BR112012023838A2 - composição catalítica e processo para produzir acrilontrila, acetonitrila e ácido cianídrico - Google Patents
composição catalítica e processo para produzir acrilontrila, acetonitrila e ácido cianídricoInfo
- Publication number
- BR112012023838A2 BR112012023838A2 BR112012023838A BR112012023838A BR112012023838A2 BR 112012023838 A2 BR112012023838 A2 BR 112012023838A2 BR 112012023838 A BR112012023838 A BR 112012023838A BR 112012023838 A BR112012023838 A BR 112012023838A BR 112012023838 A2 BR112012023838 A2 BR 112012023838A2
- Authority
- BR
- Brazil
- Prior art keywords
- acetonitrile
- hydrocyanic acid
- acrylonitrile
- catalytic composition
- producing acrylonitrile
- Prior art date
Links
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 title abstract 15
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 title abstract 8
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 4
- 230000003197 catalytic effect Effects 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/031—Precipitation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8871—Rare earth metals or actinides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8876—Arsenic, antimony or bismuth
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8878—Chromium
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- B01J35/30—
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
- C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
- C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
- C07C255/02—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms of an acyclic and saturated carbon skeleton
- C07C255/03—Mononitriles
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
- C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
- C07C255/06—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms of an acyclic and unsaturated carbon skeleton
- C07C255/07—Mononitriles
- C07C255/08—Acrylonitrile; Methacrylonitrile
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
- B01J2523/10—Constitutive chemical elements of heterogeneous catalysts of Group I (IA or IB) of the Periodic Table
- B01J2523/12—Sodium
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Abstract
composição catalítica e processo para produzir acrilontrila, acetonitrila e ácido cianídrico um processo e catalisador novo para a produção de acrilonitrila, acetonitrila e ácido caracterizado pelos rendimentos relativos de acrilonitrila, acetonitrila e ácido cianídrico produzidos no processo e pelo catalisador, que são definidos pelo seguinte: <244> = [(%an + (3 *# hcn) + (1,5 *% acn)) <sym> % pc] * 100 em que: % an é o rendimento em acrilonitrila e % an<242>81, %hcn é o rendimento em ácido cianídrico, %acn é o rendimento em acetonitrila, %pc é a conversão de propileno e <244> é maior do que 100.
Applications Claiming Priority (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/661,716 | 2010-03-23 | ||
US12/661,720 | 2010-03-23 | ||
US12/661,705 US8153546B2 (en) | 2010-03-23 | 2010-03-23 | Mixed metal oxide ammoxidation catalysts |
US12/661,720 US8455388B2 (en) | 2010-03-23 | 2010-03-23 | Attrition resistant mixed metal oxide ammoxidation catalysts |
US12/661,705 | 2010-03-23 | ||
US12/661,716 US8258073B2 (en) | 2010-03-23 | 2010-03-23 | Process for preparing improved mixed metal oxide ammoxidation catalysts |
US13/065,134 US8420566B2 (en) | 2010-03-23 | 2011-03-15 | High efficiency ammoxidation process and mixed metal oxide catalysts |
