BR112012000169A2 - Catalisadores de hidrossililação - Google Patents
Catalisadores de hidrossililaçãoInfo
- Publication number
- BR112012000169A2 BR112012000169A2 BR112012000169A BR112012000169A BR112012000169A2 BR 112012000169 A2 BR112012000169 A2 BR 112012000169A2 BR 112012000169 A BR112012000169 A BR 112012000169A BR 112012000169 A BR112012000169 A BR 112012000169A BR 112012000169 A2 BR112012000169 A2 BR 112012000169A2
- Authority
- BR
- Brazil
- Prior art keywords
- hydrosilation catalyst
- manganese
- cobalt
- iron
- efficient
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 3
- 238000006459 hydrosilylation reaction Methods 0.000 title abstract 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 2
- 239000010941 cobalt Substances 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- RAABOESOVLLHRU-UHFFFAOYSA-N diazene Chemical compound N=N RAABOESOVLLHRU-UHFFFAOYSA-N 0.000 abstract 1
- 229910000071 diazene Inorganic materials 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract 1
- 150000002815 nickel Chemical class 0.000 abstract 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
- C07F7/1804—Compounds having Si-O-C linkages
- C07F7/1872—Preparation; Treatments not provided for in C07F7/20
- C07F7/1876—Preparation; Treatments not provided for in C07F7/20 by reactions involving the formation of Si-C linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/02—Iron compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/02—Iron compounds
- C07F15/025—Iron compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/11—Compounds covalently bound to a solid support
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S71/00—Chemistry: fertilizers
- Y10S71/02—Chelating agent
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Pyridine Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
CATALISADORES DE HIDROSSILILAÇÃO. A presente invenção refere-se a complexos de manganês,ferro, cobalto,ou níquel contendo ligantes de terdentato piridina diimina e seu uso como catalisadoresde hidrossililação eficientes e seletivos.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US22459809P | 2009-07-10 | 2009-07-10 | |
US12/832,627 US8236915B2 (en) | 2009-07-10 | 2010-07-08 | Hydrosilylation catalysts |
PCT/US2010/041487 WO2011006044A2 (en) | 2009-07-10 | 2010-07-09 | Hydrosilylation catalysts |
Publications (1)
Publication Number | Publication Date |
---|---|
BR112012000169A2 true BR112012000169A2 (pt) | 2017-08-22 |
Family
ID=43427966
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112012000169A BR112012000169A2 (pt) | 2009-07-10 | 2010-07-09 | Catalisadores de hidrossililação |
Country Status (8)
Country | Link |
---|---|
US (1) | US8236915B2 (pt) |
EP (1) | EP2451820B1 (pt) |
JP (2) | JP6059987B2 (pt) |
KR (2) | KR20120023149A (pt) |
CN (3) | CN109289923B (pt) |
BR (1) | BR112012000169A2 (pt) |
TW (1) | TWI492789B (pt) |
WO (1) | WO2011006044A2 (pt) |
Families Citing this family (46)
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US8765987B2 (en) | 2010-11-24 | 2014-07-01 | Cornell University | In-situ activation of metal complexes containing terdentate nitrogen ligands used as hydrosilylation catalysts |
