BR0007150A - Catalisadores de metal de transição e produção de alfa-olefinas e polìmeros de compostos de vinila - Google Patents

Catalisadores de metal de transição e produção de alfa-olefinas e polìmeros de compostos de vinila

Info

Publication number
BR0007150A
BR0007150A BR0007150-1A BR0007150A BR0007150A BR 0007150 A BR0007150 A BR 0007150A BR 0007150 A BR0007150 A BR 0007150A BR 0007150 A BR0007150 A BR 0007150A
Authority
BR
Brazil
Prior art keywords
transition metal
olefins
group
periodic table
compound
Prior art date
Application number
BR0007150-1A
Other languages
English (en)
Inventor
Haruhito Sato
Masahiko Kuramoto
Masami Watanabe
Original Assignee
Idemitsu Petrochemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Idemitsu Petrochemical Co filed Critical Idemitsu Petrochemical Co
Publication of BR0007150A publication Critical patent/BR0007150A/pt

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/70—Iron group metals, platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06—Hydrocarbons
    • C08F12/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/16—Clays or other mineral silicates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Patente de Invenção: <B>"CATALISADORES DE METAL DE TRANSIçãO E PRODUçãO DE ALFA-OLEFINAS E POLìMEROS DE COMPOSTOS DE VINILA"<D>. Trata-se de um catalisador que compreende (a) um complexo de metal de transição do Grupo 8 a 10 da Tabela Periódica, (b) uma argila, mineral de argila ou composto disposto em camadas passível de troca iónica, (c) um composto de amina ou seu aduto com ácido de Bronsted; um catalisador que compreende (a) um complexo de quelato de metal de transição do Grupo 4 a 6 da Tabela Periódica ou um complexo de metal de transição do Grupo 8 a 10 da Tabela Periódica, (b) uma argila, mineral de argila ou composto disposto em camadas passível de troca iónica, e (c) um sal de amónio quaternário; e um catalisador que compreende (a) um complexo de metal de transição do Grupo 4 a 6 da Tabela Periódica ou um complexo de metal de transição do Grupo 8 a 10 da Tabela Periódica e um componente de co-catalisador produzido ao se contatar (b) argila, mineral de argila ou composto disposto em camadas passível de troca iónica, (c) um composto de amina, seu aduto com ácido de Bronsted ou um sal de amónio quaternário, e (d) um composto de organossilano. Uma vez que esses catalisadores apresentam alta atividade de oligomerização de etileno, as <244>-olefinas podem ser eficientemente produzidas com baixos custos de etileno. Ao usar os catalisadores, as <244>-olefinas lineares terminadas em vinila (oligómeros) com um peso molecular de 10000 ou menos ou poliolefinas com peso molecular excedente a 10000 podem ser também produzidas eficientemente com baixos custos.
BR0007150-1A 1999-09-16 2000-09-14 Catalisadores de metal de transição e produção de alfa-olefinas e polìmeros de compostos de vinila BR0007150A (pt)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP26256599 1999-09-16
JP32292899 1999-11-12
JP2000180875 2000-06-16
PCT/JP2000/006317 WO2001019513A1 (en) 1999-09-16 2000-09-14 TRANSITION METAL CATALYSTS AND PROCESSES FOR PRODUCING α-OLEFIN AND VINYL COMPOUND POLYMER

Publications (1)

Publication Number Publication Date
BR0007150A true BR0007150A (pt) 2001-08-14

Family

ID=27335140

Family Applications (1)

Application Number Title Priority Date Filing Date
BR0007150-1A BR0007150A (pt) 1999-09-16 2000-09-14 Catalisadores de metal de transição e produção de alfa-olefinas e polìmeros de compostos de vinila

Country Status (8)

