BR112014014517A2 - catalisadores de hidrossililação à base de metal não-precioso - Google Patents

catalisadores de hidrossililação à base de metal não-precioso

Info

Publication number
BR112014014517A2
BR112014014517A2 BR112014014517A BR112014014517A BR112014014517A2 BR 112014014517 A2 BR112014014517 A2 BR 112014014517A2 BR 112014014517 A BR112014014517 A BR 112014014517A BR 112014014517 A BR112014014517 A BR 112014014517A BR 112014014517 A2 BR112014014517 A2 BR 112014014517A2
Authority
BR
Brazil
Prior art keywords
hydrosilylation catalysts
precious metal
metal based
based hydrosilylation
catalysts
Prior art date
Application number
BR112014014517A
Other languages
English (en)
Inventor
Carmen H Atienza Crisita
G P Delis Johannes
Boyer Julie
J Weller Keith
Lewis Kenrick
Chirik Paul
A Nye Susan
Original Assignee
Momentive Performance Mat Inc
Univ Princeton
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Momentive Performance Mat Inc, Univ Princeton filed Critical Momentive Performance Mat Inc
Publication of BR112014014517A2 publication Critical patent/BR112014014517A2/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/0244—Pincer-type complexes, i.e. consisting of a tridentate skeleton bound to a metal, e.g. by one to three metal-carbon sigma-bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

resumo “catalisadores de hidrossililação à base de metal não-precioso” a presente invenção refere-se aqui ao uso de complexos de manganês, ferro, cobalto, ou níquel contendo os ligandos de di-imina piridina tridentado como catalisadores de hidrossililação. estes complexos são eficazes para catalisar eficientemente as reações de hidrossililação, bem como oferecer uma melhor seletividade e rendimento em relação aos sistemas de catalisadores existentes.
BR112014014517A 2011-12-14 2012-12-13 catalisadores de hidrossililação à base de metal não-precioso BR112014014517A2 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US13/325,250 US9782763B2 (en) 2011-12-14 2011-12-14 Non-precious metal-based hyrdosilylation catalysts exhibiting improved selectivity
PCT/US2012/069469 WO2013090548A1 (en) 2011-12-14 2012-12-13 Non- precious metal -based hydrosilylation catalysts

Publications (1)

Publication Number Publication Date
BR112014014517A2 true BR112014014517A2 (pt) 2017-06-13

Family

ID=47459175

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112014014517A BR112014014517A2 (pt) 2011-12-14 2012-12-13 catalisadores de hidrossililação à base de metal não-precioso

Country Status (8)

