BR112013012742A2 - catalisadores de hidrossililação - Google Patents
catalisadores de hidrossililaçãoInfo
- Publication number
- BR112013012742A2 BR112013012742A2 BR112013012742A BR112013012742A BR112013012742A2 BR 112013012742 A2 BR112013012742 A2 BR 112013012742A2 BR 112013012742 A BR112013012742 A BR 112013012742A BR 112013012742 A BR112013012742 A BR 112013012742A BR 112013012742 A2 BR112013012742 A2 BR 112013012742A2
- Authority
- BR
- Brazil
- Prior art keywords
- hydrosilylation catalysts
- catalysts
- hydrosilylation
- imino
- quinoline
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 3
- 238000006459 hydrosilylation reaction Methods 0.000 title abstract 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- 239000011230 binding agent Substances 0.000 abstract 1
- 239000012018 catalyst precursor Substances 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract 1
- 150000002815 nickel Chemical class 0.000 abstract 1
- XNMAMTNGGHXEQF-UHFFFAOYSA-N quinoline-2,8-diimine Chemical compound C1=CC(=N)C2=NC(=N)C=CC2=C1 XNMAMTNGGHXEQF-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/02—Iron compounds
- C07F15/025—Iron compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/02—Iron compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0803—Compounds with Si-C or Si-Si linkages
- C07F7/0825—Preparations of compounds not comprising Si-Si or Si-cyano linkages
- C07F7/0827—Syntheses with formation of a Si-C bond
- C07F7/0829—Hydrosilylation reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0834—Compounds having one or more O-Si linkage
- C07F7/0838—Compounds with one or more Si-O-Si sequences
- C07F7/0872—Preparation and treatment thereof
- C07F7/0876—Reactions involving the formation of bonds to a Si atom of a Si-O-Si sequence other than a bond of the Si-O-Si linkage
- C07F7/0878—Si-C bond
- C07F7/0879—Hydrosilylation reactions
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
catalisadores de hidrossililação. descritos aqui são manganês, ferro, cobalto, ou complexos de níquel que contêm ligantes de 2,8-bis(imino)quinolina e seu uso como catalisadores ou precursores de catalisadores para reações de hidrossililação.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US41709310P | 2010-11-24 | 2010-11-24 | |
US41708410P | 2010-11-24 | 2010-11-24 | |
PCT/US2011/061751 WO2012071359A1 (en) | 2010-11-24 | 2011-11-22 | Hydrosilylation catalyst |
Publications (1)
Publication Number | Publication Date |
---|---|
BR112013012742A2 true BR112013012742A2 (pt) | 2016-09-13 |
Family
ID=45319391
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112013012742A BR112013012742A2 (pt) | 2010-11-24 | 2011-11-22 | catalisadores de hidrossililação |
Country Status (8)
Country | Link |
---|---|
US (1) | US8637626B2 (pt) |
EP (1) | EP2643335B1 (pt) |
JP (1) | JP2014503507A (pt) |
KR (1) | KR20140042766A (pt) |
CN (1) | CN103347889A (pt) |
BR (1) | BR112013012742A2 (pt) |
TW (1) | TWI450903B (pt) |
WO (1) | WO2012071359A1 (pt) |
Families Citing this family (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9139699B2 (en) * | 2012-10-04 | 2015-09-22 | Dow Corning Corporation | Metal containing condensation reaction catalysts, methods for preparing the catalysts, and compositions containing the catalysts |
