BR112014014648A2 - catalisador para a síntese de mercaptanos de alquila e processo para a sua produção - Google Patents
catalisador para a síntese de mercaptanos de alquila e processo para a sua produçãoInfo
- Publication number
- BR112014014648A2 BR112014014648A2 BR112014014648A BR112014014648A BR112014014648A2 BR 112014014648 A2 BR112014014648 A2 BR 112014014648A2 BR 112014014648 A BR112014014648 A BR 112014014648A BR 112014014648 A BR112014014648 A BR 112014014648A BR 112014014648 A2 BR112014014648 A2 BR 112014014648A2
- Authority
- BR
- Brazil
- Prior art keywords
- catalyst
- alkyl mercaptans
- synthesis
- production
- mercaptans
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 5
- -1 alkyl mercaptans Chemical class 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 230000015572 biosynthetic process Effects 0.000 title abstract 2
- 238000003786 synthesis reaction Methods 0.000 title abstract 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical group 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical group [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 abstract 1
- 229910052721 tungsten Chemical group 0.000 abstract 1
- 239000010937 tungsten Chemical group 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/30—Tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
- B01J23/04—Alkali metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/31—Density
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/635—0.5-1.0 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0027—Powdering
- B01J37/0036—Grinding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/02—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/02—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols
- C07C319/08—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols by replacement of hydroxy groups or etherified or esterified hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C321/00—Thiols, sulfides, hydropolysulfides or polysulfides
- C07C321/02—Thiols having mercapto groups bound to acyclic carbon atoms
- C07C321/04—Thiols having mercapto groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0205—Impregnation in several steps
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
resumo patente de invenção: "catalisador para a síntese de mercaptanos de alquila e processo para a sua produção". a presente invenção refere-se a um catalisador que compreende um material de suporte e uma composição oxídica contendo pelo menos um metal alcalino e tungstênio, um processo para a produção de tais catalisadores e também um processo para a preparação de mercaptanos de alquila através da reação de alcanóis com sulfeto de hidrogênio, na presença de um tal catalisador.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP11194327.0A EP2606967A1 (de) | 2011-12-19 | 2011-12-19 | Katalysator zur Synthese von Alkylmercaptanen und Verfahren zu seiner Herstellung |
PCT/EP2012/073724 WO2013092129A1 (en) | 2011-12-19 | 2012-11-27 | Catalyst for the synthesis of alkyl mercaptans and process for producing it |
Publications (2)
Publication Number | Publication Date |
---|---|
BR112014014648A2 true BR112014014648A2 (pt) | 2017-06-13 |
BR112014014648A8 BR112014014648A8 (pt) | 2017-06-13 |
Family
ID=47297192
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112014014648A BR112014014648A8 (pt) | 2011-12-19 | 2012-11-27 | catalisador para a síntese de mercaptanos de alquila e processo para a sua produção |
Country Status (12)
Country | Link |
---|---|
US (1) | US9764309B2 (pt) |
EP (2) | EP2606967A1 (pt) |
JP (1) | JP6226875B2 (pt) |
KR (1) | KR102058418B1 (pt) |
CN (1) | CN104010726B (pt) |
BR (1) | BR112014014648A8 (pt) |
IN (1) | IN2014KN01202A (pt) |
MX (1) | MX2014007085A (pt) |
MY (1) | MY167904A (pt) |
RU (1) | RU2635922C2 (pt) |
SG (1) | SG11201403338UA (pt) |
WO (1) | WO2013092129A1 (pt) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR3023287B1 (fr) | 2014-07-04 | 2016-07-22 | Arkema France | Procede de preparation de methylmercaptan |
FR3023288B1 (fr) | 2014-07-04 | 2016-07-15 | Arkema France | Procede de preparation de disulfure de dimethyle |
EP3034490A1 (en) | 2014-12-19 | 2016-06-22 | Evonik Degussa GmbH | Process for the preparation of alkyl mercaptans |
EP3035046A1 (de) | 2014-12-19 | 2016-06-22 | Evonik Degussa GmbH | Verfahren zur Bestimmung eines Dialkyldisulfids |
FR3041636B1 (fr) | 2015-09-30 | 2018-11-16 | Arkema France | Procede de production de mercaptans par hydrogenolyse enzymatique de disulfures a l'aide d'hydrogene |
FR3041635B1 (fr) | 2015-09-30 | 2019-01-25 | Arkema France | Procede de production de mercaptans par hydrogenolyse enzymatique de disulfures |
EP3187261A1 (de) * | 2015-12-30 | 2017-07-05 | Evonik Degussa GmbH | Verfahren zur herstellung eines ein alkalimetall und eines übergangsmetall in oxidierter form enthaltenden katalysators |
FR3091869B1 (fr) | 2019-01-18 | 2021-01-22 | Adisseo France Sas | Procede de preparation d’un compose de formule rsh par hydrosulfuration |