KR101896423B1 (ko) | 2010-11-24 | 2018-10-04 | 모멘티브 퍼포먼스 머티리얼즈 인크. | 폴리불포화 화합물의 금속-촉매 모노-하이드로실릴화 |
BR112013012742A2 (pt) | 2010-11-24 | 2016-09-13 | Univ Cornell | catalisadores de hidrossililação |
US9394325B2 (en) * | 2011-08-19 | 2016-07-19 | The Trustees Of Princeton University | Enantiopure base-metal catalysts for asymmetric catalysis and bis(imino)pyridine iron alkyl complexes for catalysis |
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EP2785454B1 (en) * | 2011-12-01 | 2019-10-09 | Dow Silicones Corporation | Hydrosilylation reaction catalysts and curable compositions and methods for their preparation and use |
US9782763B2 (en) * | 2011-12-14 | 2017-10-10 | Momentive Performance Materials Inc. | Non-precious metal-based hyrdosilylation catalysts exhibiting improved selectivity |
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JP6125222B2 (ja) * | 2012-08-16 | 2017-05-10 | モメンティブ パフォーマンス マテリアルズ インコーポレイテッド | コバルト触媒を用いる脱水素シリル化および架橋 |
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US9371340B2 (en) | 2012-08-16 | 2016-06-21 | Momentive Performance Materials Inc. | Dehydrogenative silylation, hydrosilylation and crosslinking using cobalt catalysts |
FR3000069B1 (fr) | 2012-12-21 | 2015-02-06 | Bluestar Silicones France | Procede d'hydrosilylation d'un siloxane photocatalyse par un compose polyoxometallate |
US9890182B2 (en) * | 2013-05-06 | 2018-02-13 | Momentive Performance Materials Inc. | Selective 1,2-hydrosilylation of terminally unsaturated 1,3-dienes using iron catalysts |
US9371339B2 (en) | 2013-05-06 | 2016-06-21 | Momentive Performance Materials Inc. | Saturated and unsaturated silahydrocarbons via iron and cobalt pyridine diimine catalyzed olefin silylation |
EP2996804B1 (en) | 2013-05-15 | 2020-12-30 | Momentive Performance Materials Inc. | Activation of metal salts with silylhydrides and their use in hydrosilylation reactions |
US9708355B2 (en) | 2013-06-12 | 2017-07-18 | Arizona Board Of Regents On Behalf Of Arizona State University | First-row transition metal hydrogenation and hydrosilylation catalysts |
WO2015023328A1 (en) | 2013-08-14 | 2015-02-19 | Momentive Performance Materials Inc. | Reusable homogeneous cobalt pyridine dimine catalysts for dehydrogenative silylation and tandem dehydrogenative-silylation-hydrogenation |
KR20160065850A (ko) * | 2013-10-02 | 2016-06-09 | 바스프 에스이 | 분산제로서의 폴리(옥시알킬렌)옥시- 및/또는 폴리(옥시알킬렌)아미노알킬트리알콕시실란의 용도 |
EP3071552A1 (en) | 2013-11-19 | 2016-09-28 | The Trustees of Princeton University | Hydroboration and borylation with cobalt catalysts |
TW201524604A (zh) | 2013-11-19 | 2015-07-01 | Momentive Performance Mat Inc | 使用鈷觸媒之脫氫甲矽烷化、矽氫化及交聯 |
US9381505B2 (en) | 2013-11-19 | 2016-07-05 | Momentive Performance Materials Inc. | Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation |
CN105916871B (zh) * | 2013-11-19 | 2019-08-20 | 莫门蒂夫性能材料股份有限公司 | 钴催化剂及其用于氢化硅烷化和脱氢硅烷化的应用 |
EP3140037A4 (en) * | 2014-05-08 | 2018-02-14 | Momentive Performance Materials Inc. | Dialkyl cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation |
WO2016024611A1 (ja) | 2014-08-12 | 2016-02-18 | 国立大学法人九州大学 | ヒドロシリル化反応触媒 |
WO2016024607A1 (ja) | 2014-08-12 | 2016-02-18 | 国立大学法人九州大学 | ヒドロシリル化反応触媒 |
