inventor
Amandine Cabiac
Nicolas Cadran
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Compagnie Generale des Etablissements Michelin SCA
IFP Energies Nouvelles IFPEN
Original Assignee
Compagnie Generale des Etablissements Michelin SCA
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Compagnie Generale des Etablissements Michelin SCA, IFP Energies Nouvelles IFPEN filed Critical Compagnie Generale des Etablissements Michelin SCA
Priority to FR1753303A priority Critical patent/FR3065174B1/fr
Priority to PCT/EP2018/000195 priority patent/WO2018188801A1/fr
Publication of FR3065174A1 publication Critical patent/FR3065174A1/fr
Application granted granted Critical
Publication of FR3065174B1 publication Critical patent/FR3065174B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B01J35/613—
    • B01J35/615—
    • B01J35/617—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/088—Decomposition of a metal salt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/002—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by dehydrogenation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Abstract

L'invention concerne un catalyseur comprenant du cuivre, du cérium et du barium sur un support silice, le rapport molaire Ce/Cu étant compris entre 0,1 et 2, le rapport molaire Ba/Cu étant compris entre 0,1 et 1,1 et le rapport molaire (Ce+Ba)/Cu étant compris entre 0,2 et 2,0, le procédé de préparation de ce catalyseur, ainsi qu'un procédé de production de carbonyles mettant en œuvre ce catalyseur.
FR1753303A 2017-04-14 2017-04-14 Procede de transformation d'alcool par des catalyseurs metalliques solides a base de cuivre de cerium et de barium Active FR3065174B1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
FR1753303A FR3065174B1 (fr) 2017-04-14 2017-04-14 Procede de transformation d'alcool par des catalyseurs metalliques solides a base de cuivre de cerium et de barium
PCT/EP2018/000195 WO2018188801A1 (fr) 2017-04-14 2018-04-12 Catalyseurs à base de cuivre, de cérium et de barium sur silice pour procédé de transformation d'alcool en carbonyles, leur préparation

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1753303A FR3065174B1 (fr) 2017-04-14 2017-04-14 Procede de transformation d'alcool par des catalyseurs metalliques solides a base de cuivre de cerium et de barium
FR1753303 2017-04-14

Publications (2)

Publication Number Publication Date
FR3065174A1 FR3065174A1 (fr) 2018-10-19
FR3065174B1 true FR3065174B1 (fr) 2022-01-14

Family

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Family Applications (1)

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FR1753303A Active FR3065174B1 (fr) 2017-04-14 2017-04-14 Procede de transformation d'alcool par des catalyseurs metalliques solides a base de cuivre de cerium et de barium

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Country Link
FR (1) FR3065174B1 (fr)
WO (1) WO2018188801A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113680345B (zh) * 2021-05-31 2023-08-25 陕西延长石油（集团）有限责任公司 含铜多相催化剂及其制备方法、应用

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1977750A (en) 1931-12-07 1934-10-23 Carbide & Carbon Chem Corp Process for making acetaldehyde and a catalyst therefor
DE3942064A1 (de) * 1989-10-04 1991-04-11 Henkel Kgaa Verfahren zur herstellung von saeurefesten katalysatoren fuer die direkte hydrierung von carbonsaeuren zu alkoholen
KR101270678B1 (ko) 2010-12-27 2013-06-03 금호석유화학 주식회사 에탄올로부터 아세트알데하이드를 합성하기 위한 탈수소화 반응용 구리계 촉매 및 이의 제조방법
US8962902B2 (en) * 2011-11-23 2015-02-24 Virent, Inc. Dehydrogenation of alkanols to increase yield of aromatics
US9018427B2 (en) * 2013-02-19 2015-04-28 Greenyug, Llc Production of higher alcohols
CN108430961A (zh) * 2015-09-24 2018-08-21 沙特基础全球技术有限公司 用于直接co2氢化成甲醇的混合金属氧化物催化剂

Also Published As

Publication number Publication date
WO2018188801A1 (fr) 2018-10-18
FR3065174A1 (fr) 2018-10-19

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