Country Link
EP (1) EP1136122A4 (pt)
JP (2) JP4819270B2 (pt)
KR (1) KR20010089455A (pt)
CN (1) CN1321111A (pt)
AU (1) AU7314100A (pt)
BR (1) BR0007150A (pt)
CA (1) CA2345621A1 (pt)
WO (1) WO2001019513A1 (pt)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9923072D0 (en) * 1999-09-29 1999-12-01 Bp Chem Int Ltd Polymerisation catalyst
KR20020084170A (ko) * 2000-03-06 2002-11-04 이데미쓰세끼유가가꾸가부시끼가이샤 비닐 화합물 중합용 촉매 및 비닐 중합체의 제조 방법
KR100844062B1 (ko) 2001-02-21 2008-07-07 미쓰이 가가쿠 가부시키가이샤 올레핀 중합용 촉매 및 이 촉매를 사용하는 올레핀중합체의 제조방법
US6767975B1 (en) * 2003-07-14 2004-07-27 Equistar Chemicals, Lp Olefin polymerization with pyridine moiety-containing singe-site catalysts
JP2005139111A (ja) * 2003-11-06 2005-06-02 Sumitomo Chemical Co Ltd オレフィンのオリゴマー化触媒及びオレフィンのオリゴマー化方法
US6903169B1 (en) 2003-12-30 2005-06-07 Equistar Chemicals, Lp LTMC polymerization of unsaturated monomers
JP5318366B2 (ja) * 2007-04-27 2013-10-16 日本ポリプロ株式会社 オレフィン重合用触媒及びその触媒の製造方法
DE102007022052A1 (de) * 2007-05-08 2008-11-13 Basell Polyolefine Gmbh Katalysatorsystem zur Olefinpolymerisation, Verfahren zu ihrer Herstellung, sowie ein Verfahren zur Polymerisation von a-Olefinen unter Verwendung des Katalysatorsystems
JP5475314B2 (ja) * 2009-04-22 2014-04-16 出光興産株式会社 錯体触媒及びそれを用いた線状α−オレフィンの製造方法
JP5489688B2 (ja) * 2009-12-14 2014-05-14 日本ポリプロ株式会社 オレフィン重合用触媒の製造法
ES2409707T3 (es) 2011-02-16 2013-06-27 Linde Ag Procedimiento de preparación de una composición catalítica para oligomerización de etileno y unidad de preformación de composición de catalizador respectiva
KR20170129693A (ko) * 2015-03-17 2017-11-27 제이엑스티지 에네루기 가부시키가이샤 올리고머의 제조방법 및 촉매
JP6848195B2 (ja) * 2016-03-29 2021-03-24 日本ポリエチレン株式会社 特定の触媒と特定の工程によるエチレン共重合体の製造方法
KR102448156B1 (ko) * 2016-08-30 2022-09-29 에네오스 가부시키가이샤 올리고머의 제조 방법 및 촉매
RU2749592C2 (ru) 2016-12-30 2021-06-15 Сабик Глобал Текнолоджис Б.В. Способ получения раствора катализатора для селективного производства 1-гексена
ES2962319T3 (es) 2016-12-30 2024-03-18 Sabic Global Technologies Bv Método de preparación de un catalizador homogéneo para la producción selectiva de 1-hexeno
WO2023042898A1 (ja) * 2021-09-17 2023-03-23 花王株式会社 内部オレフィンの製造方法
CN116063591B (zh) * 2021-10-29 2024-06-04 中国石油化工股份有限公司 一种烯烃聚合用金属有机复合物催化剂及其制备方法和应用
CN116328752B (zh) * 2022-12-13 2024-08-16 中国科学院大连化学物理研究所 一种催化剂、制备方法及制备碳酸丙烯酯的应用
CN116393168A (zh) * 2023-04-06 2023-07-07 厦门中科易工化学科技有限公司 一种用于制备氯甲烷的催化剂及其用途和氯甲烷的制备方法

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59216631A (ja) * 1983-05-25 1984-12-06 Agency Of Ind Science & Technol 鉄−スメクタイト複合体及びそれを主成分とする触媒
US5286367A (en) * 1991-09-03 1994-02-15 Uop Hydrocarbon conversion process using a gallium/germanium dioctahedral smectite clay
JPH09278821A (ja) * 1996-04-08 1997-10-28 Mitsui Petrochem Ind Ltd オレフィン重合用触媒およびオレフィンの重合方法
US6110858A (en) * 1996-12-18 2000-08-29 Tosoh Corporation Olefin polymerization catalysts and process for producing olefin polymers
JP3460553B2 (ja) * 1996-12-18 2003-10-27 東ソー株式会社 オレフィン重合用触媒およびオレフィン重合体の製造方法
PL198619B1 (pl) * 1997-09-05 2008-07-31 Bp Chem Int Ltd Sposób (ko)polimeryzacji etylenu z jedną lub większą liczbą 1-olefin w obecności gazowego wodoru oraz katalizatory (ko)polimeryzacji etylenu z jedną lub większą liczbą 1-olefin w obecności gazowego wodoru
TW381097B (en) * 1997-09-18 2000-02-01 Idemitsu Petrochemical Co Catalyst for use in alkene monomer polymerization, manufacturing method for alkene polymers, and manufacturing method for styrine polymers
JPH11140111A (ja) * 1997-11-06 1999-05-25 Mitsubishi Chemical Corp オレフィン重合用触媒及びこれを用いたオレフィン重合体の製造方法
KR20010012693A (ko) * 1998-03-20 2001-02-26 가즈토 도미나가 올레핀 중합체 제조 촉매 및 올레핀 중합체의 제조 방법
JPH11335408A (ja) * 1998-05-25 1999-12-07 Tosoh Corp オレフィン重合用触媒およびオレフィン重合体の製造方法
JP4186285B2 (ja) * 1998-12-07 2008-11-26 東ソー株式会社 オレフィン重合用触媒およびオレフィン重合体の製造方法
WO2000043123A1 (fr) * 1999-01-21 2000-07-27 Idemitsu Petrochemical Co., Ltd. CATALYSEURS DESTINES A LA PRODUCTION DE α-OLEFINE ET PROCEDES DE FABRICATION DE α-OLEFINE
JP4409694B2 (ja) * 1999-01-21 2010-02-03 出光興産株式会社 α−オレフィン製造用触媒及びα−オレフィンの製造方法
JP4140131B2 (ja) * 1999-06-11 2008-08-27 東ソー株式会社 オレフィン重合体製造用触媒およびオレフィン重合体の製造方法

Also Published As

Publication number Publication date
JP2011006711A (ja) 2011-01-13
JP4819270B2 (ja) 2011-11-24
AU7314100A (en) 2001-04-17
KR20010089455A (ko) 2001-10-06
CN1321111A (zh) 2001-11-07
WO2001019513A1 (en) 2001-03-22
EP1136122A1 (en) 2001-09-26
EP1136122A4 (en) 2002-08-07
CA2345621A1 (en) 2001-03-22

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