Country Link
US (2) US9782763B2 (pt)
EP (1) EP2790829B1 (pt)
JP (1) JP6211531B2 (pt)
KR (1) KR20140116100A (pt)
CN (1) CN104114278A (pt)
BR (1) BR112014014517A2 (pt)
TW (1) TWI614063B (pt)
WO (1) WO2013090548A1 (pt)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9782763B2 (en) 2011-12-14 2017-10-10 Momentive Performance Materials Inc. Non-precious metal-based hyrdosilylation catalysts exhibiting improved selectivity
US9447125B2 (en) 2012-08-16 2016-09-20 Momentive Performance Materials Inc. Reusable homogeneous cobalt pyridine diimine catalysts for dehydrogenative silylation and tandem dehydrogenative-silylation-hydrogenation
US9371340B2 (en) 2012-08-16 2016-06-21 Momentive Performance Materials Inc. Dehydrogenative silylation, hydrosilylation and crosslinking using cobalt catalysts
WO2014182670A2 (en) * 2013-05-06 2014-11-13 Momentive Performance Materials Inc. Selective 1,2-hydrosilylation of terminally unsaturated 1,3-dienes using iron catalysts
US9371339B2 (en) 2013-05-06 2016-06-21 Momentive Performance Materials Inc. Saturated and unsaturated silahydrocarbons via iron and cobalt pyridine diimine catalyzed olefin silylation
EP2996804B1 (en) 2013-05-15 2020-12-30 Momentive Performance Materials Inc. Activation of metal salts with silylhydrides and their use in hydrosilylation reactions
US10112961B2 (en) 2013-11-19 2018-10-30 The Trustees Of Princeton University Hydroboration and borylation with cobalt catalysts
US9387468B2 (en) 2013-11-19 2016-07-12 Momentive Performance Materials Inc. Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation
EP3071585B1 (en) 2013-11-19 2018-11-07 Momentive Performance Materials Inc. Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation
WO2017072084A1 (en) * 2015-10-26 2017-05-04 Shell Internationale Research Maatschappij B.V. Mechanically strong catalyst and catalyst carrier, its preparation, and its use
ES2689324T3 (es) 2016-07-22 2018-11-13 Evonik Degussa Gmbh Procedimiento para preparar tris[3-(alcoxisilil)propil]isocianuratos
ES2881271T3 (es) 2017-03-08 2021-11-29 Evonik Operations Gmbh Procedimiento para preparar tris[3-(alcoxisilil)propil]isocianuratos
ES2880788T3 (es) 2017-03-08 2021-11-25 Evonik Operations Gmbh Procedimiento para preparar tris[3-(alcoxisilil)propil]isocianuratos
US10377776B2 (en) 2017-03-08 2019-08-13 Evonik Degussa Gmbh Process for preparing tris[3-(alkoxysilyl)propyl]isocyanurates
CN107511176B (zh) * 2017-08-15 2020-02-14 常州大学 一种铁基吡咯烷酮离子液体催化不饱和烷基酯硅氢加成反应的方法
DK3473631T3 (da) 2017-10-19 2020-03-30 Evonik Operations Gmbh Nye epoxy-funktionelle alkoxysilaner, fremgangsmåde til deres fremstilling og deres anvendelse
CN110343128B (zh) * 2018-04-04 2021-02-19 中国科学院化学研究所 一种通过硅氢化反应制备硅烷的方法
DE102018210886A1 (de) 2018-07-03 2020-01-09 Evonik Degussa Gmbh Verfahren zur Herstellung von Alkylalkoxysilanen
ES2944442T3 (es) 2018-09-13 2023-06-21 Momentive Performance Mat Gmbh Polisiloxanos funcionales
BR112021007572A2 (pt) 2018-11-02 2021-07-27 Shell Internationale Research Maatschappij B.V. processo para a produção de etileno por desidrogenação oxidativa de etano
EP3915995A1 (en) 2020-05-29 2021-12-01 Momentive Performance Materials Inc. Process for the stepwise synthesis of silahydrocarbons

