BR0305627A - Sistema catalisador para a polimerização de olefinas - Google Patents

Sistema catalisador para a polimerização de olefinas

Info

Publication number
BR0305627A
BR0305627A BR0305627-9A BR0305627A BR0305627A BR 0305627 A BR0305627 A BR 0305627A BR 0305627 A BR0305627 A BR 0305627A BR 0305627 A BR0305627 A BR 0305627A
Authority
BR
Brazil
Prior art keywords
catalyst system
olefin polymerization
group
halogenated
halogen atoms
Prior art date
Application number
BR0305627-9A
Other languages
English (en)
Inventor
Luigi Resconi
Francesca Focante
Isabella Camurati
Simona Guidotti
Original Assignee
Basell Polyolefine Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Polyolefine Gmbh filed Critical Basell Polyolefine Gmbh
Publication of BR0305627A publication Critical patent/BR0305627A/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00Compounds containing elements of Groups 3 or 13 of the Periodic System
    • C07F5/02Boron compounds
    • C07F5/027Organoboranes and organoborohydrides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged

Abstract

"SISTEMA CATALISADOR PARA A POLIMERIZAçãO DE OLEFINAS". Um composto organometálico que pode ser obtido pela colocação em contato de: um composto apresentando a seguinte fórmula (I) na qual: R^ a^ é um radical hidrocarbono; R^ b^, R^ c^ R^ d^ São átomos de hidrogênio, átomos de halogênio ou radicais hidrocarbónicos; com um ácido de Lewis de fórmula (II) MtR^ 1^~ 3~ (II) no qual Mt é um metal pertencente ao grupo 13 da Tabela Periódica dos Elementos; R^ 1~ é selecionado do grupo que consiste de átomos de halogênio, grupos aril C~ 6~-C~ 20~ halogenados e alquilaril C~ 7~-C~ 20~ halogenados.
BR0305627-9A 2002-07-09 2003-07-09 Sistema catalisador para a polimerização de olefinas BR0305627A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US39461402P 2002-07-09 2002-07-09
PCT/EP2003/007485 WO2004005360A2 (en) 2002-07-09 2003-07-09 Catalyst system for the polymerization of olefins

Publications (1)

Publication Number Publication Date
BR0305627A true BR0305627A (pt) 2004-09-08

Family

ID=30115746

Family Applications (1)

Application Number Title Priority Date Filing Date
BR0305627-9A BR0305627A (pt) 2002-07-09 2003-07-09 Sistema catalisador para a polimerização de olefinas

Country Status (7)

Country Link
US (1) US7314903B2 (pt)
EP (1) EP1611167A2 (pt)
JP (1) JP2006508903A (pt)
CN (1) CN100532400C (pt)
AU (1) AU2003257448A1 (pt)
BR (1) BR0305627A (pt)
WO (1) WO2004005360A2 (pt)