EP3689451A1 (en) | 2019-01-29 | 2020-08-05 | Evonik Operations GmbH | Catalyst for the synthesis of alkyl mercaptan and process for its preparation |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2820062A (en) | 1954-08-11 | 1958-01-14 | Pure Oil Co | Preparation of organic thiols |
US3312751A (en) * | 1963-11-19 | 1967-04-04 | Mobil Oil Corp | Production of mercaptans or their olefinic derivatives |
FR2735773B1 (fr) * | 1995-06-23 | 1997-09-12 | Rhone Poulenc Nutrition Animal | Procede de preparation de methylmercaptan |
DE19639520C2 (de) | 1996-09-26 | 1998-10-01 | Degussa | Katalysator, Verfahren zu seiner Herstellung und Verwendung zur Synthese von Alkylmercaptanen |
RU2120822C1 (ru) * | 1997-09-18 | 1998-10-27 | Институт катализа им.Г.К.Борескова СО РАН | Катализатор синтеза метилмеркаптана |
WO2004043583A2 (en) * | 2002-11-11 | 2004-05-27 | Conocophillips Company | Improved supports for high surface area catalysts |
US7229946B2 (en) * | 2003-03-24 | 2007-06-12 | Saudi Basic Industries Corporation | Catalyst composition for the selective conversion of alkanes to unsaturated carboxylic acids, method of making and method of using thereof |
DE10319739A1 (de) * | 2003-04-30 | 2004-11-18 | Basf Ag | Katalysator zur Herstellung von Methylmercaptan aus Methanol und Schwefelwasserstoff |
DE10338887A1 (de) | 2003-08-23 | 2005-03-17 | Degussa Ag | Katalysator zur Synthese von Alkylmercaptan und Verfahren zu seiner Herstellung |
DE102004037739A1 (de) * | 2004-08-04 | 2006-03-16 | Degussa Ag | Wolframat enthaltende Katalysatoren zur Synthese von Alkylmercaptan und Verfahren zu ihrer Herstellung |
JP4499513B2 (ja) * | 2004-09-03 | 2010-07-07 | 株式会社日本触媒 | 窒素酸化物および臭気成分を含む排ガスの処理方法 |
US20060199730A1 (en) * | 2005-03-02 | 2006-09-07 | Seely Michael J | Composition and method for improving density and hardness of fluid bed catalysts |
US20090118531A1 (en) * | 2006-04-28 | 2009-05-07 | Basf Aktiengesellschaft | Novel supported catalyst for ammoxidation |
DE102007004351A1 (de) * | 2007-01-29 | 2008-07-31 | Evonik Degussa Gmbh | Neue Katalysatoren und Verfahren zur Dehydratisierung von Glycerin |
KR101207962B1 (ko) * | 2007-01-31 | 2012-12-04 | 오사카 유니버시티 | 고상계 산화반응 혼합물 |
EP1982764A1 (en) * | 2007-04-17 | 2008-10-22 | Evonik Degussa GmbH | Catalyst for the preparation of methyl mercaptan |
DE102007024576A1 (de) * | 2007-05-25 | 2009-05-20 | Evonik Degussa Gmbh | Verfahren zur kontinuierlichen Herstellung von Methylmercaptan aus kohlenstoff- und wasserstoffhaltigen Verbindungen |
JP5493928B2 (ja) | 2009-07-10 | 2014-05-14 | 三菱化学株式会社 | 炭化水素の製造方法 |
EP2488298A4 (en) * | 2009-10-15 | 2013-06-19 | Nippon Kayaku Kk | PROCESS FOR PREPARING A CATALYST FOR USE IN THE PREPARATION OF UNSATURATED ALDEHYDE AND / OR UNSATURATED CARBOXYLIC ACID BY DEHYDRATING THE REACTION OF GLYCERIN AND THE CATALYZER OBTAINED THEREON |
-
2011
- 2011-12-19 EP EP11194327.0A patent/EP2606967A1/de not_active Withdrawn
-
2012
- 2012-11-27 MX MX2014007085A patent/MX2014007085A/es unknown
- 2012-11-27 MY MYPI2014001794A patent/MY167904A/en unknown
- 2012-11-27 CN CN201280062865.XA patent/CN104010726B/zh not_active Expired - Fee Related
- 2012-11-27 JP JP2014547808A patent/JP6226875B2/ja not_active Expired - Fee Related
- 2012-11-27 SG SG11201403338UA patent/SG11201403338UA/en unknown
- 2012-11-27 WO PCT/EP2012/073724 patent/WO2013092129A1/en active Application Filing
- 2012-11-27 KR KR1020147016327A patent/KR102058418B1/ko active IP Right Grant
- 2012-11-27 RU RU2014129624A patent/RU2635922C2/ru not_active IP Right Cessation
- 2012-11-27 US US14/365,801 patent/US9764309B2/en not_active Expired - Fee Related
- 2012-11-27 EP EP12797820.3A patent/EP2794095A1/en not_active Withdrawn
- 2012-11-27 IN IN1202KON2014 patent/IN2014KN01202A/en unknown
- 2012-11-27 BR BR112014014648A patent/BR112014014648A8/pt not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
MY167904A (en) | 2018-09-26 |
EP2794095A1 (en) | 2014-10-29 |
JP2015506825A (ja) | 2015-03-05 |
MX2014007085A (es) | 2014-07-22 |
CN104010726A (zh) | 2014-08-27 |
RU2014129624A (ru) | 2016-02-10 |
SG11201403338UA (en) | 2014-07-30 |
KR20140104962A (ko) | 2014-08-29 |
CN104010726B (zh) | 2017-09-12 |
US20140357897A1 (en) | 2014-12-04 |
KR102058418B1 (ko) | 2019-12-24 |
EP2606967A1 (de) | 2013-06-26 |
JP6226875B2 (ja) | 2017-11-08 |
US9764309B2 (en) | 2017-09-19 |
WO2013092129A1 (en) | 2013-06-27 |
IN2014KN01202A (pt) | 2015-10-16 |
RU2635922C2 (ru) | 2017-11-17 |
BR112014014648A8 (pt) | 2017-06-13 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
B06F | Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette] | ||
B06T | Formal requirements before examination [chapter 6.20 patent gazette] | ||
B11E | Dismissal acc. art. 34 of ipl - requirements for examination incomplete | ||
B11T | Dismissal of application maintained [chapter 11.20 patent gazette] | ||
B350 | Update of information on the portal [chapter 15.35 patent gazette] |