Family Cites Families (60)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3220972A (en) 1962-07-02 1965-11-30 Gen Electric Organosilicon process using a chloroplatinic acid reaction product as the catalyst
US3159601A (en) 1962-07-02 1964-12-01 Gen Electric Platinum-olefin complex catalyzed addition of hydrogen- and alkenyl-substituted siloxanes
US3296291A (en) 1962-07-02 1967-01-03 Gen Electric Reaction of silanes with unsaturated olefinic compounds
US3775452A (en) 1971-04-28 1973-11-27 Gen Electric Platinum complexes of unsaturated siloxanes and platinum containing organopolysiloxanes
GB1476314A (en) 1973-06-23 1977-06-10 Dow Corning Ltd Coating process
GB2013207B (en) 1977-11-14 1982-10-27 Spencer J L Hydrosilylation catalysts
US4550152A (en) 1983-10-28 1985-10-29 General Electric Company Nickel complex catalyst for hydrosilation reactions
US4578497A (en) 1984-11-30 1986-03-25 Gulf Research & Development Company Tetraalkylsilane synthetic fluids
US4572791A (en) 1984-12-06 1986-02-25 Gulf Research & Development Company Production of saturated and unsaturated silahydrocarbon mixtures using rhodium catalyst, and to products produced thereby
US4729821A (en) 1986-11-03 1988-03-08 Board Of Regents, The University Of Texas System In situ activation of catalysts by applied electrical potentials
US4788312A (en) 1988-03-16 1988-11-29 Technolube Division Lubricating Specialties Co. Trisilahydrocarbon lubricants
FR2641785B1 (fr) 1989-01-19 1992-07-31 Essilor Int Composition de polymeres transparents pour lentilles de contact de type rigide, permeables a l'oxygene
US5026893A (en) 1990-06-11 1991-06-25 Lubricating Specialties Company Polysilahydrocarbon lubricants
JPH06503592A (ja) 1990-12-13 1994-04-21 ミネソタ・マイニング・アンド・マニュファクチュアリング・カンパニー 照射活性化されたヒドロシレーション反応
JPH05295269A (ja) 1991-11-29 1993-11-09 General Electric Co <Ge> 熱硬化性オルガノポリシロキサン組成物、予備生成済み潜伏性白金触媒およびそれの調製方法
CA2080153A1 (en) 1991-11-29 1993-05-30 Chris A. Sumpter Heat curable organopolysiloxane compositions, preformed latent platinum catalysts, and methods for making
US5880241A (en) 1995-01-24 1999-03-09 E. I. Du Pont De Nemours And Company Olefin polymers
US5691435A (en) 1996-01-25 1997-11-25 Wacker-Chemie Gmbh Crosslinkable compositions
IL129929A0 (en) 1996-12-17 2000-02-29 Du Pont Polymerization of ethylene with specific iron or cobalt complexes novel pyridinebis (imines) and novel complexes of pyridinebis(imines) with iron and cobalt
US6423848B2 (en) 1996-12-17 2002-07-23 E. I. Du Pont De Nemours And Company Tridentate ligand
US6417305B2 (en) 1996-12-17 2002-07-09 E. I. Du Pont De Nemours And Company Oligomerization of ethylene
US6214761B1 (en) 1996-12-17 2001-04-10 E. I. Du Pont De Nemours And Company Iron catalyst for the polymerization of olefins
US6432862B1 (en) 1996-12-17 2002-08-13 E. I. Du Pont De Nemours And Company Cobalt catalysts for the polymerization of olefins
US6103946A (en) 1997-07-15 2000-08-15 E. I. Du Pont De Nemours And Company Manufacture of α-olefins
ID24448A (id) 1997-09-05 2000-07-20 Bp Chemical Ltd Katalis-katalis polimerisasi
WO1999046303A1 (en) 1998-03-12 1999-09-16 Bp Chemicals Limited Polymerisation catalysts
EP1062255B1 (en) 1998-03-12 2003-07-02 BP Chemicals Limited Homopolymer of ethylene
TWI238833B (en) * 1998-03-12 2005-09-01 Bp Chem Int Ltd Catalysts and method for polymerization of olefins
ID27209A (id) 1998-03-12 2001-03-08 Bp Chem Int Ltd Katalis-katalis polimerisasi
ID26574A (id) 1998-03-12 2001-01-18 Bp Chem Int Ltd Katalis-katalis polimerisasi
US7906451B2 (en) 1998-03-30 2011-03-15 E.I. Du Pont De Nemours And Company Mixed polymerization catalyst component for polymerizing olefins
US6297338B1 (en) 1998-03-30 2001-10-02 E. I. Du Pont De Nemours And Company Polymerization of olefins
GB9819847D0 (en) 1998-09-12 1998-11-04 Bp Chem Int Ltd Novel compounds
DE19856115A1 (de) 1998-12-04 2000-06-21 Wacker Chemie Gmbh Alkenylgruppen aufweisende Siloxancopolymere