Families Citing this family (50)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1392705B1 (en) * 2001-05-21 2005-01-05 Basell Polyolefine GmbH Catalyst system for the polymerization of olefins
JP2005538198A (ja) * 2002-09-06 2005-12-15 バセル ポリオレフィン ジーエムビーエイチ エチレンの共重合方法
WO2004033510A2 (en) * 2002-10-10 2004-04-22 Basell Polyolefine Gmbh Process for the copolymerization of ethylene
US7741417B2 (en) 2004-01-07 2010-06-22 Exxonmobil Chemical Patents Inc. Preparation of polymerization catalyst activators utilizing indole-modified silica supports
WO2005105865A1 (en) 2004-05-04 2005-11-10 Basell Polyolefine Gmbh Process for the preparation of atactic 1-butene polymers
WO2006031067A1 (en) 2004-09-16 2006-03-23 Lg Chem, Ltd. Catalyst system for polymerizing cyclic olefin having polar functional group, polymerizing method using the catalyst system, olefin polymer produced by the method and optical anisotropic film comprising the olefin polymer
CN101039967B (zh) * 2004-10-18 2010-06-09 巴塞尔聚烯烃意大利有限责任公司 低全同立构规整度丁烯-1均聚物或共聚物
CN101044172B (zh) 2004-10-21 2010-09-29 巴塞尔聚烯烃股份有限公司 1-丁烯聚合物及其制备方法
EP1655314A1 (en) * 2004-11-09 2006-05-10 Basell Polyolefine GmbH Process for the preparation of 1-butene/propylene copolymers
CN101061142B (zh) 2004-11-22 2012-04-18 巴塞尔聚烯烃股份有限公司 基于丙烯的三元共聚物
JP2008523231A (ja) * 2004-12-13 2008-07-03 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ ポリオレフィン繊維
DE602006020691D1 (de) 2005-02-03 2011-04-28 Basell Polyolefine Gmbh Verfahren zur herstellung von warmgeformten artikeln
WO2006097497A1 (en) * 2005-03-18 2006-09-21 Basell Polyolefine Gmbh Metallocene compounds
WO2006097500A1 (en) * 2005-03-18 2006-09-21 Basell Polyolefine Gmbh Metallocene compounds
US7799880B2 (en) * 2005-03-23 2010-09-21 Basell Polyolefine Gmbh Process for the polymerization of olefins
AU2006226366A1 (en) * 2005-03-23 2006-09-28 Basell Polyolefine Gmbh Process for the polymerizatio of olefins
US7964679B2 (en) * 2005-05-03 2011-06-21 Basell Poliolefine Italia S.R.L. Process for the polymerization of alpha olefins
US7985799B2 (en) 2005-05-11 2011-07-26 Basell Poliolefine Italia S.R.L. Polymerization process for preparing polyolefin blends
US8051611B2 (en) * 2005-06-24 2011-11-08 Dryvit Systems, Inc. Exterior insulation and finish system and method and tool for installing same
DE602006014709D1 (de) * 2005-10-21 2010-07-15 Basell Polyolefine Gmbh Propylenpolymere
DE602006014708D1 (de) * 2005-10-21 2010-07-15 Basell Polyolefine Gmbh Statistische polypropylencopolymere mit hohen schmelzflussraten für spritzguss- und schmelzblasanwendungen
US8394907B2 (en) * 2005-10-21 2013-03-12 Basell Polyolefine Gmbh Polypropylene for injection molding
EP1957545A2 (en) * 2005-12-06 2008-08-20 Basell Poliolefine Italia S.r.l. Catalyst components for the polymerization of olefins
CA2766253A1 (en) * 2006-02-02 2007-08-09 Basell Polyolefine Gmbh Propylene homopolymer melt blown resins
US8343602B2 (en) 2006-02-23 2013-01-01 Basell Poliolefine Italia, s.r.l. Propylene polymers for injection molding applications
EP2010580B1 (en) 2006-04-21 2016-07-13 Basell Polyolefine GmbH Process for the preparation of ethylene copolymers
WO2007122097A1 (en) 2006-04-21 2007-11-01 Basell Polyolefine Gmbh Process for the preparation of ethylene propylene copolymers
US8022005B2 (en) * 2007-11-08 2011-09-20 Exxonmobil Chemical Patents Inc. Halogen substituted heterocyclic heteroatom containing ligands-alumoxane activation of metallocenes
US7799879B2 (en) 2008-08-01 2010-09-21 Exxonmobil Chemical Patents Inc. Catalyst system and process for olefin polymerization
SG195587A1 (en) 2008-08-01 2013-12-30 Exxonmobil Chem Patents Inc Catalyst system and process for olefin polymerization
US8580902B2 (en) 2008-08-01 2013-11-12 Exxonmobil Chemical Patents Inc. Catalyst system, process for olefin polymerization, and polymer compositions produced therefrom
CN103857706B (zh) 2011-09-30 2016-09-28 埃克森美孚化学专利公司 金属茂催化剂的动力学调制
EP3022236B1 (en) 2013-07-17 2017-11-15 ExxonMobil Chemical Patents Inc. Process using substituted metallocene catalysts and products therefrom
CN110845546A (zh) 2013-07-17 2020-02-28 埃克森美孚化学专利公司 取代的茂金属催化剂
WO2015009472A1 (en) 2013-07-17 2015-01-22 Exxonmobil Chemcal Patents Inc. Metallocenes and catalyst compositions derived therefrom
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
CN105377904B (zh) 2013-07-17 2018-07-10 埃克森美孚化学专利公司 金属茂和由其衍生的催化剂组合物
CN105358586A (zh) 2013-07-17 2016-02-24 埃克森美孚化学专利公司 环丙基取代的茂金属催化剂
US9266910B2 (en) 2013-10-29 2016-02-23 Exxonmobil Chemical Patents Inc. Asymmetric polypropylene catalysts
US9809664B2 (en) 2015-06-05 2017-11-07 Exxonmobil Chemical Patents Inc. Bimodal propylene polymers and sequential polymerization
US10723821B2 (en) 2015-06-05 2020-07-28 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems for polymerization
US10280235B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers
US10329360B2 (en) 2015-06-05 2019-06-25 Exxonmobil Chemical Patents Inc. Catalyst system comprising supported alumoxane and unsupported alumoxane particles
CN107690441A (zh) 2015-06-05 2018-02-13 埃克森美孚化学专利公司 聚合物在气相或淤浆相中的单反应器制备
WO2016196339A2 (en) 2015-06-05 2016-12-08 Exxonmobil Chemical Patents Inc. Production of heterophasic polymers in gas or slurry phase
US10280233B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst systems and methods of making and using the same
US10294316B2 (en) 2015-06-05 2019-05-21 Exxonmobil Chemical Patents Inc. Silica supports with high aluminoxane loading capability
US11059918B2 (en) 2016-05-27 2021-07-13 Exxonmobil Chemical Patents Inc. Metallocene catalyst compositions and polymerization process therewith
US11472828B2 (en) 2019-10-11 2022-10-18 Exxonmobil Chemical Patents Inc. Indacene based metallocene catalysts useful in the production of propylene polymers
WO2023150480A1 (en) 2022-02-07 2023-08-10 Exxonmobil Chemical Patents Inc. C1 symmetric 5-ome-6-alkyl substituted metallocenes