US13/065,134 | 2011-03-15 | ||
PCT/US2011/000499 WO2011119203A1 (en) | 2010-03-23 | 2011-03-18 | High efficiency ammoxidation process and mixed metal oxide catalysts |
Publications (2)
Publication Number | Publication Date |
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BR112012023838A2 true BR112012023838A2 (pt) | 2017-08-08 |
BR112012023838B1 BR112012023838B1 (pt) | 2023-10-31 |
Family
ID=44063963
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112012023838-8A BR112012023838B1 (pt) | 2010-03-23 | 2011-03-18 | Composição catalítica e processo para produzir acrilonitrila,acetonitrila e ácido cianídrico |
Country Status (10)
Country | Link |
---|---|
EP (1) | EP2550097B1 (pt) |
JP (3) | JP2013527141A (pt) |
KR (1) | KR101772249B1 (pt) |
CN (1) | CN102892496B (pt) |
BR (1) | BR112012023838B1 (pt) |
MX (1) | MX2012010925A (pt) |
MY (1) | MY162343A (pt) |
RU (1) | RU2575933C2 (pt) |
TW (1) | TWI579044B (pt) |
WO (1) | WO2011119203A1 (pt) |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2550097B1 (en) * | 2010-03-23 | 2020-11-11 | INEOS Europe AG | High efficiency ammoxidation process and mixed metal oxide catalysts |
US8153546B2 (en) * | 2010-03-23 | 2012-04-10 | Ineos Usa Llc | Mixed metal oxide ammoxidation catalysts |
US8258073B2 (en) * | 2010-03-23 | 2012-09-04 | Ineos Usa Llc | Process for preparing improved mixed metal oxide ammoxidation catalysts |
US9433929B2 (en) * | 2011-09-21 | 2016-09-06 | Ineos Europe Ag | Mixed metal oxide catalysts |
US8835666B2 (en) * | 2012-11-26 | 2014-09-16 | Ineos Usa Llc | Pre calcination additives for mixed metal oxide ammoxidation catalysts |
WO2015183284A1 (en) * | 2014-05-29 | 2015-12-03 | Ineos Usa, Llc | Improved selective ammoxidation catalysts |
US10315969B2 (en) | 2014-06-10 | 2019-06-11 | Lg Chem, Ltd. | Method of preparing multicomponent composite metal oxide catalyst |
US9844769B2 (en) * | 2014-12-17 | 2017-12-19 | Ineos Europe Ag | Mixed metal oxide ammoxidation catalysts |
CN104894488B (zh) * | 2015-04-28 | 2017-07-28 | 广西大学 | 一种含硼铬钼镍耐磨合金及其制备方法 |
EP3409357B1 (en) * | 2016-01-25 | 2022-06-01 | Asahi Kasei Kabushiki Kaisha | Fluid bed ammoxidation reaction catalyst, and acrylonitrile production method |
CN110124679A (zh) * | 2016-01-25 | 2019-08-16 | 旭化成株式会社 | 流化床氨氧化反应催化剂及丙烯腈的制造方法 |
KR20180121625A (ko) | 2016-06-14 | 2018-11-07 | 아사히 가세이 가부시키가이샤 | 암모산화용 촉매의 제조 방법 및 아크릴로니트릴의 제조 방법 |
US10626082B2 (en) * | 2016-10-11 | 2020-04-21 | Ineos Europe Ag | Ammoxidation catalyst with selective co-product HCN production |
US10343148B2 (en) * | 2016-12-01 | 2019-07-09 | Southern Research Institute | Mixed metal oxide catalysts and methods for olefin production in an oxidative dehydrogenation reaction process |
WO2018141826A1 (en) * | 2017-02-06 | 2018-08-09 | Haldor Topsøe A/S | Production of acetonitrile and/or hydrogen cyanide from ammonia and methanol |
WO2019187840A1 (ja) * | 2018-03-30 | 2019-10-03 | 旭化成株式会社 | 触媒、触媒の製造方法、アクリロニトリルの製造方法 |
WO2020039998A1 (ja) * | 2018-08-23 | 2020-02-27 | 旭化成株式会社 | アンモ酸化用触媒の製造方法、及び、アクリロニトリルの製造方法 |
WO2020213361A1 (ja) * | 2019-04-15 | 2020-10-22 | 旭化成株式会社 | 触媒、触媒の製造方法、アクリロニトリルの製造方法 |
US20220153689A1 (en) * | 2019-04-16 | 2022-05-19 | Asahi Kasei Kabushiki Kaisha | Catalyst, method for producing catalyst, and method for producing acrylonitrile |
WO2021066409A1 (ko) * | 2019-09-30 | 2021-04-08 | 주식회사 엘지화학 | 프로필렌의 암모산화용 촉매, 이의 제조 방법, 이를 이용한 프로필렌의 암모산화 방법 |