US6620895B1 (en) 1999-03-22 2003-09-16 E. I. Du Pont De Nemours And Company Processing polyethylenes
US6281303B1 (en) 1999-07-27 2001-08-28 Eastman Chemical Company Olefin oligomerization and polymerization catalysts
US6458905B1 (en) 1999-08-16 2002-10-01 Phillips Petroleum Company Complexes of pyridldiimines with vanadium and other transition metals, and their use as olefin oligomerization and polymerization catalysts
US6278011B1 (en) 1999-08-30 2001-08-21 The University Of Dayton Polysilahydrocarbons as lubricants for aerospace application
US7161005B2 (en) 2001-04-30 2007-01-09 Ciba Specialty Chemicals Corporation Use of metal complex compounds as oxidation catalysts
WO2003042131A1 (en) 2001-11-15 2003-05-22 Stichting Voor De Technische Wetenschappen Hydrogenation catalyst and catalysed hydrogenation process
AU2003259148A1 (en) 2002-07-17 2004-02-02 Exxonmobil Chemical Patents Inc. Late transition metal catalysts for olefin polymerization and oligomerization
ES2260678T3 (es) 2002-09-25 2006-11-01 Shell Internationale Research Maatschappij B.V. Sistema cataliticos para la oligomerizacion de etileno a alfa-olefinas lineales.
DE10258126B3 (de) * 2002-12-12 2004-01-29 Wacker-Chemie Gmbh Alkinolgruppen aufweisende Organosiliciumverbindungen sowie diese enthaltend vernetzbare Massen und daraus herstellbare Formkörper
US7442819B2 (en) 2004-07-09 2008-10-28 E. I. Du Pont De Nemours And Company Catalysts for olefin polymerization or oligomerization
US8062552B2 (en) 2005-05-19 2011-11-22 Brookhaven Science Associates, Llc Electrocatalyst for oxygen reduction with reduced platinum oxidation and dissolution rates
CN100378111C (zh) 2005-07-01 2008-04-02 中国科学院上海有机化学研究所 含碳氧醚键有机硅化合物、合成方法及其应用
US7268096B2 (en) 2005-07-21 2007-09-11 Chevron Phillips Chemical Company Lp Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization
EP1948738B1 (en) 2005-10-26 2018-02-28 Basf Se Coloured particles for electrophoretic displays
DE102005057460A1 (de) 2005-12-01 2007-06-06 Wacker Chemie Ag Zu hochfesten Elastomeren vernetzbare ionisch und/oder organometallisch funktionalisierte Siliconpolymere
US7429672B2 (en) 2006-06-09 2008-09-30 Momentive Performance Materials Inc. Process for the direct synthesis of trialkoxysilane
US7696269B2 (en) 2006-12-28 2010-04-13 Momentive Performance Materials Inc. Silated core polysulfides, their preparation and use in filled elastomer compositions
US8415443B2 (en) * 2009-07-10 2013-04-09 Momentive Performance Materials Inc. Hydrosilylation catalysts
US8236915B2 (en) * 2009-07-10 2012-08-07 Momentive Performance Materials Inc. Hydrosilylation catalysts
EP2407187A3 (de) 2010-07-15 2012-06-20 ECP Entwicklungsgesellschaft mbH Blutpumpe für die invasive Anwendung innerhalb eines Körpers eines Patienten
US8765987B2 (en) 2010-11-24 2014-07-01 Cornell University In-situ activation of metal complexes containing terdentate nitrogen ligands used as hydrosilylation catalysts
EP2643330B1 (en) 2010-11-24 2017-01-04 Momentive Performance Materials Inc. Metal-catalyzed mono-hydrosilylation of polyunsaturated compounds
KR20140042766A (ko) 2010-11-24 2014-04-07 모멘티브 퍼포먼스 머티리얼즈 인크. 하이드로실릴화 촉매
CN104024264A (zh) 2011-09-20 2014-09-03 道康宁公司 含金属的硅氢加成催化剂以及含该催化剂的组合物
CN103946228A (zh) 2011-09-20 2014-07-23 道康宁公司 含钴硅氢加成催化剂及含有该催化剂的组合物
US9782763B2 (en) 2011-12-14 2017-10-10 Momentive Performance Materials Inc. Non-precious metal-based hyrdosilylation catalysts exhibiting improved selectivity

Also Published As

Publication number Publication date
US9782763B2 (en) 2017-10-10
TW201330930A (zh) 2013-08-01
KR20140116100A (ko) 2014-10-01
EP2790829A1 (en) 2014-10-22
CN104114278A (zh) 2014-10-22
US20130158281A1 (en) 2013-06-20
WO2013090548A1 (en) 2013-06-20
TWI614063B (zh) 2018-02-11
US11052383B2 (en) 2021-07-06
JP2015501842A (ja) 2015-01-19
US20180015449A1 (en) 2018-01-18
EP2790829B1 (en) 2022-12-07
JP6211531B2 (ja) 2017-10-11

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