IN2014DN06596A - - Google Patents

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Publication number
IN2014DN06596A
IN2014DN06596A IN6596DEN2014A IN2014DN06596A IN 2014DN06596 A IN2014DN06596 A IN 2014DN06596A IN 6596DEN2014 A IN6596DEN2014 A IN 6596DEN2014A IN 2014DN06596 A IN2014DN06596 A IN 2014DN06596A
Authority
IN
India
Prior art keywords
hexanediol
reduction
hmda
catalyst
production
Prior art date
Application number
Inventor
Eric L Dias
James A W Shoemaker
Thomas R Boussie
Vincent J Murphy
Original Assignee
Rennovia Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rennovia Inc filed Critical Rennovia Inc
Publication of IN2014DN06596A publication Critical patent/IN2014DN06596A/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/156—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof
    • C07C29/157—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
    • C07C209/14—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups
    • C07C209/16—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups with formation of amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C07C29/175—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with simultaneous reduction of an oxo group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C07D307/48—Furfural
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C07D307/48—Furfural
    • C07D307/50—Preparation from natural products

Abstract

Processes are disclosed for the conversion of a carbohydrate source to hexamethylenediamine (HMDA) and to intermediates useful for the production of hexamethylenediamine and other industrial chemicals. HMDA is produced by direct reduction of a furfural substrate to 1 6 hexanediol in the presence of hydrogen and a heterogeneous reduction catalyst comprising Pt or by indirect reduction of a furfural substrate to 1 6 hexanediol wherein 1 2 6 hexanetriol is produced by reduction of the furfural substrate in the presence of hydrogen and a catalyst comprising Pt and 1 2 6 hexanediol is then converted by hydro genation in the presence of a catalyst comprising Pt to 1 6 hexanediol each process then proceding to the production of HMDA by known routes such as amination of the 1 6 hexanediol. Catalysts useful for the direct and indirect production of 1 6 hexanediol are also disclosed.
IN6596DEN2014 2012-01-18 2013-01-11 IN2014DN06596A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201261588093P 2012-01-18 2012-01-18
PCT/US2013/021315 WO2013109477A1 (en) 2012-01-18 2013-01-11 Process for production of hexamethylenediamine from 5 - hydroxymethylfurfural

Publications (1)

Publication Number Publication Date
IN2014DN06596A true IN2014DN06596A (en) 2015-05-22

Family

ID=47605786

Family Applications (1)

Application Number Title Priority Date Filing Date
IN6596DEN2014 IN2014DN06596A (en) 2012-01-18 2013-01-11

Country Status (18)

Country Link
US (7) US8853458B2 (en)
EP (2) EP3466919B1 (en)
JP (1) JP6253203B2 (en)
KR (1) KR20140113706A (en)
CN (2) CN106008163B (en)
AR (1) AR089707A1 (en)
AU (2) AU2013210005B2 (en)
BR (1) BR112014017585B1 (en)
CA (1) CA2860886A1 (en)
EA (1) EA025555B1 (en)
HK (1) HK1204318A1 (en)
IN (1) IN2014DN06596A (en)
MX (1) MX336933B (en)
MY (1) MY165219A (en)
SA (2) SA115360430B1 (en)
SG (3) SG10201700153WA (en)
WO (1) WO2013109477A1 (en)
ZA (2) ZA201405258B (en)

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CN110935447B (en) * 2018-09-25 2021-12-07 中国科学院大连化学物理研究所 Catalyst for preparing 1, 3-propylene glycol by hydrogenolysis of glycerol aqueous solution and preparation method thereof
CN109678654B (en) * 2019-01-24 2021-11-09 嘉兴学院 Method for directly producing 1,2, 6-hexanetriol by hydrogenation of 5-hydroxymethylfurfural
CN110420637B (en) * 2019-08-06 2020-10-02 北京化工大学 Method for preparing composite catalyst by using W modified carrier loaded with metal Pd and application of composite catalyst
CN110981691B (en) * 2019-12-16 2021-01-15 北京大学 Method for synthesizing 1, 6-hexanediol by using monosaccharide
CN111072490A (en) * 2019-12-16 2020-04-28 中国科学院大连化学物理研究所 Method for preparing hexamethylene diamine from hexamethylene dialdehyde based on Ni-based catalyst
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CN115353449B (en) * 2022-08-12 2024-02-20 东莞理工学院 Bivalent samarium single-electron reducing reagent, preparation method and application thereof

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Also Published As

Publication number Publication date
US9783473B2 (en) 2017-10-10
AU2013210005B2 (en) 2017-04-27
US20160068470A1 (en) 2016-03-10
AU2017208286A1 (en) 2017-08-10
CN104066710A (en) 2014-09-24
US20170144962A1 (en) 2017-05-25
AU2013210005A1 (en) 2014-07-31
SG11201404098XA (en) 2014-10-30
EP3466919A1 (en) 2019-04-10
SG10201700153WA (en) 2017-03-30
EP2804848A1 (en) 2014-11-26
US20170050906A1 (en) 2017-02-23
US9518005B2 (en) 2016-12-13
KR20140113706A (en) 2014-09-24
CN104066710B (en) 2016-06-29
EA201491289A1 (en) 2014-12-30
ZA201505891B (en) 2016-12-21
AR089707A1 (en) 2014-09-10
BR112014017585B1 (en) 2020-11-24
BR112014017585A8 (en) 2017-07-04
CN106008163A (en) 2016-10-12
HK1204318A1 (en) 2015-11-13
SA115360430B1 (en) 2015-09-03
US20130184495A1 (en) 2013-07-18
EP3466919B1 (en) 2021-10-06
ZA201405258B (en) 2016-08-31
JP2015506943A (en) 2015-03-05
US20140343323A1 (en) 2014-11-20
MX2014008638A (en) 2014-12-08
SA113340200B1 (en) 2015-07-09
WO2013109477A1 (en) 2013-07-25
US20180170844A1 (en) 2018-06-21
MX336933B (en) 2016-02-08
SG10201913670TA (en) 2020-03-30
US20160068469A1 (en) 2016-03-10
US9035109B2 (en) 2015-05-19
US8853458B2 (en) 2014-10-07
CA2860886A1 (en) 2013-07-25
MY165219A (en) 2018-03-09
EP2804848B1 (en) 2018-10-03
CN106008163B (en) 2019-10-08
EA025555B1 (en) 2017-01-30
JP6253203B2 (en) 2017-12-27
BR112014017585A2 (en) 2017-06-13

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