JP6761997B2 (ja) * | 2014-08-19 | 2020-09-30 | 国立大学法人九州大学 | ヒドロシリル化鉄触媒 |
CN104478919B (zh) * | 2014-11-18 | 2018-02-02 | 浙江大学 | 一种合成手性硅烷化合物的方法 |
EP3233800A4 (en) | 2014-12-19 | 2018-08-01 | Dow Silicones Corporation | Ligand components, associated reaction products, activated reaction products, hydrosilylation catalysts and hydrosilylation curable compositions including the ligand components, and associated methods for preparing same |
EP3323505A4 (en) | 2015-07-14 | 2019-03-20 | Kyushu University, National University Corporation | hydrosilylation reaction catalyst |
WO2017019473A1 (en) * | 2015-07-24 | 2017-02-02 | Momentive Performance Materials Inc. | Dehydrogenative silylation, hydrosilylation and crosslinking using pyridinediimine cobalt carboxylate catalysts |
JP6585298B2 (ja) * | 2015-12-07 | 2019-10-02 | ダウ シリコーンズ コーポレーション | イリジウム錯体触媒を用いたカルボン酸アルケニルエステル及び水素終端オルガノシロキサンオリゴマーのヒドロシリル化のための方法及び組成物 |
WO2017126562A1 (ja) | 2016-01-22 | 2017-07-27 | 信越化学工業株式会社 | 新規イソシアニド化合物及びヒドロシリル化反応触媒 |
JP6933835B2 (ja) * | 2017-01-25 | 2021-09-08 | 公立大学法人大阪 | 鉄錯体触媒を用いたカルボニル化合物のヒドロシリル化反応によるアルコキシシランの製造方法 |
JP6786034B2 (ja) | 2017-02-28 | 2020-11-18 | 国立大学法人九州大学 | ヒドロシリル化反応、水素化反応およびヒドロシラン還元反応用触媒 |
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JP2019064950A (ja) | 2017-09-29 | 2019-04-25 | 国立大学法人九州大学 | コバルト錯体、その製造方法およびヒドロシリル化反応用触媒 |
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CN109046463B (zh) * | 2018-08-16 | 2021-05-04 | 中山大学 | 双齿氮杂卡宾锰催化剂及其制备方法和烷基化合成应用 |
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2010
- 2010-07-08 US US12/832,627 patent/US8236915B2/en active Active
- 2010-07-09 EP EP10744762.5A patent/EP2451820B1/en active Active
- 2010-07-09 CN CN201811054969.1A patent/CN109289923B/zh active Active
- 2010-07-09 BR BR112012000169A patent/BR112012000169A2/pt not_active Application Discontinuation
- 2010-07-09 CN CN201510530811.7A patent/CN105085580B/zh active Active
- 2010-07-09 WO PCT/US2010/041487 patent/WO2011006044A2/en active Application Filing
- 2010-07-09 CN CN201080030539.1A patent/CN102471358B/zh active Active
- 2010-07-09 KR KR1020117031667A patent/KR20120023149A/ko active Application Filing
- 2010-07-09 KR KR1020147035506A patent/KR101710043B1/ko active IP Right Grant
- 2010-07-09 JP JP2012519752A patent/JP6059987B2/ja active Active
- 2010-07-12 TW TW099122882A patent/TWI492789B/zh active
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Also Published As
Publication number | Publication date |
---|---|
EP2451820B1 (en) | 2020-03-18 |
EP2451820A2 (en) | 2012-05-16 |
KR20150013833A (ko) | 2015-02-05 |
JP2012532884A (ja) | 2012-12-20 |
KR101710043B1 (ko) | 2017-03-08 |
CN109289923A (zh) | 2019-02-01 |
CN105085580B (zh) | 2018-10-09 |
CN109289923B (zh) | 2021-09-07 |
TWI492789B (zh) | 2015-07-21 |
JP6059987B2 (ja) | 2017-01-11 |
JP6389220B2 (ja) | 2018-09-12 |
TW201111040A (en) | 2011-04-01 |
CN105085580A (zh) | 2015-11-25 |
KR20120023149A (ko) | 2012-03-12 |
JP2017078068A (ja) | 2017-04-27 |
WO2011006044A3 (en) | 2011-03-03 |
WO2011006044A2 (en) | 2011-01-13 |
US8236915B2 (en) | 2012-08-07 |
CN102471358A (zh) | 2012-05-23 |
CN102471358B (zh) | 2015-09-30 |
US20110009573A1 (en) | 2011-01-13 |
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