BR112014011930A2 - método para a produção de alcano diol - Google Patents

método para a produção de alcano diol

Info

Publication number
BR112014011930A2
BR112014011930A2 BR112014011930A BR112014011930A BR112014011930A2 BR 112014011930 A2 BR112014011930 A2 BR 112014011930A2 BR 112014011930 A BR112014011930 A BR 112014011930A BR 112014011930 A BR112014011930 A BR 112014011930A BR 112014011930 A2 BR112014011930 A2 BR 112014011930A2
Authority
BR
Brazil
Prior art keywords
diol
chromium
alkane
alkane diol
atom
Prior art date
Application number
BR112014011930A
Other languages
English (en)
Inventor
Hirotsu Kenji
Kashiwagi Kouichi
Doi Takashi
Yoshida Yasutaka
Original Assignee
Ube Industries
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ube Industries filed Critical Ube Industries
Publication of BR112014011930A2 publication Critical patent/BR112014011930A2/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8892—Manganese
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/154—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
    • C07C29/84—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation by extractive distillation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

resumo patente de invenção: "método para a produção de alcano diol". é provido pela presente invenção um método para a produção de um alcano diol, tal como o pentano-1,5-diol, com uma elevada seletividade de reação ao mesmo, ao reagir um metanol contendo um grupo éter cíclico tal como o álcool tetrahidrofurfurílico ao usar um catalisador qu não de cromo que não contém um átomo de cromo. mais especificamente, o método consiste na produção de um alcano diol que tem grupos hidróxi em ambos os terminais moleculares mostrados pela fórmula (2), inclui a reação de um metanol contendo um grupo éter cíclico mostrado pela fórmula (1) com o hidrogênio na presença de um catalisador de metal que contém um átomo de cobre, pelo menos um átomo coexistente selecionado do grupo que consiste em elementos do terceiro ao sexto períodos dos grupos ii a xiv (excluindo o cromo) na tabela periódica e os elementos lantanídeos.
BR112014011930A 2011-11-18 2012-11-19 método para a produção de alcano diol BR112014011930A2 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2011252341 2011-11-18
PCT/JP2012/079998 WO2013073704A1 (ja) 2011-11-18 2012-11-19 アルカンジオールの製造方法

Publications (1)

Publication Number Publication Date
BR112014011930A2 true BR112014011930A2 (pt) 2017-05-30

Family

ID=48429756

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112014011930A BR112014011930A2 (pt) 2011-11-18 2012-11-19 método para a produção de alcano diol

Country Status (7)

Country Link
US (2) US8940946B2 (pt)
EP (2) EP2781498A4 (pt)
JP (2) JPWO2013073704A1 (pt)
KR (1) KR20140092344A (pt)
CN (2) CN103906726A (pt)
BR (1) BR112014011930A2 (pt)
WO (2) WO2013073705A1 (pt)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2804848B1 (en) 2012-01-18 2018-10-03 Archer-Daniels-Midland Company Process for production of hexamethylenediamine from 5-hydroxymethylfurfural
CN103265400B (zh) * 2013-05-28 2016-04-06 华东理工大学 一种由呋喃或四氢呋喃衍生物制备伯醇的绿色新方法
WO2015174249A1 (ja) * 2014-05-16 2015-11-19 宇部興産株式会社 バイオマス原料を用いた１，２－ペンタンジオールの製造方法、及びその使用
CN105498787B (zh) * 2014-09-25 2018-01-23 中国石油化工股份有限公司 一种糠醛气相加氢制2‑甲基呋喃催化剂及制备方法
AU2015358536A1 (en) 2014-12-02 2017-05-18 Archer-Daniels-Midland Company Process for production of 2,5-bis-hydroxymethylfuran, 2,5-bis-hydroxymethyltetrahydrofuran, 1,6-hexanediol and 1,2,6-hexanetriol from 5-hydroxymethylfurfural
US10710949B2 (en) * 2015-07-15 2020-07-14 Archer Daniels Midland Company Copper-containing multimetallic catalysts, and method for using the same to make biobased 1,2-propanediol
CN106732602B (zh) * 2016-11-22 2019-05-03 中国科学院青岛生物能源与过程研究所 一种催化生物质糠醛直接氢解制备戊二醇的催化剂及制备方法
CN109232483A (zh) * 2018-09-07 2019-01-18 沈阳化工大学 一种以糠醛为原料制备δ-戊内脂的方法
US11566010B2 (en) * 2021-04-22 2023-01-31 Penn A. Kem, LLC Single step process for production of 2-methyltetrahydrofuran from furfuryl alcohol
CN117550952B (zh) * 2024-01-11 2024-03-22 太原理工大学 一种糠醇液相氢解合成纯1,2-戊二醇的工艺