WO2021066411A1 (ko) * | 2019-09-30 | 2021-04-08 | 주식회사 엘지화학 | 프로필렌의 암모산화용 촉매, 이의 제조 방법, 및 이를 이용한 프로필렌의 암모산화 방법 |
KR102519507B1 (ko) * | 2019-09-30 | 2023-04-07 | 주식회사 엘지화학 | 프로필렌의 암모산화용 촉매, 이의 제조 방법, 및 이를 이용한 프로필렌의 암모산화 방법 |
WO2021066410A1 (ko) * | 2019-09-30 | 2021-04-08 | 주식회사 엘지화학 | 프로필렌의 암모산화용 촉매, 이의 제조 방법, 이를 이용한 프로필렌의 암모산화 방법 |
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JPS5245692B2 (pt) | 1973-10-16 | 1977-11-17 | ||
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WO2004050240A1 (en) * | 2002-12-02 | 2004-06-17 | The Standard Oil Company | Mixed oxide catalyst of k, cs, ce, cr, co, ni, fe, bi and mo for the manufacture of acrylonitrile |
CN100342969C (zh) * | 2002-12-02 | 2007-10-17 | 标准石油公司 | 用于制造丙烯腈的Rb、Ce、Cr、Ni、Fe、Bi及Mo的混合氧化物催化剂 |
US7071140B2 (en) * | 2002-12-02 | 2006-07-04 | The Standard Oil Company | Catalyst for the manufacture of acrylonitrile |
EP2075064B1 (en) * | 2006-10-26 | 2013-12-11 | Mitsubishi Rayon Co., Ltd. | Fluidized-bed catalyst for producing acrylonitrile and process for producing acrylonitrile |
JP5042658B2 (ja) * | 2007-02-14 | 2012-10-03 | ダイヤニトリックス株式会社 | アクリロニトリル製造用触媒の製造方法、およびアクリロニトリルの製造方法 |
JP5364884B2 (ja) * | 2008-02-25 | 2013-12-11 | 三菱レイヨン株式会社 | (メタ)アクリロニトリルの製造方法 |
JP5011177B2 (ja) * | 2008-03-18 | 2012-08-29 | ダイヤニトリックス株式会社 | アクリロニトリル合成用触媒の製造方法およびアクリロニトリルの製造方法 |
JP5011178B2 (ja) * | 2008-03-18 | 2012-08-29 | ダイヤニトリックス株式会社 | アクリロニトリル合成用触媒の製造方法およびアクリロニトリルの製造方法 |
JP5361034B2 (ja) * | 2008-05-29 | 2013-12-04 | 旭化成ケミカルズ株式会社 | 流動床用アンモ酸化触媒及びそれを用いたアクリロニトリル又はメタクリロニトリルの製造方法 |
EP2550097B1 (en) * | 2010-03-23 | 2020-11-11 | INEOS Europe AG | High efficiency ammoxidation process and mixed metal oxide catalysts |
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2011
- 2011-03-18 EP EP11712356.2A patent/EP2550097B1/en active Active
- 2011-03-18 CN CN201180024206.2A patent/CN102892496B/zh active Active
- 2011-03-18 MX MX2012010925A patent/MX2012010925A/es active IP Right Grant
- 2011-03-18 JP JP2013501242A patent/JP2013527141A/ja active Pending
- 2011-03-18 MY MYPI2012004180A patent/MY162343A/en unknown
- 2011-03-18 BR BR112012023838-8A patent/BR112012023838B1/pt active IP Right Grant
- 2011-03-18 WO PCT/US2011/000499 patent/WO2011119203A1/en active Application Filing
- 2011-03-18 RU RU2012143494/04A patent/RU2575933C2/ru active
- 2011-03-18 KR KR1020127027519A patent/KR101772249B1/ko active IP Right Grant
- 2011-03-22 TW TW100109691A patent/TWI579044B/zh active
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2015
- 2015-12-10 JP JP2015241104A patent/JP6306559B2/ja active Active
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2018
- 2018-01-25 JP JP2018010487A patent/JP2018104440A/ja not_active Withdrawn
Also Published As
Publication number | Publication date |
---|---|
KR20130007627A (ko) | 2013-01-18 |
JP2016040326A (ja) | 2016-03-24 |
CN102892496B (zh) | 2015-04-29 |
JP6306559B2 (ja) | 2018-04-04 |
EP2550097A1 (en) | 2013-01-30 |
CN102892496A (zh) | 2013-01-23 |
TWI579044B (zh) | 2017-04-21 |
WO2011119203A1 (en) | 2011-09-29 |
JP2013527141A (ja) | 2013-06-27 |
MX2012010925A (es) | 2012-12-17 |
MY162343A (en) | 2017-06-15 |
JP2018104440A (ja) | 2018-07-05 |
EP2550097B1 (en) | 2020-11-11 |
KR101772249B1 (ko) | 2017-08-29 |
RU2575933C2 (ru) | 2016-02-27 |
RU2012143494A (ru) | 2014-04-27 |
BR112012023838B1 (pt) | 2023-10-31 |
TW201138962A (en) | 2011-11-16 |
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