US9782763B2 (en) | 2011-12-14 | 2017-10-10 | Momentive Performance Materials Inc. | Non-precious metal-based hyrdosilylation catalysts exhibiting improved selectivity |
US8927674B2 (en) | 2012-08-16 | 2015-01-06 | Princeton University | Dehydrogenative silylation and crosslinking using cobalt catalysts |
US9371340B2 (en) | 2012-08-16 | 2016-06-21 | Momentive Performance Materials Inc. | Dehydrogenative silylation, hydrosilylation and crosslinking using cobalt catalysts |
US9447125B2 (en) | 2012-08-16 | 2016-09-20 | Momentive Performance Materials Inc. | Reusable homogeneous cobalt pyridine diimine catalysts for dehydrogenative silylation and tandem dehydrogenative-silylation-hydrogenation |
US9890182B2 (en) | 2013-05-06 | 2018-02-13 | Momentive Performance Materials Inc. | Selective 1,2-hydrosilylation of terminally unsaturated 1,3-dienes using iron catalysts |
US9371339B2 (en) | 2013-05-06 | 2016-06-21 | Momentive Performance Materials Inc. | Saturated and unsaturated silahydrocarbons via iron and cobalt pyridine diimine catalyzed olefin silylation |
WO2014186513A1 (en) * | 2013-05-15 | 2014-11-20 | Momentive Performance Materials Inc. | Activation of metal salts with silylhydrides and their use in hydrosilylation reactions |
WO2014201082A1 (en) | 2013-06-12 | 2014-12-18 | Arizona Board Of Regents On Behalf Of Arizona State University | First-row transition metal hydrogenation and hydrosilylation catalysts |
WO2015023328A1 (en) * | 2013-08-14 | 2015-02-19 | Momentive Performance Materials Inc. | Reusable homogeneous cobalt pyridine dimine catalysts for dehydrogenative silylation and tandem dehydrogenative-silylation-hydrogenation |
CN105916870A (zh) | 2013-11-19 | 2016-08-31 | 莫门蒂夫性能材料股份有限公司 | 钴催化剂及它们用于氢化硅烷化和脱氢硅烷化的用途 |
JP6486924B2 (ja) | 2013-11-19 | 2019-03-20 | モメンティブ パフォーマンス マテリアルズ インコーポレイテッド | コバルト触媒並びにヒドロシリル化及び脱水素シリル化のためのその使用 |
JP6486925B2 (ja) * | 2013-11-19 | 2019-03-20 | モメンティブ パフォーマンス マテリアルズ インコーポレイテッド | コバルト触媒並びにヒドロシリル化及び脱水素シリル化のためのその使用 |
US20170190722A1 (en) * | 2014-05-08 | 2017-07-06 | Momentive Performance Materials Inc. | Dialkyl cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation |
KR102443609B1 (ko) | 2014-08-12 | 2022-09-15 | 고쿠리쓰다이가쿠호진 규슈다이가쿠 | 하이드로실릴화 반응 촉매 |
JP6515930B2 (ja) | 2014-08-12 | 2019-05-22 | 国立大学法人九州大学 | ヒドロシリル化反応触媒 |
JP6761997B2 (ja) | 2014-08-19 | 2020-09-30 | 国立大学法人九州大学 | ヒドロシリル化鉄触媒 |
KR102564637B1 (ko) | 2015-07-14 | 2023-08-08 | 고쿠리쓰다이가쿠호진 규슈다이가쿠 | 하이드로실릴화 반응 촉매 |
JP6620823B2 (ja) | 2016-01-22 | 2019-12-18 | 信越化学工業株式会社 | 新規イソシアニド化合物及びヒドロシリル化反応触媒 |
ES2689324T3 (es) * | 2016-07-22 | 2018-11-13 | Evonik Degussa Gmbh | Procedimiento para preparar tris[3-(alcoxisilil)propil]isocianuratos |
JP6933835B2 (ja) * | 2017-01-25 | 2021-09-08 | 公立大学法人大阪 | 鉄錯体触媒を用いたカルボニル化合物のヒドロシリル化反応によるアルコキシシランの製造方法 |
JP6786034B2 (ja) | 2017-02-28 | 2020-11-18 | 国立大学法人九州大学 | ヒドロシリル化反応、水素化反応およびヒドロシラン還元反応用触媒 |
JP2019064950A (ja) | 2017-09-29 | 2019-04-25 | 国立大学法人九州大学 | コバルト錯体、その製造方法およびヒドロシリル化反応用触媒 |
US11273432B2 (en) | 2018-05-31 | 2022-03-15 | Arizona Board Of Regents On Behalf Of Arizona State University | Beta-diketiminate manganese catalysts for hydrosilylation, hydroboration, and dehydrogenative pnictogen-silicon and pnictogen-boron bond formation |