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4329756Y1 (pt) 1965-01-01 1968-12-05
JPS4413148Y1 (pt) 1966-05-14 1969-05-31
JPS446828Y1 (pt) 1966-07-09 1969-03-13
US5055438A (en) 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
JP2538595B2 (ja) * 1987-05-13 1996-09-25 三井石油化学工業株式会社 オレフイン重合用固体触媒
CN1005716B (zh) * 1987-11-20 1989-11-08 中国石油化工总公司 烯烃聚合的载体催化剂体系的制法
WO1991002012A1 (en) 1989-08-03 1991-02-21 Exxon Chemical Patents Inc. Very high molecular weight polyethylene
NZ235032A (en) 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
KR100418533B1 (ko) 1995-01-24 2004-06-11 이.아이,듀우판드네모아앤드캄파니 알파-올레핀및올레핀중합체및그의제조방법
JPH11503063A (ja) 1995-03-08 1999-03-23 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 触媒組成物における架橋ビスアミド第4族金属化合物
US5714556A (en) 1995-06-30 1998-02-03 E. I. Dupont De Nemours And Company Olefin polymerization process
WO1998040374A2 (en) 1997-03-10 1998-09-17 Eastman Chemical Company Olefin polymerization catalysts containing group 8-10 transition metals, bidentate ligands, processes employing such catalysts and polymers obtained therefrom
US6559252B1 (en) 1997-10-29 2003-05-06 Basell Technology Company Bv Catalysts and processes for the polymerization of olefins
US6211312B1 (en) 1998-06-12 2001-04-03 Univation Technologies Olefin polymerization process using activated lewis acid-base complexes
US6147173A (en) * 1998-11-13 2000-11-14 Univation Technologies, Llc Nitrogen-containing group 13 anionic complexes for olefin polymerization
JP2003524013A (ja) * 2000-02-24 2003-08-12 バセル テクノロジー カンパニー ビー.ブイ. オレフィン重合用助触媒として有用な有機金属化合物
US20040072975A1 (en) * 2000-03-17 2004-04-15 Jorg Schottek Salt-like chemical compound, its preparation and its use in catalyst systems for preparing polyolefins