Family Cites Families (17)

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US627293A (en) 1899-06-20 Douglas george brighton
GB627293A (en) 1946-02-26 1949-08-05 Frederick Starkey Improvements in and relating to the hydrogenation of furfural
DE918325C (de) * 1952-04-29 1954-09-23 Glanzstoff Ag Verfahren zur Hydrierung von Tetrahydrofurfurylalkohol
US2768978A (en) * 1952-08-28 1956-10-30 Du Pont Continuous process for making 1, 5-pentanediol from tetrahydrofurfuryl alcohol
JPS6239535A (ja) 1985-08-13 1987-02-20 Kuraray Co Ltd β−メチル−δ−バレロラクトンと３−メチルペンタン−１，５−ジオ−ルとを併産する方法
DE4127318A1 (de) 1991-08-17 1993-02-18 Hoechst Ag Kupfer-zinkoxid-aluminiumoxid enthaltende katalysatoren
JP3294640B2 (ja) 1992-08-24 2002-06-24 花王株式会社 アルコール製造用触媒の再生法及び該再生触媒を使用するアルコールの製造法
JP3369637B2 (ja) 1993-06-08 2003-01-20 ダイセル化学工業株式会社 グリコールの製造方法
JP3339655B2 (ja) * 1993-10-04 2002-10-28 花王株式会社 水素化反応用触媒前駆体、その製造法、及びアルコールの製造法
DE4403187C1 (de) 1994-02-02 1995-09-28 Degussa Geformter Kupfer-Katalysator für die selektive Hydrierung von Furfural zu Furfurylalkohol
EP0883590B1 (de) 1996-03-01 2001-05-02 Basf Aktiengesellschaft Verfahren zur herstellung von 1,6-hexandiol mit einer reinheit über 99 %
JP2000159705A (ja) * 1998-11-24 2000-06-13 Daicel Chem Ind Ltd ジオール類の製造方法
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JP2001316311A (ja) 2000-03-03 2001-11-13 Asahi Kasei Corp 高純度１，５−ペンタンジオール
DE10207443A1 (de) 2002-02-22 2003-09-04 Bayer Ag Verfahren und Katalysator zur Herstellung von Alkoholen
JP2005035974A (ja) * 2003-04-22 2005-02-10 Daicel Chem Ind Ltd １，６−ヘキサンジオールの製造方法
JP5336714B2 (ja) 2007-08-20 2013-11-06 株式会社日本触媒 環状エーテルの開環方法

Also Published As

Publication number Publication date
EP2781499A4 (en) 2015-06-24
CN103917509A (zh) 2014-07-09
EP2781498A1 (en) 2014-09-24
CN103906726A (zh) 2014-07-02
JPWO2013073704A1 (ja) 2015-04-02
JPWO2013073705A1 (ja) 2015-04-02
EP2781499A1 (en) 2014-09-24
US20140316167A1 (en) 2014-10-23
JP6060906B2 (ja) 2017-01-18
EP2781498A4 (en) 2015-10-14
US20140309461A1 (en) 2014-10-16
US9051234B2 (en) 2015-06-09
WO2013073704A1 (ja) 2013-05-23
WO2013073705A1 (ja) 2013-05-23
KR20140092344A (ko) 2014-07-23
US8940946B2 (en) 2015-01-27
CN103917509B (zh) 2016-08-31

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Legal Events

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B11A Dismissal acc. art.33 of ipl - examination not requested within 36 months of filing
B11Y Definitive dismissal acc. article 33 of ipl - extension of time limit for request of examination expired