CN112387313B (zh) * | 2020-11-17 | 2022-08-16 | 中山大学 | 三齿邻菲罗啉锰催化剂及其在合成有机硅/硼化合物中的应用 |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3159601A (en) | 1962-07-02 | 1964-12-01 | Gen Electric | Platinum-olefin complex catalyzed addition of hydrogen- and alkenyl-substituted siloxanes |
US3220972A (en) | 1962-07-02 | 1965-11-30 | Gen Electric | Organosilicon process using a chloroplatinic acid reaction product as the catalyst |
US3775452A (en) | 1971-04-28 | 1973-11-27 | Gen Electric | Platinum complexes of unsaturated siloxanes and platinum containing organopolysiloxanes |
US5508458A (en) * | 1995-05-26 | 1996-04-16 | Hoechst Celanese Corporation | Chiral catalysts and processes for preparing the same |
DE19730867A1 (de) * | 1997-07-18 | 1999-01-21 | Basf Ag | Verfahren zur Herstellung von mit bidentaten Liganden chelatisierten Monoalkylmetallkomplexen |
CN1250577C (zh) * | 2003-12-16 | 2006-04-12 | 中国科学院长春应用化学研究所 | 树状多核吡啶双亚胺铁烯烃聚合催化剂前体及其制备方法 |
JP4908400B2 (ja) * | 2004-04-20 | 2012-04-04 | ダウ・コーニング・コーポレイション | シリコーンポリエーテルブロック共重合体の水性分散液 |
EP1832579A1 (en) * | 2006-03-10 | 2007-09-12 | Total Petrochemicals Research Feluy | Polymerisation of ethylene and alpha-olefins with imino-quinolinol complexes |
WO2009080237A1 (en) * | 2007-12-21 | 2009-07-02 | Basell Polyolefine Gmbh | Catalyst sytem for olefin polymerization comprising phenantroline-comprising iron complexes |
US8236915B2 (en) * | 2009-07-10 | 2012-08-07 | Momentive Performance Materials Inc. | Hydrosilylation catalysts |
US8415443B2 (en) | 2009-07-10 | 2013-04-09 | Momentive Performance Materials Inc. | Hydrosilylation catalysts |
CN102060852B (zh) * | 2009-11-17 | 2012-07-04 | 中国科学院化学研究所 | 喹啉类配合物及制备方法以及含有所述喹啉类配合物的催化剂及在催化乙烯聚合中的用途 |
CN103339135B (zh) * | 2010-11-24 | 2016-09-14 | 莫门蒂夫性能材料股份有限公司 | 用作氢化硅烷化催化剂的金属络合物的原位活化 |
WO2012071360A1 (en) * | 2010-11-24 | 2012-05-31 | Momentive Performance Materials Inc. | Metal - catalyzed mono - hydrosilylation of polyunsaturated compounds |
-
2011
- 2011-11-22 EP EP11794590.7A patent/EP2643335B1/en not_active Not-in-force
- 2011-11-22 US US13/302,448 patent/US8637626B2/en active Active
- 2011-11-22 KR KR1020137016387A patent/KR20140042766A/ko not_active Application Discontinuation
- 2011-11-22 BR BR112013012742A patent/BR112013012742A2/pt not_active Application Discontinuation
- 2011-11-22 CN CN2011800658735A patent/CN103347889A/zh active Pending
- 2011-11-22 WO PCT/US2011/061751 patent/WO2012071359A1/en active Application Filing
- 2011-11-22 JP JP2013541002A patent/JP2014503507A/ja active Pending
- 2011-11-23 TW TW100142962A patent/TWI450903B/zh not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
JP2014503507A (ja) | 2014-02-13 |
CN103347889A (zh) | 2013-10-09 |
US20120130021A1 (en) | 2012-05-24 |
TW201235355A (en) | 2012-09-01 |
TWI450903B (zh) | 2014-09-01 |
KR20140042766A (ko) | 2014-04-07 |
US8637626B2 (en) | 2014-01-28 |
EP2643335B1 (en) | 2015-03-11 |
WO2012071359A1 (en) | 2012-05-31 |
EP2643335A1 (en) | 2013-10-02 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
B06A | Patent application procedure suspended [chapter 6.1 patent gazette] | ||
B11B | Dismissal acc. art. 36, par 1 of ipl - no reply within 90 days to fullfil the necessary requirements |