Also Published As

Publication number Publication date
US7314903B2 (en) 2008-01-01
CN100532400C (zh) 2009-08-26
AU2003257448A8 (en) 2004-01-23
CN1832970A (zh) 2006-09-13
US20060094840A1 (en) 2006-05-04
WO2004005360A3 (en) 2005-11-10
JP2006508903A (ja) 2006-03-16
AU2003257448A1 (en) 2004-01-23
EP1611167A2 (en) 2006-01-04
WO2004005360A2 (en) 2004-01-15

Similar Documents

Publication Publication Date Title
BR0305627A (pt) Sistema catalisador para a polimerização de olefinas
BR0105430A (pt) Compostos organometálicos cocatalisadores, sistema catalìtico e processo para a polimerização de olefinas
BR0014616A (pt) Sistema catalìtico e processo para a polimerização de olefinas
BRPI0606424A2 (pt) componente catalisador de titánio sólido, catalisador para polimeração de olefina e processo para produzir um polìmero de olefina
BR9404707A (pt) Compostos de metaloceno,sistema de catalisador,processos para a preparação de tais compostos e para a preparação de um polímero de olefina,artigo moldado e aplicação dos ditos compostos
BR0006002A (pt) Componentes catalìticos catalisadores e processo a polimerização de olefinas.
BR112012033011A2 (pt) sistema catalisador para a polimerização de olefinas
BR0305247A (pt) Processo de preparação de copolìmeros de etileno
MA29702B1 (fr) Procede de preparation de base bitume.
BRPI0413961A (pt) processo multi-etapas para preparar copolìmeros heterofásicos de propileno
ATE355308T1 (de) Lewis-säure cokatalysatoren auf aluminium-basis für die olefinpolymerisation
BR9814410A (pt) Sistema catalisador suportado, uso do mesmo, e, processos para preparar um polìmero de olefina e, um sistema catalisador suportado.
BR0005488A (pt) Processo para a preparação de carbonato de vinileno, e o uso do mesmo
BR9807851A (pt) Copolìmeros de olefinas a partir de compostos de catalisadores do grupo 4 e bis(arilamido) ligados em ponte
BR9915468A (pt) Componentes catalìticos pré polimerizados para polimerização de olefinas, processo, polìmeros olefinos obtidos e copolìmeros propilenos obtidos
BR9806141A (pt) Componente catalisador sólido e catalisador para a polimerização de olefinas ch2=chr.
BR0206037A (pt) Componentes e catalisadores para a polimerização de olefinas
EA201001484A1 (ru) Каталитическая система и способ получения полиэтилена в ее присутствии
BRPI0709454A8 (pt) complexo de haleto de magnésio, processo para preparar o complexo de olefínica, catalisador para a polimerização de uma olefina e processo para polimerizar olefinas
BR9804309A (pt) Tensoativos
BR9915769A (pt) Substituintes do grupo 13 que contêm haloarilaem catalisadores de poliolefina de metalocenoligados por ponte
SG91850A1 (en) Olefin polymerization catalyst and process for olefin polymerization
BRPI0417857A (pt) processo para a produção de um produto alimentìcio congelado
BRPI0418130A (pt) sistema catalisador para a polimerização de olefinas
DE60224671D1 (de) Verzweigte polymere auf alpha-olefin basis

Legal Events

Date Code Title Description
B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]

Free format text: REFERENTE A 8A ANUIDADE

B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 2116 DE 26/07/2011.